CN108636343A - A kind of reinforcing absorption clinker and preparation method thereof and purposes - Google Patents
A kind of reinforcing absorption clinker and preparation method thereof and purposes Download PDFInfo
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- CN108636343A CN108636343A CN201810489622.3A CN201810489622A CN108636343A CN 108636343 A CN108636343 A CN 108636343A CN 201810489622 A CN201810489622 A CN 201810489622A CN 108636343 A CN108636343 A CN 108636343A
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 51
- 230000003014 reinforcing effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000000243 solution Substances 0.000 claims abstract description 103
- 238000007385 chemical modification Methods 0.000 claims abstract description 71
- 238000012986 modification Methods 0.000 claims abstract description 68
- 241000894006 Bacteria Species 0.000 claims abstract description 51
- 230000004048 modification Effects 0.000 claims abstract description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 13
- 238000005728 strengthening Methods 0.000 claims abstract description 13
- 239000012670 alkaline solution Substances 0.000 claims abstract description 8
- 238000003900 soil pollution Methods 0.000 claims abstract description 7
- 238000003911 water pollution Methods 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000010865 sewage Substances 0.000 claims description 39
- 239000007787 solid Substances 0.000 claims description 38
- 239000010802 sludge Substances 0.000 claims description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 24
- 244000063299 Bacillus subtilis Species 0.000 claims description 21
- 238000012545 processing Methods 0.000 claims description 16
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 8
- 238000005273 aeration Methods 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 6
- 230000003068 static effect Effects 0.000 claims description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 24
- 238000001179 sorption measurement Methods 0.000 abstract description 16
- 230000015556 catabolic process Effects 0.000 abstract description 5
- 238000006731 degradation reaction Methods 0.000 abstract description 5
- 239000002893 slag Substances 0.000 description 31
- 239000012153 distilled water Substances 0.000 description 24
- 239000006210 lotion Substances 0.000 description 20
- 238000005406 washing Methods 0.000 description 20
- 230000008569 process Effects 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000011449 brick Substances 0.000 description 16
- 239000000919 ceramic Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 16
- 239000011521 glass Substances 0.000 description 16
- 244000005700 microbiome Species 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 238000011010 flushing procedure Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000002351 wastewater Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 6
- 238000005286 illumination Methods 0.000 description 6
- 239000002609 medium Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 235000014469 Bacillus subtilis Nutrition 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 239000005416 organic matter Substances 0.000 description 4
- 125000001477 organic nitrogen group Chemical group 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000010882 bottom ash Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000005067 remediation Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical class [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000007836 KH2PO4 Substances 0.000 description 1
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 description 1
- 239000001888 Peptone Substances 0.000 description 1
- 108010080698 Peptones Proteins 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000010884 boiler slag Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000019319 peptone Nutrition 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
- B01J2220/4887—Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
Abstract
The invention discloses a kind of reinforcings to adsorb clinker and preparation method thereof and purposes, and the present invention passes through physical modification, chemical modification and bio-modification using clinker as raw material, by clinker to get to absorption clinker is strengthened successively, specifically comprises the following steps：(1) physical modification：Clinker is modified using microwave, obtains the clinker that physical modification is crossed；(2) chemical modification：Acid solution or alkaline solution are added in the clinker that physical modification is crossed, after reaction, are washed till neutrality, it is dry, obtain the clinker that chemical modification is crossed；(3) bio-modification：In the clinker that bacterium solution addition chemical modification is crossed, carries out the biofilm of clinker and adsorb clinker to get to the reinforcing.It is provided by the invention to prepare the method for strengthening absorption clinker as raw material using clinker, it is possible to increase the specific surface area of existing clinker extends adsorption saturation time, promotes adsorption capacity, and effectively realizing the absorption to water and soil pollution object, conversion and degradation.
Description
Technical field
The present invention relates to the water and soil pollution object processing technology field of clinker, a kind of reinforcing absorption clinker and its system are particularly related to
Preparation Method and purposes.
Background technology
Coal burning and incineration process of domestic garbage will generate a large amount of clinkers.Currently, these clinkers are primarily as building
Low value-added product is made in the raw material of material, cement, concrete etc..Also small part clinker is applied to wastewater treatment, this
It is to have the characteristics that porosity height, large specific surface area, and contain a large amount of sial since clinker is the product through high temperature sintering
The substances such as hydrochlorate, features described above show that clinker is a kind of multifunctional material with absorption property, be clinker as adsorbing medium
Theoretical foundation has been established applied to the processing of water and soil pollution object.
Slag treatment waste water is a kind of wastewater processing technology of more environmentally friendly " treatment of wastes with processes of wastes against one another ", but at present using at clinker
It is mainly the physical absorption effect by clinker to manage waste water, and not yet adsorbing medium is used as to be applied to soil remediation.In practical work
In Cheng Yingyong, it is primarily present the defect of following three aspect：(1) specific surface area of clinker, which also has, increases space；(2) clinker absorption master
If physical absorption, chemical ion replacement is weak with chelation, can only play the role of temporarily being enriched with to some organic pollutions；
(3) the adsorption saturation duration of clinker is short, and adsorption capacity is insufficient, and the power of regeneration after saturation is weak, and there are pollutants for clinker
Desorption, need to often update filler, it is difficult to become plant, animal and microorganism growth and development medium.
Invention content
In view of this, it is an object of the invention to propose that clinker and the preparation method and application thereof, this hair are adsorbed in a kind of reinforcing
The bright specific surface area that can be increased existing clinker using clinker as the reinforcing absorption clinker that raw material obtains, is extended adsorption saturation time, carried
Its adsorption capacity is risen, the physical absorption of water and soil pollution object, chemistry and bioconversion and the medium of degradation are become.
Based on above-mentioned purpose, a kind of preparation method for strengthening absorption clinker provided by the invention, using clinker as raw material, by stove
Slag passes through physical modification, chemical modification and bio-modification and adsorbs clinker to get to reinforcing successively.
In some embodiments of the invention, include the following steps：
(1) physical modification：Clinker is modified using microwave, obtains the clinker that physical modification is crossed；
(2) chemical modification：Acid solution or alkaline solution are added in the clinker that physical modification is crossed, after reaction, are washed till
Neutrality, it is dry, obtain the clinker that chemical modification is crossed；
(3) bio-modification：In the clinker crossed of bacterium solution addition chemical modification, the biofilm of clinker will be carried out to get to described
Strengthen absorption clinker.
In the present invention, used clinker can be coal-fired clinker and dregs of incinerator, and coal-fired clinker is the bottom of coal-burning boiler
Slag, it is fluidized combustion bottom slag that main component, which has calcium oxide, iron oxide, silica, aluminium oxide etc., dregs of incinerator, mainly
Ingredient has silica, calcium oxide, magnesia, iron oxide, di-iron trioxide, aluminium oxide etc..
In some embodiments of the invention, in step (1), the condition of the microwave is：With 10~100% microwave
3~8min of Power Processing；The more or less aperture structure for improving clinker of microwave modification, some that can make inside clinker have
Machine object decomposes so that its specific surface area improves, to which absorption property is reinforced.
In step (2), the acid solution be sulfuric acid solution, a concentration of the 30~60% of the sulfuric acid solution；It is described
Alkaline solution is NaOH solution, and the molar concentration of the NaOH solution is 3~10mol/L.
In the present invention, under thermokalite environment Na ions combined with clinker generate some Na salt compounds or with Si, Al
Etc. forming spatial skeleton structure.Na elements generate Na salt, Na zeolites point with the mineralogical composition in clinker under heated alkaline environment
Son sieve or spatial skeleton structure.
In some embodiments of the invention, in step (2), stove that acid solution or alkaline solution are crossed with physical modification
The liquid-solid ratio of slag is 1:1~2:1, unit mL/g；
When carrying out the chemical modification using acid solution, the time of the reaction is 10~18h, and temperature is room temperature；
When carrying out the chemical modification using alkaline solution, time of the reaction is 9~12h, temperature is 110~
150℃。
In the present invention, described to be washed till neutral concrete operations and be：It is rinsed to washing lotion and is in neutrality repeatedly with distilled water.It is described
Utilization can be prepared repeatedly by the compound concentration of above-mentioned steps using the washing lotion of distilled water flushing after chemical modification, make washing lotion to reach
The purpose recycled；
In some embodiments of the invention, in step (2), after carrying out the chemical modification using acid solution,
Further include that FeCl is added3Solution carries out hydrothermal synthesis reaction, is washed till neutrality, dry step.
In the present invention, FeCl is added3After solution carries out hydrothermal synthesis reaction, after taking-up sample is cooled to room temperature, with distillation
Water rinses several times, until washing lotion is in neutrality.
In some embodiments of the invention, FeCl3The liquid-solid ratio for the clinker that solution is crossed with physical modification is 1:1~2:1,
Unit is mL/g；
The FeCl3The molar concentration of solution is 2.0~3.0mol/L；
The temperature of the hydrothermal synthesis reaction is 100~120 DEG C, and the time of reaction is 10~18h.
In some embodiments of the invention, in step (3), the bacterium solution is EM bacterium bacterium solution, has cultivated and tamed
Bacillus natto bacterium solution or sludge base bacterium solution through sludge acclimatization culture；
1) when the bacterium solution is EM bacterium bacterium solutions, the liquid-solid ratio for the clinker that the EM bacterium bacterium solution is crossed with chemical modification is 1:1
~3:1, the condition of unit mL/g, biofilm is：Static 18~36h of biofilm at normal temperatures；
2) when the bacterium solution is the Bacillus natto bacterium solution cultivated and tamed, Bacillus natto bacterium that will cultivate and tamed
Liquid is added in the clinker crossed of chemical modification, and sanitary sewage is added and is cultivated, the Bacillus natto bacterium solution cultivated and tame with
The liquid-solid ratio for the clinker that the total amount of sanitary sewage is crossed with chemical modification is 1:1~3:1, the condition of unit mL/g, biofilm is：
18~36h of biofilm at 30~40 DEG C；
3) when the bacterium solution is the sludge base bacterium solution through sludge acclimatization culture, the sludge base bacterium solution through sludge acclimatization culture
The liquid-solid ratio for the clinker crossed with chemical modification is 1:1~3:1, the condition of unit mL/g, biofilm is：It is aerated biofilm at normal temperatures
18~36h.
In the present invention, the EM bacterium bacterium solution is EM bacterium former dew distilled water with volume ratio 1:100~5:100 ratio is dilute
It releases.
In some embodiments of the present invention, the sludge base bacterium solution be undercurrent garden wetland, artificial swamp, natural wetland or
Or mixtures thereof one kind in the sludge of sewage treatment plant cultivates 2~5 days bacterium solutions through domestication.
In the present invention, the clinker that the clinker that chemical modification is crossed is crossed as microorganism carrier, microorganism in chemical modification
Surface is easier to grow, and biofilm effect is preferable.
In the present invention, the room temperature refers to the temperature range of this field routine, is 10~30 DEG C.
Further, the present invention also provides the reinforcings that the preparation method is prepared to adsorb clinker.
The present invention also provides purposes of the reinforcing absorption clinker in the processing of water and soil pollution object, specifically, this hair
Bright reinforcing absorption clinker is as the physical absorption of water and soil pollution object, chemistry and bioconversion and the medium of degradation.
From the above it can be seen that the present invention has the following advantages；
(1) present invention strengthens the specific surface area increase of absorption clinker：The present invention makes full use of microwave and strong acid can be to clinker
The characteristics of internal organic matter is decomposed is modified clinker, to make the specific surface area of clinker dramatically increase (about increase by 2~
10 times).
(2) present invention strengthens the ion-exchange capacity enhancing of absorption clinker：After chemical modification, M-OH and O- in modified clinker
H keys are remarkably reinforced.
(3) present invention solves the problems, such as that clinker only relies on physical absorption treated sewage, realizes (special to Pollutants in Wastewater
Not organic pollution) absorption, conversion and degradation：Microorganism is easy growth in slag surface, and biofilm effect is preferable.In waste water
Nitrogen exist substantially in the form of two kinds of organic nitrogen and ammonia nitrogen, organic nitrogen can be decomposed by the microorganisms, be converted into ammonia nitrogen；Organophosphor and phosphorus
Hydrochlorate precipitation is mainly converted by the coordinative role of microorganism, is degraded to soluble phosphate；It is biodegradable in waste water
Organic matter is decomposed by the microorganisms into inorganic salts, carbon dioxide and water；Ammonia nitrogen, soluble phosphate, inorganic salts etc. are adsorbed by clinker
And it is supplied to the microbial nutrition of attachment.
(4) present invention strengthens the saturation time extension of absorption clinker, and adsorption capacity improves：Change by physics, chemistry, biology
Property after, extended by modified clinker adsorption saturation time known to adsorption dynamics adsorption kinetics, adsorption capacity improves.
(5) present invention strengthens absorption clinker and is improved to the treatment effect of sanitary sewage：Nitrogen removal rate can reach
50~80%, the removal rate that total tp removal rate can reach 50~95%, COD can reach 30~92%.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this hair
Bright further description.
It should be noted that the EM bacterium former dew and Bacillus natto particle that use in the examples below are commercially available, sludge comes
From undercurrent garden wetland, artificial swamp, natural wetland or sewage treatment plant.
The culture medium of Bacillus natto is：Glucose 3%, peptone 2%, MgSO40.2%, K2HPO40.1%, KH2PO4
0.2%, 250ml distilled water.
Sludge base bacterium solution culture and domestication：Take a certain amount of undercurrent garden wetland, artificial swamp, natural wetland or sewage disposal
The sludge of factory is added suitable sanitary sewage and carbon source, nitrogen source, and is aerated 2~5 days.
The culture and domestication of Bacillus natto：By suitable excellent Bacillus natto strain particle, the culture medium of Bacillus natto is added, is placed in
Illumination constant incubator, with 37 DEG C of illumination cultivation 48h.
Embodiment 1
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：The pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-
In wave stove, microwave treatment is carried out with 100% power, processing time 5min obtains the clinker that physical modification is crossed.
(3) chemical modification：The sulfuric acid solution that compound concentration is 50%, by liquid-solid ratio 1:1 (unit：ML/g ratio) is poured into
In the clinker that physical modification is crossed, 12h is impregnated, is rinsed to washing lotion and is in neutrality repeatedly with distilled water after taking-up, dried for standby；Then it presses
Liquid-solid ratio 1:1 (unit：ML/g the FeCl of 2.5mol/L is added in ratio)3Solution is placed in hydrothermal synthesis reaction kettle at 110 DEG C
Under conditions of react 12h, take out sample and be cooled to room temperature after (25 DEG C) with distilled water flushing several times, until washing lotion is in neutrality, dry
It is dry spare, obtain the clinker that chemical modification is crossed.
(4) bio-modification：Undercurrent garden wetland sludge base bacterium solutions of the 250mL after sanitary sewage aeration is cultivated 3 days is taken, is added
Enter in the clinker that chemical modification is crossed, sanitary sewage is aerated undercurrent garden wetland sludge base bacterium solution and chemical modification after cultivating 3 days
The liquid-solid ratio for the clinker crossed is 1:1 (unit：ML/g), it is aerated biofilm under room temperature (25 DEG C) and adsorbs stove for 24 hours to get to reinforcing
Slag.
Embodiment 2
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：It weighs the pretreated g of slag sample of 100g and (is derived from the bottom of circulating fluid bed garbage furnace
Slag), it is placed in micro-wave oven, microwave treatment is carried out with 70% power, processing time 7min obtains the stove that physical modification is crossed
Slag.
(3) chemical modification：The sulfuric acid solution that compound concentration is 30%, by liquid-solid ratio 2:1 (unit：ML/g ratio) is poured into
In the clinker that physical modification is crossed, 10h is impregnated, is rinsed to washing lotion and is in neutrality repeatedly with distilled water after taking-up, dried for standby；Then it presses
Liquid-solid ratio 2:1 (unit：ML/g the FeCl of 2.0mol/L is added in ratio)3Solution is placed in hydrothermal synthesis reaction kettle at 100 DEG C
Under conditions of react 10h, take out sample and be cooled to room temperature after (30 DEG C) with distilled water flushing several times, until washing lotion is in neutrality, dry
It is dry spare, obtain the clinker that chemical modification is crossed.
(4) bio-modification：Activated sludge base bacterium solutions of the 500mL after sanitary sewage aeration is cultivated 2 days is taken, chemistry is added and changes
Property the clinker crossed in, the liquid-solid ratio for the clinker that the activated sludge base bacterium solution after sanitary sewage aeration culture 2 days is crossed with chemical modification
It is 2:1 (unit：ML/g), it is aerated biofilm 18h under room temperature (30 DEG C) and adsorbs clinker to get to reinforcing.
Embodiment 3
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：The pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-
In wave stove, microwave treatment is carried out with 50% power, processing time 8min obtains the clinker that physical modification is crossed.
(3) chemical modification：The sulfuric acid solution that compound concentration is 60%, by liquid-solid ratio 1.5:1 (unit：ML/g ratio) is fallen
Enter in the clinker that physical modification is crossed, impregnates 18h, rinsed to washing lotion and be in neutrality repeatedly with distilled water after taking-up, dried for standby；Then
By liquid-solid ratio 1.5:1 (unit：ML/g the FeCl of 3.0mol/L is added in ratio)3Solution is placed in hydrothermal synthesis reaction kettle
18h is reacted under conditions of 150 DEG C, sample is taken out and is cooled to room temperature after (20 DEG C) with distilled water flushing several times, until during washing lotion is in
Property, it is dried for standby, obtains the clinker that chemical modification is crossed.
(4) bio-modification：Take natural wetland sludge base bacterium solutions of the 750mL after sanitary sewage aeration is cultivated 4 days, additionization
It learns in the clinker being modified, sanitary sewage is aerated the clinker that the natural wetland sludge base bacterium solution after cultivating 4 days is crossed with chemical modification
Liquid-solid ratio be 3:1 (unit：ML/g), it is aerated biofilm 36h under room temperature (20 DEG C) and adsorbs clinker to get to reinforcing.
Embodiment 4
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：The pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-
In wave stove, microwave treatment is carried out with 70% power, processing time 5min obtains the clinker that physical modification is crossed.
(3) chemical modification：The sulfuric acid solution that compound concentration is 50%, according to liquid-solid ratio 1:1 (unit：ML/g) change with physics
Property cross clinker mixing, impregnate 12h, rinsed repeatedly to washing lotion and be in neutrality with distilled water after taking-up, drying for standby obtains chemistry and changes
The clinker that property is crossed.
(4) bio-modification：It takes on a small quantity through sanitary sewage culture and the Bacillus natto bacterium solution tamed, is added what chemical modification was crossed
In clinker, it is added 250mL sanitary sewages, the liquid-solid ratio for the clinker that total amount and the chemical modification of Bacillus natto bacterium solution and sanitary sewage are crossed
It is 1:1, unit mL/g are then placed in illumination constant incubator, and biofilm adsorbs clinker to get to reinforcing for 24 hours at 37 DEG C.
Embodiment 5
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：It weighs the pretreated g of slag sample of 100g and (is derived from the bottom of circulating fluid bed garbage furnace
Slag), it is placed in micro-wave oven, microwave treatment is carried out with 100% power, processing time 3min obtains the stove that physical modification is crossed
Slag.
(3) chemical modification：The sulfuric acid solution that compound concentration is 40%, according to liquid-solid ratio 2:1 (unit：ML/g) change with physics
Property cross clinker mixing, impregnate 15h, rinsed repeatedly to washing lotion and be in neutrality with distilled water after taking-up, drying for standby obtains chemistry and changes
The clinker that property is crossed.
(4) bio-modification：It takes on a small quantity through sanitary sewage culture and the Bacillus natto bacterium solution tamed, is added what chemical modification was crossed
In clinker, it is added 500mL sanitary sewages, the liquid-solid ratio for the clinker that total amount and the chemical modification of Bacillus natto bacterium solution and sanitary sewage are crossed
It is 2:1, unit mL/g are then placed in illumination constant incubator, and biofilm 36h adsorbs clinker to get to reinforcing at 30 DEG C.
Embodiment 6
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：It weighs the pretreated g of slag sample of 100g and (is derived from the bottom of circulating fluid bed garbage furnace
Slag), it is placed in micro-wave oven, microwave treatment is carried out with 50% power, processing time 7min obtains the stove that physical modification is crossed
Slag.
(3) chemical modification：The sulfuric acid solution that compound concentration is 35%, according to liquid-solid ratio 1.5:1 (unit：) and physics mL/g
The clinker mixing being modified, impregnates 18h, is rinsed to washing lotion and be in neutrality repeatedly with distilled water after taking-up, drying for standby obtains chemistry
The clinker being modified.
(4) bio-modification：It takes on a small quantity through sanitary sewage culture and the Bacillus natto bacterium solution tamed, is added what chemical modification was crossed
In clinker, it is added 750mL sanitary sewages, the liquid-solid ratio for the clinker that total amount and the chemical modification of Bacillus natto bacterium solution and sanitary sewage are crossed
It is 3:1, unit mL/g are then placed in illumination constant incubator, and biofilm 19h adsorbs clinker to get to reinforcing at 39 DEG C.
Embodiment 7
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：The pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-
In wave stove, microwave treatment is carried out with 40% power, processing time is 5min, obtains the clinker that physical modification is crossed.
(3) chemical modification：The NaOH solution of 6mol/L is pressed into liquid-solid ratio 1:1 (unit：ML/g ratio) is added physics and changes
Property the clinker crossed in, 10h is reacted under 120 DEG C of condition, taking-up is cooled to room temperature after (25 DEG C) with distilled water flushing several times,
Until washing lotion is in neutrality, it is dried for standby, obtains the clinker that chemical modification is crossed.
(4) bio-modification：By EM bacterium former dew distilled water with 3:The dilution proportion of 100 (volume ratios), after taking 250mL to dilute
EM bacterium bacterium solutions be added in the clinker crossed of chemical modification, the liquid-solid ratio for the clinker that EM bacterium bacterium solution is crossed with chemical modification is 1:1 is (single
Position：ML/g), static biofilm adsorbs clinker to get to reinforcing for 24 hours under room temperature (25 DEG C).
Embodiment 8
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：It weighs the pretreated g of slag sample of 100g and (is derived from the bottom of circulating fluid bed garbage furnace
Slag), it is placed in micro-wave oven, microwave treatment is carried out with 90% power, processing time is 8min, obtains the stove that physical modification is crossed
Slag.
(3) chemical modification：The NaOH solution of 3mol/L is pressed into liquid-solid ratio 2:1 (unit：ML/g ratio) is added physics and changes
Property the clinker crossed in, 12h is reacted under 100 DEG C of condition, taking-up is cooled to room temperature after (30 DEG C) with distilled water flushing several times,
Until washing lotion is in neutrality, it is dried for standby, obtains the clinker that chemical modification is crossed.
(4) bio-modification：By EM bacterium former dew distilled water with 1:The dilution proportion of 100 (volume ratios), after taking 500mL to dilute
EM bacterium bacterium solutions be added in the clinker crossed of chemical modification, the liquid-solid ratio for the clinker that EM bacterium bacterium solution is crossed with chemical modification is 2:1 is (single
Position：ML/g), static biofilm 20h adsorbs clinker to get to reinforcing under room temperature (30 DEG C).
Embodiment 9
In the present embodiment, the preparation method for strengthening absorption clinker, includes the following steps：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) physical modification：The pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-
In wave stove, microwave treatment is carried out with 10% power, processing time is 3min, obtains the clinker that physical modification is crossed.
(3) chemical modification：The NaOH solution of 10mol/L is pressed into liquid-solid ratio 1.2:1 (unit：ML/g physics is added in ratio)
In the clinker being modified, 9h is reacted under 150 DEG C of condition, is taken out after being cooled to room temperature (25 DEG C) with distilled water flushing number
Time, until washing lotion is in neutrality, it is dried for standby, obtains the clinker that chemical modification is crossed.
(4) bio-modification：By EM bacterium former dew distilled water with 5:The dilution proportion of 100 (volume ratios), after taking 750mL to dilute
EM bacterium bacterium solutions be added in the clinker crossed of chemical modification, the liquid-solid ratio for the clinker that EM bacterium bacterium solution is crossed with chemical modification is 3:1 is (single
Position：ML/g), static biofilm 18h adsorbs clinker to get to reinforcing under room temperature (25 DEG C).
Comparative example 1
Physical modification, without chemical modification and bio-modification, the specific step of physical modification are only carried out in this comparative example
Suddenly it is：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) the pretreated g of slag sample of 100g (the coal-fired clinker for being derived from heating boiler) is weighed, is placed in micro-wave oven, with
100% power carries out microwave treatment, and processing time 5min, strengthened absorption clinker.
Comparative example 2
Chemical modification, without physical modification and bio-modification, the specific step of chemical modification are only carried out in this comparative example
Suddenly it is：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) sulfuric acid solution that compound concentration is 50%, by liquid-solid ratio 1:1 (unit：ML/g after ratio) pours into pretreatment
G of slag sample (the coal-fired clinker for being derived from heating boiler) in, 12h is impregnated, in being rinsed repeatedly with distilled water after taking-up and being in washing lotion
Property, dried for standby；Then liquid-solid ratio 1 is pressed:1 (unit：ML/g the FeCl of 2.5mol/L is added in ratio)3Solution is placed in hydro-thermal
It reacts 12h in synthesis reaction vessel under conditions of 110 DEG C, takes out sample and be cooled to room temperature after (25 DEG C) with distilled water flushing number
Time, until washing lotion is in neutrality, it is dried for standby, strengthened absorption clinker.
Comparative example 3
Chemical modification, without physical modification and bio-modification, the specific step of chemical modification are only carried out in this comparative example
Suddenly it is：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) sulfuric acid solution that compound concentration is 50%, according to liquid-solid ratio 1:1 (unit：ML/g) with pretreated clinker
Sample (bottom ash for being derived from circulating fluid bed garbage furnace) mixes, and impregnates 12h, is rinsed repeatedly to washing lotion with distilled water after taking-up
It is in neutrality, drying for standby, strengthened absorption clinker.
Comparative example 4
Chemical modification, without physical modification and bio-modification, the specific step of chemical modification are only carried out in this comparative example
Suddenly it is：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) NaOH solution of 6mol/L is pressed into liquid-solid ratio 1:1 (unit：ML/g pretreated clinker sample is added in ratio)
In product (bottom ash for being derived from circulating fluid bed garbage furnace), 10h is reacted under 120 DEG C of condition, taking-up is cooled to room temperature
After (25 DEG C) several times with distilled water flushing, it until washing lotion is in neutrality, is dried for standby, strengthened absorption clinker.
Comparative example 5
Bio-modification, without physical modification and chemical modification, the specific step of bio-modification are only carried out in this comparative example
Suddenly it is：
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) undercurrent garden wetland sludge base bacterium solutions of the 250mL after sanitary sewage aeration is cultivated 3 days is taken, pretreatment is added
In g of slag sample (the coal-fired clinker for being derived from heating boiler) afterwards, the undercurrent garden wetland after sanitary sewage aeration is cultivated 3 days is dirty
Mud base bacterium solution and the liquid-solid ratio of clinker are 1:1 (unit：ML/g), biofilm is aerated under room temperature (25 DEG C) to inhale to get to reinforcing for 24 hours
Attached clinker.
Comparative example 6
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) it takes on a small quantity through sanitary sewage culture and the Bacillus natto bacterium solution tamed, pretreated g of slag sample is added and (takes
From the coal-fired clinker of heating boiler) in, 250mL sanitary sewages are added, the total amount and clinker of Bacillus natto bacterium solution and sanitary sewage
Liquid-solid ratio is 1:1, unit mL/g are then placed in illumination constant incubator, and biofilm is inhaled to get to reinforcing for 24 hours at 37 DEG C
Attached clinker.
Comparative example 7
(1) it pre-processes：The sundries such as glass, ceramics, brick and tile in clinker are removed, 0.2mm sieves is crossed, takes oversize.
(2) by EM bacterium former dew distilled water with 3:The dilution proportion of 100 (volume ratios), the EM bacterium bacterium after taking 250mL to dilute
Liquid is added in pretreated g of slag sample (bottom ash for being derived from circulating fluid bed garbage furnace), EM bacterium bacterium solution and chemical modification
The liquid-solid ratio for the clinker crossed is 1:1 (unit：ML/g), static biofilm adsorbs stove to get to reinforcing for 24 hours under room temperature (25 DEG C)
Slag.
Clinker is adsorbed respectively to sanitary sewage using each reinforcing of gained in 1-9 of the embodiment of the present invention and comparative example 1-7
It is handled：
Each reinforcing absorption clinker of gained in 1-9 of the embodiment of the present invention and comparative example 1-7 is taken, it is (high to plastic barrel respectively
15cm, diameter 10cm) in press solid-to-liquid ratio 1:3 addition sanitary sewages (are derived from septic tank overflow water outlet), it is ensured that sanitary sewage can
Above-mentioned slag filler is submerged, then measures the content of total nitrogen, total phosphorus and COD every 24 hours difference water samplings.Continuous monitoring, directly
Little to the pollutant concentration variation in water, the results are shown in Table 1.
The index of nitrogen is total nitrogen in sewage (TN) content in sewage, and monitoring method is alkaline chitinase resolution ultraviolet spectrometry
Photometry (GB 11894-89).The index of phosphor in sewage is total phosphorus in sewage (TP) content, and monitoring method is ammonium molybdate light splitting light
Spend meter method (GB 11893-1989).This experiment is measured using rapid-digestion spectrophotometry (HJ/T 399-2007) in water sample
COD (COD).
Treatment effect of 1 present invention gained clinker of table to sanitary sewage
As can be seen from Table 1, obtained reinforcing adsorbs clinker to total in sanitary sewage in 1-9 of the embodiment of the present invention
The removal rate of nitrogen, total phosphorus and COD is above in comparative example 1-7 obtained reinforcing absorption clinker to total nitrogen in sanitary sewage, total
The removal rate of phosphorus and COD, this also illustrates to pass through physical modification, chemical modification and bio-modification in the present invention successively, and what is obtained is strong
Change absorption property of the absorption property higher than the clinker being modified by single method in comparative example of absorption clinker.Cause
This, is improved to the treatment effect of sanitary sewage by the modified clinker of method of the invention.
The reinforcing absorption clinker that the present invention is prepared also can and be applied to soil remediation as adsorbing medium.
From the above it can be seen that the present invention has the following advantages；
(1) present invention strengthens the specific surface area increase of absorption clinker：The present invention makes full use of microwave and strong acid can be to clinker
The characteristics of internal organic matter is decomposed is modified clinker, to make the specific surface area of clinker dramatically increase (about increase by 2~
10 times).
(2) present invention strengthens the ion-exchange capacity enhancing of absorption clinker：After chemical modification, M-OH and O- in modified clinker
H keys are remarkably reinforced.
(3) present invention solves the problems, such as that clinker only relies on physical absorption treated sewage, realizes (special to Pollutants in Wastewater
Not organic pollution) absorption, conversion and degradation：Microorganism is easy growth in slag surface, and biofilm effect is preferable.In waste water
Nitrogen exist substantially in the form of two kinds of organic nitrogen and ammonia nitrogen, organic nitrogen can be decomposed by the microorganisms, be converted into ammonia nitrogen；Organophosphor and phosphorus
Hydrochlorate precipitation is mainly converted by the coordinative role of microorganism, is degraded to soluble phosphate；It is biodegradable in waste water
Organic matter is decomposed by the microorganisms into inorganic salts, carbon dioxide and water；Ammonia nitrogen, soluble phosphate, inorganic salts etc. are adsorbed by clinker
And it is supplied to the microbial nutrition of attachment.
(4) present invention strengthens the saturation time extension of absorption clinker, and adsorption capacity improves：Change by physics, chemistry, biology
Property after, extended by modified clinker adsorption saturation time known to adsorption dynamics adsorption kinetics, adsorption capacity improves.
(5) present invention strengthens absorption clinker and is improved to the treatment effect of sanitary sewage：Nitrogen removal rate can reach
50~80%, the removal rate that total tp removal rate can reach 50~95%, COD can reach 30~92%.
Those of ordinary skills in the art should understand that：The discussion of any of the above embodiment is exemplary only, not
It is intended to imply that the scope of the present disclosure (including claim) is limited to these examples；Under the thinking of the present invention, above example
Or can also be combined between the technical characteristic in different embodiments, step can be realized with random order, and be existed such as
Many other variations of the different aspect of the upper present invention, for simplicity, they are not provided in details.
The embodiment of the present invention be intended to cover fall within the broad range of appended claims it is all it is such replace,
Modifications and variations.Therefore, all within the spirits and principles of the present invention, any omission, modification, equivalent replacement, the improvement made
Deng should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of preparation method for strengthening absorption clinker, which is characterized in that using clinker as raw material, clinker is changed by physics successively
Property, chemical modification and bio-modification be to get adsorbing clinker to strengthening.
2. preparation method according to claim 1, which is characterized in that include the following steps：
(1) physical modification：Clinker is modified using microwave, obtains the clinker that physical modification is crossed；
(2) chemical modification：Acid solution or alkaline solution are added in the clinker that physical modification is crossed, after reaction, are washed till neutrality,
It is dry, obtain the clinker that chemical modification is crossed；
(3) bio-modification：In the clinker crossed of bacterium solution addition chemical modification, the biofilm of clinker will be carried out to get to the reinforcing
Adsorb clinker.
3. preparation method according to claim 2, which is characterized in that in step (1), the condition of the microwave is：With
10~100% microwave power handles 3~8min；
In step (2), the acid solution be sulfuric acid solution, a concentration of the 30~60% of the sulfuric acid solution；The alkalinity
Solution is NaOH solution, and the molar concentration of the NaOH solution is 3~10mol/L.
4. preparation method according to claim 2, which is characterized in that in step (2), acid solution or alkaline solution with
The liquid-solid ratio for the clinker that physical modification is crossed is 1:1~2:1；
When carrying out the chemical modification using acid solution, the time of the reaction is 10~18h, and temperature is room temperature；
When carrying out the chemical modification using alkaline solution, the time of the reaction is 9~12h, and temperature is 110~150 DEG C.
5. preparation method according to claim 4, which is characterized in that in step (2), when using acid solution progress institute
Further include that FeCl is added after stating chemical modification3Solution carries out hydrothermal synthesis reaction, is washed till neutrality, dry step.
6. preparation method according to claim 5, which is characterized in that FeCl3The liquid for the clinker that solution is crossed with physical modification is solid
Than being 1:1~2:1；
The FeCl3The molar concentration of solution is 2.0~3.0mol/L；
The temperature of the hydrothermal synthesis reaction is 100~120 DEG C, and the time of reaction is 10~18h.
7. preparation method according to claim 2, which is characterized in that in step (3), the bacterium solution be EM bacterium bacterium solution,
The Bacillus natto bacterium solution cultivated and tamed or the sludge base bacterium solution through sludge acclimatization culture；
1) when the bacterium solution is EM bacterium bacterium solutions, the liquid-solid ratio for the clinker that the EM bacterium bacterium solution is crossed with chemical modification is 1:1~3:
1, the condition of biofilm is：Static 18~36h of biofilm at normal temperatures；
2) when the bacterium solution is the Bacillus natto bacterium solution cultivated and tamed, the Bacillus natto bacterium solution cultivated and tamed is added
Enter in the clinker that chemical modification is crossed, and sanitary sewage is added and is cultivated, the Bacillus natto bacterium solution cultivated and tamed and life
The liquid-solid ratio for the clinker that the total amount of sewage is crossed with chemical modification is 1:1~3:1, the condition of biofilm is：The biofilm at 30~40 DEG C
18~36h；
3) when the bacterium solution is the sludge base bacterium solution through sludge acclimatization culture, the sludge base bacterium solution through sludge acclimatization culture and change
The liquid-solid ratio for learning the clinker being modified is 1:1~3:1, the condition of biofilm is：18~36h of aeration biofilm at normal temperatures.
8. preparation method according to claim 7, which is characterized in that the sludge base bacterium solution is undercurrent garden wetland, people
Or mixtures thereof one kind in work wetland, natural wetland or the sludge of sewage treatment plant cultivates 2~5 days bacterium solutions through domestication.
9. clinker is adsorbed in the reinforcing that the preparation method described in any one of claim 1 to 8 is prepared.
10. purposes of the reinforcing absorption clinker in the processing of water and soil pollution object described in claim 9.
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| CN110102177B (en) * | 2019-04-09 | 2021-11-26 | 内蒙古阜丰生物科技有限公司 | Process for purifying flue gas generated in guniting granulation |
| CN113060791A (en) * | 2021-04-01 | 2021-07-02 | 昆明理工大学 | Method for treating high-arsenic waste acid by using modified coal slag adsorbent |
| CN113735384A (en) * | 2021-09-24 | 2021-12-03 | 北京嘉博文生物科技有限公司 | Biogas slurry treatment device and biogas slurry treatment method |
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