CN108676364A - A kind of plasticizer - Google Patents
A kind of plasticizer Download PDFInfo
- Publication number
- CN108676364A CN108676364A CN201810465552.8A CN201810465552A CN108676364A CN 108676364 A CN108676364 A CN 108676364A CN 201810465552 A CN201810465552 A CN 201810465552A CN 108676364 A CN108676364 A CN 108676364A
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- CN
- China
- Prior art keywords
- parts
- acid
- glycol
- plasticizer
- ethylenediamine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of plasticizer, which is characterized in that is made of the raw material of following parts by weight：15 20 parts of terephthalic acid (TPA), 18 25 parts of methyl benzoate, 20 30 parts of dioctyl terephthalate, 15 20 parts of P-hydroxybenzoic acid, 6 15 parts of dibutyl ester, 8 12 parts of ethylenediamine, 35 parts of zinc borate, 5 10 parts of paraffin, 35 parts of diethylene glycol (DEG), 45 parts of triethylene glycol, 25 parts of roseolic acid, 5 10 parts of polyethylene glycol, 68 parts of polyvinyl alcohol of acetalization, 56 parts of ethylene glycol monobutyl ether, 67 parts of amido silicon oil, 34 parts of soda ash.The present invention provides a kind of plasticizer, environmentally friendly, of low cost, plasticization temperature is low, and adhesiveness is good, low-residual viscosity, and weatherability is stronger.
Description
Technical field
The present invention relates to field of material technology more particularly to a kind of plasticizer.
Background technology
Conventional plasticizers usually used at present, the flexibility and elasticity of moulded products vary over, and influence
Product quality, and make product surface that there is viscosity.And conventional plasticizer weatherability is poor, and purposes has apparent limitation
Property.Chemical stability at plasticizer performance major criterion.People also increasingly increase the environmental requirement of plasticizer simultaneously.
Invention content
Environmentally friendly, of low cost, plasticization temperature is low the object of the present invention is to provide a kind of plasticizer, adhesiveness is good, low
Residual tack, and weatherability is stronger.
Technical scheme of the present invention：A kind of plasticizer, which is characterized in that be made of the raw material of following parts by weight：It is right
15-20 parts of phthalic acid, 18-25 parts of methyl benzoate, 20-30 parts of dioctyl terephthalate, P-hydroxybenzoic acid 15-20
Part, 6-15 parts of dibutyl ester, 8-12 parts of ethylenediamine, 3-5 parts of zinc borate, 5-10 parts of paraffin, 3-5 parts of diethylene glycol (DEG), 4-5 parts of triethylene glycol,
2-5 parts of roseolic acid, 5-10 parts of polyethylene glycol, 6-8 parts of polyvinyl alcohol of acetalization, 5-6 parts of ethylene glycol monobutyl ether, amido silicon oil 6-7
Part, 3-4 parts of soda ash.
A kind of plasticizer above-mentioned, which is characterized in that be made of the raw material of following parts by weight：Terephthalic acid (TPA) 15
Part, 18 parts of methyl benzoate, 20 parts of dioctyl terephthalate, 15 parts of P-hydroxybenzoic acid, 6 parts of dibutyl ester, 8 parts of ethylenediamine,
3 parts of zinc borate, 5 parts of paraffin, 3 parts of diethylene glycol (DEG), 4 parts of triethylene glycol, 2 parts of roseolic acid, 5 parts of polyethylene glycol, polyvinyl alcohol of acetalization 6
Part, 5 parts of ethylene glycol monobutyl ether, 6 parts of amido silicon oil, 3 parts of soda ash.
A kind of plasticizer above-mentioned, which is characterized in that be made of the raw material of following parts by weight：Terephthalic acid (TPA) 20
Part, 25 parts of methyl benzoate, 30 parts of dioctyl terephthalate, 20 parts of P-hydroxybenzoic acid, 15 parts of dibutyl ester, ethylenediamine 12
Part, 5 parts of zinc borate, 10 parts of paraffin, 5 parts of diethylene glycol (DEG), 5 parts of triethylene glycol, 5 parts of roseolic acid, 10 parts of polyethylene glycol, acetalation polyethylene
8 parts of alcohol, 6 parts of ethylene glycol monobutyl ether, 7 parts of amido silicon oil, 4 parts of soda ash.
A kind of plasticizer above-mentioned, which is characterized in that be made of the raw material of following parts by weight：Terephthalic acid (TPA) 18
Part, 22 parts of methyl benzoate, 25 parts of dioctyl terephthalate, 18 parts of P-hydroxybenzoic acid, 10 parts of dibutyl ester, ethylenediamine 10
Part, 4 parts of zinc borate, 8 parts of paraffin, 4 parts of diethylene glycol (DEG), 4.5 parts of triethylene glycol, 3 parts of roseolic acid, 8 parts of polyethylene glycol, acetalation polyethylene
7 parts of alcohol, 5.5 parts of ethylene glycol monobutyl ether, 6.5 parts of amido silicon oil, 3.5 parts of soda ash.
Beneficial effects of the present invention：It is environmentally friendly, of low cost, plasticization temperature is low, adhesiveness is good, low-residual viscosity, and weather-proof
Property is stronger.
Specific implementation mode
The present invention is further illustrated for following example, but is not intended as the foundation limited the present invention.
Embodiment 1：A kind of plasticizer is made of the raw material of following parts by weight：15-20 parts of terephthalic acid (TPA), benzene first
Sour methyl esters 18-25 parts, 20-30 parts of dioctyl terephthalate, 15-20 parts of P-hydroxybenzoic acid, 6-15 parts of dibutyl ester, ethylenediamine
8-12 parts, 3-5 parts of zinc borate, 5-10 parts of paraffin, 3-5 parts of diethylene glycol (DEG), 4-5 parts of triethylene glycol, 2-5 parts of roseolic acid, polyethylene glycol 5-
10 parts, 6-8 parts of polyvinyl alcohol of acetalization, 5-6 parts of ethylene glycol monobutyl ether, 6-7 parts of amido silicon oil, 3-4 parts of soda ash.
Embodiment 2：A kind of plasticizer is made of the raw material of following parts by weight：15 parts of terephthalic acid (TPA), benzoic acid first
18 parts of ester, 20 parts of dioctyl terephthalate, 15 parts of P-hydroxybenzoic acid, 6 parts of dibutyl ester, 8 parts of ethylenediamine, 3 parts of zinc borate, stone
5 parts of wax, 3 parts of diethylene glycol (DEG), 4 parts of triethylene glycol, 2 parts of roseolic acid, 5 parts of polyethylene glycol, 6 parts of polyvinyl alcohol of acetalization, ethylene glycol only son
5 parts of ether, 6 parts of amido silicon oil, 3 parts of soda ash.
Embodiment 3：A kind of plasticizer is made of the raw material of following parts by weight：20 parts of terephthalic acid (TPA), benzoic acid first
25 parts of ester, 30 parts of dioctyl terephthalate, 20 parts of P-hydroxybenzoic acid, 15 parts of dibutyl ester, 12 parts of ethylenediamine, 5 parts of zinc borate,
10 parts of paraffin, 5 parts of diethylene glycol (DEG), 5 parts of triethylene glycol, 5 parts of roseolic acid, 10 parts of polyethylene glycol, 8 parts of polyvinyl alcohol of acetalization, ethylene glycol
6 parts of monobutyl ether, 7 parts of amido silicon oil, 4 parts of soda ash.
Embodiment 4：A kind of plasticizer is made of the raw material of following parts by weight：18 parts of terephthalic acid (TPA), benzoic acid first
22 parts of ester, 25 parts of dioctyl terephthalate, 18 parts of P-hydroxybenzoic acid, 10 parts of dibutyl ester, 10 parts of ethylenediamine, 4 parts of zinc borate,
8 parts of paraffin, 4 parts of diethylene glycol (DEG), 4.5 parts of triethylene glycol, 3 parts of roseolic acid, 8 parts of polyethylene glycol, 7 parts of polyvinyl alcohol of acetalization, ethylene glycol
5.5 parts of monobutyl ether, 6.5 parts of amido silicon oil, 3.5 parts of soda ash.
Claims (4)
1. a kind of plasticizer, which is characterized in that be made of the raw material of following parts by weight：15-20 parts of terephthalic acid (TPA), benzene first
Sour methyl esters 18-25 parts, 20-30 parts of dioctyl terephthalate, 15-20 parts of P-hydroxybenzoic acid, 6-15 parts of dibutyl ester, ethylenediamine
8-12 parts, 3-5 parts of zinc borate, 5-10 parts of paraffin, 3-5 parts of diethylene glycol (DEG), 4-5 parts of triethylene glycol, 2-5 parts of roseolic acid, polyethylene glycol 5-
10 parts, 6-8 parts of polyvinyl alcohol of acetalization, 5-6 parts of ethylene glycol monobutyl ether, 6-7 parts of amido silicon oil, 3-4 parts of soda ash.
2. a kind of plasticizer according to claim 1, which is characterized in that be made of the raw material of following parts by weight：It is right
15 parts of phthalic acid, 18 parts of methyl benzoate, 20 parts of dioctyl terephthalate, 15 parts of P-hydroxybenzoic acid, 6 parts of dibutyl ester,
8 parts of ethylenediamine, 3 parts of zinc borate, 5 parts of paraffin, 3 parts of diethylene glycol (DEG), 4 parts of triethylene glycol, 2 parts of roseolic acid, 5 parts of polyethylene glycol, acetalation
6 parts of polyvinyl alcohol, 5 parts of ethylene glycol monobutyl ether, 6 parts of amido silicon oil, 3 parts of soda ash.
3. a kind of plasticizer according to claim 1, which is characterized in that be made of the raw material of following parts by weight：It is right
20 parts of phthalic acid, 25 parts of methyl benzoate, 30 parts of dioctyl terephthalate, 20 parts of P-hydroxybenzoic acid, 15 parts of dibutyl ester,
12 parts of ethylenediamine, 5 parts of zinc borate, 10 parts of paraffin, 5 parts of diethylene glycol (DEG), 5 parts of triethylene glycol, 5 parts of roseolic acid, 10 parts of polyethylene glycol, acetal
Change 8 parts of polyvinyl alcohol, 6 parts of ethylene glycol monobutyl ether, 7 parts of amido silicon oil, 4 parts of soda ash.
4. a kind of plasticizer according to claim 1, which is characterized in that be made of the raw material of following parts by weight：It is right
18 parts of phthalic acid, 22 parts of methyl benzoate, 25 parts of dioctyl terephthalate, 18 parts of P-hydroxybenzoic acid, 10 parts of dibutyl ester,
10 parts of ethylenediamine, 4 parts of zinc borate, 8 parts of paraffin, 4 parts of diethylene glycol (DEG), 4.5 parts of triethylene glycol, 3 parts of roseolic acid, 8 parts of polyethylene glycol, acetal
Change 7 parts of polyvinyl alcohol, 5.5 parts of ethylene glycol monobutyl ether, 6.5 parts of amido silicon oil, 3.5 parts of soda ash.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810465552.8A CN108676364A (en) | 2018-05-16 | 2018-05-16 | A kind of plasticizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810465552.8A CN108676364A (en) | 2018-05-16 | 2018-05-16 | A kind of plasticizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108676364A true CN108676364A (en) | 2018-10-19 |
Family
ID=63806601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810465552.8A Withdrawn CN108676364A (en) | 2018-05-16 | 2018-05-16 | A kind of plasticizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108676364A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110832019A (en) * | 2017-12-04 | 2020-02-21 | 株式会社Lg化学 | Plasticizer composition and resin composition comprising the same |
-
2018
- 2018-05-16 CN CN201810465552.8A patent/CN108676364A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110832019A (en) * | 2017-12-04 | 2020-02-21 | 株式会社Lg化学 | Plasticizer composition and resin composition comprising the same |
| CN110832019B (en) * | 2017-12-04 | 2021-07-23 | 株式会社Lg化学 | Plasticizer composition and resin composition comprising the same |
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Application publication date: 20181019 |