CN108658368A - The processing method of leather waste water - Google Patents

The processing method of leather waste water Download PDF

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Publication number
CN108658368A
CN108658368A CN201810348211.2A CN201810348211A CN108658368A CN 108658368 A CN108658368 A CN 108658368A CN 201810348211 A CN201810348211 A CN 201810348211A CN 108658368 A CN108658368 A CN 108658368A
Authority
CN
China
Prior art keywords
waste water
pond
processing method
leather waste
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810348211.2A
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Chinese (zh)
Inventor
李家毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Haining Jiuzhou Furniture Co Ltd
Original Assignee
Haining Jiuzhou Furniture Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haining Jiuzhou Furniture Co Ltd filed Critical Haining Jiuzhou Furniture Co Ltd
Priority to CN201810348211.2A priority Critical patent/CN108658368A/en
Publication of CN108658368A publication Critical patent/CN108658368A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • C02F2103/24Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof from tanneries
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The present invention discloses the processing method of leather waste water, and using coagulating treatment as pre-treatment, in conjunction with biochemical treatment, treated, and waste water reaches emission request;It is followed successively by filtering ponds, coagulating treatment pond, flotation tank, transition pond, anaerobism aeration tank, intermediate sedimentation pond, oxidation pond, sedimentation basin;Present invention process flow is simple, small investment, and a large amount of COD and SS cannot be precipitated while removing chromium.

Description

The processing method of leather waste water
Technical field
The present invention relates to the processing methods of a kind of wastewater treatment method more particularly to leather waste water.
Background technology
China is leather industry big country, and leather industry is also faced with the serious restriction of resource and ecological environment, leather row Industry plays an important role in China's economic development, produces a large amount of waste water accordingly, and discharge capacity is up to 7 × 107t/a.Its Middle Chrome Tanning Liquor toxicity is very high, and Cr concentration reaches 3000mg/L~6000mg/L;Also contain certain density Cr in comprehensive wastewater;This There is a large amount of SS and COD outside.And these wastewater flow rates only have about 30% qualified discharge, seriously pollute environment, endanger health of people. A low major reason of leather waste water improvement rate is its pollutional load height, complicated component, is difficult to handle, most of process hides factory rules and regulations Mould is small, administers waste water and has any problem in economy, technology.Therefore, developing the leather waste water being simple and efficient and administering has greatly Realistic meaning.
Invention content
Based on the above issues, the purpose of the present invention is to provide the processing methods of leather waste water, are handled based on conventional sewage Technique add suitable preparation for the particularity of leather waste water, technological process is simple, and high treating effect, reaches discharge Standard;Technical solution is as follows:
The processing method of leather waste water of the present invention, using coagulating treatment as pre-treatment, in conjunction with biochemical treatment, after processing Waste water reach emission request;It is followed successively by filtering ponds, coagulating treatment pond, flotation tank, transition pond, anaerobism aeration tank, intermediate sedimentation Pond, oxidation pond, sedimentation basin;Wherein,
In coagulating treatment pond, Organic Matter Coagulation agent and inorganic matter coagulant are added;Organic matter selection PAM, molecular weight 900 × 104-1200×104, inorganic matter selection Al2(SO4)3
In flotation tank, aluminium chloride and FeSO are added4
In anaerobism aeration tank, hydraulic retention 4 hours,
In oxidation pond, hydraulic retention 8 hours.
PAM dosages are 40mg/L.
Al2(SO4)3, dosage 1000mg/L.
The dosage of aluminium chloride is 100-200mg/L.
FeSO4Dosage be 300-500mg/L.
The processing method of leather waste water of the present invention, first passes through filter tank, removes big suspended matter, enters coagulating treatment pond afterwards, Dosing coagulant is organic and inorganic combination, and organic matter selects PAM, molecular weight 900 × 104-1200×104, inorganic matter selection Al2(SO4)3, coloration removes substantially, and the removal rate of chromium ion is dirty up to 92%, SS removal rates up to 71%, COD removal rates nearly 40% Mud sedimentation is fast, and resultant effect is good;Alkaline cleaning is carried out again, while being added in acid FeSO4, further go to oil removal and portion While dividing COD, the pH value of waste water also declines therewith, plays neutralization, catchments through transition pond, is promoted to anaerobism aeration Pond is stopped 4 hours, is separated by solid-liquid separation through intermediate sedimentation pond after aerating wastewater, supernatant using activated sludge process and boring aeration Liquid stream enters oxidation pond, is most discharged afterwards through sedimentation basin.
Description of the drawings
Fig. 1 is the process flow schematic diagram of leather waste water of the present invention.
Specific implementation mode
Technical scheme of the present invention described in detail below.The embodiment of the present invention is only for illustrating concrete structure, the rule of the structure Mould should not be limited by the examples.
As shown in Figure 1, the processing method of leather waste water of the present invention, using coagulating treatment as pre-treatment, in conjunction with biochemistry Processing, treated, and waste water reaches emission request;It is followed successively by filtering ponds 1, coagulating treatment pond 2, flotation tank 3, transition pond 4, anaerobism Aeration tank 5, centre 6, oxidation pond 7, sedimentation basin 8;
In coagulating treatment pond 2, Organic Matter Coagulation agent and inorganic matter coagulant are added;Organic matter selects PAM, molecular weight 900 ×104-1200×104, inorganic matter selection Al2(SO4)3;PAM dosages are 40mg/L, Al2(SO4)3, dosage 1000mg/L;
In flotation tank 3, aluminium chloride and FeSO are added4;The dosage of aluminium chloride is 100-200mg/L, FeSO4's Dosage is 300-500mg/L;
In anaerobism aeration tank, hydraulic retention 4 hours, in oxidation pond, hydraulic retention 8 hours.
The leather waste water of workshop discharge after removing big suspended matter through filtering ponds 1, into coagulating treatment pond 2, adds PAM And Al2(SO4)3, remove S and Cr and discoloration;Waste water is lifted into flotation tank 3 through pump, adds aluminium chloride and FeSO4, into One step removes oil removal and part COD;After transition pond 4 is catchmented, is promoted and arrive anaerobic pond 5, hydraulic retention 4 hours, aerating wastewater It is separated by solid-liquid separation by intermediate sedimentation pond 6, for supernatant from oxidation pond 7 is flowed into, hydraulic retention 8 hours is most solid through sedimentation basin 8 afterwards After liquid separation, discharged wastewater met the national standard.

Claims (5)

1. the processing method of leather waste water, which is characterized in that using coagulating treatment as pre-treatment, in conjunction with biochemical treatment, place Waste water after reason reaches emission request;It is followed successively by filtering ponds, coagulating treatment pond, flotation tank, transition pond, anaerobism aeration tank, centre Sedimentation basin, oxidation pond, sedimentation basin;Wherein,
In coagulating treatment pond, Organic Matter Coagulation agent and inorganic matter coagulant are added;Organic matter selects PAM, 900 × 104- of molecular weight 1200 × 104, inorganic matter selects Al2 (SO4) 3;
In flotation tank, aluminium chloride and FeSO4 are added;
In anaerobism aeration tank, hydraulic retention 4 hours,
In oxidation pond, hydraulic retention 8 hours.
2. the processing method of leather waste water according to claim 1, it is characterised in that the PAM dosages are 40mg/L.
3. the processing method of leather waste water according to claim 1, it is characterised in that the Al2 (SO4) 3, dosage are 1000mg/L。
4. the processing method of leather waste water according to claim 1, it is characterised in that the dosage of the aluminium chloride is 100-200mg/L。
5. the processing method of leather waste water according to claim 1, it is characterised in that the dosage of the FeSO4 is 300- 500mg/L。
CN201810348211.2A 2018-06-14 2018-06-14 The processing method of leather waste water Pending CN108658368A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810348211.2A CN108658368A (en) 2018-06-14 2018-06-14 The processing method of leather waste water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810348211.2A CN108658368A (en) 2018-06-14 2018-06-14 The processing method of leather waste water

Publications (1)

Publication Number Publication Date
CN108658368A true CN108658368A (en) 2018-10-16

Family

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Family Applications (1)

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CN201810348211.2A Pending CN108658368A (en) 2018-06-14 2018-06-14 The processing method of leather waste water

Country Status (1)

Country Link
CN (1) CN108658368A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110902957A (en) * 2019-12-06 2020-03-24 山东海景天环保科技股份公司 Method for realizing synchronous desulfurization and denitrification of leather wastewater by using sulfur autotrophic denitrification process
CN111153528A (en) * 2020-01-22 2020-05-15 江苏鼎弘环境科技有限公司 Method for treating chromium-containing wastewater in leather production

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105731716A (en) * 2014-12-06 2016-07-06 哈尔滨金大环境工程有限公司 Starch waste water treatment apparatus and method
CN106242189A (en) * 2016-08-30 2016-12-21 安徽银河皮革有限公司 A kind of process hides Water Sproading Biochemical method technique
CN206720972U (en) * 2017-03-20 2017-12-08 天津黛青生物科技有限公司 A kind of medicine adornment wastewater treatment integrated apparatus
CN108033654A (en) * 2018-01-23 2018-05-15 中信环境技术(广州)有限公司 A kind of embrane method printing waste water processing system and method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105731716A (en) * 2014-12-06 2016-07-06 哈尔滨金大环境工程有限公司 Starch waste water treatment apparatus and method
CN106242189A (en) * 2016-08-30 2016-12-21 安徽银河皮革有限公司 A kind of process hides Water Sproading Biochemical method technique
CN206720972U (en) * 2017-03-20 2017-12-08 天津黛青生物科技有限公司 A kind of medicine adornment wastewater treatment integrated apparatus
CN108033654A (en) * 2018-01-23 2018-05-15 中信环境技术(广州)有限公司 A kind of embrane method printing waste water processing system and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110902957A (en) * 2019-12-06 2020-03-24 山东海景天环保科技股份公司 Method for realizing synchronous desulfurization and denitrification of leather wastewater by using sulfur autotrophic denitrification process
CN111153528A (en) * 2020-01-22 2020-05-15 江苏鼎弘环境科技有限公司 Method for treating chromium-containing wastewater in leather production

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Application publication date: 20181016

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