CN108640636A - Under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method - Google Patents

Under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method Download PDF

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Publication number
CN108640636A
CN108640636A CN201810459904.9A CN201810459904A CN108640636A CN 108640636 A CN108640636 A CN 108640636A CN 201810459904 A CN201810459904 A CN 201810459904A CN 108640636 A CN108640636 A CN 108640636A
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China
Prior art keywords
wall plate
heat
insulation wall
plate material
preparation
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CN201810459904.9A
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Chinese (zh)
Inventor
张文华
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Nanjing Forestry University
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Nanjing Forestry University
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Priority to CN201810459904.9A priority Critical patent/CN108640636A/en
Publication of CN108640636A publication Critical patent/CN108640636A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method, by mass percentage include following substance:Light calcined magnesia 25.1~42.6%, magnesium chloride 7.2~13.3%, cinder 13.4~24.1%, silicon ash 4.0%~8.5%, flyash 14.2%~25.6%, water 10.5~28.8%, polypropylene fibre 0.5~1.0%, how series high-efficiency water-reducing agent 0.1~0.5%, thickener 0.1%~0.5%, air entraining agent 0.1%~0.4%, haydite 15~20%, eps foam particle 0.5%~1.0%.Using material provided by the invention and the produced heat-insulation wall plate of preparation method, it can be achieved that the quick form removals of 2~5h, have the advantages that striking time is short, production efficiency is high, production equipment is simple, low energy consumption;In addition, this bright produced assembling thermal-insulating wall board, lightweight, high-strength, heat preservation, thermal insulation are good, are suitable for the inside and outside wall board of modern assembled industrialized building.

Description

Under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method
Technical field
The present invention relates under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method, belong to In building material field.It solving the problems, such as that the heat-insulation wall plate production cycle is grown more particularly to a kind of, is mainly used for assembled architecture guarantor The preparation of warm wallboard.
Background technology
Building industrialization and housing industrialization and Urbanization Construction require actively to promote prefabricated construction.For building Building enclosure, it is exactly the assembling degree of wall to examine the key index of building industrialization level.Promote and apply assembled light Heat insulating type concrete Side fascia meets the industrial policy of national green building and building energy conservation, is that building trade realizes sustainable development Open up the important content of strategy.
Assembling thermal-insulating wall board is building industrialization important component.Current assembling thermal-insulating wall board is general to use Portland cement makes, and there is the shortcomings that condensation hardening is slow, demoulding time is long, low production efficiency.Many enterprises are in order to add Fast production efficiency shortens striking time using steam-cured method, but this needs complicated steaming and cultivating equipment, enterprise to need to put into Huge fund;In addition it needs to consume a large amount of energy in maintenance processes, significantly increases enterprise's production cost.Above-mentioned reason All significantly limit popularization and application of the existing assembling thermal-insulating wall board in building industrialization, be badly in need of wanting it is a kind of can fast demoulding Assembling thermal-insulating wall board material and preparation method thereof.
Invention content
For the deficiency present in existing assembling thermal-insulating wall board material, the present invention proposes under a kind of room temperature curing condition Can fast demoulding heat-insulation wall plate material and preparation method, technical solution be:
Under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method, wrap by mass percentage Include following substance:
The light-burning magnesium powder activity > 60%, 200 mesh of fineness <, free CaO content < 2%, Fe2O3Content < 1.5%..
The polypropylene fiber filaments equivalent diameter 0.1 ± 0.05mm, 20 ± 1mm of length, tensile strength >=560MPa, bullet Property modulus >=3700MPa.Polypropylene fibre is mixed, energy to failure can be effectively improved, slowed down and cut short the extension of crackle, improve crimping Than promoting the mechanical property of assembling thermal-insulating wall board.
The thickener be cellulose ether, including methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, The types such as hydroxyethyl cellulose.Cellulose ether can increase substantially the moulding viscosity of cement mortar, yield stress and critical answer Become, increase the stickiness of cement slurry, to increase the resistance of lightweight aggregate particle floating, it is steady in slurry to be conducive to particle It is fixed.
The air entraining agent is fatty alcohol sulfonate class air entraining agent, including fatty alcohol polyoxyethylene ether, aliphatic alcohol polyethenoxy Sodium sulfonate and sodium alkyl sulfate.Air entraining agent is added, it is intended to introduce suitable bubble in cement slurry, can reduce cement slurry Density, reduce haydite, EPS particles and cement slurry density gap, to reduce the buoyancy of haydite, EPS particles, raising Uniformity of the lightweight aggregate particle inside wallboard.
The water-reducing agent be how series high-efficiency water-reducing agent, such water-reducing agent and magnesia oxychloride cement with good applicability with it is simultaneous Capacitive can increase the mobility of cement slurry.
The silicon ash is byproduct of the ferroalloy in smelting duriron and industrial silicon (metallic silicon), and appearance is grey or greyish white Color powder, SiO290% or more content, mean particle size is at 0.1~0.3 μm, and specific surface area is between 20~28m2/ g, accumulation Density is between 160kg/m3~700kg/m3.Silicon ash grain diameter is small, specific surface area is very big, and the incorporation of silicon ash can significantly improve The cohesiveness and water-retaining property of concrete improve viscosity, are conducive to the stabilization of haydite, EPS particles.
The flyash is dark gray powder, SiO2Content is between 50%~65%, Al2O3Content between 20%~ 45%, mean particle size is at 0.5~300 μm, and bulk density is between 500kg/m3~1300kg/m3.Fly ash grain is circle Smooth glass plastid can play ball effect, improve the mobility of concrete, while can also increase cohesiveness.Flyash adds The setting time of magnesia oxychloride cement can also be adjusted by entering, and be extended as volume increases setting time.
The cinder is the waste residue that thermal power plant, industry and civil boiler and other equipment fire coal are discharged.Coal slag granules Average grain diameter is in 1.0~6.0mm, and bulk density is between 460kg/m3~840kg/m3.Contain a large amount of holes inside cinder, therefore Grain density is smaller, light, and the incorporation of cinder can significantly reduce the density of heat-insulation wall plate, reduces weight, while a large amount of holes Introducing, the heat-insulating property and sound insulation property of assembling thermal-insulating wall board can be improved.
The assembled wallboard preparation method, includes the following steps:
(1) load weighted light calcined magnesia, magnesium chloride, silicon ash, flyash are poured into stirring container, stirring 30s to material Material is uniformly mixed;
(2) suitable vessel is taken, by load weighted air entraining agent, thickener, how based water reducer pours into load weighted water, stirs It is uniformly mixed to all liq to mix 30s;
(3) liquid being stirred is poured into blender, first stirring at low speed 15s, then high-speed stirred 30s, flowing shape is made Slurry;
(4) load weighted cinder, haydite and eps foam particle are poured into blender, first stirring at low speed 30s, then high speed Stir 30s;
(5) polypropylene fibre will have been weighed to be sprinkled into blender, has been stopped after high-speed stirred 30s, discharged;
(6) concrete being stirred is poured into assembled wallboard mold, vibrates 15s with plug-in type vibrating stick with closely knit;
(7) 2h~5h demouldings are stood at ambient temperature, and assembling thermal-insulating wall board is made.
Compared to the prior art the present invention, has the following advantages that:
(1) the present invention provides under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method, It can realize adjustable fast demoulding in 2~5 hours, it is simple for production, adapt to plant layoutization construction.The present invention can pole The earth reduces the Production Time of assembling thermal-insulating wall board, shortens the production cycle, significantly improves the benefit of enterprise.
(2) assembling thermal-insulating wall board material of the invention and method in raw material, production, preparation, construction, use every link In all fully illustrate the feature of itself and environmental-friendly Ecological Building Materials, be a kind of economic benefit, social benefit and environmental benefit all Very high construction material has wide development space in following building energy saving field.
(2) the present invention provides it is a kind of can fast demoulding assembled wallboard material and preparation method, both had inorganic guarantor The advantages that durability of adiabator is good, fire-protection rating is high, at the same have water absorption rate is small, heat insulation property is good, it is cheap, construction The advantages that facilitating good mechanical properties.
(3) industrial residues such as the present invention a large amount of silicon ash, flyash, clinkers, have environmentally protective feature.
Specific implementation mode
Density of the present invention, compression strength, flexural strength test method refer to JGJ51-2002《Lightweight aggregate concrete skill Art regulation》、GB/T50080-2002《Normal concrete mix method for testing performance》And GB/T50081-2002《It is common mixed Solidifying soil mechanics method for testing performance standard》It is tested.
Embodiment 1-4
It is a kind of can the assembled wallboard material of fast demoulding get out following raw material by mass percentage:
Raw material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Light-burning magnesium powder 20.10% 20.10% 20.10% 20.10%
Magnesium chloride 5.00% 5.00% 5.00% 5.00%
Flyash 7.00% 7.80% 8.10% 8.40%
Cinder 20.00% 19.00% 18.00% 17.00%
Silicon ash 5.00% 6.00% 7.00% 8.00%
Water 25.30% 25.30% 25.30% 25.30%
Polypropylene fibre 0.50% 0.50% 0.50% 0.50%
How based water reducer 1.10% 1.20% 1.40% 1.60%
Thickener 0.10% 0.10% 0.10% 0.10%
Air entraining agent 0.10% 0.10% 0.10% 0.10%
Haydite 15.29% 14.39% 13.89% 13.39%
Eps foam particle 0.51% 0.51% 0.51% 0.51%
By above-mentioned load weighted material, prepared according to the following steps:
(1) load weighted light calcined magnesia, magnesium chloride, silicon ash, flyash are poured into stirring container, stirring 30s to material Material is uniformly mixed;
(2) suitable vessel is taken, by load weighted air entraining agent, thickener, how based water reducer pours into load weighted water, stirs It is uniformly mixed to all liq to mix 30s;
(3) liquid being stirred is poured into blender, first stirring at low speed 15s, then high-speed stirred 30s, flowing shape is made Slurry;
(4) load weighted cinder, haydite and eps foam particle are poured into blender, first stirring at low speed 30s, then high speed Stir 30s;
(5) polypropylene fibre will have been weighed to be sprinkled into blender, has been stopped after high-speed stirred 30s, discharged;
(6) concrete being stirred is poured into assembled wallboard mold, vibrates 15s with plug-in type vibrating stick with closely knit;
(7) 2h~5h demouldings are stood at ambient temperature, and assembling thermal-insulating wall board is made.
By above-mentioned preparation process carry out test specimen preparation, and according to code requirement test the results are shown in table below:

Claims (7)

1. under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material, it is characterised in that include by mass percentage Following substance:
2. heat-insulation wall plate material according to claim 1, it is characterised in that in the light-burning magnesium powder, active > 60%, carefully Spend 200 mesh of <, free CaO content < 2%, Fe2O3Content < 1.5%.
3. heat-insulation wall plate material according to claim 1, it is characterised in that the polypropylene fiber filaments equivalent diameter 0.1 ± 0.05mm, 20 ± 1mm of length, tensile strength >=560MPa, elasticity modulus >=3700MPa.
4. heat-insulation wall plate material according to claim 1, it is characterised in that thickener is cellulose ether, including Methyl cellulose The types such as element, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose.
5. heat-insulation wall plate material according to claim 1, it is characterised in that air entraining agent is fatty alcohol sulfonate class air entraining agent, Including fatty alcohol polyoxyethylene ether, aliphatic alcohol polyethenoxy sodium sulfonate and sodium alkyl sulfate.
6. heat-insulation wall plate material according to claim 1, it is characterised in that water-reducing agent be how series high-efficiency water-reducing agent.
7. it is a kind of can fast demoulding assembled wallboard material and preparation method, it is characterised in that preparation method according to the following steps into Row:
(1) load weighted light calcined magnesia, magnesium chloride, silicon ash, flyash are poured into stirring container, stirring 30s is mixed to material It closes uniform;
(2) suitable vessel is taken, by load weighted air entraining agent, thickener, how based water reducer pours into load weighted water, stirring 30s is uniformly mixed to all liq;
(3) liquid being stirred is poured into blender, first stirring at low speed 15s, then high-speed stirred 30s, flowing shape slurry is made;
(4) load weighted cinder, haydite and eps foam particle are poured into blender, first stirring at low speed 30s, then high-speed stirred 30s;
(5) polypropylene fibre will have been weighed to be sprinkled into blender, has been stopped after high-speed stirred 30s, discharged;
(6) concrete being stirred is poured into assembled wallboard mold, vibrates 15s with plug-in type vibrating stick with closely knit;
(7) 2h~5h demouldings are stood at ambient temperature, and assembling thermal-insulating wall board is made.
CN201810459904.9A 2018-05-04 2018-05-04 Under a kind of room temperature curing condition can fast demoulding heat-insulation wall plate material and preparation method Withdrawn CN108640636A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109851311A (en) * 2019-02-28 2019-06-07 海南鑫申绿色建筑科技有限公司 A kind of water-fast building panel and preparation method thereof
CN116514520A (en) * 2023-04-24 2023-08-01 灌南县灌铁实业有限公司 Light fireproof building material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109851311A (en) * 2019-02-28 2019-06-07 海南鑫申绿色建筑科技有限公司 A kind of water-fast building panel and preparation method thereof
CN116514520A (en) * 2023-04-24 2023-08-01 灌南县灌铁实业有限公司 Light fireproof building material and preparation method thereof
CN116514520B (en) * 2023-04-24 2023-10-20 灌南县灌铁实业有限公司 Light fireproof building material and preparation method thereof

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