CN108659710B - Solvent-free finish paint composition for wind power blade and preparation method and application thereof - Google Patents
Solvent-free finish paint composition for wind power blade and preparation method and application thereof Download PDFInfo
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- CN108659710B CN108659710B CN201711086613.1A CN201711086613A CN108659710B CN 108659710 B CN108659710 B CN 108659710B CN 201711086613 A CN201711086613 A CN 201711086613A CN 108659710 B CN108659710 B CN 108659710B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a solvent-free finish paint composition for a wind power blade, and a preparation method and application thereof. The finish paint composition has excellent elongation at break, salt spray resistance, aging resistance, wear resistance and the like.
Description
Technical Field
The invention relates to a solvent-free finish paint composition for a wind power blade and a preparation method and application thereof.
Background
The finish paint for the wind power blade is used for protecting the blade of a wind field, and has a protective effect on the blade no matter in a wind and sand zone or an oceanic high-salt environment. This requires a blade finish having very good weatherability, salt spray resistance, abrasion and wind sand resistance, and good elongation at break. At the same time, it must have very good adhesion to the blade putty and the glass fibre reinforced plastic substrate.
Disclosure of Invention
The invention aims to provide a solvent-free finish paint composition for a wind power blade and a preparation method and application thereof.
The solvent-free finish paint composition for the wind power blade comprises the following components:
further, wherein the bio-based polyol flexible resin is obtained by esterification dehydration reaction (for example, 3 to 10 hours, preferably 4 to 6 hours) of 55 to 85 parts by weight, preferably 60 to 80 parts by weight, more preferably 65 to 75 parts by weight of vegetable oil with 10 to 35 parts by weight, preferably 15 to 30 parts by weight, more preferably 20 to 25 parts by weight of glycerin and 3 to 18 parts by weight, preferably 5 to 15 parts by weight, more preferably 8 to 12 parts by weight of 1, 4-butanediol at 200-. The reaction pressure may be normal pressure. Plumbum preparatium can be used in an amount of 4-10 wt%, preferably 5-8 wt%, based on the total weight of the vegetable oil, glycerin and 1, 4-butanediol. The vegetable oil can be one or more selected from soybean oil, rapeseed oil, castor oil, palm kernel oil, etc.
The reactive diluent may be selected from low molecular weight polyols from BASF, such as Sovermol series with viscosities of 300 to 3500mPas at 20 ℃ or 25 ℃, e.g. Sovermol 1102, Sovermol 1092, etc.
The water scavenger may be selected from the oxazolidine series available from ANGS such as ZOLDINE MS-PLUS (3-ethyl-2-methyl-2- (3-methylbutyl) -1, 3-oxazolidine) and the like.
The matting agent may be selected from fumed silica from the company degussa, such as OK500, and the like.
The drier may be chosen from dibutyltin dilaurate from Islam, such as T-12, and the like.
The defoaming agent may be selected from polyether modified siloxanes available from BYK company, such as BYK085, BYK066N, and the like.
The age resister may be selected from benzotriazole mixtures and sebacate mixtures from BASF corporation, such as Tinuvin 1130 and Tinuvin 292.
The dispersant may be selected from the diko series of dego Dispers 760W.
The filler may be selected from mica powder, barium sulfate, ground calcium carbonate, etc.
The leveling agent may be selected from, for example, the YCK series of Yike chemistry, such as YCK-1010, YCK-1020, YCK-1040, etc.
Another object of the present invention is to provide a method for preparing a topcoat composition for solventless wind blades, which comprises mixing the various components.
The invention further aims to provide application of the solvent-free finishing paint composition for the wind power blade in coating the wind power blade.
The invention has the following advantages:
partially esterifying multifunctional alcohol polymer such as vegetable oil such as soybean oil, rapeseed oil, castor oil, palm kernel oil and the like, glycerol and 1, 4-butanediol to obtain a solvent-free low-viscosity bio-based polyol flexible resin which is used as a film forming material of a solvent-free blade finish paint;
adding a reactive diluent with low viscosity and high toughness to reduce the viscosity of the finish paint so as to facilitate roll coating construction;
the oxazolidine water remover is added to remove trace water brought by the pigment, the filler and the resin in the solvent-free finish paint, so that the possibility of generating bubbles and pinholes in finish paint construction is solved.
Detailed Description
The invention is further illustrated by the following examples.
Preparation example 1
70 parts by weight of soybean oil, 20 parts by weight of glycerol and 10 parts by weight of 1, 4-butanediol are mixed, 6 parts by weight of yellow lead is used as a catalyst, and the mixture is subjected to esterification dehydration at a high temperature of about 220 ℃ and normal pressure reaction for about 5 hours (product viscosity: 2500mPa.s/23 ℃) to obtain the bio-based polyol flexible resin 1.
Preparation example 2
75 parts by weight of castor oil, 18 parts by weight of glycerol and 12 parts by weight of 1, 4-butanediol are mixed, 8 parts by weight of yellow lead is used as a catalyst, and the mixture is esterified, dehydrated and reacted for 4 hours under normal pressure at the high temperature of 240 ℃ (product viscosity: 3000mPa.s/23 ℃) to obtain the bio-based polyol flexible resin 2.
Preparation example 3
Mixing 80 parts by weight of palm kernel oil, 15 parts by weight of glycerol and 5 parts by weight of 1, 4-butanediol, and carrying out esterification dehydration at a high temperature of 230 ℃ and normal pressure reaction for 6 hours (product viscosity: 2800mPa.s/23 ℃) by using 7 parts by weight of yellow lead as a catalyst to obtain the bio-based polyol flexible resin 3.
Example 1
The following components were mixed to prepare a topcoat 1:
example 2
The following components were mixed to prepare a topcoat 2:
comparison of principal Properties
From the above, it can be seen that the topcoats of the present invention are similar or superior in primary performance to imported brand topcoats.
Claims (11)
1. A finish paint composition for solvent-free wind power blades comprises the following components:
wherein the bio-based polyol flexible resin is obtained by esterification dehydration reaction of 55-85 parts by weight of vegetable oil, 10-35 parts by weight of glycerin and 3-18 parts by weight of 1, 4-butanediol at the temperature of 200-260 ℃ by using yellow lead as a catalyst.
2. The topcoat composition of claim 1, comprising the following components:
3. the topcoat composition as claimed in claim 1, wherein the bio-based polyol flexible resin is obtained by esterification dehydration reaction of 60-80 parts by weight of vegetable oil with 15-30 parts by weight of glycerin and 5-15 parts by weight of 1, 4-butanediol at 220-240 ℃ using yellow lead as a catalyst.
4. The topcoat composition as claimed in claim 1, wherein the bio-based polyol flexible resin is obtained by esterification dehydration reaction of 65-75 parts by weight of vegetable oil with 20-25 parts by weight of glycerin and 8-12 parts by weight of 1, 4-butanediol at 220-240 ℃ using yellow lead as a catalyst.
5. The topcoat composition of any one of claims 1-4, wherein the yellow lead is used in an amount of 4-10 wt% of the total weight of the vegetable oil, the glycerin, and the 1, 4-butanediol.
6. The topcoat composition of any one of claims 1-4, wherein the yellow lead is used in an amount of 5-8 wt% of the total weight of the vegetable oil, the glycerin, and the 1, 4-butanediol.
7. The topcoat composition of any one of claims 1-4, wherein the vegetable oil is selected from one or more of soybean oil, rapeseed oil, castor oil, palm kernel oil.
8. The topcoat composition of any one of claims 1-4, wherein the reactive diluent is selected from a Sovermol series low molecular weight polyol having a viscosity of 300 to 3500mPa.s at 20 ℃ or 25 ℃.
9. The topcoat composition of any one of claims 1-4, wherein the water scavenger is selected from 3-ethyl-2-methyl-2- (3-methylbutyl) -1, 3-oxazolidine.
10. A method of preparing a topcoat composition for solventless wind blades as defined in any one of claims 1 to 9 comprising mixing the components.
11. Use of a topcoat composition for solventless wind power blades according to any one of claims 1 to 9 for coating wind power blades.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711086613.1A CN108659710B (en) | 2017-11-07 | 2017-11-07 | Solvent-free finish paint composition for wind power blade and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711086613.1A CN108659710B (en) | 2017-11-07 | 2017-11-07 | Solvent-free finish paint composition for wind power blade and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108659710A CN108659710A (en) | 2018-10-16 |
| CN108659710B true CN108659710B (en) | 2021-02-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711086613.1A Active CN108659710B (en) | 2017-11-07 | 2017-11-07 | Solvent-free finish paint composition for wind power blade and preparation method and application thereof |
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| CN (1) | CN108659710B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111171688A (en) * | 2018-11-12 | 2020-05-19 | 湖南航天三丰科工有限公司 | Wind power blade edge protection paint based on bio-based polyol |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1869184A (en) * | 2006-04-13 | 2006-11-29 | 上海中科合臣股份有限公司 | Preparation method of plant oil polyalcohol |
| CN102408768A (en) * | 2011-11-24 | 2012-04-11 | 中国海洋石油总公司 | Solvent-free two-component polyurethane putty for rotor wing |
| CN103421420A (en) * | 2013-07-17 | 2013-12-04 | 中国石油天然气集团公司 | Dissolvent-free polyurethane weather-proof anticorrosive coating for storage tank |
| CN105017880A (en) * | 2015-07-29 | 2015-11-04 | 洛阳双瑞防腐工程技术有限公司 | Super-weather-resistance wear-resistant finish paint for offshore wind power blades and preparation method thereof |
| CN105062337A (en) * | 2015-07-23 | 2015-11-18 | 安吉祺隆新型建材有限公司 | Resin coating and preparation method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3674076B2 (en) * | 1995-03-22 | 2005-07-20 | 大日本インキ化学工業株式会社 | Resin composition, civil engineering and building materials and covering materials |
| GB0411842D0 (en) * | 2004-05-27 | 2004-06-30 | Ici Plc | Colour changing coating composition |
-
2017
- 2017-11-07 CN CN201711086613.1A patent/CN108659710B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1869184A (en) * | 2006-04-13 | 2006-11-29 | 上海中科合臣股份有限公司 | Preparation method of plant oil polyalcohol |
| CN102408768A (en) * | 2011-11-24 | 2012-04-11 | 中国海洋石油总公司 | Solvent-free two-component polyurethane putty for rotor wing |
| CN103421420A (en) * | 2013-07-17 | 2013-12-04 | 中国石油天然气集团公司 | Dissolvent-free polyurethane weather-proof anticorrosive coating for storage tank |
| CN105062337A (en) * | 2015-07-23 | 2015-11-18 | 安吉祺隆新型建材有限公司 | Resin coating and preparation method |
| CN105017880A (en) * | 2015-07-29 | 2015-11-04 | 洛阳双瑞防腐工程技术有限公司 | Super-weather-resistance wear-resistant finish paint for offshore wind power blades and preparation method thereof |
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| Publication number | Publication date |
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| CN108659710A (en) | 2018-10-16 |
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