CN108706742A - A kind of Anammox type wet land system for high nitrogen sewage disposal - Google Patents

A kind of Anammox type wet land system for high nitrogen sewage disposal Download PDF

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Publication number
CN108706742A
CN108706742A CN201810897163.2A CN201810897163A CN108706742A CN 108706742 A CN108706742 A CN 108706742A CN 201810897163 A CN201810897163 A CN 201810897163A CN 108706742 A CN108706742 A CN 108706742A
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China
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wet land
high nitrogen
days
filler
sewage
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CN201810897163.2A
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Chinese (zh)
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刘琳
李�杰
刘超翔
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Institute of Urban Environment of CAS
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Institute of Urban Environment of CAS
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Engineering & Computer Science (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses a kind of Anammox type wet land systems for high nitrogen sewage disposal, it is distributed rationally by filler and cultivates structure strengthened denitrification wet land system for high nitrogen sewage disposal with the anaerobic ammonia oxidation microbiological stage, realize that the stabilization of nitrogen is handled with low-carbon in high nitrogen sewage.System of the present invention includes artificial swamp pond body, seed sludge and wet land filler, the wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wet land filler of three's arbitrary proportion mixing, and standard modular wet land filler is made using suppressing or firing mode.Anaerobic ammonia oxidation microbiological carries out stage culture by controlling hydraulic loading with culture solution.Implementing process of the present invention is simple, of low cost, can large-scale industrialization application.

Description

A kind of Anammox type wet land system for high nitrogen sewage disposal
Technical field
The present invention relates to sewage disposal systems, wet more particularly to a kind of Anammox type for high nitrogen sewage disposal Ground system.
Background technology
With China's rapid economic development, agricultural or food production sewage yield also increasingly increase, while such sewage There is also the higher features of nitrogen content.By taking livestock and poultry cultivation sewage as an example, important composition of the livestock and poultry breeding industry as China's agricultural The discharge capacity of part, nitrogen is 102.48 ten thousand tons, accounts for the 21.7% of the nitrogen discharged total amount in the whole nation, and total nitrogen contains in livestock and poultry cultivation sewage Amount is about 400-1500 mg/L.Therefore, the Important Problems as the Chinese government and social concerns high nitrogen sewage are effectively treated. In general, such sewage disposal mainly uses biological treatment, nitrogen is realized using aerobic nitrifying process and anaerobic denitrifying process The removal of element, but since traditional anaerobic denitrifying process needs a large amount of carbon source materials, to cause, processing cost is higher to ask Topic.For this present situation, Anammox treatment process increasingly mature in recent years to solve the problems, such as that this provides new approach, but Be due to anaerobic ammonia oxidation microbiological there are growth rates slowly, environmental requirement is higher and the spies such as capacity of resisting impact load is weaker Property, traditional bioreactor stability during handling this high nitrogen sewage is weaker, and reaction system operation is complex, How to build a kind of low-carbon, stabilization and simple Anaerobic ammonium oxidation system becomes the focal point of high nitrogen sewage treatment field.
Artificial swamp is a kind of ecological wastewater processing technique to grow up the 1970s, it be by manually building and The ground similar with marshland for controlling operation, by sewage, sludge controlled dosing to the wetland through manually building, sewage With sludge in a certain direction flow during, mainly utilize soil, artificial dielectric, plant, the physics of microorganism, chemistry, The triple synergistic effects of biology, a kind of technology that sewage, sludge are handled.Its mechanism of action include absorption, be detained, filtering, Redox, precipitation, microorganism decomposition, conversion, plant masking, residue accumulated, water transpiration and Nutrient Absorption and all kinds of dynamic The effect of object.Artificial swamp unit is made of plant, microorganism, filler and animal, and each constituent plays different works respectively With, and mutually act synergistically so that entire Constructed Wetland Ecology System equilbrium running plays good purification function.At this Wet land filler plays decisive skeleton function in a little units, and wet land filler first has the works such as filtering, precipitation, absorption and flocculation With the suspended matter in water body being effectively removed, secondly wet land filler is that the growth of plant and microorganism and oxygen are transmitted and provided Necessary requirement.Currently, being directed to different sewage type, many kinds of substance has been chosen for wet land filler, for example, soil, volcanic rock, Cinder, red soil, brick, extra large oyster shell, zeolite, haydite, cobble etc..Since there are hydraulic detention time is longer and anti-impact for wet land system The stronger characteristic of load-bearing capacity is hit, therefore the mechanism is can guarantee as the effect carrier of anaerobic ammonia oxidation microbiological Stabilization effect, and simplify process operation program.
Invention content
The technical problem to be solved in the present invention is to provide a kind of Anammox type wetland systems for high nitrogen sewage disposal System.
In order to achieve the above object, a kind of Anammox type wet land system for high nitrogen sewage disposal of the invention, the system System includes artificial swamp pond body, seed sludge and wet land filler, and the high nitrogen COD of sewage content is 100-1000mg/L, ammonia nitrogen Content is 50-800mg/L, total nitrogen 50-800mg/L, total phosphorus content 5-40mg/L.
The wherein described artificial swamp pond body is the mixed structure of brick, and pond body length-width ratio is 10:1-5:1.
The wherein described wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wetland of three's arbitrary proportion mixing Filler.
The wherein described seed sludge is anaerobic ammonium oxidation sludge, the cotton-shaped activated sludge of sewage treatment plant, granule sludge or three The sludge of person's arbitrary proportion.
The structure and operation method of a kind of Anammox type wet land system for high nitrogen sewage disposal, including following step Suddenly:
(1)Using the wetland pond body of the mixed structure of brick as running gear, carried out with the intermittent or continuous flow method of operation, pool bottom slope Degree is set as 2%-5%, and water inlet setting is 5-30cm, water outlet setting apart from bottom of pond height in pond body front bottom end, water inlet In pond body upper rear end, water outlet is 10-30cm apart from pond body upper end level;
(2)The standard modular wet land filler that wet land filler is gravel, zeolite, sea oyster shell or three's arbitrary proportion mix, gravel, Porosity is set as 20%-80% when zeolite and extra large oyster shell are as filler, and packing material size size is 1-10 cm, standard module dampness elimination Ground filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis, and the porosity of modularization wet land filler is 10%-80%, modularization wet land filler are the penetrating rectangle in both sides, and gravel, zeolite and extra large oyster shells agent particle size are 0.1- 1cm;
(3)After the completion of prepared by standard modular wet land filler, it is arranged in wetland pond body according to its permeability direction, standard Modularization wet land filler permeability direction is parallel or vertical with water (flow) direction;
(4)After wet land system is built, dipping pretreatment need to be carried out 1-10 days with culture solution, the culture solution is river Water, lake water, sewage or three's arbitrary proportion mixed aqueous solutions, iron ion content need to be added to 1-10mg/L in the solution;In advance After processing, wet land system can be used for high nitrogen sewage disposal, and the control of artificial wet land system hydraulic loading is 1-50cm/ days, and waterpower is stopped It is 2-10 days to stay time control.
Specific implementation mode
With reference to embodiments, the technical characteristic above-mentioned to the present invention is described in more detail.
A kind of apllied Anammox type wet land system for high nitrogen sewage disposal of this patent can be used for it is various can The purified treatment of biochemical high nitrogen sewage(Including cultivating biogas slurry and food processing sewage etc.), can be used for effectively removing organic in sewage Object, nitrogen and phosphorous nutrient, heavy metal, persistent organism(Such as antibiotic and estrogen)And pathogenic microorganisms.This system is suitble to The COD contents of treated sewage are 100-2000mg/L, ammonia-nitrogen content 50-800mg/L, total nitrogen 50-800mg/L, and total phosphorus contains Amount is 5-40mg/L.
This system starts with operation using the wetland pond body of the mixed structure of brick as running gear, and wetland pond body length-width ratio is 10:1- 5:1, wetland pond body height is 0.5-2m, and it is 2%-5% that wetland, which reacts pool bottom gradient, and pool bottom passes through permeation-preventing film or soil property Compacting carries out permeation-proof processing.
Cloth pond can be arranged in wetland front end, arrange suspended matter Screening Network in cloth pond, coupling type mode is used to be fixed on In the pond body of cloth pond periphery, when the water passing rate of suspended matter Screening Network reduces 20%-60%, it can be disassembled and be cleared up.
Wet land filler is gravel, zeolite, extra large oyster shell or the standard modular wet land filler of three's arbitrary proportion mixing, gravel Porosity is set as 20%-80% when stone, zeolite and extra large oyster shell are as filler, and packing material size size is 1-10cm.Standard modular Wet land filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis, and the porosity of modularization wet land filler is 10%-80%, modularization wet land filler are the penetrating cuboid in both sides, and gravel, zeolite and extra large oyster shells agent particle size are 0.1- 1cm.Modularization wet land filler, which prepares mold, a column solid structure, filler prepare raw material can it is mixed therebetween, to work as Realize that there is ideal porosity and hole distributed effect in modularization filler after demoulding.Standard modular filler after demoulding is put Set and conserved in the place of aeration-drying, curing field temperature be 10-40 DEG C, humidity 10-50%, curing time 1-28 It.Wet land system build after, carries out dipping pretreatment 1-10 days with culture solution, the culture solution be river water, lake water, Sewage or three's arbitrary proportion mixed aqueous solutions, iron ion content need to be added to 1-10mg/L in the solution;After pretreatment, mould Block filler wet land system can be used for high nitrogen sewage disposal, and the control of artificial wet land system hydraulic loading is 1-50cm/ days, and waterpower is stopped It is 2-10 days to stay time control.
Addition seed sludge consolidation system starts speed inside wetland, and seed sludge can be wet mud form or dewatered sludge Form, seed sludge type can be anaerobic ammonium oxidation sludge, sludge sewage, granule sludge or three's arbitrary proportion Sludge, sludge seeding amount is calculated as 0.1-10g/m with dry weight2
Wet land filler layer top generates if any weeds and need to clear up in time without planting wetland plant.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention It encloses and is defined, under the premise of not departing from design spirit of the present invention, technical side of the those of ordinary skill in the art to the present invention The various modifications and improvement that case is made should all be fallen into the protection domain of claims of the present invention determination.

Claims (3)

1. a kind of Anammox type wet land system for high nitrogen sewage disposal, it is characterised in that:The system comprises artificial Wetland pond body, seed sludge and wet land filler, the wet land filler are gravel, zeolite, extra large oyster shell or the mixing of three's arbitrary proportion Standard modular wet land filler, porosity is set as 20%-80%, packing material size when gravel, zeolite and extra large oyster shell are as filler Size is 1-10cm;Standard modular wet land filler is suppressed or is fired after being mixed according to arbitrary proportion using three's pulvis, The porosity of modularization wet land filler is 10%-80%, and modularization wet land filler is the penetrating cuboid in both sides, gravel, zeolite and Extra large oyster shells agent particle size be 0.1-1cm, the seed sludge be anaerobic ammonium oxidation sludge, sludge sewage, The sludge of granule sludge or three's arbitrary proportion, sludge seeding amount dry weight are 0.1-10g/m2
2. a kind of Anammox type wet land system for high nitrogen sewage disposal according to claim 1, feature exist In:Using the combined sewage of the water outlet of high nitrogen sewerage short-cut denitrification processing system and high nitrogen sewage as wet land system treated sewage, when When BOD content is 10-500 mg/L in high nitrogen sewage, the two mixed proportion is 1/0.1-1/1, after mixing in sewage Ammonia nitrogen/nitrite nitrogen content ratio control is 1/0.8-1/1.8;When BOD content is more than 500mg/L in high nitrogen sewage When, the two mixed proportion is 1/0.1-1/0.8, and ammonia nitrogen in sewage/nitrite nitrogen content ratio control is 1/1-1/2 after mixing.
3. a kind of Anammox type wetland system for high nitrogen sewage disposal according to any one of claim 1-2 System, it is characterised in that:It is opened with wet land system by controlling anaerobic ammonia oxidation microbiological culture in hydraulic loading progress wet land system Dynamic, the control of the 1-10 days wet land system startup stages hydraulic loading is 0.5-5cm/ days, and hydraulic loading control in the 5-20 days is 1- 10cm/ days, hydraulic loading control in the 10-60 days was 2-10 cm/ days, and hydraulic loading control in the 15-90 days is 3-20cm/ days, the Hydraulic loading control in 20-120 days is 4-30cm/ days;System can be used for practical high nitrogen sewage disposal process after starting, practical High nitrogen sewage disposal stage technique hydraulic loading control is 1-50cm/ days.
CN201810897163.2A 2018-08-08 2018-08-08 A kind of Anammox type wet land system for high nitrogen sewage disposal Pending CN108706742A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113321369A (en) * 2021-02-08 2021-08-31 重庆大学 Tidal flow artificial wetland capable of simultaneously removing nitrogen and phosphorus

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464406A (en) * 2010-11-09 2012-05-23 中国科学院生态环境研究中心 Method for realizing denitrification of anaerobic ammonium oxidation by utilizing constructed wetland
CN107487856A (en) * 2017-09-22 2017-12-19 中国科学院城市环境研究所 A kind of artificial wet land system for handling mariculture sewage
CN107720967A (en) * 2017-10-19 2018-02-23 中国科学院城市环境研究所 A kind of modularization filler wet land system for livestock and poultry cultivation sewage disposal

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464406A (en) * 2010-11-09 2012-05-23 中国科学院生态环境研究中心 Method for realizing denitrification of anaerobic ammonium oxidation by utilizing constructed wetland
CN107487856A (en) * 2017-09-22 2017-12-19 中国科学院城市环境研究所 A kind of artificial wet land system for handling mariculture sewage
CN107720967A (en) * 2017-10-19 2018-02-23 中国科学院城市环境研究所 A kind of modularization filler wet land system for livestock and poultry cultivation sewage disposal

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113321369A (en) * 2021-02-08 2021-08-31 重庆大学 Tidal flow artificial wetland capable of simultaneously removing nitrogen and phosphorus

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