CN108707408A - A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof - Google Patents
A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof Download PDFInfo
- Publication number
- CN108707408A CN108707408A CN201810635419.2A CN201810635419A CN108707408A CN 108707408 A CN108707408 A CN 108707408A CN 201810635419 A CN201810635419 A CN 201810635419A CN 108707408 A CN108707408 A CN 108707408A
- Authority
- CN
- China
- Prior art keywords
- parts
- aqueous polyurethane
- finish coat
- coat varnish
- thickener
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
Include following components and its parts by weight the invention discloses a kind of high finish coat varnish of aqueous polyurethane：50-75 parts of hydroxy acryl acid resin；20-35 parts of curing agent；10-20 parts of water；2-5 parts of isopropanol；10-15 parts of filler；3-5 parts of coupling agent；1-2 parts of thickener；0.1-4 parts of auxiliary agent.The aqueous polyurethane bloom topcoating cures time of the present invention is short, and hardness is high；The selection and use of coupling agent, enable filler preferably to be disperseed, and improve the wearability and impact resistance of the present invention；Thickener selects aqueous association type polyurethane thickener; it does not select inorganic to thicken class, avoids the extinction effect of inorganic thickener, ensured the high photosensitiveness of the present invention; the high finish coat varnish VOC volatilizations of the aqueous polyurethane of the present invention simultaneously are few, protect environmental and human health impacts.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of high finish coat varnish of aqueous polyurethane and preparation method thereof.
Background technology
Currently, solvent type finishing coat is still in occupation of the larger market share, continuous however as people's environmental consciousness carries
It rising, the VOC volatilizations of solvent type finishing coat cause the attention of people, and a large amount of VOC volatilizations meeting welding damages health,
And aqueous polyurethane finishing coat is due to its wearability, weatherability is good, glossiness is high, while VOC volatilizations are few, cause the note of people
Meaning, but aqueous polyurethane finishing coat there is also viscositys it is low, impact resistance is insufficient, complicated construction technique the defects of, application range
It is wideless.
Invention content
The purpose of the present invention is exactly to solve the above-mentioned problems and provides a kind of high finish coat varnish of aqueous polyurethane and its system
Preparation Method, while low VOC emission, product has wear-resisting, resistance to compression, high photosensitiveness.
The object of the present invention is achieved like this：
A kind of high finish coat varnish of aqueous polyurethane of the present invention includes following components and its parts by weight：
The above-mentioned high finish coat varnish of a kind of aqueous polyurethane, wherein curing agent is isocyanate curing agent.
A kind of above-mentioned high finish coat varnish of aqueous polyurethane, wherein filler in talcum powder, mica powder, silica flour extremely
Few one kind.
The above-mentioned high finish coat varnish of a kind of aqueous polyurethane, wherein coupling agent is oxidized polyethylene wax.
The above-mentioned high finish coat varnish of a kind of aqueous polyurethane, wherein thickener is aqueous association type polyurethane thickener.
A kind of above-mentioned high finish coat varnish of aqueous polyurethane, wherein auxiliary agent include in antifoaming agent, levelling agent, dispersant extremely
Few one kind.
The above-mentioned high finish coat varnish of a kind of aqueous polyurethane, wherein the hydroxyl in hydroxy acryl acid resin accounts for described containing hydroxyl
The mass percent of base acrylic resin is 4.1%.
The preparation method of the high finish coat varnish of a kind of aqueous polyurethane of the present invention, wherein include the following steps：
Step 1：Prepare raw material according to following components and parts by weight：
Step 2：By in step 1 hydroxy acryl acid resin, water, coupling agent, isopropanol, filler, thickener and help
Agent mixes, high-speed stirred 20-30min；
Step 3：Curing agent in step 1 is added in the product after step 2 stirring, high-speed stirred 20-30min,
30min is stood again.
The invention has the advantages that：
1, the high finish coat varnish of aqueous polyurethane of the invention greatly reduces VOC's compared to solvent type finishing coat on the market
Volatilization, protects environmental and human health impacts；
2, the selection of filler improves the wearability and impact resistance of the high finish coat varnish of aqueous polyurethane of the present invention；
3, the selection and use of coupling agent, enables filler preferably to be disperseed；
4, thickener selects aqueous association type polyurethane thickener, and inorganic is not selected to thicken class, avoids inorganic increasing
Thick dose of extinction effect has ensured the high photosensitiveness of the present invention.
Specific implementation mode
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Prepare raw material according to following components and its parts by weight：
The mass percent that hydroxyl in hydroxy acryl acid resin accounts for the hydroxy acryl acid resin is 4.1%.
After getting out above-mentioned raw material, prepared according to the following steps：
S1：By ready 50 parts of hydroxy acryl acid resins, 10 parts of water, 2 parts of isopropanols, 10 parts of talcum powder, 3 parts of oxidations
Polyethylene wax, 1 part of aqueous association type polyurethane thickener, 1 part of antifoaming agent, 1 part of levelling agent mixing, high-speed stirred 30min；
S2：Ready 20 parts of isocyanate curing agents are added in the product after S1 stirrings, high-speed stirred 30min,
30min is stood again.
Embodiment 2
Prepare raw material according to following components and its parts by weight：
The mass percent that hydroxyl in hydroxy acryl acid resin accounts for the hydroxy acryl acid resin is 4.1%.
After getting out above-mentioned raw material, prepared according to the following steps：
S1：By ready 60 parts of hydroxy acryl acid resins, 15 parts of water, 4 parts of isopropanols, 12 parts of talcum powder, 3 parts of oxidations
Polyethylene wax, 1 part of aqueous association type polyurethane thickener, 1 part of antifoaming agent, 1 part of levelling agent mixing, high-speed stirred 30min；
S2：Ready 25 parts of isocyanate curing agents are added in the product after S1 stirrings, high-speed stirred 30min,
30min is stood again.
Embodiment 3
Prepare raw material according to following components and its parts by weight：
The mass percent that hydroxyl in hydroxy acryl acid resin accounts for the hydroxy acryl acid resin is 4.1%.
After getting out above-mentioned raw material, prepared according to the following steps：
S1：By ready 75 parts of hydroxy acryl acid resins, 20 parts of water, 5 parts of isopropanols, 15 parts of talcum powder, 5 parts of oxidations
Polyethylene wax, 2 parts of aqueous association type polyurethane thickeners, 2 parts of antifoaming agent, 2 parts of levelling agent mixing, high-speed stirred 30min；
S2：Ready 35 parts of isocyanate curing agents are added in the product after S1 stirrings, high-speed stirred 30min,
30min is stood again.
The high finish coat varnish of manufactured aqueous polyurethane in embodiment 1-3 is tested for the property, test result is shown in Table 1.
1 the performance test results of table
From table 1 it follows that the aqueous polyurethane bloom topcoating cures time of the present invention is short, hardness is high；Coupling agent
It chooses and uses, filler is enable preferably to be disperseed, improve the wearability and impact resistance of the present invention；Thickener is selected
Aqueous association type polyurethane thickener does not select inorganic to thicken class, avoids the extinction effect of inorganic thickener, ensures
The high photosensitiveness of the present invention, while the high finish coat varnish VOC volatilizations of aqueous polyurethane of the present invention are few, protect environmental and human health impacts.
Above example is used for illustrative purposes only rather than limitation of the present invention, the technology people in relation to technical field
Member, without departing from the spirit and scope of the present invention, can also make various transformation or modification, therefore all equivalent
Technical solution should also belong to scope of the invention, should be limited by each claim.
Claims (8)
1. a kind of high finish coat varnish of aqueous polyurethane, which is characterized in that including following components and its parts by weight：
2. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the curing agent is isocyanates
Curing agent.
3. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the filler be selected from talcum powder,
At least one of mica powder, silica flour.
4. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the coupling agent is to aoxidize poly- second
Alkene wax.
5. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the thickener is aqueous association
Type polyurethane thickener.
6. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the auxiliary agent include antifoaming agent,
At least one of levelling agent, dispersant.
7. a kind of high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that the hydroxy acryl acid resin
In hydroxyl account for the hydroxy acryl acid resin mass percent be 4.1%.
8. a kind of preparation method of the high finish coat varnish of aqueous polyurethane as described in claim 1, which is characterized in that including following step
Suddenly：
Step 1：Prepare raw material according to following components and parts by weight：
Step 2：By in the step 1 hydroxy acryl acid resin, water, coupling agent, isopropanol, filler, thickener and help
Agent mixes, high-speed stirred 20-30min；
Step 3：Curing agent in the step 1 is added in the product after the step 2 stirring, high-speed stirred 20-
30min, then stand 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810635419.2A CN108707408A (en) | 2018-06-20 | 2018-06-20 | A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810635419.2A CN108707408A (en) | 2018-06-20 | 2018-06-20 | A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108707408A true CN108707408A (en) | 2018-10-26 |
Family
ID=63872915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810635419.2A Pending CN108707408A (en) | 2018-06-20 | 2018-06-20 | A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108707408A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627720A (en) * | 2012-02-17 | 2012-08-08 | 汤汉良 | Normal-temperature quick-drying aqueous hydroxy acrylic resin and its preparation method and application |
| CN104559718A (en) * | 2014-12-24 | 2015-04-29 | 上海三恩化工有限公司 | Water-based automobile finish as well as preparation and usage methods thereof |
| CN106243965A (en) * | 2016-08-26 | 2016-12-21 | 太仓市美航涂料有限公司 | A kind of glass baseplate water paint and preparation method thereof |
| CN106479343A (en) * | 2016-12-02 | 2017-03-08 | 陕西环珂生物科技有限公司 | A kind of preparation method of water paint |
| CN107090231A (en) * | 2017-06-19 | 2017-08-25 | 沈阳美星科技发展有限公司 | A kind of application of imitative ice and snow road in driving school trains |
-
2018
- 2018-06-20 CN CN201810635419.2A patent/CN108707408A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627720A (en) * | 2012-02-17 | 2012-08-08 | 汤汉良 | Normal-temperature quick-drying aqueous hydroxy acrylic resin and its preparation method and application |
| CN104559718A (en) * | 2014-12-24 | 2015-04-29 | 上海三恩化工有限公司 | Water-based automobile finish as well as preparation and usage methods thereof |
| CN106243965A (en) * | 2016-08-26 | 2016-12-21 | 太仓市美航涂料有限公司 | A kind of glass baseplate water paint and preparation method thereof |
| CN106479343A (en) * | 2016-12-02 | 2017-03-08 | 陕西环珂生物科技有限公司 | A kind of preparation method of water paint |
| CN107090231A (en) * | 2017-06-19 | 2017-08-25 | 沈阳美星科技发展有限公司 | A kind of application of imitative ice and snow road in driving school trains |
Non-Patent Citations (4)
| Title |
|---|
| 卢少忠: "《建筑涂料工程性能·生产·施工》", 31 August 2007, 中国建材工业出版社 * |
| 李国莱等: "《重防腐涂料》", 30 September 1999, 化学工业出版社 * |
| 王锡娇: "《涂料与颜料标准应用手册 上册》", 30 April 2005, 军事谊文出版社 * |
| 耿耀宗: "《新型建筑涂料的生产与施工》", 31 January 1996, 河北科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107365549A (en) | A kind of aqueous one-component orange-peel paint and preparation method thereof | |
| CN102719181B (en) | Priming paint with absorption resistance, preparation method and application | |
| CN105505165A (en) | Scratch-resistant double-component waterborne glossy varnish and preparation method thereof | |
| US20190218417A1 (en) | Waterborne amino baking varnish and method for preparing the same | |
| CN103497604A (en) | High-fullness automobile exterior trimming varnish and preparation method thereof | |
| CN102493198A (en) | Bright aqueous polyurethane surface finishing agent for synthetic leather and preparation method thereof | |
| CN105505167A (en) | Waterborne bi-component bright white finish and application thereof | |
| CN105155275A (en) | Waterborne ultra-misty ultra-black velvet-feel treating agent used for synthetic leather | |
| CN106010198A (en) | Water-borne children toy varnish and preparation method thereof | |
| CN104610863A (en) | Single-component and double-component compound water-based wood top-coat paint and preparation method thereof | |
| CN106398482A (en) | Low-temperature curing hammer tone powder coating and preparation method thereof | |
| CN108795236A (en) | A kind of superpower anti-corrosion function aqueous double-component epoxy orange-peel paint and preparation method thereof convenient for application | |
| CN106928822A (en) | Aobvious line paint of a kind of woodenware and its preparation method and application | |
| CN107177299A (en) | Aqueous middle painting coating composition for the vehicles and preparation method thereof | |
| CN108948952A (en) | A kind of solvent-free color sand Self-leveling finishing coat and preparation method thereof | |
| CN106675399A (en) | Moisture curable crylic acid modified polysiloxane coating and preparation method thereof | |
| CN114163887A (en) | Environment-friendly single-component floor paint and preparation method thereof | |
| CN109181446B (en) | Roller finishing hammer effect water-based transparent coating and preparation method and application thereof | |
| CN105442323A (en) | Water-based polishing treatment agent for synthetic leather and preparation method of agent | |
| CN108707408A (en) | A kind of high finish coat varnish of aqueous polyurethane and preparation method thereof | |
| CN109867998A (en) | A kind of high-performance elastic poly-putty base and preparation method thereof | |
| CN105238264B (en) | A kind of clear varnish of spot-resistant and preparation method thereof | |
| CN104032578A (en) | Waterborne oily leather treatment agent for synthetic leather and preparation method of leather treatment agent | |
| CN104788997B (en) | Modified oxide, powdery paints and its preparation method and application | |
| CN107286756A (en) | A kind of low temperature resistant corrosion-resistant epoxy paint and preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181026 |