CN108707383A - It is a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof - Google Patents
It is a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof Download PDFInfo
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- CN108707383A CN108707383A CN201810642878.3A CN201810642878A CN108707383A CN 108707383 A CN108707383 A CN 108707383A CN 201810642878 A CN201810642878 A CN 201810642878A CN 108707383 A CN108707383 A CN 108707383A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Abstract
It is antibacterial except formaldehyde interior wall coating that the invention discloses one kind, it is made of the raw material of following weight parts：Silicone acrylic emulsion 110-130, Isooctyl acrylate monomer 20-24, initiator 0.6-0.7, sorbitan monooleate 1-2, N hydroxymethyl acrylamide 0.8-1, scolecite 10-16, calcium propionate 2-4, methylisothiazolinone 1-2, abienol 3-4, barium stearate 1-2, cyanuric acid zinc 0.1-0.3, ethoxylated alkyl ammonium sulfate 1-2, the present invention is also added into methylisothiazolinone, effectively raise the antibacterial antiseptic property of finished product coating, the coatings of the present invention contain micro, can play certain erasure effect.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof.
Background technology
The current indoor finishing due to having used a variety of artificial materials, thus there is the pollution such as formaldehyde, toluene and be harmful to
Gas is widely present, this produces serious harm to people's health.Material for air purification mainly passes through physics at present
The technologies such as absorption, chemical method, catalysis remove nuisance；
Formaldehyde is a kind of gas flammable, colourless and excitatory under normal conditions.Soluble easily in water, alcohol and ether.Formaldehyde pair
Eyes, respiratory tract and skin have intense irritation.Formaldehyde Exposed steam causes conjunctivitis, keratitis, rhinitis, bronchitis etc..
Laryngospasm, glottic oedema, pneumonia, pulmonary edema occur for emphasis.There are primary sexual stimulus and sensitization to skin.Formaldehyde has simultaneously
Mutagenicity and carcinogenicity.Therefore, it in the new house of finishing, carries out removing formaldehyde, reduces harm of the formaldehyde for people；
Constantly enhance with the environmental consciousness of people, it is also higher and higher to the safety and environmental protection performance requirement of furniture application, especially
It is interior wall application between be related to people's lives environment, and traditional interior wall coating only serves protection wall, U.S. mostly
The effect of sight, some also contain therefore how volatile poisonous and harmful substances further improve interior wall quality, provide a kind of ring
It protects, multi-functional coating just seems very necessary.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide it is a kind of it is antibacterial except formaldehyde interior wall coating and
Preparation method.
To achieve the above object, the present invention uses following technical scheme：
A kind of antibacterial except formaldehyde interior wall coating, it is made of the raw material of following weight parts：
Silicone acrylic emulsion 110-130, Isooctyl acrylate monomer 20-24, initiator 0.6-0.7, sorbitan monooleate 1-2, N-
Hydroxymethyl acrylamide 0.8-1, scolecite 10-16, calcium propionate 2-4, methylisothiazolinone 1-2, abienol 3-4, stearic acid
Barium 1-2, cyanuric acid zinc 0.1-0.3, ethoxylated alkyl ammonium sulfate 1-2.
The initiator is cumyl peroxide.
A kind of antibacterial preparation method except formaldehyde interior wall coating, includes the following steps：
(1) scolecite is taken, is calcined 1-2 hours at 700-750 DEG C, is cooled to room temperature, wears into fine powder, it is mixed with calcium propionate
It closes, is added in the deionized water of 10-15 times of mixture weight, stirs evenly, it is 60-65 DEG C to increase temperature, and stearic acid is added
Barium, insulated and stirred 1-2 hours, obtains Zeolite dispersion；
(2) initiator is taken, is added in the absolute ethyl alcohol of 10-15 times of its weight, stirs evenly；
(3) N hydroxymethyl acrylamide is taken, is added in the deionized water of 20-30 times of its weight, stirs evenly, mountain is added
The smooth monoleate of pears, obtains amide dispersion liquid；
(4) above-mentioned Zeolite dispersion, the mixing of amide dispersion liquid are taken, is stirred evenly, Isooctyl acrylate monomer is added, stirring is equal
It is even, it is sent in reaction kettle, is passed through nitrogen, it is 65-70 DEG C to adjust temperature of reaction kettle, and above-mentioned initiator alcoholic solution is added, and is kept the temperature
Stirring 3-4 hours, discharging cooling, obtains Zeolite modifying polyester liquid；
(5) methylisothiazolinone is taken, is added in the absolute ethyl alcohol of 6-8 times of its weight, stirs evenly, cyanuric acid is added
Zinc, it is 50-60 DEG C to increase temperature, and insulated and stirred 10-20 minutes obtains antibacterial alcoholic solution；
(6) above-mentioned Zeolite modifying polyester liquid, the mixing of antibacterial alcoholic solution are taken, is stirred evenly, it is 60-70 DEG C to increase temperature,
Insulated and stirred 20-30 minutes, is distilled off ethyl alcohol, obtains antibacterial polyester liquid；
(7) above-mentioned antibacterial polyester liquid is taken, is mixed with remaining each raw material, ultrasonic 1-2 hours to get described antibacterial except formaldehyde
Interior wall coating.
Advantages of the present invention：
Scolecite is carried out activation process by the present invention first, is subsequently dispersed in N hydroxymethyl acrylamide solution, then with
This dispersion liquid is reaction dissolvent, using Isooctyl acrylate monomer as monomer, polymerize under initiator effect, obtains the poly- of scolecite doping
Ester solution realizes the dispersion compatibility of scolecite in the polyester by the polymerisation, and the mechanics for improving finished product coating is steady
Qualitative, the present invention is also added into methylisothiazolinone, effectively raises the antibacterial antiseptic property of finished product coating, of the invention
Coatings contain micropore, can play certain adsorption effect, have the auxiliaring effect of any for purification air.
Specific implementation mode
Embodiment 1
A kind of antibacterial except formaldehyde interior wall coating, it is made of the raw material of following weight parts：
Silicone acrylic emulsion 110, Isooctyl acrylate monomer 20, initiator 0.6, sorbitan monooleate 1, N hydroxymethyl acrylamide
0.8, scolecite 10, calcium propionate 2, methylisothiazolinone 1, abienol 3, barium stearate 1, cyanuric acid zinc 0.1, ethoxylation alkane
Base ammonium sulfate 1.
The initiator is cumyl peroxide.
A kind of antibacterial preparation method except formaldehyde interior wall coating, includes the following steps：
(1) scolecite is taken, is calcined 1 hour at 700 DEG C, is cooled to room temperature, wears into fine powder, mixed with calcium propionate, is added
It into the deionized water of 10 times of mixture weight, stirs evenly, it is 60 DEG C to increase temperature, and barium stearate is added, and insulated and stirred 1 is small
When, obtain Zeolite dispersion；
(2) initiator is taken, is added in the absolute ethyl alcohol of 10 times of its weight, stirs evenly；
(3) N hydroxymethyl acrylamide is taken, is added in the deionized water of 20 times of its weight, stirs evenly, sorb is added
Smooth monoleate obtains amide dispersion liquid；
(4) above-mentioned Zeolite dispersion, the mixing of amide dispersion liquid are taken, is stirred evenly, Isooctyl acrylate monomer is added, stirring is equal
It is even, it is sent in reaction kettle, is passed through nitrogen, it is 65 DEG C to adjust temperature of reaction kettle, and above-mentioned initiator alcoholic solution, insulated and stirred is added
3 hours, discharging cooling obtained Zeolite modifying polyester liquid；
(5) methylisothiazolinone is taken, is added in the absolute ethyl alcohol of 6 times of its weight, stirs evenly, cyanuric acid is added
Zinc, it is 50 DEG C to increase temperature, and insulated and stirred 10 minutes obtains antibacterial alcoholic solution；
(6) above-mentioned Zeolite modifying polyester liquid, the mixing of antibacterial alcoholic solution are taken, is stirred evenly, it is 60 DEG C to increase temperature, heat preservation
Stirring 20 minutes, is distilled off ethyl alcohol, obtains antibacterial polyester liquid；
(7) above-mentioned antibacterial polyester liquid is taken, is mixed with remaining each raw material, ultrasonic 1 hour to get described antibacterial except in formaldehyde
Wall coating.
Embodiment 2
A kind of antibacterial except formaldehyde interior wall coating, it is made of the raw material of following weight parts：
Silicone acrylic emulsion 130, Isooctyl acrylate monomer 24, initiator 0.7, sorbitan monooleate 2, N hydroxymethyl acrylamide
1, scolecite 16, calcium propionate 4, methylisothiazolinone 2, abienol 4, barium stearate 2, cyanuric acid zinc 0.3, ethoxylated alkyl
Ammonium sulfate 2.
The initiator is cumyl peroxide.
A kind of antibacterial preparation method except formaldehyde interior wall coating, includes the following steps：
(1) scolecite is taken, is calcined 2 hours at 750 DEG C, is cooled to room temperature, wears into fine powder, mixed with calcium propionate, is added
It into the deionized water of 15 times of mixture weight, stirs evenly, it is 65 DEG C to increase temperature, and barium stearate is added, and insulated and stirred 2 is small
When, obtain Zeolite dispersion；
(2) initiator is taken, is added in the absolute ethyl alcohol of 15 times of its weight, stirs evenly；
(3) N hydroxymethyl acrylamide is taken, is added in the deionized water of 30 times of its weight, stirs evenly, sorb is added
Smooth monoleate obtains amide dispersion liquid；
(4) above-mentioned Zeolite dispersion, the mixing of amide dispersion liquid are taken, is stirred evenly, Isooctyl acrylate monomer is added, stirring is equal
It is even, it is sent in reaction kettle, is passed through nitrogen, it is 70 DEG C to adjust temperature of reaction kettle, and above-mentioned initiator alcoholic solution, insulated and stirred is added
4 hours, discharging cooling obtained Zeolite modifying polyester liquid；
(5) methylisothiazolinone is taken, is added in the absolute ethyl alcohol of 8 times of its weight, stirs evenly, cyanuric acid is added
Zinc, it is 60 DEG C to increase temperature, and insulated and stirred 20 minutes obtains antibacterial alcoholic solution；
(6) above-mentioned Zeolite modifying polyester liquid, the mixing of antibacterial alcoholic solution are taken, is stirred evenly, it is 60-70 DEG C to increase temperature,
Insulated and stirred 30 minutes, is distilled off ethyl alcohol, obtains antibacterial polyester liquid；
(7) above-mentioned antibacterial polyester liquid is taken, is mixed with remaining each raw material, ultrasonic 1-2 hours to get described antibacterial except formaldehyde
Interior wall coating.
Performance test：
To same newly-decorated 2 experiment houses, each house is 50 ㎡, initially measures a concentration of of formaldehyde
2.10mg/m3, benzene a concentration of 1.47mg/m3, carbon monoxide a concentration of 35.4mg/m3, sulfur dioxide it is a concentration of
1.13mg/m3, ammonia a concentration of 0.68mg/m3, coating and the commercial coating of the present invention is respectively coated, sealing carries out air after 2 days
Quality testing：
The experiment house of coating coating of the present invention：
A concentration of 0.03mg/m of formaldehyde3, benzene a concentration of 0.06mg/m3, carbon monoxide a concentration of 4.1mg/m3, two
A concentration of 0.10mg/m of sulfur oxide3, ammonia a concentration of 0.03mg/m3。
Coat the experiment house of commercial coating：
A concentration of 1.03mg/m of formaldehyde3, benzene a concentration of 1.09mg/m3, carbon monoxide a concentration of 27.1mg/m3, two
A concentration of 1.00mg/m of sulfur oxide3, ammonia a concentration of 0.57mg/m3。
Claims (3)
1. a kind of antibacterial except formaldehyde interior wall coating, which is characterized in that it is made of the raw material of following weight parts：
Silicone acrylic emulsion 110-130, Isooctyl acrylate monomer 20-24, initiator 0.6-0.7, sorbitan monooleate 1-2, N- hydroxyl first
Base acrylamide 0.8-1, scolecite 10-16, calcium propionate 2-4, methylisothiazolinone 1-2, abienol 3-4, barium stearate 1-
2, cyanuric acid zinc 0.1-0.3, ethoxylated alkyl ammonium sulfate 1-2.
2. one kind according to claim 1 is antibacterial to remove formaldehyde interior wall coating, which is characterized in that the initiator is peroxide
Change diisopropylbenzene (DIPB).
3. a kind of antibacterial preparation method except formaldehyde interior wall coating as described in claim 1, which is characterized in that including following step
Suddenly：
(1) scolecite is taken, is calcined 1-2 hours at 700-750 DEG C, is cooled to room temperature, wears into fine powder, mixed with calcium propionate, added
Enter into the deionized water of 10-15 times of mixture weight, stir evenly, it is 60-65 DEG C to increase temperature, and barium stearate is added, and is protected
Temperature stirring 1-2 hours, obtains Zeolite dispersion；
(2) initiator is taken, is added in the absolute ethyl alcohol of 10-15 times of its weight, stirs evenly；
(3) N hydroxymethyl acrylamide is taken, is added in the deionized water of 20-30 times of its weight, stirs evenly, it is smooth that sorb is added
Monoleate obtains amide dispersion liquid；
(4) above-mentioned Zeolite dispersion, the mixing of amide dispersion liquid are taken, stirs evenly, Isooctyl acrylate monomer is added, stirs evenly, send
Enter into reaction kettle, be passed through nitrogen, it is 65-70 DEG C to adjust temperature of reaction kettle, and above-mentioned initiator alcoholic solution, insulated and stirred 3- is added
4 hours, discharging cooling obtained Zeolite modifying polyester liquid；
(5) methylisothiazolinone is taken, is added in the absolute ethyl alcohol of 6-8 times of its weight, stirs evenly, cyanuric acid zinc is added,
It is 50-60 DEG C to increase temperature, and insulated and stirred 10-20 minutes obtains antibacterial alcoholic solution；
(6) above-mentioned Zeolite modifying polyester liquid, the mixing of antibacterial alcoholic solution are taken, is stirred evenly, it is 60-70 DEG C to increase temperature, heat preservation
Stirring 20-30 minutes, is distilled off ethyl alcohol, obtains antibacterial polyester liquid；
(7) above-mentioned antibacterial polyester liquid is taken, is mixed with remaining each raw material, ultrasonic 1-2 hours to get described antibacterial except formaldehyde interior wall
Coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810642878.3A CN108707383A (en) | 2018-06-21 | 2018-06-21 | It is a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810642878.3A CN108707383A (en) | 2018-06-21 | 2018-06-21 | It is a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108707383A true CN108707383A (en) | 2018-10-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810642878.3A Pending CN108707383A (en) | 2018-06-21 | 2018-06-21 | It is a kind of antibacterial except formaldehyde interior wall coating and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109943174A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of decorative exterior wall water-water coating and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059679A (en) * | 2013-01-30 | 2013-04-24 | 中国地质大学（武汉） | Odorless anti-formaldehyde environment-friendly internal wall latex paint and preparation method thereof |
| CN106947348A (en) * | 2017-04-06 | 2017-07-14 | 合肥欧克斯新型建材有限公司 | A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof |
| CN107434946A (en) * | 2017-09-08 | 2017-12-05 | 苏州聚慧邦新材料科技有限公司 | A kind of preparation method of antibacterial organosol paint |
| CN107502114A (en) * | 2017-09-05 | 2017-12-22 | 霍邱金木鱼农业科技有限公司 | A kind of water paint for internal walls for formaldehyde absorbing and preparation method thereof |
| CN107537451A (en) * | 2017-09-05 | 2018-01-05 | 霍邱金木鱼农业科技有限公司 | A kind of porous zeolite material for air purification and preparation method thereof |
| CN107892850A (en) * | 2017-11-24 | 2018-04-10 | 广东瑞安杰智能科技有限公司 | A kind of nano-far-infrared silicone acrylic emulsion interior wall coating |
-
2018
- 2018-06-21 CN CN201810642878.3A patent/CN108707383A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059679A (en) * | 2013-01-30 | 2013-04-24 | 中国地质大学（武汉） | Odorless anti-formaldehyde environment-friendly internal wall latex paint and preparation method thereof |
| CN106947348A (en) * | 2017-04-06 | 2017-07-14 | 合肥欧克斯新型建材有限公司 | A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof |
| CN107502114A (en) * | 2017-09-05 | 2017-12-22 | 霍邱金木鱼农业科技有限公司 | A kind of water paint for internal walls for formaldehyde absorbing and preparation method thereof |
| CN107537451A (en) * | 2017-09-05 | 2018-01-05 | 霍邱金木鱼农业科技有限公司 | A kind of porous zeolite material for air purification and preparation method thereof |
| CN107434946A (en) * | 2017-09-08 | 2017-12-05 | 苏州聚慧邦新材料科技有限公司 | A kind of preparation method of antibacterial organosol paint |
| CN107892850A (en) * | 2017-11-24 | 2018-04-10 | 广东瑞安杰智能科技有限公司 | A kind of nano-far-infrared silicone acrylic emulsion interior wall coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109943174A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of decorative exterior wall water-water coating and preparation method thereof |
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