CN108690169A - A kind of preparation method of Cypres - Google Patents
A kind of preparation method of Cypres Download PDFInfo
- Publication number
- CN108690169A CN108690169A CN201810593783.7A CN201810593783A CN108690169A CN 108690169 A CN108690169 A CN 108690169A CN 201810593783 A CN201810593783 A CN 201810593783A CN 108690169 A CN108690169 A CN 108690169A
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- parts
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- cypres
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Abstract
The invention discloses a kind of preparation methods of Cypres, include the following steps:Prepare mix monomer, prepare initiator solution, 350 parts by weight of deionized water are added into a jacketed stirred tank, stirring is opened, the oxidised maize starch of 45~50 parts by weight is added, opens heating, when temperature of charge reaches 90 DEG C, heat preservation 30 minutes, sequentially adds 8~10 parts by weight of vitamin C, 2~3 parts by weight of hydrogen peroxide, then keeps the temperature 15 minutes;Add 1~1.5 parts by weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains Cypres.
Description
Technical field
The present invention relates to a kind of preparation method of Cypres, specifically a kind of system of surface sizing agent for paper making
Preparation Method.
Background technology
Top sizing be it is a kind of to paper surface processing to improve the important way of its application performance.It is needed in processing procedure
It to be coated with a certain amount of sizing material in the equal sentence of paper surface(General coating weight control is in 0.3~2g/m2Between).At top sizing
Reason not only increases the resistant to liquids penetrating power of paper, and can also improve its mechanical strength, surface property and printing performance, together
When reduce the dosage of internal sizing agent, alleviate due to the problems such as machinery stains caused by plasm-glue-blending.Cypres
Type is divided into three kinds of cationic, anionic and nonionic.Cationic surface-sizing agent can be to the moon of paper fibre
Ionic group generates suction-operated, and hydrophobic grouping forms hydrophobic layer after stablizing, so as to improve the performance of paper.Anionic surface
Sizing agent using when need additional precipitating reagent to be complexed and be gathered in paper surface, the performance of paper is improved after film forming.
The principal item of Cypres have starch, guar gum, gelatin, cellulose and hemicellulose, shellac, chitin and
Alginic acid, gum rosin etc..With the development of petrochemical industry and high polymer synthesis industry, the surface of acrylate polymer series is applied
Application of the jelly in papermaking is more and more extensive.It includes the homopolymer and copolymer of acrylic ester monomer.For producing third
The monomer of olefine acid ester polymer can be divided into soft monomer, hard monomer and function monomer three classes.Glass transition temperature is lower(Methyl)
Alkyl acrylate is common soft monomer, it has softness, good fluidity, adhesion strength high and is easy to soak sticker surface etc.
Feature.But since cohesive performance is undesirable, polymer prepared by when exclusive use is too soft to influence practical application performance.Therefore,
People are generally copolymerized using the higher hard monomer of glass transition temperature and soft monomer to adjust the glass transition temperature of polymer, and raising makes
With temperature, improve hydrophobicity, adhesive strength and the transparency.In the molecule of function monomer containing carboxyl, epoxy group, hydroxyl, amido,
The functional groups such as amide groups can adjust the polarity of polymerizate, and can form crosslinking polymer, realize the work(of polymer
Energyization.Due to acrylate polymer have excellent weatherability, film forming and caking property, molecular structure can as needed into
Row adjustment, and multiple functions monomer can be added, polymer is made to have special function, it can significantly improve the property of paper
Can, become the research hotspot of domestic and foreign scholars.Someone has synthesized the cationic crosslinked polymerization containing epoxy and quaternary ammonium group
Object Cypres have studied influence of the factors such as monomeric species and dosage, initiator type to top sizing effect.Grind the hair that makes internal disorder or usurp
The film forming of existing surface size can significantly improve paper performance.Azodiisobutyronitrile is to be suitable for preparing efficient surface sizing agent
Initiator.
Chinese patent CN201711098672.0 discloses a kind of Cypres and its preparation method and application, wherein table
Surface sizing agent percentage composition by weight includes following raw material components:Bulk composition 20%~40%, hydrophilic resin 3%~15%,
Mould inhibitor 2%~12%, ethylene absorbent 1%~6%, auxiliary agent 0.5%~2%, water 50%~70%;The wherein described main body at
It is selected from one or more in rosin, gelatin and starch, the ethylene absorbent is the carrier for loading active ingredient, institute
It states active constituent and is selected from least one of potassium permanganate, calper calcium peroxide and silver chlorate.The combination of the Cypres and fiber
Power is good, and the surface that can be applied to paper forms one layer of fine and close film, and paper is made to have certain water-retaining property.Especially suitable for fruits and vegetables
Packaging and fresh-keeping, play the role of bacteria mildew-proof, reduce ethylene concentration in packaging, avoid fruits and vegetables water loss, extend fruits and vegetables
Freshness date.Meanwhile the film that densification is formed in paper surface can also improve the toughness and surface strength of paper.
Chinese patent CN201710665792.8 discloses a kind of double corrugated paper Cypres, by the raw material of following number
Group is grouped as:25~35 parts of cornstarch, 15~25 parts of purple sweet potato starch, 10~20 parts of sodium sulphate, perfluoro butyl sulfonic acid fluoride 10~
15 parts, it is 2~18 parts of triethanolamine, 1~5 part of citric acid, 5~15 parts of petroleum sodium sulfonate, 2~4 parts of fatty alcohol polyoxyethylene ether, right
2~4 parts of nitrobenzoic acid, 1~2 part of sodium tetraborate, 2~3 parts of dimethyl maleic anhydride, modified oxidized dose 10~15 parts, go from
Sub- water is several, and sizing agent of the present invention of the invention is glittering and translucent, and no foreign pigment, viscosity greatly enhances, stronger than common sizing agent
70-80%.
Chinese patent CN201710630865.X discloses a kind of preparation method of the anti-Cypres that get damp, composition portion
It includes 600-700 parts of polyamino resin, 195-215 parts, 135-160 parts glyoxals of styrene-acrylic resin, 70-90 parts of aluminum sulfate, 7-12 to divide
180-195 parts and 650-750 parts part zirconium oxychloride, alkyl Xi ketone dimers water.These types of goods and materials compounding composition it is anti-get damp it is poly-
Polyimide resin emulsifier can form highly stable lotion after emulsifying alkyl Xi ketone dimers, after top sizing, in paper
The excellent water resistant coating of the quick forming properties in surface, this coating is with little need for curing, and machine is generate 100% anti-under paper
Outlet capacity, will not be grown because of the maturation period causes paper to get damp and influences intensity and water resistant ability.
Chinese patent CN201710607175.2 discloses a kind of corrugated paper Cypres and preparation method thereof, the corrugation
Paper Cypres include the raw material of following parts by weight:20-35 parts of siloxanes, 50-100 parts of stearic acid, (methyl) acrylate
20-35 parts of class monomer, 60-70 parts of (methyl) styrene, 6-7 parts of cationic monomer, 20-30 parts of dispersant, cross-linking monomer 2-3
Part, 2-3 parts of emulsifier, 0.5-3 parts of initiator, 800-1000 parts of water.It is a large amount of to contain due to the stearic acid used in the present invention
The reason of carboxyl can be combined with the carboxyl of fiber surface, improved its bonding force between corrugated paper, improved corrugated paper
Ring crush intensity.
Invention content
A kind of preparation method of Cypres of the present invention, includes the following steps:Prepare mix monomer:By acrylic acid fourth
30~35 parts by weight of ester, 55~60 parts by weight of styrene, 8~12 parts by weight of acrylonitrile carry out being mixed and made into mix monomer;
Prepare initiator solution:1~2 parts by weight of hydrogen peroxide, 50 parts by weight of deionized water carry out being mixed and made into initiator water-soluble
Liquid;
350 parts by weight of deionized water are added into a jacketed stirred tank, open stirring, the oxidation that 45~50 parts by weight are added is beautiful
Rice starch, open heating, when temperature of charge reaches 90 DEG C, keep the temperature 30 minutes, sequentially add 8~10 parts by weight of vitamin C,
Then 2~3 parts by weight of hydrogen peroxide keep the temperature 15 minutes;Add 1~1.5 weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate
Measure part;Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, had fed
1 hour is kept the temperature in 90 DEG C of temperature after, obtains Cypres.
Specific implementation mode
Embodiment 1
Prepare mix monomer:35 kg of butyl acrylate, 60 kg of styrene, 12 kg of acrylonitrile are carried out to be mixed and made into mixing list
Body;
Prepare initiator solution:2 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution;
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 50 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 10 kg of vitamin C, 3 kg of hydrogen peroxide, then
Heat preservation 15 minutes;Add 1.5 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to mix simultaneously
Close monomer and initiator solution, the time is added at 4 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains
Cypres.
Embodiment 2
Prepare mix monomer:30 kg of butyl acrylate, 55 kg of styrene, 8 kg of acrylonitrile are carried out to be mixed and made into mixing list
Body;
Prepare initiator solution:1 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution;
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 45 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8 kg of vitamin C, 2 kg of hydrogen peroxide, then protect
Temperature 15 minutes;Add 1 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to mixing list simultaneously
Body and initiator solution, control are added the time at 2 hours, keep the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtain surface
Sizing agent.
Embodiment 3
Prepare mix monomer:35 kg of butyl acrylate, 55 kg of styrene, 12 kg of acrylonitrile are carried out to be mixed and made into mixing list
Body;
Prepare initiator solution:1 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution;
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 50 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8 kg of vitamin C, 3 kg of hydrogen peroxide, then protect
Temperature 15 minutes;Add 1 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to mixing list simultaneously
Body and initiator solution, control are added the time at 4 hours, keep the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtain surface
Sizing agent.
Embodiment 4
Prepare mix monomer:33 kg of butyl acrylate, 58 kg of styrene, 10 kg of acrylonitrile are carried out to be mixed and made into mixing list
Body;
Prepare initiator solution:Hydrogen peroxide 1.5kg, 50 kg of deionized water carry out being mixed and made into initiator solution;
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 48 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 9 kg of vitamin C, 2.5 kg of hydrogen peroxide, then
Heat preservation 15 minutes;Add 1.2 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to mix simultaneously
Close monomer and initiator solution, the time is added at 3 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains
Cypres.
Embodiment 5
Prepare mix monomer:34 kg of butyl acrylate, 56 kg of styrene, 11 kg of acrylonitrile are carried out to be mixed and made into mixing list
Body;
Prepare initiator solution:1.8 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution;
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 47 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8.8 kg of vitamin C, 2.8 kg of hydrogen peroxide, so
Keep the temperature 15 minutes afterwards;Add 1.3 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate;Then start to be slowly added to simultaneously
Mix monomer and initiator solution, control are added the time at 3.5 hours, 1 hour are kept the temperature in 90 DEG C of temperature after the completion of charging,
Obtain Cypres.
Claims (1)
1. a kind of preparation method of Cypres, includes the following steps:Prepare mix monomer:By 30~35 weight of butyl acrylate
Amount part, 55~60 parts by weight of styrene, 8~12 parts by weight of acrylonitrile carry out being mixed and made into mix monomer;
Prepare initiator solution:1~2 parts by weight of hydrogen peroxide, 50 parts by weight of deionized water carry out being mixed and made into initiator water-soluble
Liquid;
350 parts by weight of deionized water are added into a jacketed stirred tank, open stirring, the oxidation that 45~50 parts by weight are added is beautiful
Rice starch, open heating, when temperature of charge reaches 90 DEG C, keep the temperature 30 minutes, sequentially add 8~10 parts by weight of vitamin C,
Then 2~3 parts by weight of hydrogen peroxide keep the temperature 15 minutes;Add 1~1.5 weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate
Measure part;Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, had fed
1 hour is kept the temperature in 90 DEG C of temperature after, obtains Cypres.
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CN201810593783.7A CN108690169A (en) | 2018-06-11 | 2018-06-11 | A kind of preparation method of Cypres |
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CN201810593783.7A CN108690169A (en) | 2018-06-11 | 2018-06-11 | A kind of preparation method of Cypres |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112593451A (en) * | 2020-12-16 | 2021-04-02 | 苏州恒康新材料有限公司 | Folding-resistant and breaking-resistant sizing agent, production line and process |
CN113150215A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of environment-friendly emulsion for coating synthetic paper |
CN113150202A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of surface sizing agent |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4171407A (en) * | 1976-10-18 | 1979-10-16 | Rohm Gmbh | Method of making aqueous emulsions of acrylate copolymers in the presence of a degraded starch protective colloid |
CN104141259A (en) * | 2014-07-01 | 2014-11-12 | 江苏思利达化工有限公司 | Environment-friendly cationic phenylpropyl surface sizing agent and preparation method thereof |
CN106320073A (en) * | 2015-06-19 | 2017-01-11 | 上海东升新材料有限公司 | Surface sizing agent emulsion and preparation method and application thereof |
-
2018
- 2018-06-11 CN CN201810593783.7A patent/CN108690169A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4171407A (en) * | 1976-10-18 | 1979-10-16 | Rohm Gmbh | Method of making aqueous emulsions of acrylate copolymers in the presence of a degraded starch protective colloid |
CN104141259A (en) * | 2014-07-01 | 2014-11-12 | 江苏思利达化工有限公司 | Environment-friendly cationic phenylpropyl surface sizing agent and preparation method thereof |
CN106320073A (en) * | 2015-06-19 | 2017-01-11 | 上海东升新材料有限公司 | Surface sizing agent emulsion and preparation method and application thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112593451A (en) * | 2020-12-16 | 2021-04-02 | 苏州恒康新材料有限公司 | Folding-resistant and breaking-resistant sizing agent, production line and process |
CN113150215A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of environment-friendly emulsion for coating synthetic paper |
CN113150202A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of surface sizing agent |
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