A kind of water-purifying filter
Technical field
The present invention relates to technical field of water purification, and in particular to a kind of water-purifying filter.
Background technology
With increased population, industry and expanding economy, the pollution getting worse that surface drainage is subject to, factory's blowdown, life
Sewage living makes national good water sources constantly reduce;Underground water pollution is more startling, and garbage loading embeading, septic tank, mining site are dirty
It contaminates, the ground down blow of factory so that the quality of groundwater in the whole nation nearly 60% is " poor ".Currently, China waterworks is still using biography
System treatment process, the most of pollutant that cannot be removed effectively, the organic and inorganic pollutant having been detected by water is
More than 2100 kinds.
For different types of pollutant, a variety of water-purifying materials have been developed, have been applied in the equipment such as water purifier.However it is existing
All there is the problems such as process range is narrow, of high cost or there are secondary pollution risks in some materials:If PP cottons in water only for suspending
The removal of the large particulate matters such as object, silt, iron rust, colloid, it is all helpless for bacterium, organic molecule etc.;Common activity
Charcoal can remove chlorine residue, pesticide residue, pigment etc., cannot effectively adsorb bacterium, calcium ions and magnesium ions etc.;RO (reverse osmosis) film can remove big
Partial metal ion, but the minerals beneficial to human body are had also been removed simultaneously, while cost is higher;KDF can effectively deal with
Chlorine residue in water and heavy metal, and inhibit the growth of microorganism in water, but the problem of there are still heavy metal secondary pollutions.
In actual use, it to achieve the effect that clean water source and reducing net water-purifying material biological pollution, generally adopts
With sodium hypochlorite irreversible destruction can be generated to water-purifying material, made to being carried out sterilizing, the Active Chlorine thus introduced
Water purification performance declines rapidly and can not be continuing with.Therefore, to extend the service life of water-purifying material, water inlet also needs after sterilization
Dechlorination processing is carried out, the requirement of 0.1ppm is less than with contents of residual chlorine in reaching into water, this generic operation obviously increases operating cost.
If the equipment with high desalinization water-purifying material with chlorine-resistant property can be prepared, Operating Complexity can be effectively reduced, is dropped
Low operating cost;Simultaneously because water inlet in chlorine residue presence, can effectively inhibit the quick breeding of bacterium, avoid film operational process
In biological pollution, not only be conducive to system stable operation, chemical cleaning number can also be reduced, further decrease system maintenance
Expense.
Invention content
In view of the above problems, the present invention provides a kind of water-purifying filter, efficiently can remove multiple pollutant simultaneously,
The concatenated structure of a variety of material for core is substituted, water purifying apparatus structure can be simplified, is conducive to the popularization of purifier.
Specifically, the present invention provides a kind of water-purifying filter, includes the cylinder with upper top surface and bottom surface, feature exists
In, include water-purifying material layer in the cylinder, the upper surface of the water-purifying material bed of material connects water-purifying material density regulating apparatus,
The lower face connection retainer basis of the water-purifying material filter material layer, the retainer basis is connect with the inner wall of the cylinder;It is described
The preparation method of water-purifying material is by 40~50wt% of activated carbon content, macromolecule water-purifying material 20~30%, clay content 10
~25wt%, 1~10wt% of binder content, dry-mixed ball milling by a certain percentage, after a certain amount of water wet mixing is added, through mediating,
Vacuum pugging ageing, extrusion molding, dries in the shade, obtains porous type porous material after microwave irradiation sizing, wherein macromolecule water purification
Material is that graphene oxide, nano-titanium dioxide and high molecular polymer are prepared.
The upper top surface connects waste water inlet by waste line, and the upper top surface connects exhaust outlet by gas exhaust piping,
The bottom surface connects water purification outlet by water pipeline, and the bottom surface is provided with air inlet, and the bottom surface is provided with row
Dirty mouth.
The water-purifying material density regulating apparatus connects the water-purifying material layer by stainless steel hook.
The water-purifying material density regulating apparatus connects the water-purifying material layer by stainless steel hook, and with along described
The movable fit structure of smooth motion above and below the inner wall of cylinder.
The retainer basis is fixed on the inner wall of the cylinder.
The preparation method of the macromolecule water-purifying material is:
1) graphene oxide is mixed with nano-titanium dioxide example in mass ratio, is reacted in acid condition, reaction temperature
It it is 70~80 DEG C, the reaction time is 1~15 hour, obtains product graphene oxide/nanometer titanium dioxide compound;
2) graphene oxide/nanometer titanium dioxide compound, high molecular polymer are dissolved in solvent, are stirred to complete
It dissolves, then spray-dried acquisition graphene oxide/nano-titanium dioxide/high molecular polymer composite high-molecular water purification material
Material.
Further, in step 1), graphene oxide, nano-titanium dioxide mixing quality ratio be 1:1~10;It is described
Acid condition be, pH value be 3~5 dilute acid soln;
The diluted acid is any one or more in dilute hydrochloric acid, dust technology, dilute sulfuric acid.
Further, in step 2), the macromolecule polymeric material is polyhydroxybutyrate fat, Kynoar, poly- carbon
Sour fat, any one or a few in polyurethane, addition is the 2 of graphene oxide/nanometer titanium dioxide compound weight
~3 times.
Further, in step 2), the solvent be ethyl alcohol, dichloromethane, chloroform, methanol, ethyl alcohol, formic acid,
Any one or a few in acetic acid.
The present invention be prepared integral-type high-efficiency multiple water-purifying material can remove simultaneously chlorine residue, heavy metal from
Three kinds or more in son, calcium ions and magnesium ions, bacterial micro-organism, organic matter.
The beneficial effects of the invention are as follows:1) using high than ingredient based on table activated carbon and macromolecule water-purifying material, to dirt
Dye object has big adsorbance;2) porous structure is utilized, hydraulic losses are reduced, improves the water outlet efficiency of water after purification;3) simultaneously
Efficiently removal multiple pollutant, substitutes the concatenated structure of a variety of material for core, can simplify water purifying apparatus structure, be conducive to water purification and set
Standby popularization.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
【Embodiment 1】
The preparation of S1, macromolecule water-purifying material
1) by graphene oxide and nano-titanium dioxide example 1 in mass ratio:2 mixing, the dilute hydrochloric acid solution for being 3 in pH value
In, reaction temperature is 70 DEG C, and the reaction time is 12 hours, obtains product graphene oxide/nanometer titanium dioxide compound;
2) by graphene oxide/nanometer titanium dioxide compound, the high molecular polymer polyhydroxybutyrate liposoluble of 2 times of quality
Solution is stirred to being completely dissolved, then spray-dried acquisition graphene oxide/nano-titanium dioxide/high score in etoh solvent
Sub- polymer composite high-molecular water-purifying material A.
The preparation of S2, integral-type high-efficiency multiple water-purifying material
Cocoanut active charcoal 40wt%, the macromolecule water-purifying material A 25% of above-mentioned preparation, kaolin 25wt%, methyl is fine
Dimension element ball 10wt% is sufficiently mixed, and is milled to 300~400 mesh, and 800mL water wet methods are added and mediate 1h, -0.09MPa vacuum pugging 5h,
Be aged 12h, in vertical extruder extrusion molding cellular active carbon ceramic thick embryo is made, in micro- after the 48h that dries in the air under thick embryo room temperature
Porous type composite material I is made according to sizing (microwave irradiation density 2.0kw/kg) under 550 DEG C of vacuum in amplitude.
【Embodiment 2】
The preparation of S1, macromolecule water-purifying material
1) by graphene oxide and nano-titanium dioxide example 1 in mass ratio:10 mixing, the dilution heat of sulfuric acid for being 5 in pH value
In, reaction temperature is 75 DEG C, and the reaction time is 12 hours, obtains product graphene oxide/nanometer titanium dioxide compound;
2) graphene oxide/nanometer titanium dioxide compound, high molecular polymer polyhydroxybutyrate fat and polyurethane is molten
In agent ethyl alcohol and formic acid, stir to being completely dissolved, then spray-dried acquisition graphene oxide/nano-titanium dioxide/high score
Sub- polymer composite high-molecular water-purifying material B.
The preparation of S2, integral-type high-efficiency multiple water-purifying material
Cocoanut active charcoal 40wt%, the macromolecule water-purifying material B 25% of above-mentioned preparation, kaolin 25wt%, methyl is fine
Dimension element ball 10wt% is sufficiently mixed, and is milled to 300~400 mesh, and 800mL water wet methods are added and mediate 1h, -0.09MPa vacuum pugging 5h,
Be aged 12h, in vertical extruder extrusion molding cellular active carbon ceramic thick embryo is made, in micro- after the 48h that dries in the air under thick embryo room temperature
Porous type composite material II is made according to sizing (microwave irradiation density 2.0kw/kg) under 550 DEG C of vacuum in amplitude.
【Embodiment 3】
The preparation of S1, macromolecule water-purifying material
1) by graphene oxide and nano-titanium dioxide example 1 in mass ratio:5 mixing, in the dilute acid soln that pH value is 4,
Reaction temperature is 80 DEG C, and the reaction time is 5 hours, obtains product graphene oxide/nanometer titanium dioxide compound;
2) graphene oxide/nanometer titanium dioxide compound, high molecular polymer polycarbonate are dissolved in solvent formic acid
In, it stirs to being completely dissolved, then spray-dried acquisition graphene oxide/nano-titanium dioxide/high molecular polymer is compound
Macromolecule water-purifying material C.
The preparation of S2, integral-type high-efficiency multiple water-purifying material
Cocoanut active charcoal 40wt%, the macromolecule water-purifying material C 25% of above-mentioned preparation, kaolin 25wt%, methyl is fine
Dimension element ball 10wt% is sufficiently mixed, and is milled to 300~400 mesh, and 800mL water wet methods are added and mediate 1h, -0.09MPa vacuum pugging 5h,
Be aged 12h, in vertical extruder extrusion molding cellular active carbon ceramic thick embryo is made, in micro- after the 48h that dries in the air under thick embryo room temperature
Porous type composite material III is made according to sizing (microwave irradiation density 2.0kw/kg) under 550 DEG C of vacuum in amplitude.
【Embodiment 4】
The present embodiment provides a kind of water-purifying filter, includes the cylinder with upper top surface and bottom surface, set in the cylinder
Set water-purifying material layer, the upper surface of the water-purifying material connects water-purifying material density regulating apparatus, under the water-purifying material layer
End face connects retainer basis, and the retainer basis is connect with the inner wall of the cylinder.The upper top surface is connected by waste line
Waste water inlet, the upper top surface connect exhaust outlet by gas exhaust piping, and the bottom surface connects water purification outlet by water pipeline,
The bottom surface is provided with air inlet, and the bottom surface is provided with sewage draining exit.The water-purifying material density regulating apparatus passes through not
The steel hook that becomes rusty connects the water-purifying material filter material layer.The retainer basis is fixed on the inner wall of the cylinder.The water purification material
Expect that density regulating apparatus has the movable fit structure of the smooth motion above and below the inner wall of the cylinder.
Porous type composite material I~III prepared by Examples 1 to 3 is packed into above-mentioned Confucian classics material layer respectively, detects water purification
Device treated water is according to GB/T 5750-2006《The drinking water standard method of inspection》Detection and GB4789-2010《Food
Safe national standard》, contents of residual chlorine<0.005mg/L, Pb content<0.001mg/L, Cu content<0.001mg/L, total plate count<
0.2cfu/ml, coliform and staphylococcus aureus are not detected.
Above description has fully disclosed the specific implementation mode of the present invention.It should be pointed out that being familiar with the field
Technical staff is to any change for being done of specific implementation mode of the present invention all without departing from the range of claims of the present invention.
Correspondingly, the scope of the claims of the invention is also not limited only to previous embodiment.