CN108660789A - A kind of method that outdoor goods are dyed with Fypro - Google Patents
A kind of method that outdoor goods are dyed with Fypro Download PDFInfo
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- CN108660789A CN108660789A CN201810571415.2A CN201810571415A CN108660789A CN 108660789 A CN108660789 A CN 108660789A CN 201810571415 A CN201810571415 A CN 201810571415A CN 108660789 A CN108660789 A CN 108660789A
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- China
- Prior art keywords
- fypro
- dyeing
- dyed
- temperature
- mixed liquor
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/08—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
- D06M14/12—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M14/16—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The present invention discloses a kind of method of Fypro dyeing, including following operating procedure：（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；（2）2 hydroxypropyl acrylate of methacrylic acid, dimethacrylate diethylene glycol (DEG) ester are added into ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, after mixing, thereto plus initiator, then after the temperature of mixed liquor being risen to 88 90 DEG C, insulation reaction takes out Fypro after 23 hours；（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.The method that a kind of outdoor goods provided by the invention are dyed with Fypro, easy to operate, of low cost, coloring is good, and dye-uptake is high, the phenomenon that being not susceptible to decolourize after dyeing.
Description
Technical field
The invention belongs to outdoor goods staining technique fields, and in particular to what a kind of outdoor goods were dyed with Fypro
Method.
Background technology
Polyamide is commonly called as nylon, density 1.15g/cm3, it is the thermoplastic resin rolled into a ball containing recurring amide radical on molecular backbone
General name, including aliphatic PA, fat-aromatic series PA and aromatic series PA, wherein aliphatic PA is wide in variety, and yield is big, using wide
It is general, depending on name is by the specific carbon atom number of synthon.Polyamide is mainly used for synthetic fibers, and most prominent advantage is
Wearability is higher than other all fibres, 10 times higher than cotton wearability, 20 times higher than wool, slightly enters in blended fabric
Fypro is greatly improved its wearability；When being stretched to 3-6%, elastic recovery rate is up to 100%；It is amenable to up to ten thousand times
Folding is scratched and not broken.Some outdoor goods at present, as tent, knapsack, sleeping bag, moistureproof cushion or air cushion mostly use greatly Fypro
It is made, there is a wide development space in articles for use field outdoors, but Fypro there is colorings poor, dye-uptake
Low technological deficiency.
Invention content
In order to solve the above technical problem, the present invention provides a kind of methods that outdoor goods are dyed with Fypro.
The present invention is achieved by the following technical solutions.
A kind of method that outdoor goods are dyed with Fypro, including following operating procedure：
（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；
（2）By weight, 13-16 parts of Hydroxypropyl methacrylates, 20-25 parts of dimethacrylate diethylene glycol (DEG) esters are added
Enter into 80-100 parts of ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, mixes
After uniformly, 0.1-0.3 parts of initiators, after the temperature of mixed liquor is then risen to 88-90 DEG C, insulation reaction 2-3 are added thereto
After hour, Fypro is taken out；
（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.
Specifically, above-mentioned steps（1）In, when Low-temperature oxygen plasma is handled, the pressure of gas is 80Pa, and discharge power is
100W, processing time 200s.
Specifically, above-mentioned steps（2）In, initiator is any one in benzoyl peroxide, lauroyl peroxide.
Specifically, above-mentioned steps（3）In, the mass fraction of dyestuff is 2-4% in dyeing liquor, and the dyestuff is that molecular weight is
Single sulphonic-acid azo dyes of 400-500.
Specifically, above-mentioned steps（3）In, the temperature for playing dye is 30 DEG C, and dyeing temperature is 100 DEG C, and soaking time is
40min, bath raio 1:20.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
The method that a kind of outdoor goods provided by the invention are dyed with Fypro, easy to operate, of low cost, coloring
Good, dye-uptake is high, the phenomenon that being not susceptible to decolourize after dyeing.Wherein, the present invention is first by Fypro Low-temperature oxygen plasma
After processing, the effect of graft reaction can be effectively promoted so that containing a large amount of active organic group on Fypro；This
Invention can be carried effectively by grafted methacrylic acid -2- hydroxypropyl acrylates, dimethacrylate diethylene glycol (DEG) ester on Fypro
Dye-uptake is risen, combination effect of the pigment on Fypro is promoted.
Specific implementation mode
Following embodiment cannot be used for limiting the scope of the invention for illustrating the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of method that outdoor goods are dyed with Fypro, including following operating procedure：
（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；
（2）By weight, 13 parts of Hydroxypropyl methacrylates, 20 parts of dimethacrylate diethylene glycol (DEG) esters are added to 80
In part ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, after mixing, to
0.1 part of initiator is wherein added, after the temperature of mixed liquor is then risen to 88 DEG C, it is fine to take out polyamide after 2 hours for insulation reaction
Dimension；
（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.
Specifically, above-mentioned steps（1）In, when Low-temperature oxygen plasma is handled, the pressure of gas is 80Pa, and discharge power is
100W, processing time 200s.
Specifically, above-mentioned steps（2）In, initiator is benzoyl peroxide.
Specifically, above-mentioned steps（3）In, the mass fraction of dyestuff is 2% in dyeing liquor, and the dyestuff is that molecular weight is
Single sulphonic-acid azo dyes of 400-500.
Specifically, above-mentioned steps（3）In, the temperature for playing dye is 30 DEG C, and dyeing temperature is 100 DEG C, and soaking time is
40min, bath raio 1:20.
Embodiment 2
A kind of method that outdoor goods are dyed with Fypro, including following operating procedure：
（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；
（2）By weight, 15 parts of Hydroxypropyl methacrylates, 23 parts of dimethacrylate diethylene glycol (DEG) esters are added to 90
In part ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, after mixing, to
0.2 part of initiator is wherein added, after the temperature of mixed liquor is then risen to 89 DEG C, insulation reaction takes out polyamide after 2.5 hours
Fiber；
（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.
Specifically, above-mentioned steps（1）In, when Low-temperature oxygen plasma is handled, the pressure of gas is 80Pa, and discharge power is
100W, processing time 200s.
Specifically, above-mentioned steps（2）In, initiator is lauroyl peroxide.
Specifically, above-mentioned steps（3）In, the mass fraction of dyestuff is 3% in dyeing liquor, and the dyestuff is that molecular weight is
Single sulphonic-acid azo dyes of 400-500.
Specifically, above-mentioned steps（3）In, the temperature for playing dye is 30 DEG C, and dyeing temperature is 100 DEG C, and soaking time is
40min, bath raio 1:20.
Embodiment 3
A kind of method that outdoor goods are dyed with Fypro, including following operating procedure：
（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；
（2）By weight, 16 parts of Hydroxypropyl methacrylates, 25 parts of dimethacrylate diethylene glycol (DEG) esters are added to 100
In part ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, after mixing, to
0.3 part of initiator is wherein added, after the temperature of mixed liquor is then risen to 90 DEG C, it is fine to take out polyamide after 3 hours for insulation reaction
Dimension；
（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.
Specifically, above-mentioned steps（1）In, when Low-temperature oxygen plasma is handled, the pressure of gas is 80Pa, and discharge power is
100W, processing time 200s.
Specifically, above-mentioned steps（2）In, initiator is lauroyl peroxide.
Specifically, above-mentioned steps（3）In, the mass fraction of dyestuff is 4% in dyeing liquor, and the dyestuff is that molecular weight is
Single sulphonic-acid azo dyes of 400-500.
Specifically, above-mentioned steps（3）In, the temperature for playing dye is 30 DEG C, and dyeing temperature is 100 DEG C, and soaking time is
40min, bath raio 1:20.
Comparative example 1
Fypro is without step of the present invention（1）And step（2）Processing, remaining operating procedure and 1 complete phase of embodiment
Together.
Dyeing processing is carried out to Fypro with the method for each embodiment and comparative example respectively, in addition to above-mentioned operation item
Part is different outer, remaining operating procedure is identical, then tests the upper dye amount of each group Fypro, test result such as table 1
It is shown：
The upper dye amount of 1 Fypro of table
| Project | The upper dye amount of Fypro, mg/g |
| Embodiment 1 | 41 |
| Comparative example 1 | 32 |
| Embodiment 2 | 43 |
| Embodiment 3 | 44 |
As shown in Table 1, the method that a kind of outdoor goods provided by the invention are dyed with Fypro, can effectively promote polyamides
The upper dye amount of amine fiber.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention
Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention
In sharp claimed range.
Claims (5)
1. a kind of method that outdoor goods are dyed with Fypro, which is characterized in that including following operating procedure：
（1）Fypro after melt spinning is handled using Low-temperature oxygen plasma；
（2）By weight, 13-16 parts of Hydroxypropyl methacrylates, 20-25 parts of dimethacrylate diethylene glycol (DEG) esters are added
Enter into 80-100 parts of ethyl acetate, mixed liquor is made after mixing, Fypro is completely immersed in mixed liquor, mixes
After uniformly, 0.1-0.3 parts of initiators, after the temperature of mixed liquor is then risen to 88-90 DEG C, insulation reaction 2-3 are added thereto
After hour, Fypro is taken out；
（3）Then Fypro is put into dyeing liquor and carries out dyeing processing.
2. the method that a kind of outdoor goods according to claim 1 are dyed with Fypro, which is characterized in that above-mentioned step
Suddenly（1）In, when Low-temperature oxygen plasma is handled, the pressure of gas is 80Pa, discharge power 100W, processing time 200s.
3. the method that a kind of outdoor goods according to claim 1 are dyed with Fypro, which is characterized in that above-mentioned step
Suddenly（2）In, initiator is any one in benzoyl peroxide, lauroyl peroxide.
4. the method that a kind of outdoor goods according to claim 1 are dyed with Fypro, which is characterized in that above-mentioned step
Suddenly（3）In, the mass fraction of dyestuff is 2-4% in dyeing liquor, and the dyestuff is single sulfonation azo dye that molecular weight is 400-500
Material.
5. the method that a kind of outdoor goods according to claim 4 are dyed with Fypro, which is characterized in that above-mentioned step
Suddenly（3）In, the temperature for playing dye is 30 DEG C, and dyeing temperature is 100 DEG C, soaking time 40min, bath raio 1:20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810571415.2A CN108660789A (en) | 2018-06-06 | 2018-06-06 | A kind of method that outdoor goods are dyed with Fypro |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810571415.2A CN108660789A (en) | 2018-06-06 | 2018-06-06 | A kind of method that outdoor goods are dyed with Fypro |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108660789A true CN108660789A (en) | 2018-10-16 |
Family
ID=63774299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810571415.2A Pending CN108660789A (en) | 2018-06-06 | 2018-06-06 | A kind of method that outdoor goods are dyed with Fypro |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2638586B2 (en) * | 1996-02-13 | 1997-08-06 | 東レ株式会社 | Method for producing high-strength, high-modulus polyamide fiber dyed deeply |
| CN1231005A (en) * | 1996-09-20 | 1999-10-06 | 英特拉技术公司 | Process for improving polyamide, acrylic, aramid, cellulosic and polyester properties, and modified polymers produced thereby |
| CN1566515A (en) * | 2003-06-11 | 2005-01-19 | 财团法人工业技术研究院 | Method for manufacturing fabric with moisture absorption and sweat discharge performance |
| CN1729237A (en) * | 2002-12-20 | 2006-02-01 | 西巴特殊化学品控股有限公司 | Method for forming reactive coatings |
| CN103074769A (en) * | 2013-01-19 | 2013-05-01 | 北京化工大学 | Method of surface grafting modification for nylon fabric |
-
2018
- 2018-06-06 CN CN201810571415.2A patent/CN108660789A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2638586B2 (en) * | 1996-02-13 | 1997-08-06 | 東レ株式会社 | Method for producing high-strength, high-modulus polyamide fiber dyed deeply |
| CN1231005A (en) * | 1996-09-20 | 1999-10-06 | 英特拉技术公司 | Process for improving polyamide, acrylic, aramid, cellulosic and polyester properties, and modified polymers produced thereby |
| CN1729237A (en) * | 2002-12-20 | 2006-02-01 | 西巴特殊化学品控股有限公司 | Method for forming reactive coatings |
| CN1566515A (en) * | 2003-06-11 | 2005-01-19 | 财团法人工业技术研究院 | Method for manufacturing fabric with moisture absorption and sweat discharge performance |
| CN103074769A (en) * | 2013-01-19 | 2013-05-01 | 北京化工大学 | Method of surface grafting modification for nylon fabric |
Non-Patent Citations (1)
| Title |
|---|
| 曹学新译: "聚酰胺接枝共聚物纤维的制造方法及纤维的性能", 《国外纺织技术》 * |
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Application publication date: 20181016 |