CN108707841A - Allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing and its technique - Google Patents

Allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing and its technique Download PDF

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Publication number
CN108707841A
CN108707841A CN201810592659.9A CN201810592659A CN108707841A CN 108707841 A CN108707841 A CN 108707841A CN 201810592659 A CN201810592659 A CN 201810592659A CN 108707841 A CN108707841 A CN 108707841A
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hot
zinc
alloy
corrosion
iron
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杨长江
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Guangzhou Xianzhi Technology Co Ltd
Guangzhou Yuzhi Technology Co Ltd
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Guangzhou Xianzhi Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus

Abstract

The invention discloses allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing and its processing technologys.According to weight percent, the ingredient of the alloy is:Li:1.0-1.2wt.%,Mo:0.2-0.3wt.%,Ca:0.1-0.2wt.%,Cr:8.0-9.5wt.%,Ni:6.2-7.5wt.%,Si:4.0-8.0wt.%,Co:1.5-1.8wt.%, B:0.2-0.5wt.%, surplus are iron.The exploitation and industrialization of the material, too short for existing iron pan service life in solution hot dipping of zinc-aluminum alloy production, the inconvenient present situation that changes the outfit provides a kind of solution of materialogy.For solving the Industry in China, the product competitiveness for improving China's metallurgical industry is of great significance for the implementation and industrialization of the material.

Description

Allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing and its technique
Technical field
The present invention relates to technical field of alloy, specifically, being related to a kind of kirsite.
Background technology
Ocean about covers 71% earth surface, and marine industries have become the mainstay of current world economy development. Salinity in seawater is high, oxygen-enriched, and there is a large amount of marine microorganisms and macro biology, in addition sea beat and sunlight, Marine corrosion environment is more harsh.Marine environment have become influence facility military service safety, the service life, reliability it is most important Factor causes the great attention of countries in the world government and industrial quarters.
After steel are zinc-plated, corrosion resistance increases substantially, and can save material and resource, plays more good economic effect Benefit and environmental benefit.Steel make coating by local failure in use, and the steel matrix exposed will soon be corroded Fall.But the distinctive sacrificing protection performance of galvanized steel can make corrosion rate become very slow.Main cause is that zinc exists with the iron in steel wire Primary battery is constituted in moist environment, since the standard electrode potential of zinc only has -1.05V, is less than-the 0.036V of iron, thus Zinc is aoxidized as anode, and iron is protected as cathode.The later product of zine corrosion is very fine and close, and reaction speed is very slow, So that overall corrosion resistance increases substantially.
Hot-dip is by the method to obtain coating in steel piece immersion molten metal, and the metal as coating is low Melting point metals.Wherein galvanizing is most widely used.Steel performance after zinc-plated is excellent, the intensity and plasticity of existing base steel, again There are the strong anti-corrosive properties of zinc coating.Because galvanized layer thickness is big, there are pure zinc layer and fe-zn alloy layer, so corrosion resistance and good.With Other metal phase ratios, the price of zinc is relatively low, and production cost is low, and technique is suitable for automating, thus productivity is especially high.Separately Outside, coating belongs to that anodic protection, coating is secured, appearance is beautiful, these advantages make the production capacity of whole world galvanizing be plating Seven times or so of zinc.
As the requirement to hot dip zinc product inherent quality, presentation quality, use quality is continuously improved, traditional hot-dip Zinc cannot fully meet the environmental corrosion needs of existing getting worse.Presently, the hot dipping of anti-corrosion ability is had more Alloy plating system is allumen.In at the international level, develops new zinc-aluminum based alloy and pass through the hot spot for becoming and studying both at home and abroad.It is beautiful State develops the coating material of Zn-Si in the 50-60 ages, and it is rare earth coated that Belgium in the eighties develops entitled Galfan zinc-aluminiums Material, nippon iron company developed the Zn-A1-Mg-Si high corrosion-resistant coating that name is Supekdima in 2000 Steel plate, product corrosion resistance are 5-8 times of Galfan coated plates, and notch corrosion resistance is better than Galvalume coating, alternative stainless steel Plate and aluminium sheet.
The iron pan in galvanizing by dipping field mainly uses outside mode of heating.Zinc pot be welded with low carbon steel plate or cylinder iron cast and At heat source is placed on zinc pot bottom or both sides and heat is transmitted to zinc liquid by the heat transfer of wall.Casting iron pan is to use gray cast iron Casting melts zinc amount generally at 2 tons hereinafter, being mainly used for the miniature parts galvanizing such as steel part, bolt.The pot material of steel plate welding Mostly low carbon low silicon steel plate is used to manufacture.Galvanizing by dipping iron pan is at low cost, manufacturing process is simple, quick heating, easy to maintenance, obtains Relatively broad application.But when the iron pan of these conventional hot-dip zinc is used for hot dipping of zinc-aluminum alloy, iron pan Aluminium alloy seriously corroded, service life is extremely short, and improper zinc consumption is big.
There is also a certain distance compared with world standard for the development of China's thermal dip plating of steel zinc.Existing hot dip zinc-aluminium production Line majority there are backward in technique, product yield is low, poor product quality, production cost are high, energy charge is big, environmental protection measure is ineffective, The shortcomings of often resulting in Heavy environmental pollution, such production line are difficult to meet the needs of Chinese national economy rapid development.Seek preferably Hot-dip aluminum zinc technique is one of the critical issue in application study and industrialization.Wherein, hot-dip aluminum zinc crucible is existing Overcoming for quagmire can make hot dipping of zinc-aluminum alloy expand industry size and improve productivity effect.In the near future, such Novel hot-dip plating zinc-aluminium will be widely used with iron pan in more hot dipping of zinc-aluminum alloy.
Invention content
The purpose of the present invention is to overcome the deficiency in the prior art, and providing one kind can make under 420-480 degree atmospheric conditions Allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing.
To achieve the goals above, the present invention adopts the following technical scheme that:
A kind of allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing.By weight percentage, the group of alloy becomes Li:1.0- 1.2wt.%,Mo:0.2-0.3wt.%,Ca:0.1-0.2wt.%,Cr:8.0-9.5wt.%,Ni:6.2-7.5wt.%,Si:4.0- 8.0wt.%,Co:1.5-1.8wt.%, B:0.2-0.5wt.%, surplus are iron.The ferroalloy is in fusion process because of volatilization and shape The weight lost at reasons such as clinkers is in 1.0-2.0wt.% or so.
The preparation method of above-mentioned corrosion-resistant stainless steel pot material used for hot dip galvanizing, includes the following steps:The original that will as above match Material is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible;Sensing heating is molten to 1500-1600 degree formation alloy Liquid, and be sufficiently stirred 10 minutes or so using electromagnetic agitation effect;Alloy liquid is stood 10 minutes in the heat preservation of 1500-1600 degree After be cast into required billet.The ingot casting of gained is subjected to hot rolling under 800 degree, amount is 10-15% under every time rolling.Often Intermediate anneal temperature is 900 degree after hot rolling twice, keeps the temperature 1 hour.Material is finally rolled into the steel plate that thickness is 40-60mm, The iron crucible of galvanizing by dipping can be prepared with these steel plates by way of deforming and welding.Hot dipping of zinc-aluminum alloy Technique is:Hot-dip temperature is 420-480 degree, and the hot-dip time is 30-60 seconds.
Compared with prior art, the present invention has the advantages that:
(1)Patent of the present invention provides a kind of materialogy for current hot-dip aluminum zinc with the short present situation of the service life of iron crucible Solution.Iron pan in hot dipping of zinc-aluminum alloy is made of cast iron or ordinary low-carbon steel.These iron pans are in galvanizing by dipping By the strong corrosion of zinc liquid in aluminum alloy production process, the service life is very short, only one year or so.Meanwhile in the corrosion process of iron, A large amount of pure zinc is consumed, this is the main reason for galvanizing is of high cost.The damage type of general zinc pot is divided into two classes:(1) Even property damage, it is determined to the dissolving of iron in steel by zinc liquid.(2) exedens damage, it refers to by crackle or zinc and steel office Portion's reaction generates premature breakdown caused by hole.In addition, the service life of hot dipping of zinc-aluminum alloy iron pan additionally depends on heating speed Rate and heating type;Molten bath state, as the temperature in molten bath, ingredient, bath movement situation and the temperature in heat temperature raising stage control Deng.The novel hot-dip zinc-aluminium-alloy iron pan of present patent application protection can significantly be reduced in hot dipping of zinc-aluminum alloy with alloy Dissolving and alloy melt and iron pan of the middle iron pan in alloy melt generate the speed of growth of intermetallic compounds layer when contacting And product types.Due to starting with from physical interaction and chemical interaction, the corruption of alloy melt and iron pan is greatly reduced Erosion and dissolving, hence it is evident that improve the service life of iron pan.
(2)Alloying element in iron crucible can form fine and close compound layer in the environment of galvanizing by dipping with zinc liquid.This The appearance of a compact transition layer, can be effectively reduced zinc in zinc liquid further with the Reaction-diffusion terms of iron-based.In addition, the densification The bond strength of compound layer and matrix is high, and the high-strength hot-dip galvanized operation under lower temperature may be implemented.The alloy possesses Excellent welding performance is obtaining galvanizing by dipping iron crucible using means such as common argon arc weldings.Weld seam is closely knit, and welds shadow It is tiny equiax crystal to ring area's crystal grain.The appearance of these small isometric crystalline regions, when can greatly improve galvanizing by dipping at high temperature The corrosion of liquid zinc and leakage.For a long time using phenomenon will not be fallen off under conditions of big convection current and industry vibrations, into one Step effectively shields zinc liquid and is further corroded to iron crucible.
(3)The iron pan of traditional hot dipping of zinc-aluminum alloy zinc liquid in hot dipping of zinc-aluminum alloy corrodes iron plate and causes cadmia Excessively, galvanizing quality is influenced, zinc pot service life is shortened, there are perforation, leakage zinc phenomenon in typically less than half a year.Due to this large size The cost of manufacture of container is very high, thus caused by economic loss be huge.The galvanizing by dipping prepared using the alloy of this patent Aluminium alloy iron crucible can significantly improve the corrosion-resistant and abrasion resistance properties of inner surface.At a temperature of galvanizing by dipping(420- 480 degree)Can be using 4 years or more, in comparison the service life of the hot-dip aluminum zinc of current same type iron pan is generally 1-2 Year.The alloy had not only improved the performance of galvanizing by dipping iron pan, but also reduced manufacturing cost, thus was of great significance.
Specific implementation mode
Embodiment 1
One kind using allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing in 420-480 degree.By weight percentage, alloy Group become Li:1.0wt.%,Mo:0.2wt.%,Ca:0.1wt.%,Cr:8.0wt.%,Ni:6.2wt.%,Si:4.0wt.%,Co: 1.5wt.%, B:0.2wt.%, surplus are iron.The ferroalloy is in fusion process because volatilizing and forming the reasons such as clinker and lose Weight is in 1.0-2.0wt.% or so.The preparation method of above-mentioned corrosion-resistant stainless steel pot material used for hot dip galvanizing, includes the following steps: As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible;Sensing heating is to 1500- 1600 degree are formed alloy solution, and are sufficiently stirred 10 minutes or so using electromagnetic agitation effect;By alloy liquid in 1500-1600 Degree heat preservation is stood is cast into required billet after ten minutes.The ingot casting of gained is subjected to hot rolling under 800 degree, every time is rolled Lower amount is 10-15%.Intermediate anneal temperature is 900 degree after per hot rolling twice, keeps the temperature 1 hour.Material, which is finally rolled into thickness, is The iron crucible of the steel plate of 40-60mm, galvanizing by dipping can be prepared with these steel plates by way of deforming and welding.Heat The technique of immersion plating allumen is:Hot-dip temperature is 420-480 degree, and the hot-dip time is 30-60 seconds.
The novel hot-dip zinc-aluminium-alloy iron pan of present patent application protection can significantly be reduced in galvanizing by dipping with alloy Dissolving and alloy melt and iron pan of the Iron in Aluminium Alloy pot in alloy melt generate the life of intermetallic compounds layer when contacting Long speed and product types.Due to starting with from physical interaction and chemical interaction, alloy melt and iron are greatly reduced The corrosion and dissolving of pot, hence it is evident that improve the service life of iron pan.Alloying element in iron crucible can in the environment of galvanizing by dipping To form fine and close compound layer with zinc liquid.The appearance of this compact transition layer can be effectively reduced zinc in zinc liquid into one The Reaction-diffusion terms of step and iron-based.In addition, the bond strength of the densification compound layer and matrix is high, may be implemented under lower temperature High-strength hot-dip galvanized operation.The hot dipping of zinc-aluminum alloy iron crucible prepared using the alloy of this patent can significantly improve interior The corrosion-resistant and abrasion resistance properties on surface.At a temperature of galvanizing by dipping(420-480 degree)Can use 4 years or more, compare and Say that the service life of the hot-dip aluminum zinc iron pan of current same type is generally 1-2.The alloy had both improved hot-dip zinc-iron The performance of pot, and manufacturing cost is reduced, thus be of great significance.
Embodiment 2
One kind using allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing in 420-480 degree.By weight percentage, alloy Group become Li:1.2wt.%,Mo:0.3wt.%,Ca:0.2wt.%,Cr:9.5wt.%,Ni:7.5wt.%,Si:8.0wt.%,Co: 1.8wt.%,B:0.5wt.%, surplus are iron.The ferroalloy is in fusion process because volatilizing and forming the reasons such as clinker and lose Weight is in 1.0-2.0wt.% or so.The preparation method of above-mentioned corrosion-resistant stainless steel pot material used for hot dip galvanizing, includes the following steps: As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible;Sensing heating is to 1500- 1600 degree are formed alloy solution, and are sufficiently stirred 10 minutes or so using electromagnetic agitation effect;By alloy liquid in 1500-1600 Degree heat preservation is stood is cast into required billet after ten minutes.The ingot casting of gained is subjected to hot rolling under 800 degree, every time is rolled Lower amount is 10-15%.Intermediate anneal temperature is 900 degree after per hot rolling twice, keeps the temperature 1 hour.Material, which is finally rolled into thickness, is The iron crucible of the steel plate of 40-60mm, galvanizing by dipping can be prepared with these steel plates by way of deforming and welding.Heat The technique of immersion plating allumen is:Hot-dip temperature is 420-480 degree, and the hot-dip time is 30-60 seconds.
The novel hot-dip zinc-aluminium-alloy iron pan of present patent application protection can significantly be reduced in galvanizing by dipping with alloy Dissolving and alloy melt and iron pan of the Iron in Aluminium Alloy pot in alloy melt generate the life of intermetallic compounds layer when contacting Long speed and product types.Due to starting with from physical interaction and chemical interaction, alloy melt and iron are greatly reduced The corrosion and dissolving of pot, hence it is evident that improve the service life of iron pan.Alloying element in iron crucible can in the environment of galvanizing by dipping To form fine and close compound layer with zinc liquid.The appearance of this compact transition layer can be effectively reduced zinc in zinc liquid into one The Reaction-diffusion terms of step and iron-based.In addition, the bond strength of the densification compound layer and matrix is high, may be implemented under lower temperature High-strength hot-dip galvanized operation.The hot dipping of zinc-aluminum alloy iron crucible prepared using the alloy of this patent can significantly improve interior The corrosion-resistant and abrasion resistance properties on surface.At a temperature of galvanizing by dipping(420-480 degree)Can use 4 years or more, compare and Say that the service life of the hot-dip aluminum zinc iron pan of current same type is generally 1-2.The alloy had both improved hot-dip zinc-iron The performance of pot, and manufacturing cost is reduced, thus be of great significance.
Embodiment 3
One kind using allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing in 420-480 degree.By weight percentage, alloy Group become Li:1.0wt.%,Mo:0.2wt.%,Ca:0.1wt.%,Cr:8.5wt.%,Ni:6.8wt.%,Si:4.8wt.%,Co: 1.6wt.%,B:0.3wt.%, surplus are iron.The ferroalloy is in fusion process because volatilizing and forming the reasons such as clinker and lose Weight is in 1.0-2.0wt.% or so.The preparation method of above-mentioned corrosion-resistant stainless steel pot material used for hot dip galvanizing, includes the following steps: As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible;Sensing heating is to 1500- 1600 degree are formed alloy solution, and are sufficiently stirred 10 minutes or so using electromagnetic agitation effect;By alloy liquid in 1500-1600 Degree heat preservation is stood is cast into required billet after ten minutes.The ingot casting of gained is subjected to hot rolling under 800 degree, every time is rolled Lower amount is 10-15%.Intermediate anneal temperature is 900 degree after per hot rolling twice, keeps the temperature 1 hour.Material, which is finally rolled into thickness, is The iron crucible of the steel plate of 40-60mm, galvanizing by dipping can be prepared with these steel plates by way of deforming and welding.Heat The technique of immersion plating allumen is:Hot-dip temperature is 420-480 degree, and the hot-dip time is 30-60 seconds.
The novel hot-dip zinc-aluminium-alloy iron pan of present patent application protection can significantly be reduced in galvanizing by dipping with alloy Dissolving and alloy melt and iron pan of the Iron in Aluminium Alloy pot in alloy melt generate the life of intermetallic compounds layer when contacting Long speed and product types.Due to starting with from physical interaction and chemical interaction, alloy melt and iron are greatly reduced The corrosion and dissolving of pot, hence it is evident that improve the service life of iron pan.Alloying element in iron crucible can in the environment of galvanizing by dipping To form fine and close compound layer with zinc liquid.The appearance of this compact transition layer can be effectively reduced zinc in zinc liquid into one The Reaction-diffusion terms of step and iron-based.In addition, the bond strength of the densification compound layer and matrix is high, may be implemented under lower temperature High-strength hot-dip galvanized operation.The hot dipping of zinc-aluminum alloy iron crucible prepared using the alloy of this patent can significantly improve interior The corrosion-resistant and abrasion resistance properties on surface.At a temperature of galvanizing by dipping(420-480 degree)Can use 4 years or more, compare and Say that the service life of the hot-dip aluminum zinc iron pan of current same type is generally 1-2.The alloy had both improved hot-dip zinc-iron The performance of pot, and manufacturing cost is reduced, thus be of great significance.

Claims (3)

1. a kind of allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing;According to weight percent, the ingredient of the alloy is: Li:1.0-1.2wt.%,Mo:0.2-0.3wt.%,Ca:0.1-0.2wt.%,Cr:8.0-9.5wt.%,Ni:6.2-7.5wt.%, Si:4.0-8.0wt.%,Co:1.5-1.8wt.%,B:0.2-0.5wt.%, surplus are iron.
2. the corrosion-resistant stainless steel pot material used for hot dip galvanizing of allumen described in claim 1, it is characterised in that including smelting as follows Step:As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses silicon carbide crucible;Sensing heating arrives 1500-1600 degree forms alloy solution, and is sufficiently stirred 10 minutes or so using electromagnetic agitation effect;Alloy liquid is existed The heat preservation of 1500-1600 degree is stood is cast into required billet after ten minutes;The ingot casting of gained is subjected to hot rolling under 800 degree, Amount is 10-15% under every time rolling;Intermediate anneal temperature is 900 degree after per hot rolling twice, keeps the temperature 1 hour.
3. according to the corrosion-resistant stainless steel pot material used for hot dip galvanizing of allumen described in claim 1, it is characterised in that comprising making as follows Use step:Material is rolled into the steel plate that thickness is 40-60mm, the iron crucible of hot-dip aluminum zinc can be passed through with these steel plates The mode of deformation and welding is prepared;The technique of hot dipping of zinc-aluminum alloy is:Hot-dip temperature is 420-480 degree, hot-dip Time is 30-60 seconds.
CN201810592659.9A 2018-06-11 2018-06-11 Allumen corrosion-resistant stainless steel pot material used for hot dip galvanizing and its technique Withdrawn CN108707841A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114231876A (en) * 2021-12-20 2022-03-25 吉林大学 Aluminum alloy cylinder body embedded with gray cast iron cylinder sleeve in secondary hot dipping and casting method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114231876A (en) * 2021-12-20 2022-03-25 吉林大学 Aluminum alloy cylinder body embedded with gray cast iron cylinder sleeve in secondary hot dipping and casting method thereof
CN114231876B (en) * 2021-12-20 2023-10-13 吉林大学 Aluminum alloy cylinder body with embedded gray cast iron cylinder sleeve for secondary hot dip plating and casting method thereof

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Application publication date: 20181026