CN108641400A - A kind of no metal carbon fiber recombination line clutch surface and preparation method thereof - Google Patents
A kind of no metal carbon fiber recombination line clutch surface and preparation method thereof Download PDFInfo
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- CN108641400A CN108641400A CN201810442514.0A CN201810442514A CN108641400A CN 108641400 A CN108641400 A CN 108641400A CN 201810442514 A CN201810442514 A CN 201810442514A CN 108641400 A CN108641400 A CN 108641400A
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- fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D13/00—Friction clutches
- F16D13/58—Details
- F16D13/60—Clutching elements
- F16D13/64—Clutch-plates; Clutch-lamellae
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Operated Clutches (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Include the Compound Fabric made of the braiding of high-strength complex zygonema and the coating for being uniformly impregnated within its surface the invention discloses a kind of no metal carbon fiber recombination line clutch surface, the raw material of the high-strength complex zygonema is as follows by weight：15~20 parts of 55~60 parts of thermoplastic resin, 3~5 parts of Boron Trifluoride Ethylamine, 1~3 part of antioxidant, 15~20 parts of carbon fiber, 15~20 parts of basalt fibre, 15~20 parts of polyacrylonitrile fibre and pyroceram fibre, 1~4 part of AG80 epoxy resin；A kind of no metal carbon fiber recombination line clutch surface provided by the invention, intensity is high, and high-strength complex zygonema intensity is twice of metal wire；Clutch surface high temperature resistance is excellent, and friction coefficient is relatively low without being substantially reduced and wearing away under hot conditions.Recombination line and Compound Fabric ensure that its internal structure is stablized, and are conducive to the usage safety performance and stability that improve dough sheet assembly, extend its service life.
Description
Technical field
The invention belongs to clutch surface technical fields, and more specifically more particularly to a kind of no metal carbon fiber is compound
Line clutch surface.
Background technology
With the continuous development of Domestic Automotive Industry, requirement of the Automobile Enterprises to car clutch sheet is also higher and higher；
The clutch disc quality produced is undoubtedly poor；Its heat-resisting quantity is poor, and internal structure is unstable, and structure is slightly inadequate,
If serious, then the performance of automobile is will have a direct impact on.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of no metal carbon fiber proposed is multiple
Zygonema clutch surface and preparation method thereof.
To achieve the above object, the present invention provides the following technical solutions：A kind of no metal carbon fiber recombination line clutch surface
Piece includes Compound Fabric made of being woven by high-strength complex zygonema and is uniformly impregnated within the coating on its surface, the high-strength composite
The raw material of line is as follows by weight：55~60 parts of thermoplastic resin, 3~5 parts of Boron Trifluoride Ethylamine, 1~3 part of antioxidant,
15~20 parts of carbon fiber, 15~20 parts of basalt fibre, 15~20 parts of polyacrylonitrile fibre and pyroceram fibre 15~20
Part, 1~4 part of AG80 epoxy resin；
The high-strength complex zygonema is by basalt fibre line, polyacrylonitrile fibre line, pyroceram fibre line and carbon fiber line
It is twisted；
The raw material of the coating is as follows by weight：30~40 parts of phenol-formaldehyde resin modified；2-3 parts of beryllium-bronze powder；Nanometer titanium dioxide
15-25 parts of silicon；1.0~1.6 parts of antioxidant；1~2 part of magnesium stearate；1.0~1.3 parts of tricresyl phosphate；8~10 parts of graphite；
6~8 parts of aluminium oxide；3~5 parts of titanium dioxide；35~50 parts of dimethylbenzene；2~4 parts of vulcanizing agent.
The preparation method of the phenol-formaldehyde resin modified is：By 65 parts of phenolic resin and 10 parts of addition batch mixers of calcium dihydrogen phosphate
In, it is mixed 40 minutes in 50 DEG C, adds 4 parts of 7 parts of m-xylene diamine and hydroxypropyl acrylate, be warming up to 90 DEG C and mix 40 points
Clock, cooling to obtain the final product.
The making step of the high-strength complex zygonema is：
A, thermoplastic resin, Boron Trifluoride Ethylamine, antioxidant and AG80 epoxy resin mix 2 in high-speed kneading machine~
4min is until uniform；
B, loading hopper that the raw material mixed in step a is then put into double screw extruder, carbon fiber, basalt is fine
Dimension, polyacrylonitrile fibre and pyroceram fibre are added to by side feeding in extruder respectively, through melting extrusion, Cast Strip,
Drawing-off, then carbon fiber, basalt fibre, polyacrylonitrile fibre and pyroceram fibre carry out 10~15 one by treated
Being twisted for group, respectively obtains carbon fiber line, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line；
C, the carbon fiber line obtained in step b, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line are twisted
Synthesizing high-strength recombination line.
The Compound Fabric making step is：
D, high-strength complex zygonema carries out being woven into bulk, then dip-coatings, enters back into curing mold solidification；
E, by the blocky high-strength complex zygonema braided fabric after solidification hot pressing temperature be 140~160 DEG C, hot pressing pressure be 14~
It is hot-forming under conditions of 16Mpa, the molding drilling of positioning hole is carried out during hot-forming, and Compound Fabric is made.
The technique effect and advantage of the present invention：A kind of no metal carbon fiber recombination line clutch surface provided by the invention,
Intensity is high, and high-strength complex zygonema intensity is twice of metal wire；Clutch surface high temperature resistance is excellent, rubs under hot conditions
Coefficient is relatively low without being substantially reduced and wearing away.Recombination line and Compound Fabric ensure that its internal structure is stablized, and are conducive to improve dough sheet assembly
Usage safety performance and stability, extend its service life；High-strength composite linear expansion coefficient is small, light weight, and corrosion-resistant,
Service life is long, preferably resolves the problem of aging of long-time service.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.Based on the embodiments of the present invention, those of ordinary skill in the art are not before making creative work
The every other embodiment obtained is put, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of no metal carbon fiber recombination line clutch surface, including by high-strength complex zygonema weave made of Compound Fabric and uniformly
It is immersed in the coating on its surface, the raw material of the high-strength complex zygonema is as follows by weight：55 parts of thermoplastic resin, boron trifluoride
3 parts of mono aminoethane, 1 part of antioxidant, 15 parts of carbon fiber, 15 parts of basalt fibre, 15 parts of polyacrylonitrile fibre and refractory ceramics
15 parts of fiber, 2 parts of AG80 epoxy resin；
The high-strength complex zygonema is by basalt fibre line, polyacrylonitrile fibre line, pyroceram fibre line and carbon fiber line
It is twisted；
The raw material of the coating is as follows by weight：30 parts of phenol-formaldehyde resin modified；2 parts of beryllium-bronze powder；15 parts of nano silicon dioxide；
1.0 parts of antioxidant；1 part of magnesium stearate；1.0 parts of tricresyl phosphate；10 parts of graphite；8 parts of aluminium oxide；5 parts of titanium dioxide；Diformazan
50 parts of benzene；2 parts of vulcanizing agent.
The preparation method of the phenol-formaldehyde resin modified is：By 65 parts of phenolic resin and 10 parts of addition batch mixers of calcium dihydrogen phosphate
In, it is mixed 40 minutes in 50 DEG C, adds 4 parts of 7 parts of m-xylene diamine and hydroxypropyl acrylate, be warming up to 90 DEG C and mix 40 points
Clock, cooling to obtain the final product.
The making step of the high-strength complex zygonema is：
A, thermoplastic resin, Boron Trifluoride Ethylamine, antioxidant and AG80 epoxy resin mix 4min in high-speed kneading machine
Until uniform；
B, loading hopper that the raw material mixed in step a is then put into double screw extruder, carbon fiber, basalt is fine
Dimension, polyacrylonitrile fibre and pyroceram fibre are added to by side feeding in extruder respectively, through melting extrusion, Cast Strip,
Drawing-off, then carbon fiber, basalt fibre, polyacrylonitrile fibre and pyroceram fibre carry out 10 one group by treated
It is twisted, respectively obtain carbon fiber line, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line；
C, the carbon fiber line obtained in step b, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line are twisted
Synthesizing high-strength recombination line.
The Compound Fabric making step is：
D, high-strength complex zygonema carries out being woven into bulk, then dip-coatings, enters back into curing mold solidification；
E, by the blocky high-strength complex zygonema braided fabric after solidification in the condition that hot pressing temperature is 140 DEG C, hot pressing pressure is 14Mpa
Under it is hot-forming, the molding drilling of positioning hole is carried out during hot-forming, Compound Fabric is made.
Clutch surface is made after carrying out vulcanization heat treatment, corase grinding processing, spot-facing, fine grinding, marking packaging to Compound Fabric
Piece finished product.
Embodiment 2
A kind of no metal carbon fiber recombination line clutch surface, including by high-strength complex zygonema weave made of Compound Fabric and uniformly
It is immersed in the coating on its surface, the raw material of the high-strength complex zygonema is as follows by weight：60 parts of thermoplastic resin, boron trifluoride
5 parts of mono aminoethane, 3 parts of antioxidant, 20 parts of carbon fiber, 20 parts of basalt fibre, 20 parts of polyacrylonitrile fibre and refractory ceramics
20 parts of fiber, 3 parts of AG80 epoxy resin；
The high-strength complex zygonema is by basalt fibre line, polyacrylonitrile fibre line, pyroceram fibre line and carbon fiber line
It is twisted；
The raw material of the coating is as follows by weight：40 parts of phenol-formaldehyde resin modified；3 parts of beryllium-bronze powder；25 parts of nano silicon dioxide；
1.6 parts of antioxidant；2 parts of magnesium stearate；1.3 parts of tricresyl phosphate；8 parts of graphite；8 parts of aluminium oxide；5 parts of titanium dioxide；Diformazan
35 parts of benzene；2 parts of vulcanizing agent.
The preparation method of the phenol-formaldehyde resin modified is：By 65 parts of phenolic resin and 10 parts of addition batch mixers of calcium dihydrogen phosphate
In, it is mixed 40 minutes in 50 DEG C, adds 4 parts of 7 parts of m-xylene diamine and hydroxypropyl acrylate, be warming up to 90 DEG C and mix 40 points
Clock, cooling to obtain the final product.
The making step of the high-strength complex zygonema is：
A, thermoplastic resin, Boron Trifluoride Ethylamine, antioxidant and AG80 epoxy resin mix 2min in high-speed kneading machine
Until uniform；
B, loading hopper that the raw material mixed in step a is then put into double screw extruder, carbon fiber, basalt is fine
Dimension, polyacrylonitrile fibre and pyroceram fibre are added to by side feeding in extruder respectively, through melting extrusion, Cast Strip,
Drawing-off, then carbon fiber, basalt fibre, polyacrylonitrile fibre and pyroceram fibre carry out 15 one group by treated
It is twisted, respectively obtain carbon fiber line, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line；
C, the carbon fiber line obtained in step b, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line are twisted
Synthesizing high-strength recombination line.
The Compound Fabric making step is：
D, high-strength complex zygonema carries out being woven into bulk, then dip-coatings, enters back into curing mold solidification；
E, by the blocky high-strength complex zygonema braided fabric after solidification in the condition that hot pressing temperature is 160 DEG C, hot pressing pressure is 16Mpa
Under it is hot-forming, the molding drilling of positioning hole is carried out during hot-forming, Compound Fabric is made.
In summary：A kind of no metal carbon fiber recombination line clutch surface provided by the invention, intensity is high, high-strength complex
Zygonema intensity is twice of metal wire；Clutch surface high temperature resistance is excellent, and friction coefficient is without being substantially reduced under hot conditions
And abrasion are relatively low.Recombination line and Compound Fabric ensure that its internal structure is stablized, and are conducive to the usage safety performance for improving dough sheet assembly
And stability, extend its service life；High-strength composite linear expansion coefficient is small, light weight, and corrosion-resistant, and service life is long, compared with
The good problem of aging for solving long-time service.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (4)
1. a kind of no metal carbon fiber recombination line clutch surface, including Compound Fabric made of being woven by high-strength complex zygonema and
The even coating for being immersed in its surface, it is characterised in that：The raw material of the high-strength complex zygonema is as follows by weight：Thermoplastic resin
55~60 parts, 3~5 parts of Boron Trifluoride Ethylamine, 1~3 part of antioxidant, 15~20 parts of carbon fiber, basalt fibre 15~20
Part, 15~20 parts of polyacrylonitrile fibre and 15~20 parts of pyroceram fibre, 1~4 part of AG80 epoxy resin；
The high-strength complex zygonema is by basalt fibre line, polyacrylonitrile fibre line, pyroceram fibre line and carbon fiber line
It is twisted；
The raw material of the coating is as follows by weight：30~40 parts of phenol-formaldehyde resin modified；2-3 parts of beryllium-bronze powder；Nanometer titanium dioxide
15-25 parts of silicon；1.0~1.6 parts of antioxidant；1~2 part of magnesium stearate；1.0~1.3 parts of tricresyl phosphate；8~10 parts of graphite；
6~8 parts of aluminium oxide；3~5 parts of titanium dioxide；35~50 parts of dimethylbenzene；2~4 parts of vulcanizing agent.
2. a kind of high temperature resistant vehicle clutch surface according to claim 1, it is characterised in that：The phenol-formaldehyde resin modified
Preparation method be：It by 65 parts of phenolic resin and 10 parts of addition batch mixers of calcium dihydrogen phosphate, mixes 40 minutes, then adds in 50 DEG C
Enter 4 parts of 7 parts of m-xylene diamine and hydroxypropyl acrylate, be warming up to 90 DEG C and mix 40 minutes, cooling to obtain the final product.
3. a kind of high temperature resistant vehicle clutch surface according to claim 1, it is characterised in that：The high-strength complex zygonema
Making step be：
A, thermoplastic resin, Boron Trifluoride Ethylamine, antioxidant and AG80 epoxy resin mix 2 in high-speed kneading machine~
4min is until uniform；
B, loading hopper that the raw material mixed in step a is then put into double screw extruder, carbon fiber, basalt is fine
Dimension, polyacrylonitrile fibre and pyroceram fibre are added to by side feeding in extruder respectively, through melting extrusion, Cast Strip,
Drawing-off, then carbon fiber, basalt fibre, polyacrylonitrile fibre and pyroceram fibre carry out 10~15 one by treated
Being twisted for group, respectively obtains carbon fiber line, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line；
C, the carbon fiber line obtained in step b, basalt fibre line, polyacrylonitrile fibre line and pyroceram fibre line are twisted
Synthesizing high-strength recombination line.
4. a kind of high temperature resistant vehicle clutch surface according to claim 1, it is characterised in that：The Compound Fabric makes step
Suddenly it is：
D, high-strength complex zygonema carries out being woven into bulk, then dip-coatings, enters back into curing mold solidification；
E, by the blocky high-strength complex zygonema braided fabric after solidification hot pressing temperature be 140~160 DEG C, hot pressing pressure be 14~
It is hot-forming under conditions of 16Mpa, the molding drilling of positioning hole is carried out during hot-forming, and Compound Fabric is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810442514.0A CN108641400A (en) | 2018-05-10 | 2018-05-10 | A kind of no metal carbon fiber recombination line clutch surface and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810442514.0A CN108641400A (en) | 2018-05-10 | 2018-05-10 | A kind of no metal carbon fiber recombination line clutch surface and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108641400A true CN108641400A (en) | 2018-10-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810442514.0A Pending CN108641400A (en) | 2018-05-10 | 2018-05-10 | A kind of no metal carbon fiber recombination line clutch surface and preparation method thereof |
Country Status (1)
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106050969A (en) * | 2016-07-18 | 2016-10-26 | 张和庆 | Basalt-fiber-reinforced automobile clutch facing assembly and manufacturing method |
| CN106047036A (en) * | 2016-07-18 | 2016-10-26 | 张和庆 | Infusion coating for high-temperature-resistant sparkless vehicle clutch facing material |
| CN106147125A (en) * | 2016-08-23 | 2016-11-23 | 潘光贤 | A kind of high-strength high temperature resistant clutch surface and preparation method thereof |
| CN106317767A (en) * | 2016-08-22 | 2017-01-11 | 苏州聚冠复合材料有限公司 | Preparation method of ultrahigh-conductivity 3D printing carbon fiber composite wire |
-
2018
- 2018-05-10 CN CN201810442514.0A patent/CN108641400A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106050969A (en) * | 2016-07-18 | 2016-10-26 | 张和庆 | Basalt-fiber-reinforced automobile clutch facing assembly and manufacturing method |
| CN106047036A (en) * | 2016-07-18 | 2016-10-26 | 张和庆 | Infusion coating for high-temperature-resistant sparkless vehicle clutch facing material |
| CN106317767A (en) * | 2016-08-22 | 2017-01-11 | 苏州聚冠复合材料有限公司 | Preparation method of ultrahigh-conductivity 3D printing carbon fiber composite wire |
| CN106147125A (en) * | 2016-08-23 | 2016-11-23 | 潘光贤 | A kind of high-strength high temperature resistant clutch surface and preparation method thereof |
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