CN108659978A - A kind of white glass cleaning agent and preparation method thereof - Google Patents

A kind of white glass cleaning agent and preparation method thereof Download PDF

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Publication number
CN108659978A
CN108659978A CN201810642623.7A CN201810642623A CN108659978A CN 108659978 A CN108659978 A CN 108659978A CN 201810642623 A CN201810642623 A CN 201810642623A CN 108659978 A CN108659978 A CN 108659978A
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CN
China
Prior art keywords
cleaning agent
white glass
glass cleaning
agent
agent according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810642623.7A
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Chinese (zh)
Inventor
卢燕燕
张丽燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Dacheng Microelectronic Materials Co., Ltd.
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Shenzhen Dacheng Cleaning Agent Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201810642623.7A priority Critical patent/CN108659978A/en
Publication of CN108659978A publication Critical patent/CN108659978A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of white glass cleaning agents and preparation method thereof, which consists of the following components in percentage by weight：KOH 1%~10%；Alcohol ethers solvent 2%~5%；Anion surfactant 0.1%~2%；Nonionic surfactant 0.1%~3%；Auxiliary agent 0.05%~1%；Complexing agent 0.1%~2%；Anti redeposition agent 1%~3%；Water surplus.The present invention has the advantages that clean up, does not hinder white glass, can prevent soil redeposition compared with simple glass cleaning agent.

Description

A kind of white glass cleaning agent and preparation method thereof
Technical field
The present invention relates to glass cleaner technical fields, are to be related to a kind of white glass cleaning agent and its system more specifically Preparation Method.
Background technology
Cleaning agent can probably be divided into inorganic cleaning and organic washing two major classes, and organic washing agent is exactly to contain carbon compound Manufactured cleaning agent, inorganic cleaning agent are exactly cleaning agent made of carbon-free compound.The specific sorting technique of cleaning agent has Very much, each state is all not quite similar, and China generally falls into water system, half water system and non-water system cleaning agent three categories.However, existing glass The cleaning performance of glass cleaning agent is still to be improved, and flushing repeatedly is needed after use, can not preferably be suitable for the clear of white glass It washes, is easy to damage white glass, dirt is easy redeposition.
Invention content
It is an object of the invention to overcome drawbacks described above in the prior art, provide one kind clean up, do not hinder white glass, It can prevent the white glass cleaning agent and preparation method thereof of soil redeposition.
To achieve the above object, the first aspect of the present invention provides a kind of white glass cleaning agent, and the cleaning agent is by following The group of weight percent is grouped as：
As preferred embodiment, the alcohol ethers solvent includes propylene glycol monomethyl ether, propandiol butyl ether or diethylene glycol Ether.
As preferred embodiment, the anion surfactant includes lauryl sodium sulfate.
As preferred embodiment, the nonionic surfactant includes alkyl polyglycoside (APG).
As preferred embodiment, the auxiliary agent includes Sodium Polyacrylate.
As preferred embodiment, the complexing agent includes ethylenediamine tetra-acetic acid (EDTA), tetrasodium ethylenediamine tetraacetate (EDTA-4Na), disodium ethylene diamine tetraacetate (EDTA-2Na), sodium citrate or sodium gluconate.
As preferred embodiment, the anti redeposition agent includes hydroxymethyl cellulose.
Second aspect of the present invention provides a kind of method of the white glass cleaning agent prepared as described in above-mentioned technical proposal, packet Include following steps：
By KOH 1%~10%, alcohol ethers solvent 2%~5%, anion surfactant 0.1%~2%, nonionic Surfactant 0.1%~3%, auxiliary agent 0.05%~1%, complexing agent 0.1%~2%, anti redeposition agent 1%~3% and remaining The water of amount is added to uniform stirring in reaction vessel by corresponding weight percent and can be prepared by.
Compared with prior art, the beneficial effects of the present invention are：
1, KOH of the invention is capable of providing alkalinity, and alcohol ethers solvent chooses suitable two kinds of surface-actives as solubilizer Agent compounds, synergistic, the effects that wetting, infiltration, emulsification, dispersion, solubilising can be improved, and has good biological degradability, helps Agent has chelation to metal ion, plays alkaline buffer, and dirt disperses into water and prevent redeposition, complexing agent can be complexed Metal ion (Ca2+, Mg2+ etc.) forms white point, anti redeposition agent in order to avoid the deposition again of metal ion, remains on glass Redeposition can be prevented, the present invention has compared with simple glass cleaning agent and cleans up, do not hinder white glass, can prevent Only the advantages of soil redeposition.
2, preparation process of the invention is simple, and manufacturing cost is low.
Specific implementation mode
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than Whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work premise Lower obtained every other embodiment, shall fall within the protection scope of the present invention.
A kind of white glass cleaning agent, the cleaning agent consist of the following components in percentage by weight：KOH 1%~10%；Alcohol Ether solvent 2%~5%；Anion surfactant 0.1%~2%；Nonionic surfactant 0.1%~3%；Auxiliary agent 0.05%~1%；Complexing agent 0.1%~2%；Anti redeposition agent 1%~3%；Water surplus.
A method of the white glass cleaning agent described in above-mentioned technical proposal is prepared, is included the following steps：
By KOH, alcohol ethers solvent, anion surfactant, nonionic surfactant, auxiliary agent, complexing agent, resists and sink again The water of product agent and surplus is added to uniform stirring in reaction vessel by corresponding weight percent and can be prepared by.
The alcohol ethers solvent includes propylene glycol monomethyl ether, propandiol butyl ether or diethylene glycol ether.
The anion surfactant includes lauryl sodium sulfate.
The nonionic surfactant includes alkyl polyglycoside (APG).
The auxiliary agent includes Sodium Polyacrylate.
The complexing agent includes ethylenediamine tetra-acetic acid (EDTA), tetrasodium ethylenediamine tetraacetate (EDTA-4Na), ethylenediamine tetraacetic Acetic acid disodium (EDTA-2Na), sodium citrate or sodium gluconate.
The anti redeposition agent includes hydroxymethyl cellulose.
Wherein, KOH is capable of providing alkalinity, and alcohol ethers solvent is as solubilizer.
Single surfactant respectively has its shortcoming, if ionic surfactant stablizes temperature, but hydrophily Too strong, nonionic is good synergist, but has the limitation of certain temperature range again, chooses suitable two kinds of surfaces and lives Property agent compounding, synergistic, the effects that wetting, infiltration, emulsification, dispersion, solubilising can be improved.
Existing simple glass cleaning agent includes often alkyl phenol polyoxyethylene ether (APEO), with it is good wetting, Infiltration, emulsification, dispersion, solubilising and cleaning function, be widely used in detergent, the daily-use chemical industry of personal nursing, weaving, papermaking, The industries such as oil, metallurgy, pesticide, pharmacy, printing, synthetic rubber, synthetic resin, plastics, but biological degradability is poor, therefore can To be replaced using alkyl polyglycoside (APG), APG is minimum in nonionic surfactant to the irritation of skin and eyes, is had Good biological degradability, biological degradation rate is 80% in 5 days；Ultimate biodegradation rate is up to 99.3%.
Sodium Polyacrylate replaces the sodium polyphosphate in existing simple glass cleaning agent, has chelation to metal ion, Play alkaline buffer, dirt disperses into water and prevent redeposition.
Complexing agent can complexation of metal ions (Ca2+, Mg2+ etc.), in order to avoid the deposition again of metal ion, remains in glass On, form white point.Anti redeposition agent can prevent redeposition.
Embodiment
Embodiment 1：KOH 3%, propylene glycol monomethyl ether 2%, lauryl sodium sulfate 0.5%, APG 0.8%, polyacrylic acid Sodium 0.1%, EDTA-4Na 1.0%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 2：KOH 3%, propylene glycol monomethyl ether 2%, lauryl sodium sulfate 0.5%, APG 0.8%, polyacrylic acid Sodium 0.3%, EDTA-2Na 1.0%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 3：KOH 3%, propylene glycol monomethyl ether 3%, lauryl sodium sulfate 0.5%, APG 0.8%, polyacrylic acid Sodium 0.1%, EDTA-4Na 1.0%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 4：KOH 3%, propylene glycol monomethyl ether 3%, lauryl sodium sulfate 0.5%, APG 1.0%, polyacrylic acid Sodium 0.1%, sodium citrate 1.0%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 5：KOH 4%, propylene glycol monomethyl ether 2%, lauryl sodium sulfate 0.5%, APG 0.5%, polyacrylic acid Sodium 0.3%, EDTA-4Na 1.0%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 6：KOH 1%, propylene glycol monomethyl ether 2%, lauryl sodium sulfate 0.1%, APG 0.1%, polyacrylic acid Sodium 0.05%, EDTA-4Na 0.1%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 7：KOH 1%, propandiol butyl ether 3%, lauryl sodium sulfate 0.1%, APG 0.1%, polyacrylic acid Sodium 0.05%, EDTA-4Na 0.1%, hydroxymethyl cellulose 1%, water surplus.
Embodiment 8：KOH 8%, diethylene glycol ether 4%, lauryl sodium sulfate 1.5%, APG 2%, polyacrylic acid Sodium 0.5%, sodium gluconate 1.5%, hydroxymethyl cellulose 2%, water surplus.
Embodiment 9：KOH 10%, propylene glycol monomethyl ether 5%, lauryl sodium sulfate 2%, APG 3%, Sodium Polyacrylate 1%, EDTA2%, hydroxymethyl cellulose 3%, water surplus.
In conclusion the present invention compared with simple glass cleaning agent, has and cleans up, do not hinder white glass, can prevent dirt Dirty redeposited advantage.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications, Equivalent substitute mode is should be, is included within the scope of the present invention.

Claims (8)

1. a kind of white glass cleaning agent, which is characterized in that the cleaning agent consists of the following components in percentage by weight：
2. a kind of white glass cleaning agent according to claim 1, which is characterized in that the alcohol ethers solvent includes propylene glycol Methyl ether, propandiol butyl ether or diethylene glycol ether.
3. a kind of white glass cleaning agent according to claim 1, which is characterized in that the anion surfactant includes Lauryl sodium sulfate.
4. a kind of white glass cleaning agent according to claim 1, which is characterized in that the nonionic surfactant includes Alkyl polyglycoside.
5. a kind of white glass cleaning agent according to claim 1, which is characterized in that the auxiliary agent includes Sodium Polyacrylate.
6. a kind of white glass cleaning agent according to claim 1, which is characterized in that the complexing agent includes ethylenediamine tetrem Acid, tetrasodium ethylenediamine tetraacetate, disodium ethylene diamine tetraacetate, sodium citrate or sodium gluconate.
7. a kind of white glass cleaning agent according to claim 1, which is characterized in that the anti redeposition agent includes methylol Cellulose.
8. a kind of method of the white glass cleaning agent prepared as described in any one of claim 1~7, which is characterized in that packet Include following steps：
By KOH 1%~10%, alcohol ethers solvent 2%~5%, anion surfactant 0.1%~2%, non-ionic surface Activating agent 0.1%~3%, auxiliary agent 0.05%~1%, complexing agent 0.1%~2%, anti redeposition agent 1%~3% and surplus Water is added to uniform stirring in reaction vessel by corresponding weight percent and can be prepared by.
CN201810642623.7A 2018-06-21 2018-06-21 A kind of white glass cleaning agent and preparation method thereof Pending CN108659978A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109576077A (en) * 2018-12-13 2019-04-05 昆山市板明电子科技有限公司 Cleaning agent for optical glass

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Publication number Priority date Publication date Assignee Title
CN103103027A (en) * 2012-12-10 2013-05-15 苏州丰儒软件有限公司 Glass product cleaning agent and preparation method thereof
CN103789097A (en) * 2014-02-20 2014-05-14 苏州龙腾万里化工科技有限公司 Glass cleaner formula
CN106753873A (en) * 2017-01-13 2017-05-31 蓝思科技（长沙）有限公司 A kind of glass cleaner and its application method

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CN103103027A (en) * 2012-12-10 2013-05-15 苏州丰儒软件有限公司 Glass product cleaning agent and preparation method thereof
CN103789097A (en) * 2014-02-20 2014-05-14 苏州龙腾万里化工科技有限公司 Glass cleaner formula
CN106753873A (en) * 2017-01-13 2017-05-31 蓝思科技（长沙）有限公司 A kind of glass cleaner and its application method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109576077A (en) * 2018-12-13 2019-04-05 昆山市板明电子科技有限公司 Cleaning agent for optical glass

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