CN108690470A - Unify cathode electrophoresis dope and preparation method thereof in a kind of bottom surface for fire-fighting equipment - Google Patents
Unify cathode electrophoresis dope and preparation method thereof in a kind of bottom surface for fire-fighting equipment Download PDFInfo
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- CN108690470A CN108690470A CN201810290509.2A CN201810290509A CN108690470A CN 108690470 A CN108690470 A CN 108690470A CN 201810290509 A CN201810290509 A CN 201810290509A CN 108690470 A CN108690470 A CN 108690470A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/443—Polyepoxides
- C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
- C09D5/4442—Binder characterised by functional groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4473—Mixture of polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, specifically disclose a kind of bottom surface unification cathode electrophoresis dope and preparation method thereof for fire-fighting equipment.Cathode electrophoresis dope is unified in the bottom surface, and raw material includes the component of following mass fraction:Mill base 5%-10%, lotion 40%-45%, deionized water 50%-55%;The mill base includes following components according to the mass fraction:10-35 parts of quaternary ammonium salt dispersion resin, 25-40 parts of deionized water, 15-30 parts of color stuffing;The lotion includes following components according to the mass fraction:30-40 parts of acrylic modified epoxy resin, 9-15 parts of blocked isocyanate, 3-7 parts of emulsifier, 2-6 parts of neutralizer, 50-70 parts of deionized water.Unify cathode electrophoresis dope provided by the present invention for the bottom surface of fire-fighting equipment, hardness is high, has excellent anticorrosive property, acid resistance, alkali resistance etc..
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of bottom surface for fire-fighting equipment to unify cathode electrophoresis dope
And preparation method thereof.
Background technology
Since cathode electrophoresis dope comes out, no matter in terms of coating itself or coating application technology, all achieve many
Progress, is proposed many products and new application technology, and so far, almost 100% application ability cathode electrophoresis applies primer for automobiles
Material.
Electrophoretic coating is the water paint that developed earliest, it be mainly characterized by coating efficiency high, economic, safety,
Pollute it is small, convenient for automation size produce.After decades of development, product constantly updates, newest ability cathode electrophoresis
Coating requires the characteristics such as higher throwing power, lower P/B, better edge coverage effect.
Existing fire-fighting equipment series dip painting anticorrosive property is poor, lower hardness, and acid-fast alkali-proof poor performance, performance far can not
Meet the market demand.
Invention content
For existing fire-fighting equipment series dip painting anticorrosive property, poor, lower hardness, acid-fast alkali-proof poor performance etc. are asked
Topic, the present invention provide a kind of bottom surface unification cathode electrophoresis dope and preparation method thereof for fire-fighting equipment.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
Cathode electrophoresis dope is unified in a kind of bottom surface for fire-fighting equipment, and raw material includes the component of following mass fraction:Color
Starch 5%-10%, lotion 40%-45%, deionized water 50%-55%;
The mill base includes following components according to the mass fraction:10-35 parts of quaternary ammonium salt dispersion resin, deionized water 25-40
Part, 15-30 parts of color stuffing;
The lotion includes following components according to the mass fraction:30-40 parts of acrylic modified epoxy resin, enclosed type isocyanide
9-15 parts of acid esters, 3-7 parts of emulsifier, 2-6 parts of neutralizer, 50-70 parts of deionized water.
Compared with the existing technology, unify cathode electrophoresis dope provided by the present invention for the bottom surface of fire-fighting equipment, using third
Olefin(e) acid modified epoxy, quaternary ammonium salt dispersion resin respectively as lotion and mill base main material so that electrophoretic coating is not only
With stronger throwing power, and has preferable water-fast chemical resistance, quaternary ammonium salt dispersion resin and the function in epoxy resin
Group's reaction forms reticular structure, is that the Corrosion Protections such as hardness of paint film height, strong adhesive force, acid-fast alkali-proof are excellent, and quaternary ammonium salinity
Dissipate resin keeps paint film uniform as film forming matter, and glossiness is high;In addition, product is bi-component cathode electrophoresis dope, by mill base and
Two components of lotion are constituted, and belong to environment protecting water-based paint, anti-settling is had excellent performance, and matching is good.
Further, the present invention also provides the preparation sides that cathode electrophoresis dope is unified in the bottom surface for fire-fighting equipment
Method.The preparation method, includes the following steps:
(1) raw material proportioning for unifying cathode electrophoresis dope according to the bottom surface for fire-fighting equipment weighs each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment, milled processed, obtain mill base;
(3) by the acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water into
Row mixing treatment, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment, obtain unifying for the bottom surface of fire-fighting equipment cloudy
Pole electrophoretic coating.
Compared with the existing technology, the preparation side of cathode electrophoresis dope is unified provided by the present invention for the bottom surface of fire-fighting equipment
Method, it is simple for process, it is easy to operate, it is environmentally protective, securely and reliably.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
The embodiment of the present invention provides a kind of bottom surface unification cathode electrophoresis dope for fire-fighting equipment.This is used for fire-fighting equipment
Bottom surface unify cathode electrophoresis dope, raw material includes the component of following mass fraction:Mill base 5%-10%, lotion 40%-45%,
Deionized water 50%-55%;
The mill base includes following components according to the mass fraction:10-35 parts of quaternary ammonium salt dispersion resin, deionized water 25-40
Part, 15-30 parts of color stuffing;
The lotion includes following components according to the mass fraction:30-40 parts of acrylic modified epoxy resin, enclosed type isocyanide
9-15 parts of acid esters, 3-7 parts of emulsifier, 2-6 parts of neutralizer, 50-70 parts of deionized water.
Preferably, the quaternary ammonium salt dispersion resin reacted with epoxy resin by sulfamic acid be made, use sulfamic acid for
Quaternary ammonium salt dispersion resin is prepared from the epoxy resin reaction with different epoxide equivalents in hydrophilic monomer, as film forming matter,
It interacts simultaneously with acrylic modified epoxy resin, forms reticular structure, make hardness of paint film height, strong adhesive force, acidproof
Alkaline-resisting equal Corrosion Protections are excellent, and the paint film formed is uniform, and glossiness is high.
Preferably, the color stuffing includes MH-RC, chrome yellow 7000, titanium dioxide, for allocating different types of mill base.
Preferably, MH-RC in the color stuffing, chrome yellow 7000, titanium dioxide mass ratio be (5-13):(5-9):(5-8),
Convenient for allocating different types of mill base.
Preferably, the acrylic modified epoxy resin is acrylic acid modified glycidol lipid epoxy resin, acrylic acid
The combination of one or both of modified ester ring based epoxy resin, improves the antiseptic property of paint film.
Preferably, the closure isocyanates be enclosed type HDI crosslinking agents, one kind in closure IPDI crosslinking agents or
Two kinds of combination improves adhesive strength, water proofing property, wearability, scrub resistance, scratch resistance and the chemical-resistant of coating.
Preferably, the emulsifier is induced by alkyl hydroxybenzene polyoxyethylene ether, improves the various surfaces constituted between phase in lotion
Tension forms uniform and stable lotion, anti-settling.
Preferably, the neutralizer is at least one of lactic acid, acetic acid, formic acid, and the pH environment of adjusting coating system makes
Lotion is more stablized.
Cathode electrophoresis dope is unified in bottom surface provided in an embodiment of the present invention for fire-fighting equipment, using acrylic acid modified ring
Oxygen resin, quaternary ammonium salt dispersion resin respectively as lotion and mill base main material so that electrophoretic coating not only have it is stronger
Throwing power, and have preferable water-fast chemical resistance, quaternary ammonium salt dispersion resin is formed with the functional group reactions in epoxy resin
Reticular structure is that the Corrosion Protections such as hardness of paint film height, strong adhesive force, acid-fast alkali-proof are excellent, and paint film is uniform, and glossiness is high;
In addition, product is bi-component cathode electrophoresis dope, it is made of two components of mill base and lotion, belongs to environment protecting water-based paint, it is anti-settling
Drop is had excellent performance, and matching is good.
The present invention furthermore provides under the premise of providing the bottom surface unification cathode electrophoresis dope for fire-fighting equipment
This is used for the preparation method of bottom surface unification cathode electrophoresis dope of fire-fighting equipment.
In one embodiment, which includes the following steps:
(1) raw material proportioning for unifying cathode electrophoresis dope according to the bottom surface for fire-fighting equipment weighs each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment, milled processed, obtain mill base;
(3) by the acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water into
Row mixing treatment, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment, obtain unifying for the bottom surface of fire-fighting equipment cloudy
Pole electrophoretic coating.
Explanation is further explained to above-mentioned preparation method below:
Preferably, in step (4), the mixing speed of the mixing treatment is 1500-2000rpm, is sufficiently stirred, obtains body
It is uniform cathode electrophoresis dope.
Preferably, in step (2), the fineness of grind of the milled processed is≤15um, ensures the homogeneity of mill base.
This method preparation process is simple, easy to operate, environmentally protective, securely and reliably.
In order to better illustrate the bottom surface provided in an embodiment of the present invention for fire-fighting equipment unify cathode electrophoresis dope and
Preparation method is illustrated below by embodiment is further.
Embodiment 1
Unify cathode electrophoresis dope in a kind of bottom surface for fire-fighting equipment.This is used for the bottom surface unification cathode electricity of fire-fighting equipment
Swimming coating, raw material includes the component of following mass fraction:Mill base 5%, lotion 45%, deionized water 50%;
The mill base includes following components according to the mass fraction:30 parts of quaternary ammonium salt dispersion resin, 30 parts of deionized water, MH-
RC:9 parts, chrome yellow 7000:8 parts, titanium dioxide:6 parts;
The lotion includes following components according to the mass fraction:30 parts of acrylic modified epoxy resin, enclosed type isocyanic acid
15 parts of ester, 6 parts of emulsifier, 3 parts of neutralizer, 50 parts of deionized water.
The preparation method of bottom surface unification cathode electrophoresis dope includes the following steps:
(1) raw material proportioning for unifying cathode electrophoresis dope according to the bottom surface for fire-fighting equipment weighs each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment 10-20min, milled processed extremely
Fineness≤15um, obtains mill base;
(3) by the acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water into
Row mixing treatment 30-60min, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment 10-30min with 1500-2000rpm, are used
Unify cathode electrophoresis dope in the bottom surface of fire-fighting equipment.
Embodiment 2
Unify cathode electrophoresis dope in a kind of bottom surface for fire-fighting equipment.This is used for the bottom surface unification cathode electricity of fire-fighting equipment
Swimming coating, raw material includes the component of following mass fraction:Mill base 6%, lotion 40%, deionized water 55%;
The mill base includes following components according to the mass fraction:35 parts of quaternary ammonium salt dispersion resin, 40 parts of deionized water, MH-
RC:13 parts, chrome yellow 7000:9 parts, titanium dioxide:8 parts;
The lotion includes following components according to the mass fraction:35 parts of acrylic modified epoxy resin, enclosed type isocyanic acid
10 parts of ester, 6 parts of emulsifier, 3 parts of neutralizer, 70 parts of deionized water.
The preparation method of bottom surface unification cathode electrophoresis dope includes the following steps:
(1) raw material proportioning for unifying cathode electrophoresis dope according to the bottom surface for fire-fighting equipment weighs each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment 10-20min, milled processed extremely
Fineness≤15um, obtains mill base;
(3) by the acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water into
Row mixing treatment 30-60min, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment 10-30min with 1500-2000rpm, are used
Unify cathode electrophoresis dope in the bottom surface of fire-fighting equipment.
Embodiment 3
Unify cathode electrophoresis dope in a kind of bottom surface for fire-fighting equipment.This is used for the bottom surface unification cathode electricity of fire-fighting equipment
Swimming coating, raw material includes the component of following mass fraction:Mill base 10%, lotion 42%, deionized water 50%;
The mill base includes following components according to the mass fraction:10 parts of quaternary ammonium salt dispersion resin, 25 parts of deionized water, MH-
RC:5 parts, chrome yellow 7000:5 parts, titanium dioxide:6 parts;
The lotion includes following components according to the mass fraction:40 parts of acrylic modified epoxy resin, enclosed type isocyanic acid
9 parts of ester, 3 parts of emulsifier, 6 parts of neutralizer, 60 parts of deionized water.
The preparation method of bottom surface unification cathode electrophoresis dope includes the following steps:
(1) raw material proportioning for unifying cathode electrophoresis dope according to the bottom surface for fire-fighting equipment weighs each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment 10-20min, milled processed extremely
Fineness≤15um, obtains mill base;
(3) by the acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water into
Row mixing treatment 30-60min, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment 10-30min with 1500-2000rpm, are used
Unify cathode electrophoresis dope in the bottom surface of fire-fighting equipment.
Unify cathode electrophoresis dope to better illustrate the bottom surface provided in an embodiment of the present invention for fire-fighting equipment
Bottom surface unification cathode electrophoresis dope for fire-fighting equipment prepared by embodiment 1,2,3 is carried out respective performances by characteristic below
Test, the results are shown in Table 1.
Table 1
As can be seen from Table 1, cathode electrophoresis dope is unified in the bottom surface for fire-fighting equipment that prepared by the embodiment of the present invention, firmly
Degree is high, has excellent anticorrosive property, acid resistance, alkali resistance etc..
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.
Claims (10)
1. cathode electrophoresis dope is unified in a kind of bottom surface for fire-fighting equipment, which is characterized in that raw material includes following mass fraction
Component:Mill base 5%-10%, lotion 40%-45%, deionized water 50%-55%;
The mill base includes following components according to the mass fraction:10-35 parts of quaternary ammonium salt dispersion resin, 25-40 parts of deionized water, face
15-30 parts of filler;
The lotion includes following components according to the mass fraction:30-40 parts of acrylic modified epoxy resin, blocked isocyanate
9-15 parts, 3-7 parts of emulsifier, 2-6 parts of neutralizer, 50-70 parts of deionized water.
2. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The quaternary ammonium
Salt dispersion resin, which is reacted by sulfamic acid with epoxy resin, to be made.
3. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The face is filled out
Material includes MH-RC, chrome yellow 7000, titanium dioxide.
4. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as claimed in claim 3, it is characterised in that:The face is filled out
MH-RC in material, chrome yellow 7000, titanium dioxide mass ratio be (5-13):(5-9):(5-8).
5. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The propylene
Sour modified epoxy is one in acrylic acid modified glycidol lipid epoxy resin, acrylic acid modified ester ring based epoxy resin
Kind or two kinds of combination.
6. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The closing
Property isocyanates be enclosed type HDI crosslinking agents, one or both of closure IPDI crosslinking agents combination.
7. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The emulsification
Agent is induced by alkyl hydroxybenzene polyoxyethylene ether.
8. unifying cathode electrophoresis dope for the bottom surface of fire-fighting equipment as described in claim 1, it is characterised in that:The neutralization
Agent is at least one of lactic acid, acetic acid, formic acid.
9. the preparation method of cathode electrophoresis dope is unified in a kind of bottom surface for fire-fighting equipment, it is characterised in that:Including following step
Suddenly:
(1) raw material for unifying cathode electrophoresis dope according to the bottom surface for being used for fire-fighting equipment as described in any one of claim 1~8 is matched
Than weighing each component;
(2) the ammonium salt dispersion resin, deionized water, color stuffing are subjected to mixing treatment, milled processed, obtain mill base;
(3) acrylic modified epoxy resin, closure isocyanates, emulsifier, neutralizer and deionized water are mixed
Material processing, obtains lotion;
(4) mill base, lotion, deionized water are subjected to mixing treatment, obtain the bottom surface unification cathode electricity for fire-fighting equipment
Swimming coating.
10. the preparation method for the bottom surface of fire-fighting equipment unification cathode electrophoresis dope, feature exist as claimed in claim 9
In:In step (4), the mixing speed of the mixing treatment is 1500-2000rpm, and/or
In step (2), the fineness of grind of the milled processed is≤15um.
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CN201810290509.2A CN108690470A (en) | 2018-04-03 | 2018-04-03 | Unify cathode electrophoresis dope and preparation method thereof in a kind of bottom surface for fire-fighting equipment |
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Cited By (4)
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CN110105845A (en) * | 2019-05-27 | 2019-08-09 | 枣阳市旺前电泳涂料有限公司 | A kind of cathode epoxy electrophoretic paint and its production method |
CN110283491A (en) * | 2019-05-30 | 2019-09-27 | 河北晨阳工贸集团有限公司 | Aqueous dual-component electrophoretic coating and preparation method thereof |
CN114891412A (en) * | 2021-06-25 | 2022-08-12 | 江苏御镐智能制造有限公司 | Breakdown-resistant electrophoretic paint and application thereof |
CN115011199A (en) * | 2022-05-20 | 2022-09-06 | 上海金力泰化工股份有限公司 | Anti-aging cathode electrophoretic paint and preparation method and application thereof |
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CN107573836A (en) * | 2017-08-23 | 2018-01-12 | 河北晨阳工贸集团有限公司 | It is a kind of suitable for cathode electrophoresis dope of groove pipe fitting and preparation method thereof |
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JP2000191958A (en) * | 1998-12-28 | 2000-07-11 | Nippon Paint Co Ltd | Cationic electrodeposition coating composition, formation of multiple coating film and multiple coating film |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110105845A (en) * | 2019-05-27 | 2019-08-09 | 枣阳市旺前电泳涂料有限公司 | A kind of cathode epoxy electrophoretic paint and its production method |
CN110283491A (en) * | 2019-05-30 | 2019-09-27 | 河北晨阳工贸集团有限公司 | Aqueous dual-component electrophoretic coating and preparation method thereof |
CN114891412A (en) * | 2021-06-25 | 2022-08-12 | 江苏御镐智能制造有限公司 | Breakdown-resistant electrophoretic paint and application thereof |
CN114891412B (en) * | 2021-06-25 | 2024-01-12 | 江苏御镐智能制造有限公司 | Breakdown-resistant electrophoretic paint and application thereof |
CN115011199A (en) * | 2022-05-20 | 2022-09-06 | 上海金力泰化工股份有限公司 | Anti-aging cathode electrophoretic paint and preparation method and application thereof |
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Application publication date: 20181023 |