CN108707723A - Steel-making quick slag material and its production method - Google Patents

Steel-making quick slag material and its production method Download PDF

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Publication number
CN108707723A
CN108707723A CN201810327306.6A CN201810327306A CN108707723A CN 108707723 A CN108707723 A CN 108707723A CN 201810327306 A CN201810327306 A CN 201810327306A CN 108707723 A CN108707723 A CN 108707723A
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China
Prior art keywords
slag
making
steel
quick
materials
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CN201810327306.6A
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Chinese (zh)
Inventor
万杨知为
骆锦萌
万恩同
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Wan Yang Zhiwei
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Wan Yang Zhiwei
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Priority to CN201810327306.6A priority Critical patent/CN108707723A/en
Publication of CN108707723A publication Critical patent/CN108707723A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/076Use of slags or fluxes as treating agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a kind of steel-making quick slag material and its production methods, and for making steel the slag making in refining process, which includes slag making materials with quick slag material component, it also contains the expanding material for accounting for the slag making materials total weight 0.1~3.0%.Its production method, includes the following steps:1) slag making materials are uniformly mixed according to the weight ratio of design with expanding material, must be made steel with quick slag material coarse fodder;2) steel-making is subjected to pelletizing with quick slag material coarse fodder;3) processing is dried to pelletizing, you can obtain steel-making slag making materials.Using the slag material of the present invention under the premise of not increasing equipment investment, can react with steel or slag rapidly quick slag making, shorten the heat, reduce cost.

Description

Steel-making quick slag material and its production method
Technical field
The invention belongs to metallurgical technology fields, specifically, belong in a kind of production process applied to steel material, improve The steel-making of slag making efficiency quick slag material and its production method.
Background technology
In the metal smelts such as steel, it is necessary to which slag making has saying for " slag first being refined in steel-making, and good slag has gone out steel ", the ingredient of slag, property Can, directly influence the quality of steel.It is that raw mineral materials produces that steel-making at present, which commonly uses slag making materials largely, after being calcined such as lime stone The light dolomite that is generated after the lime of generation, dolomite calcination, fluorite, alumina, iron ore etc..Height when due to smelting Temperature, these slag making materials are added with bulk.If it is powdery, then mistake can be blown by high temperature gas flow.Therefore, if it is powdery original Material could be used for slag making after will suppressing balling-up with strength ball press.It is such as comprehensively utilized, is used using pulverized limestone pressure lime ball Slagging agent, modification agent in liquid steel refining are formed with a variety of materials pressure ball.
Blocky and spherical slag making materials have that reaction speed is slow in smelting.Steel or slag with newly plus ball or Then deblocking reaction is spread, reaction speed is greatly by the shadow of contact surface only on the surface of ball or block to the inside of ball or block It rings and limits.And high-melting-point substances, then reaction are difficult to complete once being formed.If lime is added in slag, if surface forms height The 2CaOSiO of fusing point2, modification agent containing metallic aluminium is added in ladle top slag, forms dystectic CaO2Al2O3、CaO· 6Al2O3, react and would become hard to go on.Before the present invention, in order to improve slag making reaction speed, the method commonly improved is to carry High Gas Stirring intensity, with heated by electrodes, dust smelting etc., metallurgical effect can be directly affected in this way, but new set must be increased Standby or modified technique and production cost greatly improved.
Invention content
The technical problem to be solved by the present invention is to provide a kind of steel-making quick slag material, do not increasing equipment investment Under the premise of, can react with steel or slag rapidly quick slag making, shorten the heat, reduce cost.While the present invention also provides The production method for making steel quick slag material.
In order to solve the above technical problems, the quick slag material of steel-making of the present invention, for making steel the slag making in refining process, Its component includes slag making materials, is characterized in that:It, which also contains, accounts for the swollen of the slag making materials total weight 0.1~3.0% Swollen material.
Preferably, the expanding material is expanded graphite.
Further, CaO, MgO, SiO are contained in the slag making materials2、Al2O3, F or Fe oxide in one kind or A variety of chemical compositions.Further preferably, the slag making materials be calcium aluminate, calcium ferrite, lime, dolomite, fluorite, alumina, One or several kinds in iron ore.
Further, slag making auxiliary material is also contained in the slag making materials, the slag making auxiliary material is metal alumina particles, steel One or more of grain, silicon-carbide particle, calcium carbide particle.
It is also further, binder is also contained in the slag making materials, the binder is bentonite, clay, CMC, water One or more of glass.
The production method for making steel quick slag material, includes the following steps:
1) according to the weight ratio of design by slag making materials and the expansion material for accounting for the slag making materials total weight 0.1~3.0% Material is uniformly mixed, and obtains making steel quick slag material coarse fodder;
2) steel-making is subjected to pelletizing with quick slag material coarse fodder,
3) processing is dried to pelletizing, you can obtain steel-making slag making materials.
Preferably, pelletizing process described in step 2) includes strength pressure ball, disk pelletizing, squeezes pelletizing.In step 3, institute It states and is dried temperature at 250 DEG C or less.
Present invention steel-making is with the principle of the selection of quick slag material component and manufacturing process:
The steel-making of the present invention is consistent with the main component of common slag making materials with quick slag material, to meet smelting requirements, Its component is equipped with according to conventional slag making materials, can also include that binder, slag making auxiliary material etc. are assembled, special character It is, it includes also expanding material, and expanding material is mainly expanded graphite, also referred to as acid processing graphite.It is added after expanding material, When molten steel or slag is added, expanding material expanded by heating is rapid to rupture, and greatly improves slag making materials and molten steel or slag Contact area, reaction speed increases substantially, and shortens and smelts or refining time, the reaction was complete for a variety of materials, thoroughly, improves Utilization rate reduces cost.
Specific implementation mode
The quick slag material of steel-making and its production method of the present invention are made below in conjunction with specific embodiment further detailed Description.
Embodiment 1
A kind of quick slag material of steel-making, each component percentage are:With 10% fluorite, 89% slug type aluminium Sour calcium, 1% expanded graphite can be used as the Fast Slag Melting agent in steelmaking process.
When specific operation, molten steel is added lime, improves the basicity of slag before refining, is conducive to the desulfurization dephosphorization in refining Removal is mingled with, but blocky lime is not easily dissolved in the slag of molten steel surface, and the steel-making that the present embodiment can be added at this time is used Quick slag material is as slagging agent.Slagging agent before the present invention is generally fluorite, red bauxite, calcium aluminate pre-melted slag, these changes Slag agent is also blocky, slag could be helped to dissolve lime after needing fuse itself, so slugging speed is very slow.Tradition improves slugging There are two types of ways for speed:One, increase Argon amount, make the fierce turnup impact of molten steel slag;Two, with heated by electrodes, slag temperature is improved Degree, but all cost is higher, it is complicated for operation.And the quick slag material of steel-making of the present embodiment is used, it can be in 180 tons of molten steel LF stove essences When refining, after 500kg lime is added, the steel-making that 140kg the present embodiment is added at once uses quick slag material as slagging agent, about 2.5min lime, which dissolves, to be finished, and saves 1.0~1.5min of time than common slagging agent, and do not need heated by electrodes.
Embodiment 2
The quick slag material of steel-making in embodiment 1 is used for Argon station.500kg stones are added in 180 tons of molten steel ar blowing refinings After ash, the steel-making that 1 formula of 150kg embodiments is added at once uses quick slag material as Fast Slag Melting agent, and about 0.5min lime is molten Change finishes.500kg lime is added, about 1.0min, which dissolves, to be finished.Than using existing conventional slag making materials save the time 1.0~ 2.0min。
Embodiment 3
A kind of quick slag material of steel-making, each component percentage are:10% fluorite, 45% powdery stone Ash (pulverized powder or little particle are broken in lime production and transportational process), 43.5% calcined bauxite in powder, 1.5% expanded graphite.It can make For the refining slag in refining process.
Common refining slag is sintering or pre-melted type before the present invention, i.e., is uniformly mixed agstone and bauxite powder Afterwards, it melts or is sintered under 1400~1700 DEG C of high temperature in electric furnace or rotary kiln, form uniform calcium aluminate, fusing point is low.For When liquid steel refining, slag making speed is fast, and desulphurizing ability is strong.But it is of high cost.Using the present embodiment steel-making quick slag material when, will The quick slag material of steel-making of 150kg the present embodiment formulas is added in 180 tons of molten steel Argons, and about 1.0min, which dissolves, to be finished.Than using Existing routine slag making materials save 0.5~1.0min of time, and cost is greatly lowered.
Embodiment 4
A kind of quick slag material of steel-making, each component percentage are:Fritting calcium aluminate powder 40%, metallic aluminium Powder 40%, metal abrasive grit 18%, expanded graphite 2%, density is more than 2.8g/cm after pressure ball3, can be used as in steel-making RH refining process Efficient modification agent.
Because in certain refinery practices, also to make iron oxide (Fe in raw steel slag2O3, FeO, MnO) reduction, enable slag Enough depth desulfurization avoid polluting molten steel in casting process.Modification agent before the present invention is usually with sintering or preliminary melting type calcium aluminate Powder uses after being incorporated a certain amount of metallic aluminium powder pressure ball, common are " 40Al ", " 25Al " (is indicated containing 40%, 25% Metallic aluminium).The problem is that:Metallic aluminium generates aluminium oxide after being reacted with iron oxide, it is high that aluminium oxide reacts generation with calcium aluminate The CaOAl of fusing point2O3(1590 DEG C of fusing point), CaO2Al2O3(1775 DEG C of fusing point), CaO6Al2O3(1903 DEG C of fusing point), shape At a floor height fusing point hard shell, slows down or prevent iron oxide and modify the metal reactive aluminum inside ball.And since density is low, Many modification agent balls also float on slag surface after continuous casting with spherical, do not play the role of due.
Use quick slag material as efficient modification agent using the steel-making of the present embodiment, one of feature is that density is big, is added When ladle, slag surface not being swum in instead of, is sunk in slag, metallic aluminium therein would not be reacted with the oxygen in air And it loses;Feature second is that into disperseing rapidly under the action of expanded graphite after slag, metallic aluminium and iron oxide in slag are rapid Reaction, will not be hindered by high-melting-point reaction product.So reaction speed is fast, metallic aluminium utilization rate is high, modification agent usage amount 20% or more is reduced, cost is reduced.
Embodiment 5
A kind of quick slag material of steel-making, each component percentage are:Pulverized limestone 99%, expanded graphite 1%, It can be used as the rapid melting lime in steelmaking process.
Active lime is the most common slag making materials of steel-making.During its production and transportation, 20% stone is about generated Ashes cannot be directly used to slag making.In order to utilize this part pulverized limestone, the method before the present invention is also strength pressure ball, but block Shape active lime has been not easy to dissolve, the lime intensity higher after pressure ball, density bigger, is less susceptible to occur with other slag charges anti- It answers.The quick slag material of steel-making of the present embodiment is added, when use expands rapidly, just greatlys improve its reaction speed.Lime Solution time is shorter after ball solution time even specific activity lime accelerates fast slagging agent.
Embodiment 6
A kind of quick slag material of steel-making, each component percentage are:The metal abrasive grit recycled in slag 95%, bentonite 3%, expanded graphite 2%, strength pressure ball can be used as in steelmaking process and is quickly cooled down agent.
In refining process, liquid steel temperature is too high in ladle sometimes, cannot directly enter next production process, needs to use crane It slings steel billet insertion molten steel to be cooled down, cooling velocity is slow.Using the quick slag material of steel-making of the present embodiment, i.e., with from slag The steel grit of middle recycling adds a small amount of expanded graphite pressure ball, and molten steel is added from feed bin, because gravity and Breakthrough in inertia slag enter molten steel, Expanded by heating, is dispersed into molten steel, and fusing heat absorption cools down rapidly molten steel.
Embodiment 7
A kind of quick slag material of steel-making, each component percentage are:Clay powder 30%, metallic aluminium or carbonization Silicon, calcium carbide, various ferroalloy powders 68%, expanded graphite 2%, strength pressure ball.It can be used as the slag deoxidation in steelmaking process Agent.
When it is implemented, the steel-making that the present embodiment is added in steelmaking process uses quick slag material as slag deoxidier, it can Do not change or changing less the main component of slag, and can realize the oxidisability for quickly reducing slag, it is not dirty in rear process Contaminate molten steel.
The above various embodiments makes steel the production method of quick slag material, includes the following steps:
1) slag making materials and expanding material are uniformly mixed according to the weight ratio of design, it is thick with quick slag material obtains steel-making Material;
2) steel-making is made with quick slag material coarse fodder using strength pressure ball, disk pelletizing or extruding pelletizing process Ball,
3) processing is dried at 250 DEG C or less to pelletizing, you can obtain steel-making slag making materials.

Claims (10)

1. a kind of quick slag material of steel-making, for making steel the slag making in refining process, component includes slag making materials, feature It is:It also contains the expanding material for accounting for the slag making materials total weight 0.1~3.0%.
2. making steel quick slag material according to claim 1, it is characterised in that:The expanding material is expanded graphite.
3. the quick slag material of steel-making according to claim 1 or claim 2, it is characterised in that:In the slag making materials containing CaO, MgO、SiO2、Al2O3, F or Fe oxide in one or more chemical compositions.
4. according to the quick slag material of the steel-making of claim 1,2 or 3, it is characterised in that:Contain in the slag making materials and makes Slag auxiliary material, the slag making auxiliary material are one or more of metal alumina particles, steel particles, silicon-carbide particle, calcium carbide particle.
5. according to the quick slag material of the steel-making of claim 1,2 or 3, it is characterised in that:Containing viscous in the slag making materials Agent is tied, the binder is one or more of bentonite, clay, CMC, waterglass.
6. making steel quick slag material according to claim 4, it is characterised in that:Contain binder in the slag making materials, The binder is one or more of bentonite, clay, CMC, waterglass.
7. the quick slag material of steel-making according to claim 1 or claim 2, it is characterised in that:The slag making materials are calcium aluminate, iron One or several kinds in sour calcium, lime, dolomite, fluorite, alumina, iron ore.
8. making steel the production method of quick slag material described in a kind of claim 1, include the following steps:
1) slag making materials are mixed with the expanding material for accounting for the slag making materials total weight 0.1~3.0% according to the weight ratio of design It closes uniformly, obtains making steel quick slag material coarse fodder;
2) steel-making is subjected to pelletizing with quick slag material coarse fodder,
3) processing is dried to pelletizing, you can obtain steel-making slag making materials.
9. making steel the production method of quick slag material according to claim 8, it is characterised in that:Pelletizing described in step 2) Method includes strength pressure ball, disk pelletizing, squeezes pelletizing.
10. making steel the production method of quick slag material according to claim 8, it is characterised in that:It is described dry in step 3 Dry treatment temperature is at 250 DEG C or less.
CN201810327306.6A 2018-04-12 2018-04-12 Steel-making quick slag material and its production method Pending CN108707723A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786202A (en) * 2005-12-16 2006-06-14 青岛森田金属有限公司 Composite carbon containing pellet
CN101148687A (en) * 2007-10-16 2008-03-26 攀枝花新钢钒股份有限公司 Special slag modifier for vanadium-titanium-iron magnesium hydrate desulfurization
CN103468867A (en) * 2013-09-26 2013-12-25 西宁特殊钢股份有限公司 Efficient slag mixing agent suitable for sulfur-bearing steel smelting and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786202A (en) * 2005-12-16 2006-06-14 青岛森田金属有限公司 Composite carbon containing pellet
CN101148687A (en) * 2007-10-16 2008-03-26 攀枝花新钢钒股份有限公司 Special slag modifier for vanadium-titanium-iron magnesium hydrate desulfurization
CN103468867A (en) * 2013-09-26 2013-12-25 西宁特殊钢股份有限公司 Efficient slag mixing agent suitable for sulfur-bearing steel smelting and preparing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
潘贻芳 等: "《转炉炼钢功能性辅助材料》", 31 August 2007, 冶金工业出版社 *

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