CN108675717A - A kind of preparation method of oil resistant aerated bricks - Google Patents
A kind of preparation method of oil resistant aerated bricks Download PDFInfo
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- CN108675717A CN108675717A CN201810538308.XA CN201810538308A CN108675717A CN 108675717 A CN108675717 A CN 108675717A CN 201810538308 A CN201810538308 A CN 201810538308A CN 108675717 A CN108675717 A CN 108675717A
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- parts
- water
- oil resistant
- aerated bricks
- float stone
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- 239000011449 brick Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004568 cement Substances 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 17
- 239000010881 fly ash Substances 0.000 claims abstract description 14
- 239000006004 Quartz sand Substances 0.000 claims abstract description 10
- 238000009413 insulation Methods 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims description 51
- 239000002893 slag Substances 0.000 claims description 46
- 239000002002 slurry Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000004033 plastic Substances 0.000 claims description 15
- 229920003023 plastic Polymers 0.000 claims description 15
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 claims description 14
- 238000006396 nitration reaction Methods 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000000855 fermentation Methods 0.000 claims description 12
- 230000004151 fermentation Effects 0.000 claims description 12
- 241000361919 Metaphire sieboldi Species 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- 229960003638 dopamine Drugs 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011398 Portland cement Substances 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000010903 husk Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- 238000002604 ultrasonography Methods 0.000 claims description 5
- 235000014443 Pyrus communis Nutrition 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims 2
- 230000004048 modification Effects 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 238000004321 preservation Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 26
- 239000011268 mixed slurry Substances 0.000 abstract description 10
- 239000010721 machine oil Substances 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 3
- 235000019198 oils Nutrition 0.000 description 22
- 239000004567 concrete Substances 0.000 description 13
- 239000012065 filter cake Substances 0.000 description 9
- 239000010453 quartz Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 210000002966 serum Anatomy 0.000 description 5
- 238000009368 vermiculture Methods 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 241000220324 Pyrus Species 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 230000003487 anti-permeability effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- -1 DOPA Amine Chemical class 0.000 description 1
- WTDRDQBEARUVNC-UHFFFAOYSA-N L-Dopa Natural products OC(=O)C(N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229960004502 levodopa Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K67/00—Rearing or breeding animals, not otherwise provided for; New or modified breeds of animals
- A01K67/033—Rearing or breeding invertebrates; New breeds of invertebrates
- A01K67/0332—Earthworms
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/12—Animal feeding-stuffs obtained by microbiological or biochemical processes by fermentation of natural products, e.g. of vegetable material, animal waste material or biomass
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
- A23K10/37—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/20—Inorganic substances, e.g. oligoelements
- A23K20/28—Silicates, e.g. perlites, zeolites or bentonites
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K50/00—Feeding-stuffs specially adapted for particular animals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/203—Oil-proof or grease-repellant materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
- Y02P60/87—Re-use of by-products of food processing for fodder production
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of preparation methods of oil resistant aerated bricks, belong to building material technical field.The present invention is by cement, flyash, miberal powder, quartz sand, modified coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water are placed in batch mixer, under the conditions of rotating speed is 100~200r/min, it is stirred 30~50min, obtains mixed slurry, is then sprayed into mold and discards machine oil, mixed slurry is injected in mold again, after standing 5~10h of demoulding, demoulding obtains adobe；Adobe is placed in steam-cured kettle, is 2~3MPa in pressure, under the conditions of temperature is 160~180 DEG C, heat-insulation pressure keeping conserves 10~18h, then adds vapour brick to get oil resistant within 5~10 days through natural curing.Oil resistant provided by the invention adds vapour brick to have excellent oil-resistant characteristic and mechanical property.
Description
Technical field
The invention discloses a kind of preparation methods of oil resistant aerated bricks, belong to building material technical field.
Background technology
Aerated bricks are " autoclave aerated concrete building block ", and abbreviation aerated bricks are produced by autoclave at high temperature apparatus and process
Air-entrained concrete building block." aerated bricks " can be understood as a simplified or general title.Its product model covered
The brick product of other various technique productions including steam pressure will be used by enclosing.The advantages of aerated bricks is：1, again
Amount is light.The general weight of air-entrained concrete building block is 500~700kg/m3, is only equivalent to clay brick 1/4~1/5, normal concrete
1/5, be lighter one kind in concrete.Dead weight than common brick concrete structure building reduces by 40% or more.2, thermal insulation separation
Good in thermal property.The thermal coefficient of air entrained concrete is the 1/6 of normal concrete, and heat-proof quality is significantly better than the clay of 240mm thickness
Brick wall body.3, shock resistance is strong.Air entrained concrete light capacity, overall performance be good, earthquake when inertia force it is small, so with certain
Shock resistance.4, processing performance is good.Air entrained concrete have good processing performance, can saw, dig, following closely, milling, brill, to construction band
Come prodigious convenience with flexibly.5, with certain heat-resisting quantity.Air entrained concrete is when temperature is 600 degree or less, resistance to compression
Intensity slightly increases, and when temperature is at 600 degree or so, compression strength when compression strength is close to room temperature, fire protecting performance reaches
Country-level fire-protection standard.6, sound insulation value is good.The internal structure image planes packet of air entrained concrete is the same, is evenly distributed a large amount of
Sealed porosity, therefore sound absorption qualities not having with common buildings material.7, adaptable.It can be according to local different former
Material, different condition are carried out amount body and are made surely.River sand, flyash, ore in sand form etc., adaptation to local conditions may be selected in raw material.Oil resistant aerated bricks, it is main
It refer to the special concrete for not chemically reacted with vegetable oil, animal oil and mineral oils, and it capable of being prevented to permeate.
In common mechanical industrial processes, flowed due to transmission, metal cutting and grinding splash out come oils, such as certain mineral oil or
Vegetable oil etc., most of relative density is small, viscosity is low, penetrating power is strong, it is easy to destroy cohering between aggregate, some oil
Substance of the class also containing some meta-acid classes and esters, it is very big to the intensity effect of aerated bricks, and there is also anti-for traditional aerated bricks
The problem of oiliness can not be further increased with mechanical property.
Therefore, how to improve traditional aerated bricks oil-resistant characteristic and the shortcomings that mechanical property can not further increase, to obtain
The raising for taking more high combination property is problem to be solved.
Invention content
The present invention solves the technical problem of：For traditional aerated bricks anti-permeability performance, oil-resistant characteristic and mechanics
The problem of performance can not further increase provides a kind of preparation method of oil resistant aerated bricks.
The technical solution adopted in the present invention is：
A kind of preparation method of oil resistant aerated bricks, specific preparation process are as follows：
（1）It counts in parts by weight, takes 50~80 parts of cement, 10~20 parts of flyash, 20~30 parts of miberal powders, 40~60 parts of stones successively
Sand, 40~60 parts of modified coarse aggregates, 10~20 parts of modified fillers, 5~8 parts of water-reducing agents, 60~100 parts of water；
（2）By cement, flyash, miberal powder, quartz sand, modified coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water stir
Mixing is mixed, injection molding stands demoulding, obtains adobe；
（3）Adobe heat-insulation pressure keeping is conserved, then through natural curing to get oil resistant aerated bricks.
Step（1）The cement is portland cement, any one in magnesia oxychloride cement or aluminate cement.
Step（1）The miberal powder is ground granulated blast furnace slag, iron ore ground-slag, any one in copper mine ground-slag or float stone miberal powder.
Step（1）The quartz grain fineness number modulus is 2.3~2.6.
Step（1）The preparation process of the modified coarse aggregate is：By hydrofluoric acid and hydrochloric acid by volume 1：5~1：10 stirrings
Mixing, obtains nitration mixture, float stone is crushed, and is sieved, obtains float stone slag；By float stone slag and nitration mixture in mass ratio 1：10~1：20 stirrings are mixed
It closes, filtering obtains single treatment float stone slag；By single treatment float stone slag and dopamine solution in mass ratio 1：10~1：20 stirrings are mixed
It closes, filtering obtains after-treatment float stone slag, is 1 in mass ratio by after-treatment float stone slag and liquor alumini chloridi：30~1：40 mixing
Ultrasound is then added dropwise urea liquid precipitation, is aged, filter, washs, dry, obtains modified coarse aggregate.
Step（1）The preparation process of the modified filler is：It counts in parts by weight, by 20~30 parts of rice husks, 20~30 parts
Orange peel, 20~30 parts of pear skins, 5~6 parts of biogas slurries, 40~50 parts of kaolin, 60~80 parts of water mixing, fermentation obtain fermentation slurry, will
Gained fermentation slurry is evenly laid out in plastic trough, then earthworm is added to plastic trough, and plastic trough is moved into greenhouse and is supported
It grows, after cultivation, obtains wormcast, as modified filler.
Step（1）The water-reducing agent is sodium lignin sulfonate, and TH-928 poly carboxylic acid series water reducers or YZ-1 naphthalene series high-efficiencies subtract
Any one in aqua.
Step（3）The heat-insulation pressure keeping curing condition is：Pressure is 2~3MPa, and temperature is 160~180 DEG C.
The beneficial effects of the invention are as follows：
The present invention is by the modified coarse aggregate of addition, and in preparation process, first, float stone slag is impregnated by nitration mixture so that corrosion table
The pit in face is further expanded, and dopamine solution immersion is then passed through, and neutralizes the nitration mixture Liquid Residue on float stone surface, meanwhile, DOPA
Amine is adsorbed on corrosion surface, improves the absorption property on float stone surface, is conducive to later stage aluminum hydroxide precipitation and is effectively filled in
In the pit on float stone surface so that the roughness of corrosion surface is improved, and is conducive in mixing process, is slided between coarse aggregate
It is dynamic, so that the resistance that system is subject to when being deformed is reduced, meanwhile, the more regular float stone powder specific-surface area detection in surface reduces,
The water requirement of wet granulate reduces, and under conditions of identical water, the opposite sliding between slurry particles is more easy, makes slurry
Rheological characteristic is effectively improved, and the early strength of product is effectively improved, and after aluminium hydroxide dissolves under cement alkaline environment, shape
At alumine hydroxide colloid so that the anti-permeability performance of system gets a promotion, so that the oil-resistant characteristic of system gets a promotion, with
Aluminium hydroxide gradually dissolves, and the dopamine activity group on float stone surface is made to expose again, quartz sand that can be in absorption system, floats
Stone surface roughness gets a promotion so that mechanical snap is easily formed between coarse aggregate so that the mechanical property of system obtain into
The promotion of one step.
Specific implementation mode
The hydrochloric acid by volume 1 for being 20~30% with mass fraction by hydrofluoric acid that mass fraction is 20~30%：5~1：10
It is placed in batch mixer, under the conditions of rotating speed is 300~500r/min, is stirred 30~50min, obtains nitration mixture, float stone is placed in
It is crushed in pulverizer, crosses the sieve of 5 mesh, obtain float stone slag；By float stone slag and nitration mixture in mass ratio 1：10~1：20 are placed in reaction kettle,
Under the conditions of rotating speed is 300~500r/min, it is stirred 30~50min, mixed liquor is obtained, then mixed liquor is filtered, obtains once
Handle float stone slag；It is the dopamine solution in mass ratio 1 of 2.5mg/mL by single treatment float stone slag and mass concentration：10~1：20
It is placed in No. 1 beaker, under the conditions of rotating speed is 300~500r/min, is stirred 30~50min, obtains mixed serum, then will mix
Slurries filtering is closed, after-treatment float stone slag is obtained, the liquor alumini chloridi that after-treatment float stone slag is 10~20% with mass fraction is pressed
Mass ratio is 1：30~1：40 are placed in No. 2 beakers, and No. 2 beakers are placed in ultrasonic disperse instrument, in supersonic frequency be 55~
Under the conditions of 75kHz, 40~60min of ultrasound is mixed, the urea liquid that mass fraction is 10~20% is then added dropwise into No. 2 beakers
To after no longer there is precipitation in No. 2 beakers, it is aged 3~6h, obtains ageing liquid, then by ageing liquid filtering, obtained filter cake, then spend
Filter cake after washing is then placed in baking oven by ionized water by Washing of Filter Cake 3~5 times, under the conditions of temperature is 105~110 DEG C,
Drying obtains modified coarse aggregate to constant weight；It counts in parts by weight, by 20~30 parts of rice husks, 20~30 parts of orange peels, 20~30 portions of pears
Skin, 5~6 parts of biogas slurries, 40~50 parts of kaolin, 60~80 parts of water are placed in fermentation cauldron, are 28~32 DEG C in temperature, rotating speed is
It under the conditions of 100~200r/min, ferments 3~5 days, obtains fermentation slurry, the slurry that will ferment is evenly laid out in plastic trough, control
Laying depth is 20~25cm, then earthworm is added into plastic trough for 1.2~1.4kg/m2 by cultivation density, and earthworm will be added
Plastic trough after earthworm moves into greenhouse, under the conditions of temperature is 23~28 DEG C, vermiculture is carried out 10~20 days, in the cultivation phase
Between, it sprays water into sink every 5~6h, it is 70~80% to keep soil moisture in sink, to the end of vermiculture, collects earthworm
Excrement, as modified filler；It counts in parts by weight, takes 50~80 parts of cement successively, 10~20 parts of flyash, 20~30 parts of miberal powders,
40~60 parts of quartz sands, 40~60 parts of modified coarse aggregates, 10~20 parts of modified fillers, 5~8 parts of water-reducing agents, 60~100 parts of water；
By cement, flyash, miberal powder, quartz sand, modified coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water are placed in batch mixer
In, under the conditions of rotating speed is 100~200r/min, it is stirred 30~50min, mixed slurry is obtained, is then sprayed into mold
Discarded machine oil, then mixed slurry is injected in mold, after standing 5~10h of demoulding, demoulding obtains adobe；Adobe is placed in steam-cured
Kettle is 2~3MPa in pressure, and under the conditions of temperature is 160~180 DEG C, heat-insulation pressure keeping conserves 10~18h, then through natural curing 5~
10 days to get oil resistant aerated bricks.The cement is portland cement, any one in magnesia oxychloride cement or aluminate cement.
The miberal powder is ground granulated blast furnace slag, iron ore ground-slag, any one in copper mine ground-slag or float stone miberal powder.The quartz grain fineness number mould
Number is 2.3~2.6.
The hydrochloric acid by volume 1 for being 30% with mass fraction by hydrofluoric acid that mass fraction is 30%：10 are placed in batch mixer,
Under the conditions of rotating speed is 500r/min, it is stirred 50min, obtains nitration mixture, float stone is placed in pulverizer and is crushed, crosses the sieve of 5 mesh,
Obtain float stone slag；By float stone slag and nitration mixture in mass ratio 1：20 are placed in reaction kettle, and under the conditions of rotating speed is 500r/min, stirring is mixed
50min is closed, mixed liquor is obtained, then mixed liquor is filtered, obtains single treatment float stone slag；It is with mass concentration by single treatment float stone slag
The dopamine solution of 2.5mg/mL in mass ratio 1：20 are placed in No. 1 beaker, under the conditions of rotating speed is 500r/min, are stirred
50min obtains mixed serum, then mixed serum is filtered, and obtains after-treatment float stone slag, by after-treatment float stone slag and mass fraction
Liquor alumini chloridi for 20% is 1 in mass ratio：40 are placed in No. 2 beakers, and No. 2 beakers are placed in ultrasonic disperse instrument, Yu Chao
Under the conditions of acoustic frequency is 75kHz, ultrasound 60min is mixed, the urea liquid that mass fraction is 20% is then added dropwise into No. 2 beakers
To in No. 2 beakers no longer occur precipitation after, be aged 6h, obtain ageing liquid, then will ageing liquid filtering, obtain filter cake, then spend from
Filter cake after washing is then placed in baking oven by sub- water by Washing of Filter Cake 5 times, dry to perseverance under the conditions of temperature is 110 DEG C
Weight, obtains modified coarse aggregate；It counts in parts by weight, by 30 parts of rice husks, 30 parts of orange peels, 30 parts of pear skins, 6 parts of biogas slurries, 50 parts of kaolin,
80 parts of water are placed in fermentation cauldron, are 32 DEG C in temperature, under the conditions of rotating speed is 200r/min, is fermented 5 days, obtain fermentation slurry, will send out
Ferment slurry is evenly laid out in plastic trough, and control laying depth is 25cm, then by cultivation density is 1.4kg/m2 to plastics water
Earthworm is added in slot, and the plastic trough after addition earthworm is moved into greenhouse, under the conditions of temperature is 28 DEG C, carries out earthworm and supports
It grows 20 days, during cultivation, sprays water into sink every 6h, it is 80% to keep soil moisture in sink, to the end of vermiculture,
Collect wormcast, as modified filler；It counts in parts by weight, takes 80 parts of cement successively, 20 parts of flyash, 30 parts of miberal powders, 60 parts
Quartz sand, 60 parts of modified coarse aggregates, 20 parts of modified fillers, 8 parts of water-reducing agents, 100 parts of water；By cement, flyash, miberal powder, quartz
Sand, modified coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water are placed in batch mixer, in rotating speed be 200r/min conditions
Under, it is stirred 50min, obtains mixed slurry, is then sprayed into mold and discards machine oil, then mixed slurry is injected in mold,
After standing demoulding 10h, demoulding obtains adobe；Adobe is placed in steam-cured kettle, is that 3MPa is protected under the conditions of temperature is 180 DEG C in pressure
Warm pressurize conserves 18h, then through natural curing 10 days to get oil resistant aerated bricks.The cement is portland cement.The miberal powder is
Ground granulated blast furnace slag.The quartz grain fineness number modulus is 2.6.
The hydrochloric acid by volume 1 for being 30% with mass fraction by hydrofluoric acid that mass fraction is 30%：10 are placed in batch mixer,
Under the conditions of rotating speed is 500r/min, it is stirred 50min, obtains nitration mixture, float stone is placed in pulverizer and is crushed, crosses the sieve of 5 mesh,
Obtain float stone slag；By float stone slag and nitration mixture in mass ratio 1：20 are placed in reaction kettle, and under the conditions of rotating speed is 500r/min, stirring is mixed
50min is closed, mixed liquor is obtained, then mixed liquor is filtered, obtains single treatment float stone slag；It counts in parts by weight, by 30 parts of rice husks, 30 parts
Orange peel, 30 parts of pear skins, 6 parts of biogas slurries, 50 parts of kaolin, 80 parts of water are placed in fermentation cauldron, in temperature be 32 DEG C, rotating speed 200r/
It under the conditions of min, ferments 5 days, obtains fermentation slurry, the slurry that will ferment is evenly laid out in plastic trough, and control laying depth is
25cm, then earthworm is added into plastic trough for 1.4kg/m2 by cultivation density, and the plastic trough after addition earthworm is moved into
In greenhouse, under the conditions of temperature is 28 DEG C, carries out vermiculture 20 days, during cultivation, spray water into sink every 6h, keep
Soil moisture is 80% in sink, to the end of vermiculture, collects wormcast, as modified filler；It counts in parts by weight, successively
Take 80 parts of cement, 20 parts of flyash, 30 parts of miberal powders, 60 parts of quartz sands, 60 parts of coarse aggregates, 20 parts of modified fillers, 8 parts of water-reducing agents,
100 parts of water；By cement, flyash, miberal powder, quartz sand, coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water are placed in mixed
In material machine, under the conditions of rotating speed is 200r/min, it is stirred 50min, mixed slurry is obtained, scrap machine is then sprayed into mold
Oil, then mixed slurry is injected in mold, after standing demoulding 10h, demoulding obtains adobe；Adobe is placed in steam-cured kettle, is in pressure
3MPa, under the conditions of temperature is 180 DEG C, heat-insulation pressure keeping conserves 18h, then through natural curing 10 days to get oil resistant aerated bricks.The water
Mud is portland cement.The miberal powder is ground granulated blast furnace slag.The quartz grain fineness number modulus is 2.6.
The hydrochloric acid by volume 1 for being 30% with mass fraction by hydrofluoric acid that mass fraction is 30%：10 are placed in batch mixer,
Under the conditions of rotating speed is 500r/min, it is stirred 50min, obtains nitration mixture, float stone is placed in pulverizer and is crushed, crosses the sieve of 5 mesh,
Obtain float stone slag；By float stone slag and nitration mixture in mass ratio 1：20 are placed in reaction kettle, and under the conditions of rotating speed is 500r/min, stirring is mixed
50min is closed, mixed liquor is obtained, then mixed liquor is filtered, obtains single treatment float stone slag；It is with mass concentration by single treatment float stone slag
The dopamine solution of 2.5mg/mL in mass ratio 1：20 are placed in No. 1 beaker, under the conditions of rotating speed is 500r/min, are stirred
50min obtains mixed serum, then mixed serum is filtered, and obtains after-treatment float stone slag, by after-treatment float stone slag and mass fraction
Liquor alumini chloridi for 20% is 1 in mass ratio：40 are placed in No. 2 beakers, and No. 2 beakers are placed in ultrasonic disperse instrument, Yu Chao
Under the conditions of acoustic frequency is 75kHz, ultrasound 60min is mixed, the urea liquid that mass fraction is 20% is then added dropwise into No. 2 beakers
To in No. 2 beakers no longer occur precipitation after, be aged 6h, obtain ageing liquid, then will ageing liquid filtering, obtain filter cake, then spend from
Filter cake after washing is then placed in baking oven by sub- water by Washing of Filter Cake 5 times, dry to perseverance under the conditions of temperature is 110 DEG C
Weight, obtains modified coarse aggregate；It counts in parts by weight, takes 80 parts of cement successively, 20 parts of flyash, 30 parts of miberal powders, 60 parts of quartz sands, 60
The modified coarse aggregate of part, 8 parts of water-reducing agents, 100 parts of water；By cement, flyash, miberal powder, quartz sand is modified coarse aggregate, compound closely knit
Agent, water-reducing agent and water are placed in batch mixer, under the conditions of rotating speed is 200r/min, is stirred 50min, is obtained mixed slurry, connect
It to spray into mold and discards machine oil, then mixed slurry is injected in mold, after standing demoulding 10h, demoulding obtains adobe；By brick
Base is placed in steam-cured kettle, is 3MPa in pressure, and under the conditions of temperature is 180 DEG C, heat-insulation pressure keeping conserved 18h, then through natural curing 10 days,
Up to oil resistant aerated bricks.The cement is portland cement.The miberal powder is ground granulated blast furnace slag.It is described quartz grain fineness number modulus be
2.6。
Comparative example：The aerated bricks of Guangdong construction material Co., Ltd production.
The oil resistant aerated bricks and comparative example product of example 1 to 3 gained of example are subjected to performance detection, specific detection method is such as
Under：
The average oil absorbency of test and compression strength.
Specific testing result is as shown in table 1：
The 1 specific testing result of oil resistant aerated bricks performance of table
| Detection project | Example 1 | Example 2 | Example 3 | Comparative example |
| Average oil absorbency/% | 0.8 | 1.6 | 2.3 | 2.6 |
| Compression strength/MPa | 7.7 | 5.6 | 4.9 | 3.1 |
By 1 testing result of table it is found that oil resistant aerated bricks prepared by technical solution of the present invention have excellent oil resistance and mechanics
Performance characteristics have broad prospects in the development of building material technology industry.
Claims (8)
1. a kind of preparation method of oil resistant aerated bricks, it is characterised in that specific preparation process is as follows：
（1）It counts in parts by weight, takes 50~80 parts of cement, 10~20 parts of flyash, 20~30 parts of miberal powders, 40~60 parts of stones successively
Sand, 40~60 parts of modified coarse aggregates, 10~20 parts of modified fillers, 5~8 parts of water-reducing agents, 60~100 parts of water；
（2）By cement, flyash, miberal powder, quartz sand, modified coarse aggregate, compound compacting agent, modified filler, water-reducing agent and water stir
Mixing is mixed, injection molding stands demoulding, obtains adobe；
（3）Adobe heat-insulation pressure keeping is conserved, then through natural curing to get oil resistant aerated bricks.
2. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The cement is
Any one in portland cement, magnesia oxychloride cement or aluminate cement.
3. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The miberal powder is
Any one in ground granulated blast furnace slag, iron ore ground-slag, copper mine ground-slag or float stone miberal powder.
4. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The quartz sand
Fineness modulus is 2.3~2.6.
5. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The modification is thick
Aggregate processing process is：By hydrofluoric acid and hydrochloric acid by volume 1：5~1：10 are stirred, and obtain nitration mixture, and float stone is crushed, mistake
Sieve, obtains float stone slag；By float stone slag and nitration mixture in mass ratio 1：10~1：20 are stirred, and filtering obtains single treatment float stone slag；It will
Single treatment float stone slag and dopamine solution in mass ratio 1：10~1：20 are stirred, and filtering obtains after-treatment float stone slag, will
After-treatment float stone slag is 1 in mass ratio with liquor alumini chloridi：30~1：40 mixing ultrasounds, are then added dropwise urea liquid precipitation,
Ageing is filtered, and is washed, dry, obtains modified coarse aggregate.
6. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The modification is filled out
The preparation process of material is：It counts in parts by weight, by 20~30 parts of rice husks, 20~30 parts of orange peels, 20~30 parts of pear skins, 5~6 parts of natural ponds
Liquid, 40~50 parts of kaolin, 60~80 parts of water mixing, fermentation obtain fermentation slurry, and gained fermentation slurry is evenly laid out in plastics
In sink, then to plastic trough addition earthworm, plastic trough is moved into greenhouse and is cultivated, after cultivation, obtains wormcast, as
Modified filler.
7. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（1）The water-reducing agent
Any one for sodium lignin sulfonate, in TH-928 poly carboxylic acid series water reducers or YZ-1 naphthalene series high-efficiency water-reducing agents.
8. a kind of preparation method of oil resistant aerated bricks according to claim 1, it is characterised in that：Step（3）The heat preservation is protected
Pressure curing condition be：Pressure is 2~3MPa, and temperature is 160~180 DEG C.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467399A (en) * | 2019-09-10 | 2019-11-19 | 江西科技学院 | A kind of self-compacting concrete and preparation method thereof using Copper Slag |
| CN111906896A (en) * | 2020-07-29 | 2020-11-10 | 和县明生环保材料有限责任公司 | Preparation method of rapid-forming steaming-free baking-free brick |
| CN112851239A (en) * | 2021-01-22 | 2021-05-28 | 广州市粤砼混凝土有限公司 | Pump concrete and preparation method thereof |
-
2018
- 2018-05-30 CN CN201810538308.XA patent/CN108675717A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467399A (en) * | 2019-09-10 | 2019-11-19 | 江西科技学院 | A kind of self-compacting concrete and preparation method thereof using Copper Slag |
| CN111906896A (en) * | 2020-07-29 | 2020-11-10 | 和县明生环保材料有限责任公司 | Preparation method of rapid-forming steaming-free baking-free brick |
| CN111906896B (en) * | 2020-07-29 | 2021-11-16 | 和县明生环保材料有限责任公司 | Preparation method of rapid-forming steaming-free baking-free brick |
| CN112851239A (en) * | 2021-01-22 | 2021-05-28 | 广州市粤砼混凝土有限公司 | Pump concrete and preparation method thereof |
| CN112851239B (en) * | 2021-01-22 | 2021-12-31 | 广州市粤砼混凝土有限公司 | Pump concrete and preparation method thereof |
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Application publication date: 20181019 |