CN108677605A - A kind of Cypres and preparation method thereof - Google Patents
A kind of Cypres and preparation method thereof Download PDFInfo
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- CN108677605A CN108677605A CN201810595773.7A CN201810595773A CN108677605A CN 108677605 A CN108677605 A CN 108677605A CN 201810595773 A CN201810595773 A CN 201810595773A CN 108677605 A CN108677605 A CN 108677605A
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The invention discloses a kind of Cypres and preparation method thereof, include the following steps：Prepare mix monomer, prepare initiator solution, 350 parts by weight of deionized water are added into a jacketed stirred tank, stirring is opened, the oxidised maize starch of 45~50 parts by weight is added, opens heating, when temperature of charge reaches 90 DEG C, heat preservation 30 minutes, sequentially adds 8~10 parts by weight of vitamin C, 2~3 parts by weight of hydrogen peroxide, then keeps the temperature 15 minutes；Add 1~1.5 parts by weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains Cypres.
Description
Technical field
The present invention relates to a kind of Cypres and preparation method thereof, specifically a kind of surface sizing agent for paper making
Preparation method.
Background technology
The principal item of Cypres have starch, guar gum, gelatin, cellulose and hemicellulose, shellac, chitin and
Alginic acid, gum rosin etc..With the development of petrochemical industry and high polymer synthesis industry, the surface of acrylate polymer series is applied
Application of the jelly in papermaking is more and more extensive.It includes the homopolymer and copolymer of acrylic ester monomer.For producing third
The monomer of olefine acid ester polymer can be divided into soft monomer, hard monomer and function monomer three classes.Glass transition temperature is lower（Methyl）
Alkyl acrylate is common soft monomer, it has softness, good fluidity, adhesion strength high and is easy to soak sticker surface etc.
Feature.But since cohesive performance is undesirable, polymer prepared by when exclusive use is too soft to influence practical application performance.Therefore,
People are generally copolymerized using the higher hard monomer of glass transition temperature and soft monomer to adjust the glass transition temperature of polymer, and raising makes
With temperature, improve hydrophobicity, adhesive strength and the transparency.In the molecule of function monomer containing carboxyl, epoxy group, hydroxyl, amido,
The functional groups such as amide groups can adjust the polarity of polymerizate, and can form crosslinking polymer, realize the work(of polymer
Energyization.Due to acrylate polymer have excellent weatherability, film forming and caking property, molecular structure can as needed into
Row adjustment, and multiple functions monomer can be added, polymer is made to have special function, it can significantly improve the property of paper
Can, become the research hotspot of domestic and foreign scholars.Someone has synthesized the cationic crosslinked polymerization containing epoxy and quaternary ammonium group
Object Cypres have studied influence of the factors such as monomeric species and dosage, initiator type to top sizing effect.Grind the hair that makes internal disorder or usurp
The film forming of existing surface size can significantly improve paper performance.Azodiisobutyronitrile is to be suitable for preparing efficient surface sizing agent
Initiator.
Fu little Long etc. is connect using the method for emulsifier-free emulsion polymerization on cationic starch molecule using Fenton reagent as initiator
Branch styrene-acrylic monomer, has synthesized a kind of St/ba Soap-free Emulsion Cypres.The emulsion particle diameter narrow distribution of synthesis, film forming
Property is preferable.When Cypres dosage is 0.4%, the ring crush index and degree of sizing of paper significantly improve.Somebody is with benzene second
Alkene, butyl acrylate, acrylamide, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and vinyl silane triisopropoxide are original
Material, cation type organic silicon acrylic acid ester emulsion Cypres are prepared for by semi-continuous emulsion polymerizing method.The lotion has
There is excellent stability, can significantly improve the hydrophobicity and mechanical performance of corrugated paper.It is glued body with pure anion tapioca
System compares, and is applied using what 0.4% cation type organic silicon acrylic acid ester emulsion and 99.6% anion tapioca formed
Colloid system handling of paper can make its Cobb value decline 40%, and ring crush index increases by 20%.Zhang Guanghua etc. is good using compatibility
Vinyl monomer dissolving recycling waste polystyrene foam material, be prepared for the no-solvent type Cypres haveing excellent performance,
This Cypres can make the top sizing degree of paper improve 17 times, and ring crush intensity improves 21%, and deflection improves 33%.
In emulsion polymerization systems using reactive emulsifier partly or entirely replace conventional emulsifier method be in recent years
Come a kind of New Emulsion polymerization to grow up.The method avoids the residuals of emulsifier, reduce whole system
Foaming characteristic improves the caking property, hydrophobicity and lustrous surface of film convenient for preparing pure polymer.Recent year
Outer scholar attaches great importance to the exploitation of maleic anhydride type reactive emulsifier.The emulsifier of the type both has efficient emulsifying power
Power, and being copolymerized with monomer, emulsion particle particle diameter distribution is narrow, can prepare the lotion of high solids content, and polymer is answered
It is also obviously improved with performance.
Chinese patent CN201621022116.6 discloses a kind of preparation system of Cypres, and the preparation system includes
Starch slurry preparation vessel, starch slurry accumulator tank, reactive tank, jet cooking device and the gelatinized corn starch accumulator tank being sequentially communicated, the shallow lake
The first filter device, the reactive tank and the injection are provided between slurry preparation vessel and the starch slurry accumulator tank
The second filter device is provided between boiling vessel, second filter device includes that first filter and second in parallel filters
There are one be a kind of reserve filter Cypres of the present invention in device, the first filter and the second filter
Preparation system, increase the second filter device, glue fully filtered.Second filter device includes two mistakes
Filter is arranged in parallel, the using and the reserved, and after running a period of time, filter pressure increases, and filter automatic switchover may be implemented, from
Dynamic cleaning, improves the cleanliness factor of glue, ensures the stabilization of system.
Chinese patent CN201610745869.8 discloses the preparation method of kind of Cypres, includes the following steps：Step
Rapid one, methyl styrene, acrylic ester monomer, cationic monomer and initiator are uniformly mixed and form mix monomer；Step
Two, the mix monomer obtained in 10% step 1 is added in four-hole boiling flask, is warming up to 80-140 DEG C, reaction is dripped after 5-20 minutes
Add remaining mix monomer, then keeps the temperature 0.5-1.5 hours for 80-140 DEG C；Acetic acid, 80-140 DEG C of reaction 20- is added in step 3
60 minutes；The deionized water of 80-100 DEG C of preheating is added in step 4, and the reaction was continued 0.5-2 hours, after being cooled to 25-35 DEG C, adds
Enter zirconates, stir evenly, filters, obtain Cypres.Cobb values, energy can be not only greatly reduced in the Cypres of the present invention
Rapid aging, substantially lower machine is just ripe, and the surface strength of body paper can be significantly put forward in the case where sizing agent dosage is constant.
Chinese patent CN201610747554.7 discloses preparation method and its production of a kind of corrugated paper Cypres
Product and application.Wherein, the corrugated paper Cypres are mixed by corrugated paper Cypres base-material, cationic additive
Uniformly it is made；The preparation process of corrugated paper Cypres base-material includes：By cationic monomer, zirconates,（Methyl）Acrylic acid
Esters monomer,（Methyl）Styrene, initiator, acetic acid and water are added into reaction vessel, carry out Raolical polymerizable, generate
Corrugated paper Cypres base-material；The preparation process of cationic additive includes：By alkyl ketene dimer be added Zhiyang from
It in the aqueous solution of sub- emulsifier, is sufficiently stirred, carries out emulsion dispersion, obtain cationic additive.It is provided according to the present invention
Cypres made from method can not only be greatly reduced Cobb values, and can rapid aging, substantially lower machine is just ripe, and can be
The ring crush intensity of corrugated paper is increased substantially in the case that sizing agent dosage is constant.
Chinese patent CN201610747606.0 discloses preparation method and its production of a kind of corrugated paper Cypres
Product and application.Wherein, the corrugated paper Cypres are mixed by corrugated paper Cypres base-material, cationic additive
Uniformly it is made；The preparation process of corrugated paper Cypres base-material includes：By cationic monomer, cross-linking monomer,（Methyl）Third
Olefin(e) acid esters monomer,（Methyl）Styrene, initiator, acetic acid and water are added into reaction vessel, carry out Raolical polymerizable,
Generate corrugated paper Cypres base-material；The preparation process of cationic additive includes：By alkyl ketene dimer be added to
It in the aqueous solution of cationic emulsifier, is sufficiently stirred, carries out emulsion dispersion, obtain cationic additive.It is carried according to the present invention
Cypres are not only able to rapid aging made from the method for confession, increase substantially the ring crush intensity of corrugated paper, are greatly reduced
Cobb values, and with very strong anti-performance of getting damp.
Invention content
A kind of Cypres and preparation method thereof of the present invention, include the following steps：Prepare mix monomer：By acrylic acid
30~35 parts by weight of butyl ester, 10~15 parts by weight of glycidyl methacrylate, 55~60 parts by weight of styrene, acrylonitrile 8
~12 parts by weight carry out being mixed and made into mix monomer；
Prepare initiator solution：1~2 parts by weight of hydrogen peroxide, 50 parts by weight of deionized water carry out being mixed and made into initiator water-soluble
Liquid；
350 parts by weight of deionized water are added into a jacketed stirred tank, open stirring, the oxidation that 45~50 parts by weight are added is beautiful
Rice starch, open heating, when temperature of charge reaches 90 DEG C, keep the temperature 30 minutes, sequentially add 8~10 parts by weight of vitamin C,
Then 2~3 parts by weight of hydrogen peroxide keep the temperature 15 minutes；Add 1~1.5 weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate
Measure part；Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, had fed
1 hour is kept the temperature in 90 DEG C of temperature after, obtains Cypres.
Specific implementation mode
Embodiment 1
Prepare mix monomer：By 35 kg of butyl acrylate, 10 kg of glycidyl methacrylate, 60 kg of styrene, propylene
12 kg of nitrile carries out being mixed and made into mix monomer；
Prepare initiator solution：2 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution；
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 50 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 10 kg of vitamin C, 3 kg of hydrogen peroxide, then
Heat preservation 15 minutes；Add 1.5 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to mix simultaneously
Close monomer and initiator solution, the time is added at 4 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains
Cypres.
Embodiment 2
Prepare mix monomer：By 30 kg of butyl acrylate, 15 kg of glycidyl methacrylate, 55 kg of styrene, propylene
8 kg of nitrile carries out being mixed and made into mix monomer；
Prepare initiator solution：1 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution；
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 45 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8 kg of vitamin C, 2 kg of hydrogen peroxide, then protect
Temperature 15 minutes；Add 1 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to mixing list simultaneously
Body and initiator solution, control are added the time at 2 hours, keep the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtain surface
Sizing agent.
Embodiment 3
Prepare mix monomer：By 35 kg of butyl acrylate, 15 kg of glycidyl methacrylate, 55 kg of styrene, propylene
12 kg of nitrile carries out being mixed and made into mix monomer；
Prepare initiator solution：1 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution；
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 50 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8 kg of vitamin C, 3 kg of hydrogen peroxide, then protect
Temperature 15 minutes；Add 1 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to mixing list simultaneously
Body and initiator solution, control are added the time at 4 hours, keep the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtain surface
Sizing agent.
Embodiment 4
Prepare mix monomer：By 33 kg of butyl acrylate, 13 kg of glycidyl methacrylate, 58 kg of styrene, propylene
10 kg of nitrile carries out being mixed and made into mix monomer；
Prepare initiator solution：Hydrogen peroxide 1.5kg, 50 kg of deionized water carry out being mixed and made into initiator solution；
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 48 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 9 kg of vitamin C, 2.5 kg of hydrogen peroxide, then
Heat preservation 15 minutes；Add 1.2 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to mix simultaneously
Close monomer and initiator solution, the time is added at 3 hours in control, keeps the temperature 1 hour in 90 DEG C of temperature after the completion of charging, obtains
Cypres.
Embodiment 5
Prepare mix monomer：By 34 kg of butyl acrylate, 12 kg of glycidyl methacrylate, 56 kg of styrene, propylene
11 kg of nitrile carries out being mixed and made into mix monomer；
Prepare initiator solution：1.8 kg of hydrogen peroxide, 50 kg of deionized water carry out being mixed and made into initiator solution；
350 kg of deionized water is added into a jacketed stirred tank, opens stirring, the oxidised maize starch of 47 kg is added, opens
Heating is opened, when temperature of charge reaches 90 DEG C, 30 minutes is kept the temperature, sequentially adds 8.8 kg of vitamin C, 2.8 kg of hydrogen peroxide, so
Keep the temperature 15 minutes afterwards；Add 1.3 kg of emulsifier dodecyl polyethylene glycol oxide sodium sulphate；Then start to be slowly added to simultaneously
Mix monomer and initiator solution, control are added the time at 3.5 hours, 1 hour are kept the temperature in 90 DEG C of temperature after the completion of charging,
Obtain Cypres.
Claims (1)
1. a kind of Cypres and preparation method thereof, include the following steps：Prepare mix monomer：By butyl acrylate 30~35
Parts by weight, 10~15 parts by weight of glycidyl methacrylate, 55~60 parts by weight of styrene, 8~12 parts by weight of acrylonitrile
It carries out being mixed and made into mix monomer；
Prepare initiator solution：1~2 parts by weight of hydrogen peroxide, 50 parts by weight of deionized water carry out being mixed and made into initiator water-soluble
Liquid；
350 parts by weight of deionized water are added into a jacketed stirred tank, open stirring, the oxidation that 45~50 parts by weight are added is beautiful
Rice starch, open heating, when temperature of charge reaches 90 DEG C, keep the temperature 30 minutes, sequentially add 8~10 parts by weight of vitamin C,
Then 2~3 parts by weight of hydrogen peroxide keep the temperature 15 minutes；Add 1~1.5 weight of emulsifier dodecyl polyethylene glycol oxide sodium sulphate
Measure part；Then start to be slowly added to mix monomer and initiator solution simultaneously, the time was added at 2~4 hours in control, had fed
1 hour is kept the temperature in 90 DEG C of temperature after, obtains Cypres.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810595773.7A CN108677605A (en) | 2018-06-11 | 2018-06-11 | A kind of Cypres and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810595773.7A CN108677605A (en) | 2018-06-11 | 2018-06-11 | A kind of Cypres and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108677605A true CN108677605A (en) | 2018-10-19 |
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| CN201810595773.7A Pending CN108677605A (en) | 2018-06-11 | 2018-06-11 | A kind of Cypres and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150215A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of environment-friendly emulsion for coating synthetic paper |
| CN113150202A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of surface sizing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225623A (en) * | 2008-01-09 | 2008-07-23 | 杨春先 | Surface sizing agent for paper making |
| CN101558093A (en) * | 2006-12-14 | 2009-10-14 | 巴斯夫欧洲公司 | Fine-particulate polymer dispersions comprising starch |
| CN104592448A (en) * | 2014-05-10 | 2015-05-06 | 嘉兴市汇丰环保材料有限公司 | Surface sizing agent preparation method |
| CN108004841A (en) * | 2017-12-25 | 2018-05-08 | 浙江传化华洋化工有限公司 | A kind of Cypres and preparation method thereof |
-
2018
- 2018-06-11 CN CN201810595773.7A patent/CN108677605A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101558093A (en) * | 2006-12-14 | 2009-10-14 | 巴斯夫欧洲公司 | Fine-particulate polymer dispersions comprising starch |
| CN101225623A (en) * | 2008-01-09 | 2008-07-23 | 杨春先 | Surface sizing agent for paper making |
| CN104592448A (en) * | 2014-05-10 | 2015-05-06 | 嘉兴市汇丰环保材料有限公司 | Surface sizing agent preparation method |
| CN108004841A (en) * | 2017-12-25 | 2018-05-08 | 浙江传化华洋化工有限公司 | A kind of Cypres and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150215A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of environment-friendly emulsion for coating synthetic paper |
| CN113150202A (en) * | 2021-05-10 | 2021-07-23 | 华东理工大学 | Preparation method of surface sizing agent |
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Application publication date: 20181019 |
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