CN108636144A - A kind of automatic material-absorbing type emulsifying systems - Google Patents

A kind of automatic material-absorbing type emulsifying systems Download PDF

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Publication number
CN108636144A
CN108636144A CN201810548664.XA CN201810548664A CN108636144A CN 108636144 A CN108636144 A CN 108636144A CN 201810548664 A CN201810548664 A CN 201810548664A CN 108636144 A CN108636144 A CN 108636144A
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CN
China
Prior art keywords
emulsifier
powder
high speed
absorbing type
emulsifier unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810548664.XA
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Chinese (zh)
Inventor
覃晓明
黄少清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Golden Milky Way Intelligent Equipment Co Ltd
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Foshan Golden Milky Way Intelligent Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Golden Milky Way Intelligent Equipment Co Ltd filed Critical Foshan Golden Milky Way Intelligent Equipment Co Ltd
Priority to CN201810548664.XA priority Critical patent/CN108636144A/en
Publication of CN108636144A publication Critical patent/CN108636144A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/27Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/717Feed mechanisms characterised by the means for feeding the components to the mixer
    • B01F35/71745Feed mechanisms characterised by the means for feeding the components to the mixer using pneumatic pressure, overpressure, gas or air pressure in a closed receptacle or circuit system

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The present invention discloses a kind of automatic material-absorbing type emulsifying systems, including material cylinder, seal closure, high speed shaft, emulsifier unit and powder feeding device, seal closure is set in material cylinder, high speed shaft is rotatably disposed on seal closure, the rotatable parts of emulsifier unit and high speed axis connection, and rotatable parts are located at emulsifier unit enclosure interior, rotatable parts are connected to powder feeding device, and discharge port is provided in the circumferential side wall of emulsifier unit shell.Automatic material-absorbing type emulsifying systems provided by the invention, the rotatable parts high speed rotation of emulsifier unit is driven by high speed shaft, low pressure can be formed inside emulsifier unit, powder in powder feeding device is sucked through pipeline inside emulsifier unit, last powder material and unclassified stores in emulsifier unit inner cavity by strong shock, it is broken, centrifuge and fly away after extruding, liquid layer friction, strong shear, material is dispersed to each corner of material cylinder with the cycle of whole liquid stream, and then achievees the effect that material rapid dispersion emulsifies.

Description

A kind of automatic material-absorbing type emulsifying systems
Technical field
The present invention relates to chemical equipment technical field, more particularly to a kind of automatic material-absorbing type emulsifying systems.
Background technology
With the continuous social and economic development, mechanical device processing and manufacturing required precision is increasingly improved.
Battery of mobile phone that people use now is all largely lithium battery, and lithium battery has that service life is long, quality is high Advantage, in addition to this, the application of lithium battery in other respects are also very extensive.
Emulsifier unit is mainly used for emulsification, crushing, dissolving, dispersion and the homogeneous of material, be widely used in chemical industry, food, The production of the industries such as pharmacy, daily use chemicals, coating, adhesive, lithium battery slurry has been also applied to emulsifying process, is wanted according to production technology It asks, can generally add the powder body materials such as LiFePO4, graphite, carbon, PVDF in process of production, and existing powder material adds There are two types of methods, and one is in process of production, material cylinder is fallen, by adding required powder body material inside artificial past material cylinder, Such powder material adding method is not only cumbersome, and labor intensity is big, and the powder added is difficult to be sucked into emulsification Device carries out rapid dispersion and emulsification, leads to part powder reuniting, final to influence the slurry quality of production;One is in blender One powder charge door is specially set on seal closure, direct labor is facilitated to feed, but this technical solution is separate still without solving The material dispersion of emulsifier unit, emulsifying technology problem.Therefore, the separate emulsification of the emulsifying process generally existing of lithium battery slurry at present The material of device be difficult to suck and caused by emulsification dead angle and vortex phenomenon, emulsifying materials degree it is inadequate, mixing dispersion and emulsion effect The shortcomings of fruit is bad, and mixing time is longer, and efficiency is low, and energy consumption is excessive.
Therefore, how to provide it is a kind of emulsification without the good and easy to operate emulsifier unit of dead angle, emulsifying effectiveness, be this field skill Art personnel technical problem urgently to be resolved hurrily.
Invention content
The object of the present invention is to provide a kind of automatic material-absorbing type emulsifying systems, can accomplish emulsification without dead angle, and emulsify effect Fruit is good, while easy to operate, can improve the quality of production of emulsifying process and reduce entreprise cost.
In order to solve the above technical problems, the present invention provides a kind of automatic material-absorbing type emulsifying systems, including material cylinder, seal closure, High speed shaft, emulsifier unit and powder feeding device, the seal closure are set in the material cylinder, are rotatably disposed in the sealing In cover, the rotatable parts of the emulsifier unit and the high speed axis connection, and the rotatable parts are located at the emulsifier unit shell Internal portion, the rotatable parts are connected to the powder feeding device, are provided in the circumferential side wall of the emulsifier unit shell Discharge port.
Preferably, the rotatable parts are emulsifier rotor.
Preferably, the emulsifier unit further includes emulsifier stator, and the emulsifier rotor is rotationally embedded in the breast Change in device stator, and emulsification chamber is provided between the emulsifier rotor and the emulsifier stator.
Preferably, the gap between the emulsifier stator and the emulsifier rotor is 0.2mm~2mm.
Preferably, it is provided in the circumferential outer edge of the emulsifier rotor and gets rid of hopper.
Preferably, it is provided with blow tank in the circumferential outer edge of the emulsifier stator.
Preferably, the angles such as hopper that get rid of are uniformly distributed in the circumferential outer edge of the emulsifier rotor, it is described go out The angles such as hopper are uniformly distributed in the circumferential outer edge of the emulsifier stator.
Preferably, the hopper quantity of getting rid of is 1 times~1.5 times of the blow tank quantity.
Preferably, the powder feeding device includes powder loading hopper, ball valve and powder feed pipe, the powder loading hopper Bottom is connected with the powder feed pipe, and the ball valve is set on the powder feed pipe, and the powder feeds pipe end It is connected to the rotatable parts.
Automatic material-absorbing type emulsifying systems provided by the present invention include mainly material cylinder, seal closure, high speed shaft, emulsifier unit And powder feeding device, seal closure are set in material cylinder, high speed shaft around its axial rotation, and can be placed in seal closure, breast Disguise the rotatable parts set and high speed axis connection, and rotatable parts are located at emulsifier unit enclosure interior, rotatable parts add with powder Expect device connection, discharge port is provided in the circumferential side wall of emulsifier unit shell.Automatic material-absorbing type emulsion type provided by the invention System drives the rotatable parts high speed rotation of emulsifier unit by high speed shaft, low pressure can be formed inside emulsifier unit, thus by powder Powder in body feeding device is sucked through pipeline inside emulsifier unit, while the unclassified stores in material cylinder can be also automatically drawn into, most Afterwards powder material and unclassified stores in emulsify chamber by strong shock, it is broken, centrifuge extruding, liquid layer friction, strong shear it After fly away, under the action of a variety of different directions power, generate powerful turbulent flow, material is disperseed with the cycle of whole liquid stream To each corner of material cylinder, and then achieve the effect that material rapid dispersion emulsifies.Since powder material is directly entered breast by pipeline Makeup is set, and thus, there is no emulsification dead angle, the powder material that is added after can making realizes Forced Dispersion emulsification, improve production efficiency with And the batch mixing quality of production.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this The embodiment of invention for those of ordinary skill in the art without creative efforts, can also basis The attached drawing of offer obtains other attached drawings.
Fig. 1 is a kind of overall structure diagram of specific implementation mode provided by the present invention;
Fig. 2 is emulsifier rotor shown in FIG. 1 and emulsifier stator assembled view;
Fig. 3 is the structural schematic diagram of emulsifier rotor shown in Fig. 1;
Fig. 4 is the structural schematic diagram of emulsifier stator shown in Fig. 1.
Wherein, in Fig. 1-Fig. 4:
Material cylinder -1, seal closure -2, high speed shaft -3, emulsifier unit -4, powder feeding device -5, emulsifier rotor - 41, emulsifier stator -42, stator fixed link -43, emulsifier rotor gland -44, chuck -45 gets rid of hopper -411, discharges Slot -421, powder loading hopper -51, ball valve -52, powder feed pipe -53.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Referring to FIG. 1, Fig. 1 is a kind of overall structure diagram of specific implementation mode provided by the present invention.
In a kind of specific implementation mode provided by the present invention, automatic material-absorbing type emulsifying systems include mainly material cylinder 1, close Sealing cover 2, high speed shaft 3, emulsifier unit 4 and powder feeding device 5, seal closure 2 are set in material cylinder 1, and high speed shaft 3 can be around its axial direction It is rotationally embedded on seal closure 2, the rotatable parts of emulsifier unit 4 are connect with high speed shaft 3, and rotatable parts are located at emulsifier unit 4 Enclosure interior, rotatable parts are connected to powder feeding device 5, and discharge port is provided in the circumferential side wall of 4 shell of emulsifier unit.
Wherein, seal closure 2 is set in material cylinder 1, and seal closure 2 and the contact site of material cylinder 1 are sealed with sealing material, are avoided Air enters inside material cylinder 1, and the selection of sealing material can be determined according to user's field condition, not limit herein, with energy Enough ensure that material cylinder 1 cannot enter subject to air;High speed shaft 3 is rotationally embedded in seal closure 2, and the upper end of high speed shaft 3 is rotatable Ground is connected to by modes such as shaft couplings with driving motor on seal closure 2;The rotation axis of 3 lower end of high speed shaft and emulsifier unit 4 Rotatable parts connection, and the rotatable parts of emulsifier unit 4 are located at 4 enclosure interior of emulsifier unit, the circumferential direction of 4 shell of emulsifier unit Discharge port is provided on side wall;Finally, the rotatable parts of emulsifier unit 4 are connected to powder feeding device 5, can suck powder Material, it should be noted that the rotatable parts of emulsifier unit 4 are emulsifier rotor 41.
Specifically, in actual use, high speed shaft 3 drives the operating counterclockwise of 4 high speed of emulsifier unit, emulsifier unit 4 The material of internal cavity is thrown out of to form vacuum area under the influence of centrifugal force, and 4 inner air of emulsifier unit is by pumping shape At forming pressure difference between negative pressure, with powder feeding device 5, ball valve 52 by manually, after pneumatically or electrically flowing mode is opened, powder Material is drawn onto 4 internal cavity of emulsifier unit by powder feed pipe 53, while the unclassified stores in material cylinder 1 can be also automatically drawn into 4 internal cavity of emulsifier unit, last powder material and unclassified stores in 4 internal cavity of emulsifier unit by strong shock, It flies away after broken, centrifugation extruding, liquid layer friction, strong shear, under the action of a variety of different directions power, generates powerful Turbulent flow, material are dispersed to each corner of material cylinder 1 with the cycle of whole liquid stream, and then reach the emulsification of material rapid dispersion Effect, it is ensured that powder material is uniformly dispersed, stirs fully, makes emulsification without dead angle, technological effect is more preferable.Certainly, high speed shaft 3 can To rotate clockwise, the material angle of getting rid of of the stator of emulsifier unit and rotor needs corresponding adjustment at this time.
It please refers to Fig.2, Fig. 3 and Fig. 4, Fig. 2 are emulsifier rotor shown in FIG. 1 and emulsifier stator assembled view;Fig. 3 is The structural schematic diagram of emulsifier rotor shown in Fig. 1;Fig. 4 is the structural schematic diagram of emulsifier stator shown in Fig. 1, arrow table in Fig. 2 Show the direction of motion of material.
Have to optimize automatic material-absorbing type emulsifying systems in above-described embodiment and can preferably make emulsifying materials uniform Advantage, emulsifier unit 4 further include emulsifier stator 42, and emulsifier rotor 41 is rotationally embedded in emulsifier stator 42, and breast Change and be provided with emulsification chamber between device rotor 41 and emulsifier stator 42, and the gap between emulsifier stator and emulsifier rotor exists 0.2mm~2mm chooses, and certain gap size design can be determined according to material situation treating capacity;It should be noted that emulsifier Stator 42 is hollow inverted " u "-shaped cylindrical structure, and circumferentially uniform intervals are equipped with several squares on the lower face of emulsifier stator 42 Shape blow tank 421, and emulsifier stator 42 is fixed in stator fixed link 43, emulsifier stator 42 is set with 3 contact surface of high speed shaft It is equipped with chuck 45;Emulsifier rotor 41 is hollow " u "-shaped cylindrical structure, on 41 upper surface of emulsifier rotor circumferentially uniformly between Every getting rid of hopper 411 equipped with several oblique rectangles, emulsifier rotor 41 is provided with emulsifier rotor gland 44.Emulsifier unit 4 is provided with The design of emulsifier stator 42 and emulsifier rotor 41 can pass through the phase interworking of emulsifier stator 42 and emulsifier rotor 41 It closing, emulsifier rotor 41 can form low pressure in operation between emulsifier stator 42 and emulsifier rotor 41, to Powder in powder feeding device 5 (under 5 opening state of ball valve) is sucked through pipeline inside high speed emulsifier unit 4, while material cylinder 1 Interior unclassified stores can be also automatically drawn into, last powder material and unclassified stores in emulsify chamber by strong shock, be crushed, from It is flown away after heart extruding, liquid layer friction, strong shear, under the action of a variety of different directions power, generates powerful turbulent flow, object Material is dispersed to each corner of material cylinder with the cycle of whole liquid stream, and then achievees the effect that material rapid dispersion emulsifies;By High speed emulsifier unit 4 is directly entered by pipeline in powder material, thus, there is no emulsification dead angle, the powder material added after can making It realizes Forced Dispersion emulsification, improves production efficiency and production quality;Chuck 45 can ensure high speed shaft 3 and emulsifier stator 42 Between sealing effect, make emulsification chamber is inside and outside to be isolated entirely from, ensure that the effect of emulsifying process.
Further, it is provided in the circumferential outer edge of emulsifier rotor 41 and gets rid of hopper 411;The circumferential direction of emulsifier stator 42 Blow tank 421 is provided on outer edge;And get rid of the circumferential outer edge that the angles such as hopper 411 are uniformly distributed in emulsifier rotor 41 On, the equal angles of blow tank 421 are uniformly distributed in the circumferential outer edge of emulsifier stator 42;In addition, it is to get rid of 411 quantity of hopper 1 times of 421 quantity of hopper~1.5 times.It gets rid of hopper 411 and blow tank 421 is all uniformly distributed in the circumferential direction of emulsifier rotor 41 The design of the circumferential outer edge of outer edge and emulsifier stator 42, and 411 quantity of hopper is got rid of as the 1 of 421 quantity of blow tank Times~1.5 times of design, can make powder material be inhaled into more uniformly, powder material and unclassified stores can be made mixedly Evenly, meanwhile, it is more than 421 quantity of blow tank to get rid of hopper 411, and the material mixed can be made preferentially to throw away high speed breast in this way Makeup sets 4, avoids the formation of blocking, emulsifying process can be made better.Meanwhile hopper 411 is got rid of than 421 quantity of blow tank It is more, material can be made to throw away fiercer into hitting, emulsifying process is better.
In addition, powder feeding device 5 includes powder loading hopper 51, ball valve 52 and powder feed pipe 53, powder loading hopper 51 Bottom is connected with powder feed pipe 53, and ball valve 52 is set on powder feed pipe 53,53 end of powder feed pipe with described turn Dynamic component is connected to.Powder feeding device 5 includes the setting of powder loading hopper 51, ball valve 52 and powder feed pipe 53, can make powder Body material is appropriately inhaled into the inner cavity of high speed emulsifier unit 4, and will not largely enter because of powder causes to block, while can To avoid manual operation, full-automatic supply is completed;Ball valve 52 can voluntarily be adjusted according to two-way pressure difference, ensure powder The normal supply of material;Powder loading hopper 51 can make staff predict the scarce material situation of powder material in advance, carry out follow-up Charging.
In conclusion the automatic material-absorbing type emulsifying systems that the present embodiment is provided include mainly material cylinder, seal closure, high speed Axis, emulsifier unit and powder feeding device, seal closure are set in material cylinder, and high speed shaft is rotationally embedded in seal closure, emulsification The rotatable parts of device and high speed axis connection, and rotatable parts are located at emulsifier unit enclosure interior, rotatable parts feed with powder Device is connected to, and discharge port is provided in the circumferential side wall of emulsifier unit shell.Automatic material-absorbing type emulsifying systems provided by the invention, Emulsifier rotor high speed rotation is driven by high speed shaft, low pressure can formed between emulsifier stator and emulsifier rotor, from And suck the powder in powder feeding device inside high speed emulsifier unit through pipeline, while the unclassified stores in material cylinder also can be certainly Dynamic sucking, last powder material and unclassified stores are in emulsify chamber by strong shock, broken, centrifugation extruding, liquid layer friction, by force It is flown away after power shearing, under the action of a variety of different directions power, generates powerful turbulent flow, material is followed with whole liquid stream Ring is dispersed to each corner of material cylinder, and then achievees the effect that material rapid dispersion emulsifies.Since powder material is straight by pipeline It taps into high speed emulsifier unit, thus, there is no emulsification dead angle, the powder material added after can making realizes Forced Dispersion emulsification, carries High efficiency and production quality.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest range caused.

Claims (9)

1. a kind of automatic material-absorbing type emulsifying systems, which is characterized in that including material cylinder (1), seal closure (2), high speed shaft (3), emulsification Device (4) and powder feeding device (5), the seal closure (2) are set in the material cylinder (1), and the high speed shaft (3) is rotatable Ground is placed in the seal closure (2), and the rotatable parts of the emulsifier unit (4) are connect with the high speed shaft (3), and the rotation Component is located at the emulsifier unit (4) enclosure interior, and the rotatable parts are connected to the powder feeding device (5), the breast Disguise and is provided with discharge port in the circumferential side wall for setting (4) shell.
2. automatic material-absorbing type emulsifying systems according to claim 1, which is characterized in that the rotatable parts turn for emulsifier Sub (41).
3. automatic material-absorbing type emulsifying systems according to claim 2, which is characterized in that the emulsifier unit (4) further includes Emulsifier stator (42), the emulsifier rotor (41) is rotationally embedded in the emulsifier stator (42), and the emulsification It is provided with emulsification chamber between device rotor (41) and the emulsifier stator (42).
4. automatic material-absorbing type emulsifying systems according to claim 3, which is characterized in that the emulsifier stator (42) and institute It is 0.2mm~2mm to state the gap between emulsifier rotor (41).
5. automatic material-absorbing type emulsifying systems according to claim 4, which is characterized in that the week of the emulsifier rotor (41) It is provided on outer edge and gets rid of hopper (411).
6. automatic material-absorbing type emulsifying systems according to claim 5, which is characterized in that the week of the emulsifier stator (42) Blow tank (421) is provided on outer edge.
7. automatic material-absorbing type emulsifying systems according to claim 6, which is characterized in that described to get rid of the angles such as hopper (411) It is uniformly distributed in the circumferential outer edge of the emulsifier rotor (41), the angles such as described blow tank (421) are uniformly distributed in institute In the circumferential outer edge for stating emulsifier stator (42).
8. automatic material-absorbing type emulsifying systems according to claim 7, which is characterized in that described hopper (411) quantity of getting rid of is 1 times~1.5 times of blow tank (421) quantity.
9. automatic material-absorbing type emulsifying systems according to claim 1, which is characterized in that powder feeding device (5) packet Include powder loading hopper (51), ball valve (52) and powder feed pipe (53), powder loading hopper (51) bottom and the powder into Expects pipe (53) is connected, and the ball valve (52) is set on the powder feed pipe (53), powder feed pipe (53) end It is connected to the rotatable parts.
CN201810548664.XA 2018-05-31 2018-05-31 A kind of automatic material-absorbing type emulsifying systems Pending CN108636144A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113828179A (en) * 2021-10-29 2021-12-24 浙江博业机械科技有限公司 Multifunctional mixing dispersion machine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102151538A (en) * 2011-02-21 2011-08-17 江南大学 Self-priming reactor for dispersing nano powder
CN103566791A (en) * 2013-11-15 2014-02-12 广州派勒机械设备有限公司 High shear dispersion emulsifying machine
CN207137718U (en) * 2017-08-29 2018-03-27 苏州纳康生物科技有限公司 A kind of homogeneous head for being used to prepare emulsion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102151538A (en) * 2011-02-21 2011-08-17 江南大学 Self-priming reactor for dispersing nano powder
CN103566791A (en) * 2013-11-15 2014-02-12 广州派勒机械设备有限公司 High shear dispersion emulsifying machine
CN207137718U (en) * 2017-08-29 2018-03-27 苏州纳康生物科技有限公司 A kind of homogeneous head for being used to prepare emulsion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113828179A (en) * 2021-10-29 2021-12-24 浙江博业机械科技有限公司 Multifunctional mixing dispersion machine

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Application publication date: 20181012