CN108706742A - A kind of Anammox type wet land system for high nitrogen sewage disposal - Google Patents
A kind of Anammox type wet land system for high nitrogen sewage disposal Download PDFInfo
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- CN108706742A CN108706742A CN201810897163.2A CN201810897163A CN108706742A CN 108706742 A CN108706742 A CN 108706742A CN 201810897163 A CN201810897163 A CN 201810897163A CN 108706742 A CN108706742 A CN 108706742A
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- wet land
- high nitrogen
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- sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
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- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
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Abstract
The invention discloses a kind of Anammox type wet land systems for high nitrogen sewage disposal, it is distributed rationally by filler and cultivates structure strengthened denitrification wet land system for high nitrogen sewage disposal with the anaerobic ammonia oxidation microbiological stage, realize that the stabilization of nitrogen is handled with low-carbon in high nitrogen sewage.System of the present invention includes artificial swamp pond body, seed sludge and wet land filler, the wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wet land filler of three's arbitrary proportion mixing, and standard modular wet land filler is made using suppressing or firing mode.Anaerobic ammonia oxidation microbiological carries out stage culture by controlling hydraulic loading with culture solution.Implementing process of the present invention is simple, of low cost, can large-scale industrialization application.
Description
Technical field
The present invention relates to sewage disposal systems, wet more particularly to a kind of Anammox type for high nitrogen sewage disposal
Ground system.
Background technology
With China's rapid economic development, agricultural or food production sewage yield also increasingly increase, while such sewage
There is also the higher features of nitrogen content.By taking livestock and poultry cultivation sewage as an example, important composition of the livestock and poultry breeding industry as China's agricultural
The discharge capacity of part, nitrogen is 102.48 ten thousand tons, accounts for the 21.7% of the nitrogen discharged total amount in the whole nation, and total nitrogen contains in livestock and poultry cultivation sewage
Amount is about 400-1500 mg/L.Therefore, the Important Problems as the Chinese government and social concerns high nitrogen sewage are effectively treated.
In general, such sewage disposal mainly uses biological treatment, nitrogen is realized using aerobic nitrifying process and anaerobic denitrifying process
The removal of element, but since traditional anaerobic denitrifying process needs a large amount of carbon source materials, to cause, processing cost is higher to ask
Topic.For this present situation, Anammox treatment process increasingly mature in recent years to solve the problems, such as that this provides new approach, but
Be due to anaerobic ammonia oxidation microbiological there are growth rates slowly, environmental requirement is higher and the spies such as capacity of resisting impact load is weaker
Property, traditional bioreactor stability during handling this high nitrogen sewage is weaker, and reaction system operation is complex,
How to build a kind of low-carbon, stabilization and simple Anaerobic ammonium oxidation system becomes the focal point of high nitrogen sewage treatment field.
Artificial swamp is a kind of ecological wastewater processing technique to grow up the 1970s, it be by manually building and
The ground similar with marshland for controlling operation, by sewage, sludge controlled dosing to the wetland through manually building, sewage
With sludge in a certain direction flow during, mainly utilize soil, artificial dielectric, plant, the physics of microorganism, chemistry,
The triple synergistic effects of biology, a kind of technology that sewage, sludge are handled.Its mechanism of action include absorption, be detained, filtering,
Redox, precipitation, microorganism decomposition, conversion, plant masking, residue accumulated, water transpiration and Nutrient Absorption and all kinds of dynamic
The effect of object.Artificial swamp unit is made of plant, microorganism, filler and animal, and each constituent plays different works respectively
With, and mutually act synergistically so that entire Constructed Wetland Ecology System equilbrium running plays good purification function.At this
Wet land filler plays decisive skeleton function in a little units, and wet land filler first has the works such as filtering, precipitation, absorption and flocculation
With the suspended matter in water body being effectively removed, secondly wet land filler is that the growth of plant and microorganism and oxygen are transmitted and provided
Necessary requirement.Currently, being directed to different sewage type, many kinds of substance has been chosen for wet land filler, for example, soil, volcanic rock,
Cinder, red soil, brick, extra large oyster shell, zeolite, haydite, cobble etc..Since there are hydraulic detention time is longer and anti-impact for wet land system
The stronger characteristic of load-bearing capacity is hit, therefore the mechanism is can guarantee as the effect carrier of anaerobic ammonia oxidation microbiological
Stabilization effect, and simplify process operation program.
Invention content
The technical problem to be solved in the present invention is to provide a kind of Anammox type wetland systems for high nitrogen sewage disposal
System.
In order to achieve the above object, a kind of Anammox type wet land system for high nitrogen sewage disposal of the invention, the system
System includes artificial swamp pond body, seed sludge and wet land filler, and the high nitrogen COD of sewage content is 100-1000mg/L, ammonia nitrogen
Content is 50-800mg/L, total nitrogen 50-800mg/L, total phosphorus content 5-40mg/L.
The wherein described artificial swamp pond body is the mixed structure of brick, and pond body length-width ratio is 10:1-5:1.
The wherein described wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wetland of three's arbitrary proportion mixing
Filler.
The wherein described seed sludge is anaerobic ammonium oxidation sludge, the cotton-shaped activated sludge of sewage treatment plant, granule sludge or three
The sludge of person's arbitrary proportion.
The structure and operation method of a kind of Anammox type wet land system for high nitrogen sewage disposal, including following step
Suddenly:
(1)Using the wetland pond body of the mixed structure of brick as running gear, carried out with the intermittent or continuous flow method of operation, pool bottom slope
Degree is set as 2%-5%, and water inlet setting is 5-30cm, water outlet setting apart from bottom of pond height in pond body front bottom end, water inlet
In pond body upper rear end, water outlet is 10-30cm apart from pond body upper end level;
(2)The standard modular wet land filler that wet land filler is gravel, zeolite, sea oyster shell or three's arbitrary proportion mix, gravel,
Porosity is set as 20%-80% when zeolite and extra large oyster shell are as filler, and packing material size size is 1-10 cm, standard module dampness elimination
Ground filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis, and the porosity of modularization wet land filler is
10%-80%, modularization wet land filler are the penetrating rectangle in both sides, and gravel, zeolite and extra large oyster shells agent particle size are 0.1-
1cm;
(3)After the completion of prepared by standard modular wet land filler, it is arranged in wetland pond body according to its permeability direction, standard
Modularization wet land filler permeability direction is parallel or vertical with water (flow) direction;
(4)After wet land system is built, dipping pretreatment need to be carried out 1-10 days with culture solution, the culture solution is river
Water, lake water, sewage or three's arbitrary proportion mixed aqueous solutions, iron ion content need to be added to 1-10mg/L in the solution;In advance
After processing, wet land system can be used for high nitrogen sewage disposal, and the control of artificial wet land system hydraulic loading is 1-50cm/ days, and waterpower is stopped
It is 2-10 days to stay time control.
Specific implementation mode
With reference to embodiments, the technical characteristic above-mentioned to the present invention is described in more detail.
A kind of apllied Anammox type wet land system for high nitrogen sewage disposal of this patent can be used for it is various can
The purified treatment of biochemical high nitrogen sewage(Including cultivating biogas slurry and food processing sewage etc.), can be used for effectively removing organic in sewage
Object, nitrogen and phosphorous nutrient, heavy metal, persistent organism(Such as antibiotic and estrogen)And pathogenic microorganisms.This system is suitble to
The COD contents of treated sewage are 100-2000mg/L, ammonia-nitrogen content 50-800mg/L, total nitrogen 50-800mg/L, and total phosphorus contains
Amount is 5-40mg/L.
This system starts with operation using the wetland pond body of the mixed structure of brick as running gear, and wetland pond body length-width ratio is 10:1-
5:1, wetland pond body height is 0.5-2m, and it is 2%-5% that wetland, which reacts pool bottom gradient, and pool bottom passes through permeation-preventing film or soil property
Compacting carries out permeation-proof processing.
Cloth pond can be arranged in wetland front end, arrange suspended matter Screening Network in cloth pond, coupling type mode is used to be fixed on
In the pond body of cloth pond periphery, when the water passing rate of suspended matter Screening Network reduces 20%-60%, it can be disassembled and be cleared up.
Wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wet land filler of three's arbitrary proportion mixing, gravel
Porosity is set as 20%-80% when stone, zeolite and extra large oyster shell are as filler, and packing material size size is 1-10cm.Standard modular
Wet land filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis, and the porosity of modularization wet land filler is
10%-80%, modularization wet land filler are the penetrating cuboid in both sides, and gravel, zeolite and extra large oyster shells agent particle size are 0.1-
1cm.Modularization wet land filler, which prepares mold, a column solid structure, filler prepare raw material can it is mixed therebetween, to work as
Realize that there is ideal porosity and hole distributed effect in modularization filler after demoulding.Standard modular filler after demoulding is put
Set and conserved in the place of aeration-drying, curing field temperature be 10-40 DEG C, humidity 10-50%, curing time 1-28
It.Wet land system build after, carries out dipping pretreatment 1-10 days with culture solution, the culture solution be river water, lake water,
Sewage or three's arbitrary proportion mixed aqueous solutions, iron ion content need to be added to 1-10mg/L in the solution;After pretreatment, mould
Block filler wet land system can be used for high nitrogen sewage disposal, and the control of artificial wet land system hydraulic loading is 1-50cm/ days, and waterpower is stopped
It is 2-10 days to stay time control.
Addition seed sludge consolidation system starts speed inside wetland, and seed sludge can be wet mud form or dewatered sludge
Form, seed sludge type can be anaerobic ammonium oxidation sludge, sludge sewage, granule sludge or three's arbitrary proportion
Sludge, sludge seeding amount is calculated as 0.1-10g/m with dry weight2。
Wet land filler layer top generates if any weeds and need to clear up in time without planting wetland plant.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
It encloses and is defined, under the premise of not departing from design spirit of the present invention, technical side of the those of ordinary skill in the art to the present invention
The various modifications and improvement that case is made should all be fallen into the protection domain of claims of the present invention determination.
Claims (3)
1. a kind of Anammox type wet land system for high nitrogen sewage disposal, it is characterised in that:The system comprises artificial
Wetland pond body, seed sludge and wet land filler, the wet land filler are gravel, zeolite, extra large oyster shell or the mixing of three's arbitrary proportion
Standard modular wet land filler, porosity is set as 20%-80%, packing material size when gravel, zeolite and extra large oyster shell are as filler
Size is 1-10cm;Standard modular wet land filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis,
The porosity of modularization wet land filler is 10%-80%, and modularization wet land filler is the penetrating cuboid in both sides, gravel, zeolite and
Extra large oyster shells agent particle size be 0.1-1cm, the seed sludge be anaerobic ammonium oxidation sludge, sludge sewage,
The sludge of granule sludge or three's arbitrary proportion, sludge seeding amount dry weight are 0.1-10g/m2。
2. a kind of Anammox type wet land system for high nitrogen sewage disposal according to claim 1, feature exist
In:Using the combined sewage of the water outlet of high nitrogen sewerage short-cut denitrification processing system and high nitrogen sewage as wet land system treated sewage, when
When BOD content is 10-500 mg/L in high nitrogen sewage, the two mixed proportion is 1/0.1-1/1, after mixing in sewage
Ammonia nitrogen/nitrite nitrogen content ratio control is 1/0.8-1/1.8;When BOD content is more than 500mg/L in high nitrogen sewage
When, the two mixed proportion is 1/0.1-1/0.8, and ammonia nitrogen in sewage/nitrite nitrogen content ratio control is 1/1-1/2 after mixing.
3. a kind of Anammox type wetland system for high nitrogen sewage disposal according to any one of claim 1-2
System, it is characterised in that:It is opened with wet land system by controlling anaerobic ammonia oxidation microbiological culture in hydraulic loading progress wet land system
Dynamic, the control of the 1-10 days wet land system startup stages hydraulic loading is 0.5-5cm/ days, and hydraulic loading control in the 5-20 days is 1-
10cm/ days, hydraulic loading control in the 10-60 days was 2-10 cm/ days, and hydraulic loading control in the 15-90 days is 3-20cm/ days, the
Hydraulic loading control in 20-120 days is 4-30cm/ days;System can be used for practical high nitrogen sewage disposal process after starting, practical
High nitrogen sewage disposal stage technique hydraulic loading control is 1-50cm/ days.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113321369A (en) * | 2021-02-08 | 2021-08-31 | 重庆大学 | Tidal flow artificial wetland capable of simultaneously removing nitrogen and phosphorus |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102464406A (en) * | 2010-11-09 | 2012-05-23 | 中国科学院生态环境研究中心 | Method for realizing denitrification of anaerobic ammonium oxidation by utilizing constructed wetland |
CN107487856A (en) * | 2017-09-22 | 2017-12-19 | 中国科学院城市环境研究所 | A kind of artificial wet land system for handling mariculture sewage |
CN107720967A (en) * | 2017-10-19 | 2018-02-23 | 中国科学院城市环境研究所 | A kind of modularization filler wet land system for livestock and poultry cultivation sewage disposal |
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- 2018-08-08 CN CN201810897163.2A patent/CN108706742A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102464406A (en) * | 2010-11-09 | 2012-05-23 | 中国科学院生态环境研究中心 | Method for realizing denitrification of anaerobic ammonium oxidation by utilizing constructed wetland |
CN107487856A (en) * | 2017-09-22 | 2017-12-19 | 中国科学院城市环境研究所 | A kind of artificial wet land system for handling mariculture sewage |
CN107720967A (en) * | 2017-10-19 | 2018-02-23 | 中国科学院城市环境研究所 | A kind of modularization filler wet land system for livestock and poultry cultivation sewage disposal |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113321369A (en) * | 2021-02-08 | 2021-08-31 | 重庆大学 | Tidal flow artificial wetland capable of simultaneously removing nitrogen and phosphorus |
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