CN108707828A - A kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method - Google Patents

A kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method Download PDF

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Publication number
CN108707828A
CN108707828A CN201810642103.6A CN201810642103A CN108707828A CN 108707828 A CN108707828 A CN 108707828A CN 201810642103 A CN201810642103 A CN 201810642103A CN 108707828 A CN108707828 A CN 108707828A
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steel
low
pressure container
impact toughness
temperature pressure
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CN108707828B (en
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左辉
翟万里
郑力宁
肖波
印传磊
许光乐
石可伟
谭利
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Jiangsu Lihuai Iron And Steel Co Ltd
Jiangsu Shagang Group Huaigang Special Steel Co Ltd
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Jiangsu Shagang Group Huaigang Special Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0006Adding metallic additives
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention discloses a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container, chemical composition mass percent is:C:0.06-0.08%, Si:0.20-0.35%, Mn:1.15-1.35%, Ti:0.01-0.02%, Ni:0.12-0.15%, Al:The , of 0.020-0.045%, P≤0.010%, S≤0.003% [O]≤ 0.0015% , [N]≤ 0.0050% , [H]≤ 0.00015%, surplus Fe.Known to from the above, a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of the present invention, by accurately controlling reduction C content, strong deoxidation, crystal grain thinning are carried out using Al, alloying is carried out using Ni, Ti element, so that its performance is had and is applicable in lower medium temperature compared with 09MnD steel in Q/TDGG 0040-2004(-50℃~-55℃)With higher low-temperature impact toughness, and its overall mechanical properties is also more stable.

Description

A kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production Method
Technical field
The present invention relates to the technical fields of the low-alloy steel in steel industry, and in particular to a kind of super high impact toughness, height Degree of purity steel for low-temperature pressure container and its production method.
Background technology
Low-temperature pressure container is one kind in low-temperature (low temperature) vessel.The common ferritic steel of general pressure vessel, when temperature reduces When to a certain temperature, reach brittle transition temperature, the toughness of steel drastically declines, easily broken.Pressure vessel is less than transformation temperature In use, as there are the stress raisers caused by the factors such as defect, residual stress in container under conditions of degree, container is just very May the non-plastic fracture in the case where not having to occur apparent plastic deformation, to lead to catastrophic failure.
For low-temperature pressure container, first have to select suitable material, these materials necessary according to purposes and bearing medium There is good toughness at use temperature accordingly.The low-alloy handled through crystal grain thinning can be used in -45 DEG C or more media Steel, -45 DEG C ~ -60 DEG C media can be used the steel of nickel content 2.5%, -60 DEG C ~ -104 DEG C media that the steel of nickel content 3.5% can be used, - The steel of nickel content 9.0% can be used in 104 DEG C ~ -196 DEG C media, and austenitic stainless steel or aluminium can be used to close for less than -196 DEG C media Gold.For avoid low-temperature pressure container generate stress raisers, answer close inspection during fabrication, it is dangerous in container to prevent Defect.Therefore the necessary stringent control of low-temperature pressure container manufacture overall process, must be strictly controlled since raw material and produced Journey is continuously improved purity of steel, prevents inside and outside defect.
Steel for low-temperature pressure container impact flexibility is advised in China's industry internal standard Q/TDGG 0040-2004 It is fixed(The standard analysis of 09MnD steel is as shown in Figure 1), -50 DEG C of impact flexibility requirements of middle-low alloy steel:KV2≥60J.State at present The 09MnD steel inside generally used, it is difficult to stably reach above-mentioned obdurability requirement, can only ensure -45 DEG C after normalized treatment Safe handling, to ensure that pressure vessel is used safely at -50 DEG C -55 DEG C, it is necessary to redesign ingredient and Optimal improvements technique.
Invention content
It is an object of the invention to:Overcome the deficiencies of the prior art and provide a kind of super high impact toughness, high cleanliness low temperature Steels for pressure vessel use and its production method have compared with the higher low-temperature impact toughness of 09MnD steel in Q/TDGG 0040-2004.Tool There is following mechanical property:-50℃ KV2≥250J.
The technical solution used in the present invention is:
A kind of super high impact toughness, high cleanliness steel for low-temperature pressure container, chemical composition mass percent are:C:0.06- 0.08%, Si:0.20-0.35%, Mn:1.15-1.35%, Ti:0.01-0.02%, Ni:0.12-0.15%, Al:0.020- The , of 0.045%, P≤0.010%, S≤0.003% [O]≤ 0.0015% , [N]≤ 0.0050% , [H]≤ 0.00015%, surplus Fe.
The restriction of super high impact toughness, high cleanliness steel for low-temperature pressure container chemical composition of the present invention is specifically described below Reason:
C:The intensity of steel can be significantly improved, but also deteriorates the plasticity of steel, significantly improves the brittle transition temperature of steel.So to protect It demonstrate,proves this steel grade and has good low-temperature impact toughness, prevent peritectic reaction, endanger surface quality of steel, carbon content should control 0.08% or less.C content of the present invention takes 0.06%-0.08%.
Si:Ferrite can be dissolved in steel, can be improved the intensity and hardness of steel, but be reduced the plasticity and toughness of steel.Its Minimum content can be only achieved effect for 0.18%, but excessively high Si contents easily cause steel when especially being coexisted with Mn elements Grain coarsening increases steel belt roof bolt brittleness, while Si is to significantly improve one of brittle transition temperature element of steel.Compound material Si contents are determined as 0.20%-0.35% by general requirement, this steel grade.
Mn:Ferrite can be dissolved in steel, strengthens matrix, and pearlite can be refined in roller repairing and opposite can improve pearl Therefore body of light content can improve intensity and hardness, and influenced on the plasticity of material smaller.When Mn contents are less than 1.8%, with Its content increases, and steel strength is continuously increased, and does not have notable harm to toughness.The general requirement of compound material, this steel grade Mn contents are determined as 1.15%-1.35%.
Ni:The intensity of steel can be improved, while keeping good plasticity and toughness.Certain nickel has soda acid higher resistance to Corrosive power.Nickel can reduce critical transition temperature and reduce the diffusion velocity of each element, significantly improve the low-temperature impact of steel Toughness.It is expensive but since nickel is scarce resource.So the control of Ni contents is in 0.12%-0.15% in the present invention.
Ti:Carbide is combined in steel with carbon, is formed carbonization titanium particulate, be can effectively prevent crystal grain and grow up. While improving intensity, through normalizing can abundant crystal grain thinning, so that the plasticity of steel and impact flexibility is significantly improved.But Ti is combined the bulky grain TiN brittle inclusions easily formed with N element in steel, seriously affects the impact flexibility of steel.So of the invention Middle Ti contents control is 0.01%-0.02%.
Al:The inoxidizability of steel is improved, gas content in steel is reduced, improves the fatigue strength of steel, while brilliant as refinement Grain element is present in steel grade, plays the role of the cryogenic property and corrosion resisting property that improve steel.But if Al content is excessively high, it is easy shape At hard Al2O3It is mingled with, deteriorates the impact flexibility of steel.So the present invention defines specific Composition Control ranging to Al content 0.020%-0.045%。
P:So that steel is generated cold brittleness, reduce the impact flexibility of steel, while deteriorating the welding performance of steel, reduces plasticity, make cold Curved degradation.So the present invention has carried out stringent control to P content, it is necessary to≤0.010%.
S:Easy segregation element reduces the ductility and toughness of steel, is also adversely affected to welding performance and corrosion resistance.Institute Stringent control is carried out to S contents with the present invention, it is necessary to≤0.003%.
O:It is little to the intensity effect of steel in room temperature, but the elongation of steel and reduction of area is made significantly to reduce, relatively low When temperature and extremely low O content, the intensity and plasticity of material are drastically reduced with the increase of O content.In terms of impact property, with The maximum value of the increase impact of O content continuously decreases, and brittle transition temperature but soon increases, the range of brittle transition temperature With broadening.Meanwhile with the increase of O content, the oxide inclusion occurrence probability of material greatly increases, to reduce material Fatigue life.The present invention is by O content stability contorting within 0.0015%.
H:Hydrogen makes the plasticity of steel reduce, and mainly low-temperature impact work is made to reduce.Hydrogen will produce " hairline " or be formed in steel Stressed zone, when steel carries out forging rolling processing, hairline extends and forms crackle, so that the mechanical property especially plasticity of steel is deteriorated, even " white point " is presented on steel fracture in fracture.Hydrogen can also cause splitting in spot segregation, hydrogen embrittlement and weld heat-affected zone simultaneously Seam etc..Therefore, the present invention and technique control H below 0.00015%.
N:Nitrogen can be such that steel strengthen, but significantly reduce steel plasticity, toughness, increase timeliness tendency and cold brittleness.Generally want Content is asked to be less than 0.0080%.The present invention and production technology control N content within 0.0050%.
A kind of super high impact toughness, the production method of high cleanliness steel for low-temperature pressure container, include the following steps:By upper The mass percent of component is stated,
1)Converter smelting:It smelts in 100 tons or more of top and bottom complex blowing formula converter, is carried out just as raw material using molten iron and high-quality steel scrap Refining realizes that pre- de- P, tapping are added lab-prepared refining slag, double deoxidizer and a variety of high purity alloys and carry out pre-deoxidation and ingredient initial adjustment;
2)Refining:Molten steel deep deoxidation and alloying are carried out in 100 tons or more of LF stoves;Refining process whole process stirs, after refining Phase uses weak stirring, prevents secondary oxidation of steel;
3)Vacuum outgas:Vacuum outgas and removal of inclusions processing are carried out using RH circulating degasification apparatus after LF refining;
4)Inclusion modification and soft blow:Silico-calcium silk thread is fed after being vacuum-treated to inclusion modification and carries out soft blow processing, soft blow Time is 30-35 minutes, is fully floated, removal of inclusions;
5)Continuous casting:Whole full guard casting life is carried out using tundish covering flux, crystallizer protecting residue using billet caster Produce continuous casting square billet;
6)Steel rolling:Production line of bar produces Φ 50mm ~ Φ 70mm steel for low-temperature pressure container in utilization;
7)Finishing:Steel surface defect is eliminated using the finishing process of ball blast+chamfered edge+hand inspection reconditioning.
The further improvement project of the present invention is the step 1)The anti-non-return P of steel tapping is stayed using slide plate pushing off the slag.
The further improvement project of the present invention is the step 2)The refining slag for making basicity slag R=5 ~ 8, passes through slag-metal reaction Strengthen and takes off S, goes to be mingled with.
The further improvement project of the present invention is the step 2)In, the Ventilation Rate of the weak stirring is less than 200L/ min。
The further improvement project of the present invention is the step 3)In, kept for 30 minutes under a high vacuum or more, ensure H ]≤0.00015%, [ O ]≤0.0010%, all the components enter the range of requirement.
The further improvement project of the present invention is the step 6)In, using 1050 ~ 1080 DEG C of open rollings, 980 ~ 1000 DEG C Finish to gauge temperature-controlled rolling fully refines original grain degree.
According to present invention manufacture super high impact toughness, high cleanliness steel for low-temperature pressure container(07MnNiTi), have super High/low-temperature impact toughness and high cleanliness, material mechanical property after whole normalizing can reach following level:-50℃ KV2≥250J。
The beneficial effects of the present invention are:
The first, a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of the invention, passes through essence Really control reduces C content, and strong deoxidation, crystal grain thinning are carried out using Al, carries out alloying using Ni, Ti element, its performance is made to have Have and is applicable in lower medium temperature compared with 09MnD steel in Q/TDGG 0040-2004(-50℃~-55℃)With higher low-temperature impact Toughness, and its overall mechanical properties is also more stable.
The second, a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of the invention, makes With calcium containing alloy carry out strong deoxidation, special refining slag system enhancing removal be mingled with effect, be de-gassed using RH vacuum equipments, The cleanliness factor for improving material, to improve the safety of material.
A kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of third, the present invention, this Invention uses BOF+LF+RH+CCM techniques, ensures lower P, S, H, O, N content, and material is made to have excellent synthesis mechanical property Energy.
4th, a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of the invention, this Invention gives full play to the work of Ti element crystal grain thinnings by using 1050 ~ 1080 DEG C of open rollings, 980 ~ 1000 DEG C of finish to gauge temperature-controlled rollings With raising material comprehensive mechanical property.
5th, a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container and its production method of the invention, this Invention meets the requirement of -50 DEG C ~ -55 DEG C of low-alloy steel by Rational Composition design and advanced technique, effectively reduces The consumption of nickel alloy, is greatly saved cost, improves efficiency.
Description of the drawings
Fig. 1 is the standard analysis table of 09MnD steel.
Fig. 2 is that the low-alloy steel for low-temperature pressure container 09MnD that the current country uses and the chemical composition of the present invention compare Table.
Fig. 3 is the chemical composition contrast table of 4 groups of embodiments.
Fig. 4 is that impact absorbing energy of 4 groups of embodiments with 09MnD steel at -50 DEG C, -52 DEG C and -55 DEG C compares Table.
Fig. 5 is 4 groups of embodiment non-metallic inclusion controlled level tables.
Specific implementation mode
As shown in Fig. 2, the comparative situation of the chemical constituent and 09MnD steel chemical constituents of the present invention.
And prepare 4 groups of embodiments according to production in accordance with the following methods:
1)Converter smelting:It smelts in 100 tons or more of top and bottom complex blowing formula converter, is carried out just as raw material using molten iron and high-quality steel scrap Refining realizes that pre- de- P, tapping are added lab-prepared refining slag, double deoxidizer and a variety of high purity alloys and carry out pre-deoxidation and ingredient initial adjustment, The anti-non-return P of steel tapping is stayed using slide plate pushing off the slag;
2)Refining:Molten steel deep deoxidation and alloying are carried out in 100 tons or more of LF stoves, makes the refining slag of basicity slag R=5 ~ 8, are led to Cross the de- S of slag-metal reaction reinforcing, removal is mingled with;Refining process whole process stirs, and the refining later stage uses weak stirring, prevents the secondary oxygen of molten steel Change;
3)Vacuum outgas:Vacuum outgas and removal of inclusions processing are carried out using RH circulating degasification apparatus after LF refining, in height It is kept for 30 minutes or more under vacuum, ensures that [ H ]≤0.00015%, [ O ]≤0.0010%, all the components enter the range of requirement;
4)Inclusion modification and soft blow:Silico-calcium silk thread is fed after being vacuum-treated to inclusion modification and carries out soft blow processing, soft blow Time is 30-35 minutes, is fully floated, removal of inclusions;
5)Continuous casting:Whole full guard casting life is carried out using tundish covering flux, crystallizer protecting residue using billet caster Produce continuous casting square billet;
6)Steel rolling:Production line of bar produces Φ 50mm ~ Φ 70mm steel for low-temperature pressure container in utilization, using 1050 ~ 1080 DEG C Open rolling, 980 ~ 1000 DEG C of finish to gauge temperature-controlled rollings fully refine original grain degree;
7)Finishing:Steel surface defect is eliminated using the finishing process of ball blast+chamfered edge+hand inspection reconditioning.
The process conditions limited is not added to can refer to this field routine techniques in method made above.
As shown in figure 3, the super high impact toughness of each embodiment of gained, high cleanliness steel for low-temperature pressure container (07MnNiTi)Chemical composition.
As shown in figure 4, impact absorbing energy of each embodiment of gained under the conditions of -50 DEG C, -52 DEG C and -55 DEG C and with it is existing There is the comparative situation of technology.
As shown in figure 5, the non-metallic inclusion controlled level comparative situation of each embodiment of gained.
General superfine high-quality steel non-metallic inclusion control hierarchy be each system≤1.5 grades, and the present invention pass through it is rational Technological design and process control, non-metallic inclusion stability contorting at 1.0 grades hereinafter, purity of steel is high;Moreover, wherein C is thick and C is carefully 0 grade.

Claims (7)

1. a kind of super high impact toughness, high cleanliness steel for low-temperature pressure container, it is characterised in that:Its chemical composition quality percentage Than for:C:0.06 ~ 0.08%, Si:0.20 ~ 0.35%, Mn:1.15 ~ 1.35%, Ti:0.01 ~ 0.02%, Ni:0.12 ~ 0.15%, Al: The , of 0.020 ~ 0.045%, P≤0.010%, S≤0.003% [O]≤ 0.0015% , [N]≤ 0.0050% , [H]≤ 0.00015%, surplus For Fe.
2. a kind of super high impact toughness, the method for high cleanliness steel for low-temperature pressure container as described in claim 1 are produced, It is characterized in that including the following steps:
1)Converter smelting:It smelts in 100 tons or more of top and bottom complex blowing formula converter, is carried out just as raw material using molten iron and high-quality steel scrap Refining realizes that pre- de- P, tapping are added lab-prepared refining slag, double deoxidizer and a variety of high purity alloys and carry out pre-deoxidation and ingredient initial adjustment;
2)Refining:Molten steel deep deoxidation and alloying, refining process whole process stirring, after refining are carried out in 100 tons or more of LF stoves Phase uses weak stirring, prevents secondary oxidation of steel;
3)Vacuum outgas:Vacuum outgas and removal of inclusions processing are carried out using RH circulating degasification apparatus after LF refining;
4)Inclusion modification and soft blow:Silico-calcium silk thread is fed after being vacuum-treated to inclusion modification and carries out soft blow processing, soft blow Time is 30 ~ 35 minutes, is fully floated, removal of inclusions;
5)Continuous casting:Whole full guard casting life is carried out using tundish covering flux, crystallizer protecting residue using billet caster Produce continuous casting square billet;
6)Steel rolling:Production line of bar produces Φ 50mm ~ Φ 70mm steel for low-temperature pressure container in utilization;
7)Finishing:Steel surface defect is eliminated using the finishing process of ball blast+chamfered edge+hand inspection reconditioning.
3. a kind of super high impact toughness as claimed in claim 2, the production method of high cleanliness steel for low-temperature pressure container, It is characterized in that:The step 1)In, the anti-non-return P of steel tapping is stayed using slide plate pushing off the slag.
4. a kind of super high impact toughness as claimed in claim 2, the production method of high cleanliness steel for low-temperature pressure container, It is characterized in that:The step 2)In, the refining slag of basicity slag R=5 ~ 8 is made, de- S is strengthened by slag-metal reaction, removal is mingled with.
5. a kind of super high impact toughness as claimed in claim 2, the production method of high cleanliness steel for low-temperature pressure container, It is characterized in that:The step 2)In, the Ventilation Rate of the weak stirring is less than 200L/min.
6. a kind of super high impact toughness as claimed in claim 2, the production method of high cleanliness steel for low-temperature pressure container, It is characterized in that:The step 3)In, kept for 30 minutes or more under a high vacuum, ensure [ H ]≤0.00015%, [ O ]≤ 0.0010%, all the components enter the range of requirement.
7. a kind of super high impact toughness as claimed in claim 2, the production method of high cleanliness steel for low-temperature pressure container, It is characterized in that:The step 6)In, using 1050 ~ 1080 DEG C of open rollings, 980 ~ 1000 DEG C of finish to gauge temperature-controlled rollings, fully refine original Grain size.
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CN102418036A (en) * 2011-06-29 2012-04-18 南阳汉冶特钢有限公司 15MnNiDR low alloy steel plate for low temperature pressure vessel and production method thereof
CN102242309A (en) * 2011-06-30 2011-11-16 湖南华菱湘潭钢铁有限公司 Production method of boron-containing petroleum storage tank steel plate for ultra-high heat input welding
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109680122A (en) * 2019-02-15 2019-04-26 江苏利淮钢铁有限公司 A kind of hub bearing steel and its manufacturing method
CN109680122B (en) * 2019-02-15 2020-09-22 江苏利淮钢铁有限公司 Steel for hub bearing and manufacturing method thereof

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