CN108690525A - Optical release liner - Google Patents

Optical release liner Download PDF

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Publication number
CN108690525A
CN108690525A CN201710829324.XA CN201710829324A CN108690525A CN 108690525 A CN108690525 A CN 108690525A CN 201710829324 A CN201710829324 A CN 201710829324A CN 108690525 A CN108690525 A CN 108690525A
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CN
China
Prior art keywords
parts
release liner
polymerization resin
membrane layer
parting agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710829324.XA
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Chinese (zh)
Inventor
夏厚君
杨晓明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Ouren New Material Co Ltd
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Zhejiang Ouren New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201710829324.XA priority Critical patent/CN108690525A/en
Publication of CN108690525A publication Critical patent/CN108690525A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1806C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/318Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • C09J2433/005Presence of (meth)acrylic polymer in the release coating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Epoxy Resins (AREA)

Abstract

The present invention discloses a kind of optical release liner, including base membrane layer, the parting agent layer coated on basement membrane layer surface, and the parting agent layer is cured by mould release to be obtained, this mould release is obtained by the component of following parts by weight:It is obtained by the component of following parts by weight:Pre-polymerization resin, methylnaphthohydroquinone, 3- propylene oxide, lauryl diglycidyl ether, 1- hydroxy cyclohexyl phenylketones, pre-polymerization resin are obtained by following steps:By cyclohexyl methacrylate, β-propyloic acrylic ester, acrylic acid, agitator is put into, stirring at low speed is formed uniformly primary mix;It is added in reaction kettle after primary mix, dimethylbenzene, benzoyl peroxide are mixed and obtains polymer solution;By heating distillation removal dimethylbenzene after polymer solution, 2- hydroxyethyl vinylethers high-speed stirreds, to obtain pre-polymerization resin.The present invention improves product against weather, and will not be adversely affected to the electrical of circuit board, to improve the reliability of circuit board.

Description

Optical release liner
Technical field
The present invention relates to a kind of optical release liners, belong to separated type material technical field.
Background technology
In the prior art, optical release liner is all to be coated with response type silicone-based materials on film substrate surface, is then made At traditional release film.And as optical cement field is constantly furtherd investigate, requirement limitation of the optical articles to optical cement becomes Increasingly harsher, release layer is to be coated on base material under heated or radiation curing to form crosslinking knot by processing by mould release The hard formation of structure and anti-sticking effect is carried out to adhesive, its performance is unstable at low temperature for existing mould release, and against weather is poor, such as What overcomes above-mentioned technical problem to become the direction that those skilled in the art make great efforts.
Invention content
It is an object of the present invention to provide a kind of optical release liner, which overcomes existing mould release in room temperature and height Temperature is lower could to keep low peeling force defect, and stable low stripping force can also be kept at low temperature by realizing, to improve production Product against weather, and the electrical of circuit board will not be adversely affected, to improve the reliability of circuit board.
In order to achieve the above objectives, the technical solution adopted by the present invention is:A kind of optical release liner, including base membrane layer, coating It it is 0.1 ~ 0.7 μm in the thickness of the parting agent layer of basement membrane layer surface, the parting agent layer, the parting agent layer is cured by mould release It obtains, this mould release is obtained by the component of following parts by weight:
100 parts of pre-polymerization resin,
0.8 ~ 1.2 part of methylnaphthohydroquinone,
25 ~ 40 parts of 3- propylene oxide,
10 ~ 20 parts of lauryl diglycidyl ether,
3 ~ 5 parts of 1- hydroxy cyclohexyl phenylketones;
The pre-polymerization resin is obtained by following steps:
Step 1: by 30 ~ 50 parts of cyclohexyl methacrylate, 20 ~ 30 parts of β-propyloic acrylic ester, 8 ~ 12 parts of acrylic acid, throw Enter agitator, stirring at low speed is formed uniformly primary mix;
Step 2: adding after the primary mix of step 1,100 parts of dimethylbenzene, 0.3~0.5 part of benzoyl peroxide are mixed Enter into reaction kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal after the polymer solution of step 2,5 ~ 12 parts of 2- hydroxyethyl vinylethers high-speed stirreds Dimethylbenzene, to obtain pre-polymerization resin.
Further improved scheme is as follows in above-mentioned technical proposal:
1. in said program, the stirring at low speed rate of the step 1 is 200-300 revs/min, the moderate-speed mixer speed of step 2 Rate is 300-500 revs/min, and the high-speed stirred rate of step 3 is 600-800 revs/min.
2. in said program, the temperature of reaction kettle is 70~80 DEG C in the step 2.
3. in said program, the base membrane layer is PET film, PE films, PP films, PC films, PMMA films or TAC Film.
4. in said program, the basement membrane layer thickness is 2 ~ 300 microns.
Since above-mentioned technical proposal is used, the present invention has following advantages and effect compared with prior art:
1. optical release liner of the present invention, parting agent layer overcomes existing mould release could keep low stripping at ambient and elevated temperatures Defect from power, stable low stripping force can also be kept at low temperature by realizing, to improve product against weather;Secondly, The mould release both improves residual adherence, greatly reduces the mould release rate of transform, also avoids Ion transfer, and it is insulation Body will not adversely affect the electrical of circuit board appearing in glue surface residual and being transferred on wiring board, to Improve the reliability of circuit board.
2. optical release liner of the present invention, further added methylnaphthohydroquinone in parting agent layer formula, dodecyl shrink it is sweet Oily ether improves coating ductility and uniformity, is also realized under the UV light irradiation of low energy rapid photocuring.
Description of the drawings
Attached drawing 1 is optical release liner structural schematic diagram of the present invention.
In the figures above:1, base membrane layer;2, parting agent layer.
Specific implementation mode
With reference to embodiment, the invention will be further described:
Embodiment 1:A kind of optical release liner, including base membrane layer 1, the parting agent layer 2 coated on 1 surface of base membrane layer, it is described release The thickness of oxidant layer 2 be 0.1 ~ 0.7 μm, the parting agent layer 2 by mould release cure obtain, this mould release by following parts by weight group It separately wins:
100 parts of pre-polymerization resin,
0.85 part of methylnaphthohydroquinone,
35 parts of 3- propylene oxide,
15 parts of lauryl diglycidyl ether,
3.2 parts of 1- hydroxy cyclohexyl phenylketones.
The pre-polymerization resin is obtained by following steps:
Step 1: by 32 parts of cyclohexyl methacrylate, 25 parts of β-propyloic acrylic ester, 9 parts of acrylic acid, agitator is put into, Stirring at low speed is formed uniformly primary mix;
Step 2: anti-by being added to after 0.35 part of primary mix of step 1,100 parts of dimethylbenzene, benzoyl peroxide mixing It answers in kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal diformazan after the polymer solution of step 2,6 parts of 2- hydroxyethyl vinylethers high-speed stirreds Benzene, to obtain pre-polymerization resin.
Above-mentioned optical release liner is obtained by following steps:
Step 1: 0.85 part of methylnaphthohydroquinone of addition, 35 parts of 3- propylene oxide, ten in the pre-polymerization resin for the step three being located in container 15 parts of dialkyl group glycidol ether is uniformly mixed to form mixture, adds the 3.2 parts of formation of 1- hydroxy cyclohexyl phenylketones The mould release;
Step 2: mould release is coated on base membrane layer 1, coating weight 0.8g/m2, it is 80mj/cm in UV energy2 Under the conditions of it is solid Change, optical release liner is formed after solidification.
Embodiment 2:A kind of optical release liner, including base membrane layer 1, the parting agent layer 2 coated on 1 surface of base membrane layer, it is described The thickness of parting agent layer 2 is 0.1 ~ 0.7 μm, and the parting agent layer 2 is cured by mould release to be obtained, this mould release is by following parts by weight Component obtain:
100 parts of pre-polymerization resin,
0.9 part of methylnaphthohydroquinone,
30 parts of 3- propylene oxide,
18 parts of lauryl diglycidyl ether,
4.5 parts of 1- hydroxy cyclohexyl phenylketones.
The pre-polymerization resin is obtained by following steps:
Step 1: by 45 parts of cyclohexyl methacrylate, 28 parts of β-propyloic acrylic ester, 11 parts of acrylic acid, agitator is put into, Stirring at low speed is formed uniformly primary mix;
Step 2: anti-by being added to after 0.45 part of primary mix of step 1,100 parts of dimethylbenzene, benzoyl peroxide mixing It answers in kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal diformazan after 9 parts of polymer solution of step 2,2- hydroxyethyl vinylethers high-speed stirreds Benzene, to obtain pre-polymerization resin.
Above-mentioned optical release liner is obtained by following steps:
Step 1: 0.9 part of methylnaphthohydroquinone of addition, 30 parts of 3- propylene oxide, ten in the pre-polymerization resin for the step three being located in container 18 parts of dialkyl group glycidol ether is uniformly mixed to form mixture, adds the 4.5 parts of formation of 1- hydroxy cyclohexyl phenylketones The mould release;
Step 2: mould release is coated on base membrane layer 1, coating weight 0.8g/m2, it is 80mj/cm in UV energy2 Under the conditions of it is solid Change, optical release liner is formed after solidification.
Embodiment 3:A kind of optical release liner, including base membrane layer 1, the parting agent layer 2 coated on 1 surface of base membrane layer, it is described The thickness of parting agent layer 2 is 0.1 ~ 0.7 μm, and the parting agent layer 2 is cured by mould release to be obtained, this mould release is by following parts by weight Component obtain:
100 parts of pre-polymerization resin,
1 part of methylnaphthohydroquinone,
28 parts of 3- propylene oxide,
12 parts of lauryl diglycidyl ether,
3.5 parts of 1- hydroxy cyclohexyl phenylketones.
The pre-polymerization resin is obtained by following steps:
Step 1: by 38 parts of cyclohexyl methacrylate, 22 parts of β-propyloic acrylic ester, 10 parts of acrylic acid, agitator is put into, Stirring at low speed is formed uniformly primary mix;
Step 2: anti-by being added to after 0.38 part of primary mix of step 1,100 parts of dimethylbenzene, benzoyl peroxide mixing It answers in kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal diformazan after 8 parts of polymer solution of step 2,2- hydroxyethyl vinylethers high-speed stirreds Benzene, to obtain pre-polymerization resin.
Above-mentioned optical release liner is obtained by following steps:
Step 1: 1 part of methylnaphthohydroquinone of addition, 28 parts of 3- propylene oxide, 12 in the pre-polymerization resin for the step three being located in container 12 parts of alkyl glycidyl ether is uniformly mixed to form mixture, adds 3.5 parts of formation institutes of 1- hydroxy cyclohexyl phenylketones State mould release;
Step 2: mould release is coated on base membrane layer 1, coating weight 0.8g/m2, it is 80mj/cm in UV energy2 Under the conditions of it is solid Change, optical release liner is formed after solidification.
Embodiment 4:A kind of optical release liner, including base membrane layer 1, the parting agent layer 2 coated on 1 surface of base membrane layer, it is described The thickness of parting agent layer 2 is 0.1 ~ 0.7 μm, and the parting agent layer 2 is cured by mould release to be obtained, this mould release is by following parts by weight Component obtain:
100 parts of pre-polymerization resin,
1.1 parts of methylnaphthohydroquinone,
38 parts of 3- propylene oxide,
16 parts of lauryl diglycidyl ether,
4.5 parts of 1- hydroxy cyclohexyl phenylketones.
The pre-polymerization resin is obtained by following steps:
Step 1: by 48 parts of cyclohexyl methacrylate, 20 parts of β-propyloic acrylic ester, 9 parts of acrylic acid, agitator is put into, Stirring at low speed is formed uniformly primary mix;
Step 2: anti-by being added to after 0.35 part of primary mix of step 1,100 parts of dimethylbenzene, benzoyl peroxide mixing It answers in kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal two after 11 parts of polymer solution of step 2,2- hydroxyethyl vinylethers high-speed stirreds Toluene, to obtain pre-polymerization resin.
Above-mentioned optical release liner is obtained by following steps:
Step 1: 1.1 parts of methylnaphthohydroquinone of addition, 38 parts of 3- propylene oxide, dodecane in 100 parts of pre-polymerization resins in container 16 parts of base glycidol ether is uniformly mixed to form mixture, adds described in the 4.5 parts of formation of 1- hydroxy cyclohexyl phenylketones Mould release;
Step 2: mould release is coated on base membrane layer 1, coating weight 0.8g/m2, it is 80mj/cm in UV energy2 Under the conditions of it is solid Change, optical release liner is formed after solidification.
Embodiment 5:A kind of optical release liner, including base membrane layer 1, the parting agent layer 2 coated on 1 surface of base membrane layer, it is described The thickness of parting agent layer 2 is 0.1 ~ 0.7 μm, and the parting agent layer 2 is cured by mould release to be obtained, this mould release is by following parts by weight Component obtain:
100 parts of pre-polymerization resin,
0.9 part of methylnaphthohydroquinone,
30 parts of 3- propylene oxide,
12 parts of lauryl diglycidyl ether,
3 parts of 1- hydroxy cyclohexyl phenylketones.
The pre-polymerization resin is obtained by following steps:
Step 1: by 35 parts of cyclohexyl methacrylate, 26 parts of β-propyloic acrylic ester, 10 parts of acrylic acid, agitator is put into, Stirring at low speed is formed uniformly primary mix;
Step 2: by reaction is added to after 0.4 part of primary mix of step 1,100 parts of dimethylbenzene, benzoyl peroxide mixing In kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal diformazan after 7 parts of polymer solution of step 2,2- hydroxyethyl vinylethers high-speed stirreds Benzene, to obtain pre-polymerization resin.
Above-mentioned optical release liner is obtained by following steps:
Step 1: 0.9 part of methylnaphthohydroquinone of addition, 30 parts of 3- propylene oxide, dodecane in 100 parts of pre-polymerization resins in container 12 parts of base glycidol ether is uniformly mixed to form mixture, add 3 parts of 1- hydroxy cyclohexyl phenylketones formed it is described from Type agent;
Step 2: mould release is coated on base membrane layer 1, coating weight 0.8g/m2, it is 80mj/cm in UV energy2 Under the conditions of it is solid Change, optical release liner is formed after solidification.
The optical release liner that embodiment 1 ~ 5 is obtained, test are as shown in table 1:
Table 1
By table 1 it is found that when using above-mentioned optical release liner, parting agent layer overcomes existing mould release at ambient and elevated temperatures The defect that could keep low stripping force, stable low stripping force can also be kept at low temperature by realizing, resistance to improve product It is climacteric;Secondly, which both improves residual adherence, greatly reduces the mould release rate of transform, also avoids ion and moves It moves, and it is insulator, circuit board will not electrically be caused not appearing in glue surface residual and being transferred on wiring board The influence of profit, to improve the reliability of circuit board;Again, methylnaphthohydroquinone, ten have further been added in parting agent layer formula Dialkyl group glycidol ether improves coating ductility and uniformity, and it is solid also to realize quick light under the UV light irradiation of low energy Change.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of optical release liner, it is characterised in that:Including base membrane layer(1), be coated on base membrane layer(1)The parting agent layer on surface (2), the parting agent layer(2)Thickness be 0.1 ~ 0.7 μm, the parting agent layer(2)Cured by mould release and is obtained, this mould release It is obtained by the component of following parts by weight:
100 parts of pre-polymerization resin,
0.8 ~ 1.2 part of methylnaphthohydroquinone,
25 ~ 40 parts of 3- propylene oxide,
10 ~ 20 parts of lauryl diglycidyl ether,
3 ~ 5 parts of 1- hydroxy cyclohexyl phenylketones;
The pre-polymerization resin is obtained by following steps:
Step 1: by 30 ~ 50 parts of cyclohexyl methacrylate, 20 ~ 30 parts of β-propyloic acrylic ester, 8 ~ 12 parts of acrylic acid, throw Enter agitator, stirring at low speed is formed uniformly primary mix;
Step 2: adding after the primary mix of step 1,100 parts of dimethylbenzene, 0.3~0.5 part of benzoyl peroxide are mixed Enter into reaction kettle, moderate-speed mixer obtains polymer solution after standing 1 ~ 2 hour after reaction half an hour;
Step 3: by heating distillation removal after the polymer solution of step 2,5 ~ 12 parts of 2- hydroxyethyl vinylethers high-speed stirreds Dimethylbenzene, to obtain pre-polymerization resin.
2. optical release liner according to claim 1, it is characterised in that:The stirring at low speed rate of the step 1 is 200- 300 revs/min, the moderate-speed mixer rate of step 2 is 300-500 revs/min, and the high-speed stirred rate of step 3 is 600-800 Rev/min.
3. optical release liner according to claim 1, it is characterised in that:In the step 2 temperature of reaction kettle be 70~ 80℃。
4. optical release liner according to claim 1, it is characterised in that:The base membrane layer is PET film, PE films, PP Film, PC films, PMMA films or TAC film.
5. optical release liner according to claim 1, it is characterised in that:The basement membrane layer thickness is 2 ~ 300 microns.
CN201710829324.XA 2017-09-14 2017-09-14 Optical release liner Pending CN108690525A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956803A (en) * 2021-12-08 2022-01-21 南京兰埔成新材料有限公司 TAC release base film and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956803A (en) * 2021-12-08 2022-01-21 南京兰埔成新材料有限公司 TAC release base film and preparation method thereof

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Application publication date: 20181023