CN108659991A - A kind of peroxide composite material and preparation method - Google Patents
A kind of peroxide composite material and preparation method Download PDFInfo
- Publication number
- CN108659991A CN108659991A CN201810526509.8A CN201810526509A CN108659991A CN 108659991 A CN108659991 A CN 108659991A CN 201810526509 A CN201810526509 A CN 201810526509A CN 108659991 A CN108659991 A CN 108659991A
- Authority
- CN
- China
- Prior art keywords
- acid
- peroxide
- composite material
- sodium
- bion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/38—Percompounds, e.g. peracids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of peroxide composite material and preparation method, it is desirable to provide a kind of bion peroxide composite material more particularly to a kind of bion peroxide composite material and preparation method.After the hydrop effect that pigment or spot on object decomposite in by peroxide, it can decompose to remove.Peroxide needs to be activated during use, to release active ingredient, plays the effect of bleaching.The present invention provides a kind of new peroxide combined bleach systems, and peroxide active ingredient and light-initiated material are combined, the effective advantage for playing the two.Biology advanced composite material (ACM) provided by the present invention, use is light-initiated, substantially increases convenience and actual effect in practical applications.Preparation method is easy, during storage, peroxide stable effective ingredients, in use, can effective peroxide activator active ingredient, belong to environmentally friendly peroxide composite material of new generation.
Description
Technical field
The present invention relates to multigroup part of peroxide composite woods of a kind of peroxide composite material more particularly to a kind of bion
Material and preparation method thereof.
Background technology
It is well known that peroxide can remove pigment or spot on object, commonly referred to as bleaching or whitening.General feelings
Under condition, after the hydrop effect that pigment or spot on object decomposite in by peroxide, it can decompose to go
It removes.Peroxide needs to be activated during use, to release active ingredient, plays the effect of bleaching.One kind swashs
The method for living through oxide is to improve temperature, but high temperature frequently can lead to active ingredient to be discharged in advance, to reduce drift
White effect.Another method for generating peroxide active ingredient is that peroxide is used in combination with organic compound.Such as
Sodium perborate or SODIUM PERCARBONATE are combined with tetra acetyl ethylene diamine, also by active ingredient object and an acyl group Sodium dobesilate knot
It closes.This Activiation method has several drawbacks in that organic compound is complicated molecule, and multi-step is needed to manufacture, and investment cost is high；Separately
Outside, organic compound volume accounting in bleaching composition is big, and the accounting of peroxidative activity ingredient is reduced, and needs that bleaching is being made
It is compressed when finished product, improves manufacturing cost again.
It is light-initiated that refer to initiator molecule have one in ultraviolet region (250-400 nm) or visible region (400-800 nm)
Determine absorbing ability, after directly or indirectly absorbing luminous energy, initiator molecule is from ground state transition to excited singlet, through altering jump between being
To excited triplet state；After excited singlet or triplet state experience unimolecule or bimolecular chemical action, generation can cause list
The biologically active fragment of body polymerization.It is light-initiated to be divided into that free radical polymerization is light-initiated to be caused with cationic photopolymerization according to triggering mechanism difference,
Wherein it is most widely used so that free radical polymerization is light-initiated.It to give full play in practical applications light-initiated with velocity of initiation
Soon, properties of product are easily controllable, the advantages that being easy to store.
The present invention provides a kind of new peroxide combined bleach systems, by peroxide active ingredient and light-initiated material
Material combines, the effective advantage for playing the two.And use is light-initiated, substantially increases convenience and reality in practical applications
Effect property.As is well known, currently used oxygen bleaching agent includes mainly hydrogen peroxide, urea peroxide, calper calcium peroxide, perborate
Deng.The present invention is combined using advanced visible light-initiated material and peroxide active ingredient, has prepared the list of highly effective
Multigroup part of composite material of dosage form.
Invention content
The purpose of the present invention is intended to multigroup part of peroxide of a kind of peroxide composite material more particularly to a kind of bion
Composite material and preparation method.
Bion peroxide composite material of the present invention is a kind of multigroup part of combined bleach material of one-pack type, is made
Used time activates the light-initiated factor using light irradiation, and energy transfer is caused to activate bleaching-active components, belongs to the environmental-friendly of green
Type peroxide composite material.
Bion peroxide composite material of the present invention includes mainly following component：Peroxide, water, excipient
Agent, thickener, photosensitizer, moisturizer, foaming agent, stabilizer, bleaching assistant, pH adjusting agent.
Bion peroxide composite material of the present invention, by mass fraction, Main Components proportion is：It crosses
6-50 parts of oxide, 5-65 parts of water, 0.5-6 parts of excipients, 0-10 parts of thickener, 0.5-5 parts of photosensitizer, 5-60 parts of moisturizer,
0.3-4.5 parts of foaming agent, 1-6 parts of stabilizer, 0-5 parts of bleaching assistant.
The peroxide component includes, but are not limited to hydrogen peroxide, urea peroxide, SODIUM PERCARBONATE, calper calcium peroxide, mistake
One or more kinds of compositions in borate, glyceryl peroxide, benzoyl peroxide.
The water component is deionized water.
The excipients component includes, but are not limited to carbomer（Carbomer）, xanthans, tragacanth, carragheen
（Carrageenan）, poloxamer（Poloxamer）, Arabic gum, polyvinylpyrrolidone, one kind or one kind in gelatin
Above composition.
It is fine that the thickener component includes, but are not limited to sodium carboxymethylcellulose, polyanion cellulose, hydroxyalkyl vinyl base
Tie up the one or more in element, hydroxypropyl cellulose, sodium alginate, hydroxypropyl methyl cellulose, methylcellulose etc.
Composition.
The photosensitizer component includes, but are not limited to radical photosensitive agent, cationic polymerization photosensitizer, other photosensitizers
One or more kinds of compositions in.
Above-mentioned radical photosensitive agent includes, but are not limited to benzoin ethers, benzil ketals class, acetophenones, acyl group
Aoxidize Phosphorus, benzophenone and tertiary amine complex, camphorquinone, thioxanthone and its derivative, one kind or one kind in double imidazoles
Above composition；
Above-mentioned cationic photosensitizer includes, but are not limited to aromatic diazo salt, arylsulfonium salts, aryl salt, ferrocene salt
One or more kinds of compositions in class；
Other above-mentioned photosensitizers include, but are not limited to free radical-cationic hybrid photosensitizer, visible light photosensitizer, aqueous light
Quick dose, one or more kinds of compositions in macromolecular photosensitizer.
The moisturizer component includes, but are not limited to propylene glycol, glycerine, sorbitol ester, polyethylene glycol, butanediol,
One or more kinds of compositions in glycol.
The foaming agent component includes, but are not limited to surfactant, gas foaming agent, other foaming agents.In this hair
When using surfactant as foaming agent, its main species includes, but are not limited to anion surfactant, cation in bright
One or more kinds of compositions in surfactant, nonionic surface active agent, amphoteric surfactant.In this hair
Gaseous material can be for arbitrary inert gas or by making alkaline peroxide solution and acid when with gas foaming agent in bright
The gas that solution mixing generates.
Anionic surfactant includes, but are not limited to carry the alkylsurfuric acid of about 8-20 carbon atoms on alkyl
The water soluble compound (such as sodium alkyl sulfate) of salt, with about 8-20 carbon atoms aliphatic acid sulfonated mono-acid glycerine
The water soluble compound and its mixture of ester.Such as lauryl sodium sulfate, the cocounut oil mono-acid of anionic surfactant are sweet
Grease sodium sulfonate, phospholipid；Sarcosinate, such as sarcosyl, taurate, lauryl sulfoacetate sodium, the moon
Osmanthus amide ethylsulfonic acid sodium, laureth 9 sodium sulphate and neopelex.
Cationic surfactant includes, but are not limited to the water of the quaternary ammonium salt with about 10-18 carbon atoms on alkyl
Soluble compound（Such as cetyl bromination pyrroles）, carry about 10-18 carbon atoms amine salt compound（Such as octadecane
Base stearyl amine hydrochloride）, heterocyclic compound（Such as 2-alkyl imidazolines）.Such as the 16 of cationic surfactant
Alkyl trimethyl ammonium chloride, 2-alkyl imidazolines, dodecyl dimethyl phenyl phosphonium bromide, octadecyl dimethyl benzyl chlorine
Change ammonium, dioctadecylamine hydrochloride, N, Dymanthine hydrochloride and cetyl bromination pyrroles.
It includes the compound of hydrophily and hydrophobic combination that nonionic surface active agent, which includes, but are not limited to, (can lead to
Crossing makes alkylene oxide alkyl be generated with the organo-phobicity compound condensation of aliphatic series or alkyl-aromatics).Suitable nonionic table
Such as low viscosity hydroxyethyl cellulose, polysorbate esters, polyoxyethylene sorbitan esters class, the fatty alcohol of face activating agent
Ethoxylate, the polyethylene oxide condensates of alkylbenzene phenols, from ethylene oxide and propylene oxide and reacting ethylenediamine
The product of the condensation of product, the ethylene oxide condensate of aliphatic alcohol class, long chain tertiary amine oxides, long chain tertiary phosphine oxides, long-chain dioxane
Base sulfoxide type and its mixture.
Amphoteric surfactant may include, but be not limited to the derivative of the secondary and tertiary amine of aliphatic series, and wherein aliphatic component can
Think linear chain or branched chain and one of aliphatic substituent group containing about 8-18 carbon atoms and contain anionic water solubility base
Group, such as carboxylate, sulfonate, sulfate, phosphate, sweet tea Lay alkali, especially Cocoamidopropyl betaine and its mixture.
Other foaming agents can also include the reaction product of arbitrary alkali and acid in the present invention.They may include：For example,
Alkali carbonate or bicarbonate, such as sodium bicarbonate, saleratus.Sodium carbonate or potassium carbonate or alkaline earth metal carbonate
Or bicarbonate, such as magnesium bicarbonate or carbonic acid nitrogen calcium or magnesium carbonate or calcium carbonate.Dosage can be in following range：For example, about
1-10% weight；For example, about 3-7% weight；For example, the composition of about 3.5-5. 5% weight.
The stabilizer component includes, but are not limited to phosphoric acid compound, phosphinylidyne based polycarboxylic acid series row compound, ammonia
One or more kinds of compositions in based polycarboxylic acid series compound, organic acid.
Above-mentioned phosphoric acid compound is such as：Phosphoric acid, dibastic sodium phosphate, sodium phosphate, tripolyphosphate, sodium metaphosphate, inosinicacid
Deng.
Above-mentioned phosphinylidyne based polycarboxylic acid series row compound is such as：- 1,2-dicarboxylic acids of 2- phosphate butane, 1-phosphate butane-
2,3,4-tricarboxylic acids, α-methylphosphonic acid succinic acid etc..
Above-mentioned aminopolycarboxylic series compound is such as：Ethylenediamine diacetic acid, hydroxyethyliminodiacetic acid, iminodiacetic acid (salt)
Acid, nitrilotriacetic acid, ethylenediamine tetra-acetic acid, diethylenetriamine pentaacetic acid, glycoletherdiaminotetraacetic acid, teiethylene tetramine-hexacetic acid etc..
Above-mentioned organic acid is such as：Citric acid, Citric Acid Mono, succinic acid, maleic acid, phthalic acid, terephthalic acid (TPA),
Phthalic acid, fumaric acid, adipic acid, azelaic acid, diglycolic acid, oxygen union II succinic acid, carboxy methoxy-succinic acid, lactic acid, winestone
Acid, oxalic acid, glutaric acid, malic acid, gluconic acid, methylol succinic acid, methylol tartaric acid etc..
The bleaching assistant component includes, but are not limited to ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, diethylidene
One or more kinds of compositions in the salt of pentaacetic acid, phosphonate, sodium metasilicate, sodium carbonate, magnesium fluosilicate.
The pH adjusting agent include, but are not limited to sodium carbonate, potassium carbonate, sodium hydroxide, potassium hydroxide, citric acid,
The group of sodium tetraborate one or more in acetic acid, carbonic acid, monoethanolamine, triethanolamine, diethanol amine, disodium hydrogen phosphate
Close object.Number shared by pH adjusting agent is metered according to the height of pH value, and pH is between 5-10 for control.
Bion peroxide composite material of the present invention, preparation method includes the following steps：
1. excipients are swollen in moisturizer, deionized water is then added, stirs evenly；
2. peroxide, stabilizer, foaming agent, bleaching assistant are dissolved in deionized water, stirred evenly after waiting dissolving；
3. 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine by above-mentioned steps；Then thickener is added, stirs
It mixes uniformly；
4. photosensitizer is added, stir evenly；
5. adjust pH value between 5-10 with pH adjusting agent, under vacuum conditions, degassing to colloid entirely without blister state to obtain the final product
Bion peroxide composite material.
The preparation method of bion peroxide composite material of the present invention, which does not represent, can prepare or utilize the present invention
Unique forms.Unless otherwise stated, otherwise all technical and scientific terms used herein all has and skill belonging to the present invention
The art field normally understood meaning of those of ordinary skill is identical.Biology novel whitening material provided by the present invention, preparation method
Simplicity, during storage, peroxide stable effective ingredients, while photopolymerization initiator composition is introduced, it can effectively activate peroxidating
Object active ingredient belongs to environmentally friendly bleaching material of new generation.This product can be applicable to daily nursing according to its performance characteristics
The multiple fields such as product, laundry article, oral care article, printed matter.
Specific implementation mode
With embodiment, the present invention will be further described below
Embodiment 1
（1）Weigh carbomer 5g, propylene glycol 60g, sorbitol ester 100g；Propylene glycol and sorbitol ester are added to molten in carbomer
It is swollen；Then swelling object is added in 200g water, is stirred evenly；
（2）Weigh hydrogen peroxide 60g, dibastic sodium phosphate 14g, neopelex 12g, octadecyl dimethyl benzyl chlorine
Change ammonium 10g to dissolve in 300g deionized waters, and stirs evenly；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；Weigh hydroxyethyl cellulose
70g, stirring is until be uniformly dissolved；
（4）2,2 dimethyl-α hydroxy acetophenone 20g are weighed, is drawn into vacuum Manufacturing medicine extract machine, stirs evenly；
（5）It is 8 with triethanolamine and citric acid condition pH value, then under vacuum conditions, degassing is to colloid entirely without blister state
Up to bion peroxide composite material.
Embodiment 2
（1）Weigh carbomer 4g, Arabic gum 5g, propylene glycol 16g, sorbitol ester 10g, glycerine 24g；By propylene glycol, sorbierite
Ester and glycerine are added in carbomer and Arabic gum and are swollen；Then swelling object is added in 250g water, is stirred evenly；
（2）Weigh urea peroxide 500g, neopelex 3g, ethylenediamine diacetic acid 35g, ethylenediamine tetra-acetic acid 5g exist
It dissolves, and stirs evenly in 400g deionized waters；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；Sodium alginate 100g is weighed,
Stirring is until be uniformly dissolved；
（4）2,2 dimethyl-α hydroxy acetophenone 12g are weighed, fluorinated diphenyl titanium cyclopentadienyl 2g is drawn into vacuum Manufacturing medicine extract machine, and stirring is equal
It is even；
（5）It is 7.5 with sodium carbonate and citric acid condition pH value, then under vacuum conditions, degassing is to colloid entirely without blister state
Up to bion peroxide composite material.
Embodiment 3
（1）Weigh poloxamer 15g, xanthans 45g, propylene glycol 160g, sorbitol ester 120g, butanediol 320g；By propylene glycol,
Sorbitol ester and butanediol are added in poloxamer and xanthans and are swollen；Then swelling object is added in 350g water, and stirring is equal
It is even；
（2）Weigh hydrogen peroxide 200g, urea peroxide 100g, cetyl bromination pyrroles 45g, Citric Acid Mono 25g, ethylenediamine
Oxalic acid 35g, disodium ethylene diamine tetraacetate 15g are dissolved in 300g deionized waters, and are stirred evenly；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；Sodium alginate 10g is weighed,
Hydroxypropyl cellulose 5g stirrings are until be uniformly dissolved；
（4）It weighs 2,2 dimethyl-α hydroxyl P-isopropyl acetophenone 22g, fluorinated diphenyl titanium cyclopentadienyl 28g and is drawn into vacuum Manufacturing medicine extract machine
In, it stirs evenly；
（5）It is 10 with sodium hydroxide and citric acid condition pH value, then under vacuum conditions, degassing is to colloid entirely without blister state
Up to bion peroxide composite material.
Embodiment 4
（1）Weigh poloxamer 12g, carragheen 35g, propylene glycol 150g, glycerine 120g, butanediol 320g；By propylene glycol, glycerine
It is added in poloxamer and carragheen and is swollen with butanediol；Then swelling object is added in 200g water, is stirred evenly；
（2）Weigh hydrogen peroxide 100g, benzoyl peroxide 100g, cetyl bromination pyrroles 15g, tartaric acid 25g, sodium metasilicate
3g, disodium ethylene diamine tetraacetate 15g are dissolved in 320g deionized waters, and are stirred evenly；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；Sodium alginate 10g is weighed,
Methylcellulose 15g stirrings are until be uniformly dissolved；
（4）Bis- (pentafluorophenyl group) titanium cyclopentadienyl 5g are weighed, fluorinated diphenyl titanium cyclopentadienyl 25g is drawn into vacuum Manufacturing medicine extract machine, stirs evenly；
（5）It is 6 with triethanolamine, sodium carbonate and Citric Acid Mono condition pH value, then under vacuum conditions, degassing is complete to colloid
Completely without blister state up to bion peroxide composite material.
Embodiment 5
（1）Weigh poloxamer 12g, carbomer 15g, sorbitol ester 150g, glycerine 120g；Sorbitol ester, glycerine are added to
It is swollen in poloxamer and carbomer；Then swelling object is added in 220g water, is stirred evenly；
（2）Weigh urea peroxide 100g, SODIUM PERCARBONATE 100g, cetyl benzenesulfonic acid sodium 15g, oxalic acid 5g tartaric acid 25g, silicic acid
Sodium 13g dissolves in 350g deionized waters, and stirs evenly；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；Weigh hydroxyethyl cellulose
12g, methylcellulose 25g stirrings are until be uniformly dissolved；
（4）It weighs bis- (pentafluorophenyl group) titanium cyclopentadienyl 5g to be drawn into vacuum Manufacturing medicine extract machine, stir evenly；
（5）It is 5 with triethanolamine and carbonic acid condition pH value, then under vacuum conditions, degassing is entirely without blister state to colloid
Obtain bion peroxide composite material.
Embodiment 6
（1）Weigh poloxamer 15g, carragheen 32g, carbomer 5g, propylene glycol 50g, glycerine 100g, sorbitol ester 330g；It will
Propylene glycol, glycerine and sorbitol ester are added in poloxamer, carragheen and carbomer and are swollen；Then swelling object is added to 200g
In water, stir evenly；
（2）Weigh hydrogen peroxide 120g, lauryl sulfoacetate sodium 12g, cetyl bromination pyrroles 15g, malic acid 20g, fluorine
Magnesium silicate 6g, ethylenediamine tetra-acetic acid 16g are dissolved in 380g deionized waters, and are stirred evenly；
（3）By above-mentioned steps, 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine；
（4）Camphorquinone 12g, bis- (pentafluorophenyl group) titanium cyclopentadienyl 2g are weighed, fluorinated diphenyl titanium cyclopentadienyl 15g is drawn into vacuum Manufacturing medicine extract machine,
It stirs evenly；
（5）It is 7 with triethanolamine, sodium bicarbonate and citric acid condition pH value, then under vacuum conditions, degassing is complete to colloid
Still state is up to bion peroxide composite material.
Claims (10)
1. a kind of bion peroxide composite material and preparation method provided by the invention, it is characterised in that the composite material
It is a kind of multigroup part of peroxide composite material of one-pack type；
The bion peroxide composite material includes mainly following component：Peroxide, water, excipients, thickener, light
Quick dose, moisturizer, foaming agent, stabilizer, bleaching assistant, pH adjusting agent；
The bion peroxide composite material, by mass fraction, Main Components proportion is：Peroxide 6-
50 parts, 5-65 parts of water, 0.5-6 parts of excipients, 0-10 parts of thickener, 0.5-5 parts of photosensitizer, 5-60 parts of moisturizer, foaming agent
0.3-4.5 parts, 1-6 parts of stabilizer, 0-5 parts of bleaching assistant.
2. bion peroxide composite material as described in claim 1, it is characterised in that peroxide component includes, but not
It is limited to hydrogen peroxide, urea peroxide, SODIUM PERCARBONATE, calper calcium peroxide, perborate, glyceryl peroxide, benzoyl peroxide
In one or more kinds of compositions.
3. bion peroxide composite material as described in claim 1, it is characterised in that excipients component includes, but unlimited
In carbomer（Carbomer）, xanthans, tragacanth, carragheen（Carrageenan）, poloxamer（Poloxamer）, Ah
Draw one or more kinds of compositions in primary glue, polyvinylpyrrolidone, gelatin.
4. bion peroxide composite material as described in claim 1, it is characterised in that thickener component includes, but unlimited
In sodium carboxymethylcellulose, polyanion cellulose, Hydroxyethylenecellulose, hydroxypropyl cellulose, sodium alginate, hydroxypropyl first
One or more kinds of compositions in base cellulose, methylcellulose etc..
5. bion peroxide composite material as described in claim 1, it is characterised in that photosensitizer component includes, but unlimited
One or more kinds of compositions in radical photosensitive agent, cationic polymerization photosensitizer, other photosensitizers etc.；
Above-mentioned radical photosensitive agent includes, but are not limited to benzoin ethers, benzil ketals class, acetophenones, acyl group oxidation
One or more in Phosphorus, benzophenone and tertiary amine complex, camphorquinone, thioxanthone and its derivative, double imidazoles
Composition；
Above-mentioned cationic photosensitizer includes, but are not limited to aromatic diazo salt, arylsulfonium salts, aryl salt, ferrocene salt
One or more kinds of compositions in class；
Other above-mentioned photosensitizers include, but are not limited to free radical-cationic hybrid photosensitizer, visible light photosensitizer, aqueous light
Quick dose, one or more kinds of compositions in macromolecular photosensitizer.
6. bion peroxide composite material as described in claim 1, it is characterised in that moisturizer component includes, but unlimited
One or more kinds of compositions in propylene glycol, glycerine, sorbitol ester, polyethylene glycol, butanediol, hexylene glycol.
7. bion peroxide composite material as described in claim 1, it is characterised in that foaming agent component includes, but unlimited
In surfactant, gas foaming agent, other foaming agents；
When using surfactant as foaming agent, its main species includes, but are not limited to anion surface active in the present invention
One or more kinds of combinations in agent, cationic surfactant, nonionic surface active agent, amphoteric surfactant
Object；Gaseous material can be for arbitrary inert gas or by making alkaline peroxide when with gas foaming agent in the present invention
Solution mixes the gas generated with acid solution；
Anionic surfactant includes, but are not limited to the alkyl sulfate with about 8-20 carbon atoms on alkyl
The sulfonated monoglycerides of water soluble compound (such as sodium alkyl sulfate), aliphatic acid with about 8-20 carbon atoms
Water soluble compound and its mixture；Such as lauryl sodium sulfate of anionic surfactant, sodium coconut m ester
Sodium sulfonate, phospholipid；Sarcosinate, such as sarcosyl, taurate, lauryl sulfoacetate sodium, lauroyl
Amine ethylsulfonic acid sodium, laureth 9 sodium sulphate and neopelex；
Cationic surfactant includes, but are not limited to the water solubility of the quaternary ammonium salt with about 10-18 carbon atoms on alkyl
Compound（Such as cetyl bromination pyrroles）, carry about 10-18 carbon atoms amine salt compound（Such as octadecyl is hard
Fat amine hydrochlorate）, heterocyclic compound（Such as 2-alkyl imidazolines）；Such as cetyl of cationic surfactant
Trimethyl ammonium chloride, 2-alkyl imidazolines, dodecyl dimethyl phenyl phosphonium bromide, stearyl dimethyl benzyl ammonium chloride,
Dioctadecylamine hydrochloride, N, Dymanthine hydrochloride and cetyl bromination pyrroles；
Nonionic surface active agent includes, but are not limited to include that the compound of hydrophily and hydrophobic combination (can be by making
Alkylene oxide alkyl is generated with the organo-phobicity compound condensation of aliphatic series or alkyl-aromatics) suitable non-ionic surfactant
Such as low viscosity hydroxyethyl cellulose, polysorbate esters, polyoxyethylene sorbitan esters class, the alcohol ethoxy of agent
Compound, the polyethylene oxide condensates of alkylbenzene phenols, from ethylene oxide and propylene oxide and reacting ethylenediamine product
The product of condensation, the ethylene oxide condensate of aliphatic alcohol class, long chain tertiary amine oxides, long chain tertiary phosphine oxides, long chain dialkyl sulfoxides
Class and its mixture；
Amphoteric surfactant may include, but be not limited to the derivative of the secondary and tertiary amine of aliphatic series, and wherein aliphatic component can be
One of linear chain or branched chain and aliphatic substituent group is containing about 8-18 carbon atoms and contains anionic water soluble group,
Such as carboxylate, sulfonate, sulfate, phosphate, sweet tea Lay alkali, especially Cocoamidopropyl betaine and its mixture；
Other foaming agents can also include the reaction product of arbitrary alkali and acid in the present invention, they may include：For example, alkali is golden
Belong to carbonate or bicarbonate, such as sodium bicarbonate, saleratus, sodium carbonate or potassium carbonate or alkaline earth metal carbonate or carbon
Sour hydrogen salt, such as magnesium bicarbonate or carbonic acid nitrogen calcium or magnesium carbonate or calcium carbonate, dosage can be in following ranges：For example, about 1-
10% weight；For example, about 3-7% weight；For example, the composition of about 3.5-5. 5% weight.
8. bion peroxide composite material as described in claim 1, it is characterised in that stabilizer component includes, but unlimited
One kind in phosphoric acid compound, phosphinylidyne based polycarboxylic acid series row compound, aminopolycarboxylic series compound, organic acid or
More than one composition；
Above-mentioned phosphoric acid compound is such as：Phosphoric acid, dibastic sodium phosphate, sodium phosphate, tripolyphosphate, sodium metaphosphate, inosinicacid etc.；
Above-mentioned phosphinylidyne based polycarboxylic acid series row compound is such as：- 1,2-dicarboxylic acids of 2- phosphate butane, 1-phosphate butane-2,
3,4-tricarboxylic acids, α-methylphosphonic acid succinic acid etc.；
Above-mentioned aminopolycarboxylic series compound is such as：Ethylenediamine diacetic acid, hydroxyethyliminodiacetic acid, iminodiacetic acid,
Nitrilotriacetic acid, ethylenediamine tetra-acetic acid, diethylenetriamine pentaacetic acid, glycoletherdiaminotetraacetic acid, teiethylene tetramine-hexacetic acid etc.；
Above-mentioned organic acid is such as：Citric acid, Citric Acid Mono, succinic acid, maleic acid, phthalic acid, terephthalic acid (TPA), isophthalic two
Formic acid, fumaric acid, adipic acid, azelaic acid, diglycolic acid, oxygen union II succinic acid, carboxy methoxy-succinic acid, lactic acid, tartaric acid, grass
Acid, glutaric acid, malic acid, gluconic acid, methylol succinic acid, methylol tartaric acid etc..
9. bion peroxide composite material as described in claim 1, it is characterised in that bleaching assistant component includes, but not
It is limited to ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, the salt of diethylene-triamine pentaacetic acid, phosphonate, sodium metasilicate, carbonic acid
One or more kinds of compositions in sodium, magnesium fluosilicate.
10. bion peroxide composite material as described in claim 1, it is characterised in that preparation method includes following step
Suddenly：
1. excipients are swollen in moisturizer, deionized water is then added, stirs evenly；
2. peroxide, stabilizer, foaming agent, bleaching assistant are dissolved in deionized water, stirred evenly after waiting dissolving；
3. 1. 2. gained component stirs evenly respectively in sucking vacuum Manufacturing medicine extract machine by above-mentioned steps；Then thickener is added, stirs
It mixes uniformly；
4. photosensitizer is added, stir evenly；
5. adjust pH value between 5-10 with pH adjusting agent, under vacuum conditions, degassing to colloid entirely without blister state to obtain the final product
Bion peroxide composite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810526509.8A CN108659991A (en) | 2018-05-29 | 2018-05-29 | A kind of peroxide composite material and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810526509.8A CN108659991A (en) | 2018-05-29 | 2018-05-29 | A kind of peroxide composite material and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108659991A true CN108659991A (en) | 2018-10-16 |
Family
ID=63777984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810526509.8A Withdrawn CN108659991A (en) | 2018-05-29 | 2018-05-29 | A kind of peroxide composite material and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108659991A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526740A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Photoinitiator composition capable of initiating via visible light and its use |
| CN1649991A (en) * | 2002-03-06 | 2005-08-03 | 卡内基梅隆大学 | Bleaching composition |
| CN1688938A (en) * | 2002-10-02 | 2005-10-26 | 3M创新有限公司 | Multiphoton photosensitization system |
| CN1813093A (en) * | 2003-06-27 | 2006-08-02 | 宝洁公司 | Photo bleach lipophilic fluid cleaning compositions |
| CN1981024A (en) * | 2004-06-24 | 2007-06-13 | 宝洁公司 | Photo bleach compositions |
| CN101501173A (en) * | 2006-01-23 | 2009-08-05 | 宝洁公司 | Enzyme and photobleach containing compositions |
| CN103131556A (en) * | 2013-02-20 | 2013-06-05 | 杨新莲 | Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof |
| CN107190547A (en) * | 2017-05-10 | 2017-09-22 | 点铂医疗科技（常州）有限公司 | A kind of light-initiated bleaching material and preparation method thereof |
-
2018
- 2018-05-29 CN CN201810526509.8A patent/CN108659991A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649991A (en) * | 2002-03-06 | 2005-08-03 | 卡内基梅隆大学 | Bleaching composition |
| CN1688938A (en) * | 2002-10-02 | 2005-10-26 | 3M创新有限公司 | Multiphoton photosensitization system |
| CN1526740A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Photoinitiator composition capable of initiating via visible light and its use |
| CN1813093A (en) * | 2003-06-27 | 2006-08-02 | 宝洁公司 | Photo bleach lipophilic fluid cleaning compositions |
| CN1981024A (en) * | 2004-06-24 | 2007-06-13 | 宝洁公司 | Photo bleach compositions |
| CN101501173A (en) * | 2006-01-23 | 2009-08-05 | 宝洁公司 | Enzyme and photobleach containing compositions |
| CN103131556A (en) * | 2013-02-20 | 2013-06-05 | 杨新莲 | Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof |
| CN107190547A (en) * | 2017-05-10 | 2017-09-22 | 点铂医疗科技（常州）有限公司 | A kind of light-initiated bleaching material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1038945C (en) | Granular laundry detergent compositions having improved solubility | |
| EP0088394B1 (en) | Stable, effervescent vaginal suppository composition and suppositories made therefrom | |
| CA1243262A (en) | Denture cleansing compositions | |
| JP5575070B2 (en) | Solid herbicidal composition | |
| CZ299449B6 (en) | Process for increasing concentration of a pharmaceutically active ingredient relative to fill composition viscosity for dosage units | |
| GB1185386A (en) | Abrasive Scouring Cleanser Compositions. | |
| JP2005518457A (en) | Carrier for liquid components used in foam products | |
| RU2016141961A (en) | INDEPENDENT CHEMICAL FOAM CONTAINING BENZOIL PEROXIDE | |
| JP2006525210A (en) | Coated sodium percarbonate granules with improved storage stability | |
| JPS6052193B2 (en) | Process for manufacturing fluid cleaning and cleaning agents | |
| CN108576049A (en) | Sodium peroxydisulfate sterilizes degerming cleansing tablet and preparation method thereof | |
| CN107190547A (en) | A kind of light-initiated bleaching material and preparation method thereof | |
| EP3825392A1 (en) | Detergent tablet comprising an effervescent system | |
| CA2376017A1 (en) | Potassium calcium citrate compositions and methods for production | |
| CN108659991A (en) | A kind of peroxide composite material and preparation method | |
| CN106942270A (en) | Many part kit systems for preparing disinfectant | |
| JP2000504063A (en) | Cleaning composition comprising bleach, sulfamic acid and polycarboxylate polymer | |
| JP2007522335A (en) | Laundry detergent composition comprising an anionic detersive surfactant, sulfamic acid and its water-soluble salts | |
| US8802049B2 (en) | Methods of producing metallic peroxide compositions for use in groundwater decontamination | |
| JP2869310B2 (en) | Stable sodium percarbonate, method for producing the same, and bleaching detergent composition containing stable sodium percarbonate | |
| CN111304016A (en) | Sterilizing washing powder | |
| JP2951781B2 (en) | Bleaching detergent composition for hard surfaces | |
| JPS6059280B2 (en) | Method for producing granular detergent composition | |
| JPS5851999B2 (en) | bleach composition | |
| EP3617299B1 (en) | Polymeric agents improving primary washing power |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181016 |