CN108646496A - A kind of the electrochromism doubling glass and hollow glass of splicing - Google Patents

A kind of the electrochromism doubling glass and hollow glass of splicing Download PDF

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Publication number
CN108646496A
CN108646496A CN201810786695.9A CN201810786695A CN108646496A CN 108646496 A CN108646496 A CN 108646496A CN 201810786695 A CN201810786695 A CN 201810786695A CN 108646496 A CN108646496 A CN 108646496A
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CN
China
Prior art keywords
glass
photo chromic
glass substrate
electrochromism
doubling
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Pending
Application number
CN201810786695.9A
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Chinese (zh)
Inventor
刘钧
米赛
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Hefei Wei Chi Technology Co Ltd
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Hefei Wei Chi Technology Co Ltd
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Publication date
Application filed by Hefei Wei Chi Technology Co Ltd filed Critical Hefei Wei Chi Technology Co Ltd
Priority to CN201810786695.9A priority Critical patent/CN108646496A/en
Publication of CN108646496A publication Critical patent/CN108646496A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect

Abstract

The present invention provides a kind of the electrochromism doubling glass and hollow glass of splicing, including doubling glass substrate, film layers and the photo chromic glass component being sequentially stacked, wherein electrochromism film plating layer is provided on the front or the back side of photo chromic glass component, the photo chromic glass component includes that single-row multiple rows of or multiple row is multiple rows of, and the photo chromic glass substrate that gap separates, the whole or edges at two ends in the gap between adjacent photo chromic glass substrate are filled partially with joint filling sealant.The present invention realizes the electroluminescent doubling glass of large scale by splicing, non-discolouring region between the photo chromic glass of adjacent two pieces of splicings is minimum to be controlled within 6mm, and appearance looks elegant, air-tightness is good, it can be changed colour with subregion, meet in the market the needs of to large scale full-solid electrochromic glass.

Description

A kind of the electrochromism doubling glass and hollow glass of splicing
Technical field
The present invention relates to electrochomeric glass technical fields, and in particular to a kind of sliceable electrochromism doubling glass, And the hollow glass using the electrochromism doubling glass.
Background technology
Electrochromism refers to material under the action of outer making alive, and with material doping and dedoping occurs for charged ion, leads to material Redox reaction occurs for material, and then showing for reversible change occurs in visible light IR absorbing area for the optical property of material As.The variation for showing as color and transparency of its macroscopic view.The electrochomeric glass prepared using the performance can be to sunlight Radiation carries out intelligent adjusting, optionally absorbs or reflect extraneous heat radiation, reduces the energy consumption of building, and solve increasingly Serious light pollution in cities problem represents current state-of-the-art building energy conservation glass technology.
At present building field enter volume production application electrochomeric glass be mainly based upon tungstic acid as off-color material All solid state inorganic electrochromic glass.The mode of production of inorganic electrochromic original sheet glass is to use magnetic on the glass substrate Control sputtering technology plates complex functional layer.Complex functional layer includes ion barrier, the first conductive layer, EC heaps successively from top to bottom Lamination, the second conductive layer;When applying voltage to EC stack layers by the first and second conductive layers, complex functional layer may be implemented Variation between transparent state and coloured state shows as electrochomeric glass and realizes discoloration.
Full-solid electrochromic glass uses vacuum magnetic-control sputtering technology, due to being limited by frame substrate and plated film cavity System, the size of photo chromic glass are limited.Once the size of door and window or curtain wall is more than photo chromic glass substrate itself, the insufficient of size will The application of serious limitation electrochomeric glass.
Invention content
The present invention provides a kind of large-sized electrochromism doubling glass of splicing, can solve electrochomeric glass substrate The restricted problem of size.
In order to solve the above technical problems, the present invention adopts the following technical scheme that:
A kind of electrochromism doubling glass of splicing, including the doubling glass substrate, film layers and the photo chromic glass that are sequentially stacked Component is wherein provided with electrochromism film plating layer, which is characterized in that the discoloration glass on the front or the back side of photo chromic glass component Glass component includes the photo chromic glass substrate that single-row multiple rows of and gap separates, the whole in the gap between adjacent photo chromic glass substrate or Person's edges at two ends is filled partially with joint filling sealant.
A kind of electrochromism doubling glass of splicing, including the doubling glass substrate, film layers and the discoloration that are sequentially stacked Glass assembly is wherein provided with electrochromism film plating layer, which is characterized in that the change on the front or the back side of photo chromic glass component Color glass assembly includes the photo chromic glass substrate that multiple row is multiple rows of and gap separates, the gap between adjacent photo chromic glass substrate it is complete Portion or edges at two ends are filled partially with joint filling sealant.
A kind of hollow glass, including above-mentioned electrochromism doubling glass and it is hollow use glass substrate, this is hollow to use glass Hollow cavity is formed by spacer bar between glass substrate and electrochromism doubling glass, one end of the spacer bar is arranged in photo chromic glass In the laser clear side area of component, the joint filling sealant in the gap runs through the width overlay area of spacer bar.
By above technical scheme it is found that the present invention realizes the electroluminescent doubling glass of large scale, adjacent two pieces of splicings by splicing Photo chromic glass between non-discolouring region it is minimum can control within 6mm, appearance looks elegant, air-tightness is good, can be with subregion Discoloration, meets in the market the needs of to large scale full-solid electrochromic glass.
Description of the drawings
Fig. 1 is the structural schematic diagram of electrochromism doubling glass embodiment 1 of the present invention;
Fig. 2 is the structural schematic diagram of electrochromism doubling glass embodiment 2 of the present invention;
Fig. 3 is the vertical view of the single-row multiple rows of photo chromic glass substrate of the present invention;
Fig. 4 is the vertical view of the multiple rows of photo chromic glass substrate of multiple row of the present invention;
Fig. 5 is the structural schematic diagram of hollow glass of the present invention;
Arrangement of the spacer bar of Fig. 6 hollow glasses of the present invention on single-row multiple rows of photo chromic glass substrate;
Arrangement of the spacer bar of Fig. 7 hollow glasses of the present invention on the multiple rows of photo chromic glass substrate of multiple row.
Specific implementation mode
A kind of preferred embodiment of the present invention is described in detail below in conjunction with the accompanying drawings.
As shown in Figure 1, the electrochromism doubling glass 10 includes the doubling glass substrate 11 being sequentially stacked, film layers 12 and photo chromic glass component 13, it wherein is provided with electrochromism film plating layer 14 on photo chromic glass component, the electrochromism film plating layer It is ion barrier, the first conductive layer, EC stack layers and the second conductive layer successively from the bottom up, it can be on the second conductive layer Layer protective layer is set.
The electrochromism film plating layer 14 can be contacted with film layers 12, can also be photo chromic glass component referring to Fig.1 Non- coated surface is contacted by film layers with doubling glass substrate 11, with reference to Fig. 2.
The present invention meets large scale full-solid electrochromic glass by the way that multiple photo chromic glass substrates are bolted together Demand.A kind of mode is the photo chromic glass substrate 15 that photo chromic glass component 13 is separated using single-row multiple rows of and gap, each row's packet At least two photo chromic glass substrates are included, as shown in figure 3, splicing using single-row three photo chromic glass substrates.Another way is to become The photo chromic glass substrate 15 that color glass assembly 13 uses multiple row multiple rows of and gap separates, each each row of row include at least two Photo chromic glass substrate, as shown in figure 4, using the two rows of photo chromic glass substrate splicings of two row.
In order to improve the stability of splicing, the gap 16 between adjacent photo chromic glass substrate 15 is filled with joint filling sealant 17, gap-filling adhesive can be PVB, EVA, OCA, PU, PO, epoxy glue, butyl rubber, silicone adhesive, TR sealant, polyurethane, commercially available Any one of silicone adhesive agent.Gap-filling adhesive should have good water vapor rejection performance, preferably butyl rubber and ring Oxygen glue.
Piece of the gap 16 between adjacent photo chromic glass substrate, the both sides up and down of piece, i.e., adjacent two pieces electroluminescent The adjacent both sides keeping parallelism of photo chromic glass.The width of piece is 0.5 ~ 10mm, preferably 0.5 ~ 2mm.
Gap can be stuffed entirely with by the joint filling sealant 17, can also be filled only with the edges at two ends part in gap.
The difference in level of the joint filling sealant 17 and photo chromic glass substrate 15 is -1~2mm, i.e. gap-filling adhesive Height should with the thickness of photo chromic glass substrate essentially identical or slightly larger than photo chromic glass substrate thickness.
Size of the doubling with glass substrate 11 in in-plane is more than photo chromic glass substrate 15, the ruler of in-plane Very little difference is formed with side slot 18 on the periphery of doubling glass substrate, four while while well width it is essentially identical, the width of side slot is 1 ~ 10mm, preferably 2 ~ 5mm.The corresponding photo chromic glass length of side of side ratio on every one side of doubling glass and the summation in gap are big by 2 ~ 20mm, preferably 2 ~ 10mm.
The photo chromic glass substrate 15 has laser clear side area 19, the region close to the position of doubling glass substrate edge Interior composite film is removed by laser so that photo chromic glass substrate is exposed, the exposed glass substrate in laser clear side area the later stage with When spacer bar or film layers contact, there is better adhesion strength and water vapor seal effect than the glass with film plating layer.Swash The width in light clear side area is 5 ~ 20mm, preferably 5 ~ 15mm.In order to keep relatively narrow non-discolouring region, optionally, piece both sides Electrochomeric glass film plating layer can be without laser clear side.
Above-mentioned each piece of photo chromic glass substrate can connect individual controller, can also share a controller, wherein Separate controller can realize that subregion changes colour.
Electrochromism doubling glass of the present invention can be further processed into hollow or vacuum glass, with reference to Fig. 5, in described Empty glass includes doubling glass substrate 11, film layers 12 and the photo chromic glass component 13 being sequentially stacked and hollow uses glass Substrate 20, this is hollow to be formed with hollow cavity 40 between glass substrate and electrochromism doubling glass by spacer bar 30.
Fig. 6 and 7 respectively illustrates single-row multiple rows of photo chromic glass substrate, spacer bar 30 on the multiple rows of photo chromic glass substrate of multiple row One end of arrangement, the spacer bar is arranged in the laser clear side area 19 of photo chromic glass component, and the joint filling in the gap is close Seal the width overlay area that agent runs through spacer bar.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention It encloses and is defined, under the premise of not departing from design spirit of the present invention, technical side of the those of ordinary skill in the art to the present invention The various modifications and improvement that case is made are each fallen in the protection domain of claims of the present invention determination.

Claims (9)

1. a kind of electrochromism doubling glass of splicing, including the doubling glass substrate, film layers and the discoloration glass that are sequentially stacked Glass component is wherein provided with electrochromism film plating layer, which is characterized in that the discoloration on the front or the back side of photo chromic glass component Glass assembly includes the photo chromic glass substrate that single-row multiple rows of and gap separates, the whole in the gap between adjacent photo chromic glass substrate Or both ends are filled with joint filling sealant.
2. a kind of electrochromism doubling glass of splicing, including the doubling glass substrate, film layers and the discoloration glass that are sequentially stacked Glass component is wherein provided with electrochromism film plating layer, which is characterized in that the discoloration on the front or the back side of photo chromic glass component Glass assembly includes the photo chromic glass substrate that multiple row is multiple rows of and gap separates, the whole in the gap between adjacent photo chromic glass substrate Or both ends are filled with joint filling sealant.
3. electrochromism doubling glass according to claim 1 or 2, which is characterized in that the joint filling sealant and discoloration The difference in level of glass substrate is -1~2mm.
4. electrochromism doubling glass according to claim 1 or 2, which is characterized in that the joint filling sealant used Material is any one of PVB, EVA, OCA, PU, PO, epoxy glue, butyl rubber, silicone adhesive, TR sealant, silica gel, polyurethane.
5. electrochromism doubling glass according to claim 1 or 2, which is characterized in that the doubling glass substrate exists The size of in-plane is more than photo chromic glass component, and the size difference of in-plane is formed on the periphery of doubling glass substrate Side slot.
6. electrochromism doubling glass according to claim 5, which is characterized in that the width of the side slot is 1 ~ 10mm.
7. electrochromism doubling glass according to claim 1 or 2, which is characterized in that the photo chromic glass component is close The region of doubling glass substrate edge is formed with laser clear side area, and the width in the laser clear side area is 5~20mm.
8. electrochromism doubling glass according to claim 1 or 2, which is characterized in that each piece of photo chromic glass substrate connects It connects individual controller or shares a controller.
9. a kind of hollow glass, which is characterized in that including using the electrochromism doubling glass described in claims 1 or 22, and Hollow to use glass substrate, which forms hollow cavity between glass substrate and electrochromism doubling glass by spacer bar, should One end of spacer bar is arranged in the laser clear side area of photo chromic glass component, and the joint filling sealant in the gap runs through spacer bar Width overlay area.
CN201810786695.9A 2018-07-17 2018-07-17 A kind of the electrochromism doubling glass and hollow glass of splicing Pending CN108646496A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109521620A (en) * 2018-11-01 2019-03-26 贾英新 A kind of smart home glass
CN110307490A (en) * 2019-06-20 2019-10-08 中节能晶和照明有限公司 A kind of LED tunnel lamp of adjustable color
CN112812692A (en) * 2020-12-31 2021-05-18 天津南玻节能玻璃有限公司 Laminated glass film splicing liquid
CN114985955A (en) * 2022-08-03 2022-09-02 苏州光昛智能科技有限公司 Double-scribing laser edge cleaning process

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CN201319102Y (en) * 2008-11-24 2009-09-30 上海挽鞑实业发展有限公司 Electrochromic glass device
JP2010224240A (en) * 2009-03-24 2010-10-07 Kuraray Co Ltd Electrochromic display element and method for manufacturing the same
US20110148218A1 (en) * 2009-12-22 2011-06-23 Soladigm, Inc. Wireless powered electrochromic windows
CN102922823A (en) * 2012-10-23 2013-02-13 朱杨 Electrical allochroic shading glass
CN104808412A (en) * 2015-05-19 2015-07-29 肥西县三星玻璃有限公司 Hollow glass and electrochromic glass thereof
CN105467711A (en) * 2015-12-18 2016-04-06 杭州福斯特光伏材料股份有限公司 All-solid-state electrochromic device having controllable color-changing area and method for preparing same
WO2017112685A1 (en) * 2015-12-21 2017-06-29 View, Inc. Obscuring bus bars in electrochromic glass structures
CN206960832U (en) * 2017-05-24 2018-02-02 合肥威迪变色玻璃有限公司 A kind of electrochromism vacuum glass component
CN208459740U (en) * 2018-07-17 2019-02-01 合肥威驰科技有限公司 A kind of the electrochromism doubling glass and hollow glass of splicing

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201319102Y (en) * 2008-11-24 2009-09-30 上海挽鞑实业发展有限公司 Electrochromic glass device
JP2010224240A (en) * 2009-03-24 2010-10-07 Kuraray Co Ltd Electrochromic display element and method for manufacturing the same
US20110148218A1 (en) * 2009-12-22 2011-06-23 Soladigm, Inc. Wireless powered electrochromic windows
CN102922823A (en) * 2012-10-23 2013-02-13 朱杨 Electrical allochroic shading glass
CN104808412A (en) * 2015-05-19 2015-07-29 肥西县三星玻璃有限公司 Hollow glass and electrochromic glass thereof
CN105467711A (en) * 2015-12-18 2016-04-06 杭州福斯特光伏材料股份有限公司 All-solid-state electrochromic device having controllable color-changing area and method for preparing same
WO2017112685A1 (en) * 2015-12-21 2017-06-29 View, Inc. Obscuring bus bars in electrochromic glass structures
CN206960832U (en) * 2017-05-24 2018-02-02 合肥威迪变色玻璃有限公司 A kind of electrochromism vacuum glass component
CN208459740U (en) * 2018-07-17 2019-02-01 合肥威驰科技有限公司 A kind of the electrochromism doubling glass and hollow glass of splicing

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109521620A (en) * 2018-11-01 2019-03-26 贾英新 A kind of smart home glass
CN110307490A (en) * 2019-06-20 2019-10-08 中节能晶和照明有限公司 A kind of LED tunnel lamp of adjustable color
CN112812692A (en) * 2020-12-31 2021-05-18 天津南玻节能玻璃有限公司 Laminated glass film splicing liquid
CN114985955A (en) * 2022-08-03 2022-09-02 苏州光昛智能科技有限公司 Double-scribing laser edge cleaning process

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