CN1086269A - Form the treatment process of anti-corrosion film in the metallic surface - Google Patents

Form the treatment process of anti-corrosion film in the metallic surface Download PDF

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Publication number
CN1086269A
CN1086269A CN92112560A CN92112560A CN1086269A CN 1086269 A CN1086269 A CN 1086269A CN 92112560 A CN92112560 A CN 92112560A CN 92112560 A CN92112560 A CN 92112560A CN 1086269 A CN1086269 A CN 1086269A
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Prior art keywords
resin
salt
organic polymer
cationic
metal
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CN92112560A
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Chinese (zh)
Inventor
纪古山
良治森用
仁石井
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Henkel Corp
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Henkel Corp
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Priority to JP03308227A priority Critical patent/JP3139795B2/en
Priority to EP92922276A priority patent/EP0610315A1/en
Priority to BR9206685A priority patent/BR9206685A/en
Priority to PCT/US1992/008811 priority patent/WO1993009265A1/en
Priority to AU28841/92A priority patent/AU2884192A/en
Priority to CA002121486A priority patent/CA2121486A1/en
Priority to MX9206223A priority patent/MX9206223A/en
Application filed by Henkel Corp filed Critical Henkel Corp
Priority to ZA928377A priority patent/ZA928377B/en
Priority to NZ244928A priority patent/NZ244928A/en
Priority to CN92112560A priority patent/CN1086269A/en
Publication of CN1086269A publication Critical patent/CN1086269A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • C23C22/12Orthophosphates containing zinc cations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2301/00Inorganic additives or organic salts thereof
    • B05D2301/10Phosphates, phosphoric acid or organic salts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/51One specific pretreatment, e.g. phosphatation, chromatation, in combination with one specific coating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

One bonderite that contains a kind of cationic organic polymer (or its salt) at metal (as iron, zinc, aluminium, or the like) the high anti-corrosion film of surface formation, this film also is excellent coating substrate lacquer, described cationic organic polymer contains at least one cationic nitrogen-atoms, and molecular weight is 1,000-1,000,000, the resin that this film preferably wherein is made of positively charged ion organic compound (or its salt) infiltrates the crystal boundary of phosphoric acid salt grain, and forms phosphoric acid salt/resin composite body simultaneously.

Description

Form the treatment process of anti-corrosion film in the metallic surface
The present invention relates to a kind of novelty such as iron, zinc, aluminium or the like metallic surface forms the treatment process of strong anti-corrosion film.The coating substrate that this anti-corrosion film also is an excellence.
At present, scribble the object of coating,, need more and more higher solidity to corrosion as car body and building materials.Up to the present, the metallic surface is to adopt phosphoric acid salt, chromate treating.Yet existing metal conditioner does not always show gratifying solidity to corrosion and clagging power.
The prior art that people know is, if with organic membrane, for example, and coating, binding agent, or the like, be coated in metal, for example, iron, zinc on the surface of aluminium or the like, then forms one deck phosphate layer with common applicable pretreatment process on this metallic surface.Using organic coating (being typically coating) before, the method improvement by on the metallic surface, forming one deck phosphate layer solidity to corrosion and clagging power.When requiring higher solidity to corrosion, before applying coating, carry out phosphatizing and aftertreatment (for example, with chromic acid or the like sealing) or use two kinds of processing of priming paint.Yet a less effect is only played in these aftertreatments (for example, with chromic acid or the like sealing).And, although use priming paint to improve the adhesive power of coating, also increased coating processes, therefore in fact damaged operability.
But, use priming paint for the object that scribbles coating for example car body and building materials, still need at present.For car body, form lithoform in the metallic surface, it is immersed in the water soluble paint to form electrodeposited coating then.This coating procedure is a type of primer coating, its objective is the solidity to corrosion on the surface of improving coated coating, and the solidity to corrosion of guaranteeing the car body internal surface, and this car body is difficult to be coated with finishing paint.Before using overlay coating also similarly with the priming paint application in building materials, to improve its solidity to corrosion.
The operating efficiency and the requirement that reduces cost reduce technological process, the exploitation but the gratifying method of this target awaits in applying operation.Therefore, when coating itself does not satisfy requiring of solidity to corrosion and coating adhesive power, only still has relatively poor solidity to corrosion with phosphate layer.When the higher solidity to corrosion of needs, will use phosphate layer and primer coating simultaneously.This has just caused high production cost, and needs bigger work area.Therefore, need exploitation to have the metal conditioner of high anti-corrosion and high coating adhesive power.Simultaneously, also needing to develop can be without the metal conditioner of primer coating.
As solution to the problems described above, the purpose of this invention is to provide a kind of metal conditioner, it can make the metal that is suitable for phosphate layer and handles (for example, iron, zinc, aluminium, or the like slightly be called " metal " down) have high anti-corrosion and a coating adhesive power.Further purpose of the present invention provides a kind of metal conditioner, and it can keep existing solidity to corrosion when having omitted primer coating.
For the result who addresses the above problem the extensive studies of carrying out is, have now found that, bathe film forming with the phosphatizing that contains organic polyhydroxyl compound (or its salt) with some characteristic, can obtain high anti-corrosion and coating adhesive power.The present invention just is being based on this discovery and is developing.
That is to say, anti-corrosion film with above-mentioned higher required character, can form by adopting process metal surfaces, this treatment agent can be in the metallic surface film forming, wherein this treatment agent is characterised in that comprising Bonderisation bathes, it contains this polymkeric substance of cationic organic polymer (or its salt) and contains at least 1 cationic nitrogen atom, and its molecular weight is 1,000-1,000,000 anti-corrosion film of the present invention is composite membrane preferably, and the crystal boundary that the resin that wherein constitutes positively charged ion organic compound (or its salt) has penetrated into phosphoric acid salt crystal grain forms phosphoric acid salt crystal grain/resin composite body simultaneously.
Surface treatment agent of the present invention comprises solution or the stable dispersions of cationic organic polymer in phosphate-treated solution.This phosphatizing is bathed and is comprised that any surface treatment bathes, and it can form the anti-corrosion film of phosphoric acid salt on the surface of metal (as, iron, zinc, aluminium, or the like), both can handle a kind of monomer sample of metal, the surface that also can handle two or more samples of above-mentioned metal simultaneously.Usually, its basal component is zine ion and phosphate anion, but it can contain nitrate ion arbitrarily, other metal ion (nickel, manganese, calcium, or the like), fluorochemical, and various oxygenant.But phosphatizing is bathed and do not make clear and definite qualification in text of the present invention, and the present invention has comprised all known phosphate and handled bath.
Cationic organic polymer must contain at least one cationic nitrogen-atoms, and its molecular weight is 1,000-1,000,000.Though its structure does not limit in the wideest embodiment of the present invention, but, the organic polymer that especially preferably has the resin matrix structure, wherein contain at least a Resins, epoxy that is selected from, urethane resin, polybutadiene, acrylic resin, maleic anhydride resin, wherein, these resins all contain the nitrogen atom group.
The salt of cationic organic polymer comprises its inorganic salt and organic salt, and the example of inorganic salt is as being phosphoric acid salt, nitrate, and vitriol, or the like, the example of organic salt is as being acetate, propionic salt, and gluconate, or the like.Can use the sample of one or both or multiple cationic organic polymer (or its salt).Less than 1,000 o'clock, solidity to corrosion can only obtain less improvement at molecular weight, and surpassed at 1,000,000 o'clock at molecular weight, then was difficult to obtain solution or stable dispersions in the zinc phosphate salt bath.
Further, paint additive (as pigment, or the like), the resin of other kind, activator, or the like also can on the basis of selecting, add.
About the technology of process metal surfaces, the present invention can use transformation processing method, as spraying or dipping, and electrolytic method, all treatment agents among the present invention are not subjected to the restriction of particular treatment method.
Embodiment
Effect of the present invention is carried out detailed explanation by the following examples and comparative example.Yet the present invention is not limited only to embodiment, and present embodiment has only been described typical precoating phosphatizing and typical coating system.In comparative example, with done among the embodiment with embodiment in identical evaluation and processing, but be to use the organic polymer outside the scope of the invention and omitted cationic organic polymer.
The usual conditions of embodiment and comparative example are as follows:
Workpiece: cold-rolled steel sheet; Electroplating steel plate (zinc plated film=20g/m 2); Aluminium sheet (JIS5052).
Surface treatment agent: the polymkeric substance that uses in cationic organic polymer that uses among the embodiment and the comparative example is shown in table 1.PARBOND TML3020 is used for the surface treatment agent of car body, and Japanese phosphatizing company limited produces, and the Bonderisation that is used to not have organic polymer is bathed.This is that a kind of typical phosphates surface treatment is bathed.
Processing sequence:
1) degrease: 2% FINECLEANER TML4460(Japan phosphatizing company limited) solution was in 42 ℃ of hydro-peenings 120 seconds.
2) washing: in room temperature hydro-peening 30 seconds.
3) surface conditioning: 0.1% PARCOLENE TMZN(Japan phosphatizing company limited) solution was in room temperature hydro-peening 20 seconds.
4) surface treatment agent of surface treatment agent of the present invention and comparative example is all used in following condition; Flooded 120 seconds in 42 ℃.
5) washing: in room temperature hydro-peening 30 seconds.
6) washed with de-ionized water (specific conductivity, 0.2 little Siemens/cm) was in room temperature hydro-peening 20 seconds.
After above-mentioned steps is finished,, apply (step of priming is saved sometimes, and institute's following table is described) according to following step drying:
Table 1
The chemical molecular amount of the organic polymer that treatment process adopts
Character
A HN (CH 3) 2With dihydroxyphenyl propane 8,800
The adducts of Resins, epoxy
B methyl methacrylate and methacrylic acid 20,000
The multipolymer of dimethylamino ethyl ester
C H 2NCH 2N(CH 3) 22,000
Adducts with maleic anhydride resin
a H 2NCH 2N(CH 3) 2800
Adducts with maleic anhydride resin
B polyvinyl alcohol 3,000
1) primer coating: galvanic deposit ELECRON TM9410 (Ken Sai (Kansai) coating Co., Ltd. products) are carried out galvanic deposit coated with producing film thickness=20 micron; Baked 30 minutes in 175 ℃.
2) inter coat: KPX36(agree match (Kansai) coating Co., Ltd. and produces); Thickness=30 micron; Baked 30 minutes in 140 ℃.
3) overlay coating: RUGABAKE TMB531(agree match coating Co., Ltd. and produces); Thickness=40 micron; Baked 30 minutes in 140 ℃.
The sample of all embodiment and comparative example is all handled in a like fashion by above-mentioned steps, just the chemical property difference (step 4) of the surface treatment agent that adopts.
Performance evaluation:
1) water-fast second adhesive power: the sheet material that has applied impregnated in the deionized water 240 hours in 40 ℃, and sharp icking tool marks 100 squares, and (chessboard of 2mm * 2mm), cut is to base material.After peeling off with glassine paper, calculate the quantity of being stripped from square.The area of being stripped from is more little, shows that performance is good more.
2) compound cycle test: draw a cross and be deep into base material with sharp-pointed cutting knife in the sheet surface that has applied, then with sheet material by T 1→ T 2Circulation (face as follows) re-treatment 14 times.After the test, measure the width that maximum film bubbling is gone up on a surface, come assess performance thus from cross.
T 1: salt-fog test (JIS Z2371): 24 hours
T 2: wetting test (50 ℃, 70%RH): 216 hours
Table 2,3 and 4 have reported by respectively cold-rolled steel sheet, electroplating steel plate and aluminium sheet carry out the adhesive power and the solidity to corrosion of the coating that surface treatment obtains.These tables have also comprised the experimental result of comparative example.
Test-results shows that compare with phosphatizing, solidity to corrosion and clagging power have suitable raising under the situation that adopts the metal conditioner that is used to form composite membrane of the present invention to handle.Therefore, even omitted primer coating, effect of the present invention also is similar to primer coating coating on phosphate layer.
When the organic polymer that uses not within the scope of the invention, perhaps in fact do not tell on, perhaps its performance has in fact descended.
In sum, the metal conditioner that is used to form composite membrane of the present invention has improved solidity to corrosion and clagging power, and can save primer coating.
Table 2
Figure 921125607_IMG1
Table 3
Figure 921125607_IMG2
Table 4
Figure 921125607_IMG3

Claims (6)

1, the phosphate conversion coating treatment compositions that is used for the metallic surface is characterized in that said composition contains a kind of cationic organic polymer, or the salt of this cationic organic polymer, this polymkeric substance contains at least 1 cationic nitrogen-atoms, and molecular weight is 1,000 to 1,000,000.
2, the phosphate conversion coating treatment compositions of claim 1, wherein cationic organic polymer has a kind of resin matrix structure, and it comprises at least a Resins, epoxy that is selected from, urethane resin, polyhutadiene fat, two olefin(e) acid resins, the resin of maleic anhydride resin.
3, a kind of method that forms protective coating in the metallic surface, this method is that metal is contacted with a kind of phosphate conversion coating solution, it is characterized in that containing in this phosphate conversion coating solution the composition of claim 1 or 2.
4, the method for claim 3, wherein metal is an iron, zinc, or aluminium.
5, the method for claim 4, wherein formed protective coating has composite structure, and the resin that wherein contains positively charged ion organic compound or its salt infiltrates in the crystal boundary of phosphoric acid salt crystal grain.
6, a kind of goods; this system device includes machine protective coating outside surface; be positioned at the intermediate coat of the phosphate ion below organic protectiveness film; with the metal that is positioned under the inter coat; it is characterized in that this inter coat has composite structure, the resin that wherein contains organic polymer with cationic nitrogen atom or its salt infiltrates the crystal boundary of phosphoric acid salt crystal grain.
CN92112560A 1991-10-29 1992-10-29 Form the treatment process of anti-corrosion film in the metallic surface Pending CN1086269A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP03308227A JP3139795B2 (en) 1991-10-29 1991-10-29 Metal surface treatment agent for composite film formation
CA002121486A CA2121486A1 (en) 1991-10-29 1992-10-22 Treatment for the formation of a corrosion resistant film on metal surfaces
BR9206685A BR9206685A (en) 1991-10-29 1992-10-22 Phosphate conversion coating treatment composition for metal surfaces, process for forming a protective coating on a metal, and manufactured product
PCT/US1992/008811 WO1993009265A1 (en) 1991-10-29 1992-10-22 Treatment for the formation of a corrosion resistant film on metal surfaces
AU28841/92A AU2884192A (en) 1991-10-29 1992-10-22 Treatment for the formation of a corrosion resistant film on metal surfaces
EP92922276A EP0610315A1 (en) 1991-10-29 1992-10-22 Treatment for the formation of a corrosion resistant film on metal surfaces
MX9206223A MX9206223A (en) 1991-10-29 1992-10-28 TREATMENT FOR THE FORMATION OF A FILM RESISTANT TO CORROSION ON METAL SURFACES.
ZA928377A ZA928377B (en) 1991-10-29 1992-10-29 Treatment for the formation of a corrosion resistant film on metal surfaces.
NZ244928A NZ244928A (en) 1991-10-29 1992-10-29 Phosphate conversion coatings for metal surfaces, containing an organic polymer which has cationic nitrogens; article of manufacture
CN92112560A CN1086269A (en) 1991-10-29 1992-10-29 Form the treatment process of anti-corrosion film in the metallic surface

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP03308227A JP3139795B2 (en) 1991-10-29 1991-10-29 Metal surface treatment agent for composite film formation
CN92112560A CN1086269A (en) 1991-10-29 1992-10-29 Form the treatment process of anti-corrosion film in the metallic surface

Publications (1)

Publication Number Publication Date
CN1086269A true CN1086269A (en) 1994-05-04

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Country Status (10)

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EP (1) EP0610315A1 (en)
JP (1) JP3139795B2 (en)
CN (1) CN1086269A (en)
AU (1) AU2884192A (en)
BR (1) BR9206685A (en)
CA (1) CA2121486A1 (en)
MX (1) MX9206223A (en)
NZ (1) NZ244928A (en)
WO (1) WO1993009265A1 (en)
ZA (1) ZA928377B (en)

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Publication number Priority date Publication date Assignee Title
CN100532468C (en) * 2002-03-13 2009-08-26 罗狄亚化学公司 Use of block copolymers bearing phosphate group and/or phosphonate radical functional group as adhesion promoters or as protecting agents against the corrosion of a metallic surface

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US5306526A (en) * 1992-04-02 1994-04-26 Ppg Industries, Inc. Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method
JP3193798B2 (en) * 1993-01-13 2001-07-30 日本パーカライジング株式会社 Metal surface treatment liquid for forming composite film for cold working of metal and method for forming composite film
DE4341602A1 (en) * 1993-12-07 1995-06-08 Bayer Ag Use of a polyurethane dispersion as a penetration base and a process for the production of multicoat paint systems
JPH101782A (en) * 1996-06-13 1998-01-06 Nippon Paint Co Ltd Metallic surface treating agent, treatment and surface treated metallic material
JPH1046101A (en) * 1996-08-01 1998-02-17 Nippon Parkerizing Co Ltd Coated metallic material prepared by forming undercoat for film lamination on the surface of metallic material and its production
JPH10182916A (en) * 1996-10-21 1998-07-07 Nippon Paint Co Ltd Metal surface-treating composition containing acrylic resin and containing n-heterocycle, treatment by using the same and treated metal material
WO1998017735A1 (en) 1996-10-21 1998-04-30 Nippon Paint Co., Ltd. Metal surface treatment composition containing acrylic resin, method for treatment, and treated metal materials
FR2769325B1 (en) * 1997-10-08 1999-12-03 Cfpi Ind ACID BATH FOR ZINC PHOSPHATATION OF METAL SUBSTRATES, CONCENTRATE FOR THE PREPARATION OF THE BATH AND PHOSPHATATION METHOD USING THE SAME
US5972433A (en) * 1997-12-05 1999-10-26 Calgon Corporation Method for treatment of metal substrates using Mannich-derived polyethers
JP2008057047A (en) * 2002-06-28 2008-03-13 Jfe Steel Kk Method for producing surface-treated zinc series metal plated steel sheet
EP1433877B1 (en) 2002-12-24 2008-10-22 Chemetall GmbH Pretreatment method for coating
JP4989842B2 (en) * 2002-12-24 2012-08-01 日本ペイント株式会社 Pre-painting method

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GB2159511B (en) * 1984-04-25 1988-09-21 Dearborn Chemicals Ltd A method of inhibiting corrosion in aqueous systems
US4978399A (en) * 1988-01-04 1990-12-18 Kao Corporation Metal surface treatment with an aqueous solution
DE3906898A1 (en) * 1989-03-03 1990-09-06 Henkel Kgaa ZINC-BARIUM PHOSPHATION OF METAL SURFACES
JPH04193957A (en) * 1990-11-28 1992-07-14 Nippon Parkerizing Co Ltd Chromating solution for substrate for clear coat

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100532468C (en) * 2002-03-13 2009-08-26 罗狄亚化学公司 Use of block copolymers bearing phosphate group and/or phosphonate radical functional group as adhesion promoters or as protecting agents against the corrosion of a metallic surface

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WO1993009265A1 (en) 1993-05-13
ZA928377B (en) 1993-05-14
EP0610315A1 (en) 1994-08-17
JP3139795B2 (en) 2001-03-05
CA2121486A1 (en) 1993-05-13
AU2884192A (en) 1993-06-07
NZ244928A (en) 1994-10-26
MX9206223A (en) 1993-11-30
JPH05117869A (en) 1993-05-14
BR9206685A (en) 1995-10-24

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