CN108660543A - A kind of preparation method of open air chair lift braiding resistant fiber - Google Patents

A kind of preparation method of open air chair lift braiding resistant fiber Download PDF

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Publication number
CN108660543A
CN108660543A CN201810571433.0A CN201810571433A CN108660543A CN 108660543 A CN108660543 A CN 108660543A CN 201810571433 A CN201810571433 A CN 201810571433A CN 108660543 A CN108660543 A CN 108660543A
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CN
China
Prior art keywords
sisal fiber
fiber
chair lift
added
resin particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810571433.0A
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Chinese (zh)
Inventor
王东营
杨子成
王东宝
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Anhui Hualida Outdoor Products Co Ltd
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Anhui Hualida Outdoor Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Hualida Outdoor Products Co Ltd filed Critical Anhui Hualida Outdoor Products Co Ltd
Priority to CN201810571433.0A priority Critical patent/CN108660543A/en
Publication of CN108660543A publication Critical patent/CN108660543A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention discloses a kind of preparation method of outdoor chair lift braiding resistant fiber, including following operating procedure:(1)Sisal fiber is put into benzoyl peroxide solution, immersion treatment then takes out sisal fiber, is completely immersed in boiling water, and after being heated using small fire, mixed grafting monomer is added into boiling water, and modified sisal fiber is made;(2)Macromolecule resin particle is added to open mill, completely after melting, the modification sisal fiber of macromolecule resin particle weight 25 30% is added thereto, after stirring is blended 56 minutes, modified sisal fiber filled high polymer composite material is made;(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift braiding resistant fiber is made.Method using the present invention, it is obtained open air chair lift braiding use resistant fiber, every excellent in mechanical performance, especially have antifouling property, can effectively reduce spot its surface adhesion strength.

Description

A kind of preparation method of open air chair lift braiding resistant fiber
Technical field
The invention belongs to outdoor appliance technical fields, and in particular to a kind of preparation side of open air chair lift braiding resistant fiber Method.
Background technology
Now, it is to use high score to be seen everywhere most of some unique moulding, practicality, outdoor chair lift beautiful and generous, Sub- complex fiber material braiding, there is excellent mechanical property and ageing-resistant, corrosion-resistant, water resistance.But outdoor is hung For chair due to placing for a long time outdoors, many dusts are easily infected on surface, affect the use of people.
Invention content
In order to solve the above technical problem, the present invention provides a kind of preparation methods of outdoor chair lift braiding resistant fiber.
The present invention is achieved by the following technical solutions.
A kind of preparation method of open air chair lift braiding resistant fiber, including following operating procedure:
(1)Sisal fiber is put into the benzoyl peroxide solution of a concentration of 0.15-0.2g/ml, immersion treatment 2-3 hours, Sisal fiber is then taken out, is completely immersed in the boiling water that 5-6 times of its weight weighs, after heating 10-15min using small fire, to The mixed grafting monomer of its weight 10-15% is added in boiling water, modified sisal fiber is made after 3-4 hours in graft reaction, wherein Mixed grafting monomer is made of the component of following parts by weight:6-10 parts of dodecafluorhe-ptylacrylate, 2,2,2- trifluoroethyl propylene 14-20 parts of acid esters, 36-40 parts of methyl methacrylate;
(2)Macromolecule resin particle is added to open mill, completely after melting, macromolecule resin particle weight is added thereto After stirring is blended 5-6 minutes, modified sisal fiber filled high polymer composite material is made in the modification sisal fiber of 25-30%;
(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift is made and compiles It knits and uses resistant fiber.
Specifically, above-mentioned steps(1)In, the mass ratio of sisal fiber and benzoyl peroxide solution is 1:4.
Specifically, above-mentioned steps(2)In, macromolecule resin particle is resin granules of poly lactic acid, acrylic resin particle, gathers Any one in vinyl chloride and polystyrene.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows:
Method using the present invention, chair lift braiding resistant fiber in open air obtained, every excellent in mechanical performance are corrosion-resistant, resistance to Ageing properties are excellent, especially have antifouling property, can effectively reduce spot its surface adhesion strength.Wherein, step(1) In, first initiator is attached on sisal fiber, then the sisal fiber for being attached with initiator is added into grafted monomers, connects Branch monomer can be combined effectively with sisal fiber, and final modified sisal fiber obtained can effectively reduce open air obtained and hang The chair braiding surface energy of resistant fiber, can effectively reduce spot its surface adhesion strength so that spot is easy in wind-force Under the action of be blown away, and then the effective anti-pollution characteristic for improving chair lift.
Specific implementation mode
Following embodiment cannot be used for limiting the scope of the invention for illustrating the present invention.The reality used in embodiment The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method of open air chair lift braiding resistant fiber, including following operating procedure:
(1)Sisal fiber is put into the benzoyl peroxide solution of a concentration of 0.15g/ml, then immersion treatment 2 hours takes Go out sisal fiber, be completely immersed in 5 times of heavy boiling water of its weight, after heating 10min using small fire, it is added into boiling water After 3 hours modified sisal fiber is made, wherein mixed grafting monomer is by following in the mixed grafting monomer of weight 10%, graft reaction The component of parts by weight is made:6 parts of dodecafluorhe-ptylacrylate, 14 parts of 2,2,2- trifluoroethyls acrylate, methyl methacrylate 36 parts of ester;
(2)Macromolecule resin particle is added to open mill, completely after melting, macromolecule resin particle weight is added thereto 25% modification sisal fiber, stirring are blended after five minutes, and modified sisal fiber filled high polymer composite material is made;
(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift is made and compiles It knits and uses resistant fiber.
Specifically, above-mentioned steps(1)In, the mass ratio of sisal fiber and benzoyl peroxide solution is 1:4.
Specifically, above-mentioned steps(2)In, macromolecule resin particle is resin granules of poly lactic acid.
Embodiment 2
A kind of preparation method of open air chair lift braiding resistant fiber, including following operating procedure:
(1)Sisal fiber is put into the benzoyl peroxide solution of a concentration of 0.17g/ml, immersion treatment 2.5 hours, then Sisal fiber is taken out, is completely immersed in 5.5 times of heavy boiling water of its weight, after heating 13min using small fire, is added into boiling water Enter the mixed grafting monomer of its weight 13%, modified sisal fiber, wherein mixed grafting monomer is made after 3.5 hours in graft reaction It is made of the component of following parts by weight:8 parts of dodecafluorhe-ptylacrylate, 16 parts of 2,2,2- trifluoroethyls acrylate, methyl-prop 38 parts of e pioic acid methyl ester;
(2)Macromolecule resin particle is added to open mill, completely after melting, macromolecule resin particle weight is added thereto 28% modification sisal fiber, stirring are blended after five minutes, and modified sisal fiber filled high polymer composite material is made;
(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift is made and compiles It knits and uses resistant fiber.
Specifically, above-mentioned steps(1)In, the mass ratio of sisal fiber and benzoyl peroxide solution is 1:4.
Specifically, above-mentioned steps(2)In, macromolecule resin particle is acrylic resin particle.
Embodiment 3
A kind of preparation method of open air chair lift braiding resistant fiber, including following operating procedure:
(1)Sisal fiber is put into the benzoyl peroxide solution of a concentration of 0.2g/ml, immersion treatment 3 hours then takes out Sisal fiber is completely immersed in 6 times of heavy boiling water of its weight, and after heating 15min using small fire, it is heavy that its is added into boiling water After 4 hours modified sisal fiber is made, wherein mixed grafting monomer is by following heavy in the mixed grafting monomer of amount 15%, graft reaction The component of amount part is made:10 parts of dodecafluorhe-ptylacrylate, 20 parts of 2,2,2- trifluoroethyls acrylate, methyl methacrylate 40 parts;
(2)Macromolecule resin particle is added to open mill, completely after melting, macromolecule resin particle weight is added thereto After stirring is blended 6 minutes, modified sisal fiber filled high polymer composite material is made in 30% modification sisal fiber;
(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift is made and compiles It knits and uses resistant fiber.
Specifically, above-mentioned steps(1)In, the mass ratio of sisal fiber and benzoyl peroxide solution is 1:4.
Specifically, above-mentioned steps(2)In, macromolecule resin particle is polystyrene.
Comparative example 1
By step(2)In modification sisal fiber replace with the sisal fiber of non-modified processing, remaining operating procedure with implement Example 1 is identical.
Fiber is made with the method for each embodiment and comparative example respectively, chair lift is then woven into using identical method, it will After chair lift is placed in identical outdoor environment, the spot contamination situation on each group chair lift surface, test result such as 1 institute of table are checked Show:
1 chair lift anti-pollution characteristic test result of table
As shown in Table 1, outdoor chair lift braiding resistant fiber produced by the present invention, anti-pollution characteristic is excellent, greatly improves and hangs The quality of chair.
Certainly, above description is not limitation of the present invention, and the present invention is also not limited to the example above, the art Those of ordinary skill, the present invention essential scope in, variation, change, addition or the replacement made, should all belong to the present invention Protection domain.

Claims (3)

1. a kind of preparation method of open air chair lift braiding resistant fiber, which is characterized in that including following operating procedure:
(1)Sisal fiber is put into the benzoyl peroxide solution of a concentration of 0.15-0.2g/ml, immersion treatment 2-3 hours, Sisal fiber is then taken out, is completely immersed in the boiling water that 5-6 times of its weight weighs, after heating 10-15min using small fire, to The mixed grafting monomer of its weight 10-15% is added in boiling water, modified sisal fiber is made after 3-4 hours in graft reaction, wherein Mixed grafting monomer is made of the component of following parts by weight:6-10 parts of dodecafluorhe-ptylacrylate, 2,2,2- trifluoroethyl propylene 14-20 parts of acid esters, 36-40 parts of methyl methacrylate;
(2)Macromolecule resin particle is added to open mill, completely after melting, macromolecule resin particle weight is added thereto After stirring is blended 5-6 minutes, modified sisal fiber filled high polymer composite material is made in the modification sisal fiber of 25-30%;
(3)By step(2)After modified sisal fiber filled high polymer composite material melt spinning obtained, open air chair lift is made and compiles It knits and uses resistant fiber.
2. a kind of preparation method of outdoor chair lift braiding resistant fiber according to claim 1, which is characterized in that above-mentioned Step(1)In, the mass ratio of sisal fiber and benzoyl peroxide solution is 1:4.
3. a kind of preparation method of outdoor chair lift braiding resistant fiber according to claim 1, which is characterized in that above-mentioned Step(2)In, macromolecule resin particle is in resin granules of poly lactic acid, acrylic resin particle, polyvinyl chloride and polystyrene Any one.
CN201810571433.0A 2018-06-06 2018-06-06 A kind of preparation method of open air chair lift braiding resistant fiber Pending CN108660543A (en)

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Application Number Priority Date Filing Date Title
CN201810571433.0A CN108660543A (en) 2018-06-06 2018-06-06 A kind of preparation method of open air chair lift braiding resistant fiber

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111235679A (en) * 2020-03-31 2020-06-05 孙阁 Antifouling functional fiber and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272218A (en) * 1991-02-20 1992-09-29 Kuraray Co Ltd Stain-resistant polyester-based yarn
CN101029178A (en) * 2007-02-25 2007-09-05 湖北工业大学 Production of polymer/pulp fibre composite material
CN101200524A (en) * 2007-11-22 2008-06-18 苏州大学 Polypropylene material with low surface tension and method for preparing the same
CN101200579A (en) * 2007-11-26 2008-06-18 同济大学 Natural fibre reinforced polylactic acid composite material and method for making same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272218A (en) * 1991-02-20 1992-09-29 Kuraray Co Ltd Stain-resistant polyester-based yarn
CN101029178A (en) * 2007-02-25 2007-09-05 湖北工业大学 Production of polymer/pulp fibre composite material
CN101200524A (en) * 2007-11-22 2008-06-18 苏州大学 Polypropylene material with low surface tension and method for preparing the same
CN101200579A (en) * 2007-11-26 2008-06-18 同济大学 Natural fibre reinforced polylactic acid composite material and method for making same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111235679A (en) * 2020-03-31 2020-06-05 孙阁 Antifouling functional fiber and preparation method thereof

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Application publication date: 20181016

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