CN108614216B - Battery health state estimation device and method - Google Patents

Battery health state estimation device and method Download PDF

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CN108614216B
CN108614216B CN201611137322.6A CN201611137322A CN108614216B CN 108614216 B CN108614216 B CN 108614216B CN 201611137322 A CN201611137322 A CN 201611137322A CN 108614216 B CN108614216 B CN 108614216B
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黄崇哲
林博煦
王志荣
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Automotive Research and Testing Center
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Abstract

一种电池健康状态估测装置包含:一个控制模组,在一个电池模组在充电中且充电状态达到一个预设目标值时输出一个控制信号,以致该电池模组的电流改变到一个预设电流值并维持一段预设测试时间;一个校正模组,当接收到该控制信号时,其得到该电池模组在该段预设测试时间中的温度,并据以得到一个电压校正值;及一个估算处理单元,当接收到该控制信号时,其得到该电池模组在该段预设测试时间中的一个电压变化量及一个电流变化量,且根据该电压校正值校正该电压变化量以得到一个电压变化校正值,并根据该电压变化校正值、该电流变化量及一个额定完全充电容量估算一个健康状态。

Figure 201611137322

A battery health status estimation device includes: a control module, which outputs a control signal when a battery module is charging and the charging state reaches a preset target value, so that the current of the battery module changes to a preset current value and maintains it for a preset test time; a correction module, which, when receiving the control signal, obtains the temperature of the battery module during the preset test time and obtains a voltage correction value accordingly; and an estimation processing unit, which, when receiving the control signal, obtains a voltage change and a current change of the battery module during the preset test time, corrects the voltage change according to the voltage correction value to obtain a voltage change correction value, and estimates a health status based on the voltage change correction value, the current change and a rated full charge capacity.

Figure 201611137322

Description

电池健康状态估测装置及方法Battery state of health estimation device and method

技术领域technical field

本发明涉及一种估测装置及方法,特别是涉及一种电池健康状态估测装置及方法。The present invention relates to an estimation device and method, and in particular to a battery state of health estimation device and method.

背景技术Background technique

近年来,随着环保及节能意识的抬头,装设有可充电电池模组的电动车的相关技术蓬勃发展,因此,如何检测电动车内的可充电电池模组的健康状态便为一个研发重点。目前现有电池健康状态估测装置对于可充电电池模组的健康状态的估测方式大致可分为全充放法及内阻法。In recent years, with the rising awareness of environmental protection and energy saving, the related technologies of electric vehicles equipped with rechargeable battery modules have developed vigorously. Therefore, how to detect the health status of rechargeable battery modules in electric vehicles has become a research and development focus. . At present, the methods of estimating the state of health of the rechargeable battery module by the existing battery state of health estimating device can be roughly divided into a full charge-discharge method and an internal resistance method.

然而,全充放法需先将可充电电池模组的电量充饱,再使用特定电流对可充电电池模组进行放电,此方法需耗费大量时间放电才可估测出可充电电池模组的电荷状态及健康状态,且随意对可充电电池模组放电可能引发安全问题。内阻法需提供一个输入电压给可充电电池模组,并通过现有电池健康状态估测装置对该输入电压进行量测与计算,及利用现有电池健康状态估测装置中的一个特殊高频量测仪器(此仪器成本较高)量测可充电电池模组的内阻才可估测出可充电电池模组的健康状态,导致现有电池健康状态估测装置需要花费较高成本。此外,现有电池健康状态估测装置若使用全充放法或内阻法皆需将可充电电池模组拆卸后才能进行估测健康状态,对于使用者极为不便。However, the full charge-discharge method needs to fully charge the rechargeable battery module first, and then discharge the rechargeable battery module with a specific current. state of charge and state of health, and random discharge of rechargeable battery modules may cause safety issues. The internal resistance method needs to provide an input voltage to the rechargeable battery module, and measure and calculate the input voltage through the existing battery state of health estimating device, and use a special high voltage in the existing battery state of health estimating device. Only by measuring the internal resistance of the rechargeable battery module with a frequency measuring instrument (the instrument is relatively expensive), the state of health of the rechargeable battery module can be estimated, which leads to the high cost of the existing battery state of health estimating device. In addition, if the current battery state of health estimating device uses the full charge-discharge method or the internal resistance method, the rechargeable battery module must be disassembled to estimate the state of health, which is extremely inconvenient to the user.

发明内容SUMMARY OF THE INVENTION

本发明的第一目的在于提供一种能够克服先前技术缺点的电池健康状态估测装置。The first objective of the present invention is to provide a battery state of health estimation device that can overcome the shortcomings of the prior art.

本发明的电池健康状态估测装置,适用于估测一个电池模组的一个健康状态,该电池健康状态估测装置包含一个控制模组、一个校正模组及一个估算处理单元。The battery health state estimation device of the present invention is suitable for estimating a health state of a battery module, and the battery health state estimation device includes a control module, a calibration module and an estimation processing unit.

该控制模组在该电池模组在充电中且该电池模组的一个充电状态达到一个预设目标值时,输出一个控制信号,以致该电池模组的一个电流改变到一个预设电流值并维持一段预设测试时间,造成该电池模组的一个电压在该段预设测试时间中下降。The control module outputs a control signal when the battery module is being charged and a charging state of the battery module reaches a preset target value, so that a current of the battery module is changed to a preset current value and Maintaining a predetermined test time, causing a voltage of the battery module to drop during the predetermined test time.

该校正模组电连接该控制模组以接收该控制信号,当接收到该控制信号时,该校正模组得到该电池模组在该段预设测试时间中的一个温度,且根据该温度得到一个电压校正值。The calibration module is electrically connected to the control module to receive the control signal. When receiving the control signal, the calibration module obtains a temperature of the battery module during the preset test period, and obtains the temperature according to the temperature. A voltage correction value.

该估算处理单元电连接该校正模组及该控制模组以分别接收该电压校正值及该控制信号,当接收到该控制信号时,该估算处理单元得到该电池模组在该段预设测试时间中的一个电压变化量及一个电流变化量,且根据该电压校正值校正该电压变化量因受该温度影响而产生的误差,以得到一个电压变化校正值,并根据该电压变化校正值、该电流变化量及该电池模组的一个额定完全充电容量来估算该电池模组的该健康状态。The estimation processing unit is electrically connected to the calibration module and the control module to receive the voltage calibration value and the control signal respectively. When receiving the control signal, the estimation processing unit obtains the battery module in the preset test of the segment A voltage change amount and a current change amount in time, and the error of the voltage change amount due to the influence of the temperature is corrected according to the voltage correction value, so as to obtain a voltage change correction value, and according to the voltage change correction value, The current variation and a rated full charge capacity of the battery module are used to estimate the state of health of the battery module.

本发明的电池健康状态估测装置,该校正模组根据以下方程式来得到该电压校正值:VC=a×(T1-T0)2-b×(T1-T0)+c,VC代表该电压校正值,a、b、c各自代表一个预设常数,T1代表该温度,及T0代表一个预设温度。In the battery state of health estimation device of the present invention, the calibration module obtains the voltage calibration value according to the following equation: V C =a×(T 1 -T 0 ) 2 -b×(T 1 -T 0 )+c, V C represents the voltage correction value, a, b, and c each represent a predetermined constant, T 1 represents the temperature, and T 0 represents a predetermined temperature.

本发明的电池健康状态估测装置,该校正模组根据以下方程式来得到该电压校正值:VC=-d×(T1-T0)+e,VC代表该电压校正值,d、e各自代表一个预设常数,T1代表该温度,及T0代表一个预设温度。In the battery state of health estimation device of the present invention, the calibration module obtains the voltage calibration value according to the following equation: V C =-d×(T 1 -T 0 )+e, V C represents the voltage calibration value, d, e each represents a preset constant, T 1 represents the temperature, and T 0 represents a preset temperature.

本发明的电池健康状态估测装置,该电流变化量为该电池模组在该预设电流值及紧接改变前的该电流间的电流差异,该电压变化量为该电池模组在该预设测试时间的一个起点的电压及该预设测试时间的一个终点的电压间的电压差异。In the battery state of health estimation device of the present invention, the current variation is the current difference between the preset current value of the battery module and the current immediately before the change, and the voltage variation is the battery module at the predetermined current value. Set a voltage difference between a voltage at a starting point of the test time and a voltage at an end point of the preset test time.

本发明的电池健康状态估测装置,该估算处理单元包括:一个处理模组,电连接该校正模组及该控制模组以分别接收该电压校正值及该控制信号,当接收到该控制信号时,该处理模组得到该电压变化量及该电流变化量,且根据该电压校正值校正该电压变化量以得到该电压变化校正值,并根据该电压变化校正值得到该电池模组的一个电流比率;及一个估算模组,电连接该处理模组以接收该电流变化量及该电流比率,并根据该电流比率、该电流变化量及该额定完全充电容量估算该健康状态。In the battery state of health estimation device of the present invention, the estimation processing unit includes: a processing module electrically connected to the calibration module and the control module to receive the voltage calibration value and the control signal respectively, when the control signal is received When , the processing module obtains the voltage variation and the current variation, corrects the voltage variation according to the voltage correction value to obtain the voltage variation correction value, and obtains one of the battery modules according to the voltage variation correction value a current ratio; and an estimation module electrically connected to the processing module to receive the current variation and the current ratio, and estimate the state of health according to the current ratio, the current variation and the rated full charge capacity.

本发明的电池健康状态估测装置,该处理模组将该电压校正值及该电压变化量相加来得到该电压变化校正值,并根据一个描述该电流比率及该电压变化校正值间关系的预设电压映射函式将该电压变化校正值映射成该电流比率。In the battery state of health estimation device of the present invention, the processing module adds the voltage correction value and the voltage change amount to obtain the voltage change correction value, and obtains the voltage change correction value according to a description of the relationship between the current ratio and the voltage change correction value The predetermined voltage mapping function maps the voltage variation correction value to the current ratio.

本发明的电池健康状态估测装置,该估算模组根据以下方程式来估算该健康状态:SOH=[(ΔI/CR)/AH_spec]×100%×K-1,SOH代表该健康状态,ΔI代表该电流变化量,CR代表该电流比率,AH_spec代表该额定完全充电容量,及K-1代表一个预设偏移常数。In the battery state of health estimation device of the present invention, the estimation module estimates the state of health according to the following equation: SOH=[(ΔI/CR)/AH_spec]×100%×K −1 , SOH represents the state of health, and ΔI represents the state of health The current variation, CR represents the current ratio, AH_spec represents the rated full charge capacity, and K -1 represents a preset offset constant.

本发明的电池健康状态估测装置,还包含:一个感测模组,电连接该电池模组、该控制模组、该校正模组及该估算处理单元,并定期地感测该电池模组的一个电压、一个电流、一个充电状态及一个温度,以产生一个指示该电池模组的该电压、该电流、该充电状态及该温度的感测信号,该感测模组将该感测信号输出至该控制模组、该校正模组及该估算处理单元,该校正模组根据该感测信号得到该电池模组在该段预设测试时间中的该温度,且该估算处理单元根据该感测信号得到该电池模组在该段预设测试时间中的该电压变化量及该电流变化量。The battery health state estimation device of the present invention further comprises: a sensing module, electrically connected to the battery module, the control module, the calibration module and the estimation processing unit, and periodically senses the battery module A voltage, a current, a state of charge and a temperature of the battery module to generate a sensing signal indicating the voltage, the current, the state of charge and the temperature of the battery module, the sensing module The sensing signal output to the control module, the calibration module and the estimation processing unit, the calibration module obtains the temperature of the battery module in the preset test time according to the sensing signal, and the estimation processing unit according to the The sensing signal obtains the voltage variation and the current variation of the battery module during the preset test period.

本发明的第二目的在于提供一种能够克服先前技术缺点的电池健康状态估测方法。The second object of the present invention is to provide a battery state of health estimation method that can overcome the shortcomings of the prior art.

本发明的电池健康状态估测方法,适用于估测一个电池模组的一个健康状态,且由一个电池健康状态估测装置所执行,该电池健康状态估测方法包含以下步骤:The battery state of health estimation method of the present invention is suitable for estimating a state of health of a battery module, and is executed by a battery state of health estimation device. The battery state of health estimation method includes the following steps:

(A)利用该电池健康状态估测装置根据一个指示该电池模组的一个温度、一个电流、一个电压及一个充电状态的感测信号,判断该电池模组的该充电状态是否达到一个预设目标值;(A) Using the battery state of health estimating device to determine whether the state of charge of the battery module has reached a preset level according to a sensing signal indicating a temperature, a current, a voltage and a state of charge of the battery module target value;

(B)当步骤(A)的判断结果为是,利用该电池健康状态估测装置输出一个控制信号,以致该电池模组的该电流改变到一个预设电流值并维持一段预设测试时间,造成该电压在该段预设测试时间中下降;(B) when the determination result of step (A) is yes, use the battery state of health estimating device to output a control signal, so that the current of the battery module is changed to a preset current value and maintained for a preset test time, cause the voltage to drop within the preset test time;

(C)利用该电池健康状态估测装置根据该感测信号得到该电池模组在该段预设测试时间中的一个电压变化量及一个电流变化量;(C) using the battery state of health estimating device to obtain a voltage variation and a current variation of the battery module during the preset test period according to the sensing signal;

(D)利用该电池健康状态估测装置根据该感测信号所指示的该电池模组在该段预设测试时间中的温度得到一个电压校正值;及(D) using the battery state of health estimating device to obtain a voltage correction value according to the temperature of the battery module during the predetermined test period indicated by the sensing signal; and

(E)利用该电池健康状态估测装置根据该电压校正值校正该电压变化量因受该温度影响而产生的误差,以得到一个电压变化校正值,并根据该电压变化校正值、该电流变化量及该电池模组的一个额定完全充电容量来估算该电池模组的该健康状态。(E) Using the battery state of health estimating device to correct the error of the voltage variation due to the influence of the temperature according to the voltage correction value, so as to obtain a voltage variation correction value, and according to the voltage variation correction value, the current variation and a rated full charge capacity of the battery module to estimate the state of health of the battery module.

本发明的电池健康状态估测方法,在步骤(D)中,该电池健康状态估测装置根据以下方程式来得到该电压校正值:VC=a×(T1-T0)2-b×(T1-T0)+c,VC代表该电压校正值,a、b、c各自代表一个预设常数,T1代表该温度,及T0代表一个预设温度。In the battery state of health estimation method of the present invention, in step (D), the battery state of health estimation device obtains the voltage correction value according to the following equation: V C =a×(T 1 -T 0 ) 2 -b× (T 1 -T 0 )+c, VC represents the voltage correction value, a, b, c each represent a predetermined constant, T 1 represents the temperature, and T 0 represents a predetermined temperature.

本发明的电池健康状态估测方法,在步骤(D)中,该电池健康状态估测装置根据以下方程式来得到该电压校正值:VC=-d×(T1-T0)+e,VC代表该电压校正值,d、e各自代表一个预设常数,T1代表该温度,及T0代表一个预设温度。In the battery state of health estimation method of the present invention, in step (D), the battery state of health estimation device obtains the voltage correction value according to the following equation: V C =-d×(T 1 -T 0 )+e, V C represents the voltage correction value, d and e each represent a predetermined constant, T 1 represents the temperature, and T 0 represents a predetermined temperature.

本发明的电池健康状态估测方法,步骤(E)包括以下子步骤:(E1)利用该电池健康状态估测装置将该电压校正值及该电压变化量相加来得到该电压变化校正值,并根据一个预设电压映射函式将该电压变化校正值映射成一个电流比率;及(E2)利用该电池健康状态估测装置根据该电流比率、该电流变化量及该额定完全充电容量估算该健康状态。In the battery state of health estimation method of the present invention, step (E) includes the following sub-steps: (E1) using the battery state of health estimation device to add the voltage correction value and the voltage change amount to obtain the voltage change correction value, and mapping the voltage variation correction value into a current ratio according to a predetermined voltage mapping function; and (E2) using the battery state of health estimating device to estimate the current ratio, the current variation and the rated full charge capacity health status.

本发明的电池健康状态估测方法,在子步骤(E2)中,该电池健康状态估测装置根据以下方程式来估算该健康状态:SOH=[(ΔI/CR)/AH_spec]×100%×K-1,SOH代表该健康状态,ΔI代表该电流变化量,CR代表该电流比率,AH_spec代表该额定完全充电容量,及K-1代表一个预设偏移常数。In the battery state of health estimation method of the present invention, in sub-step (E2), the battery state of health estimation device estimates the state of health according to the following equation: SOH=[(ΔI/CR)/AH_spec]×100%×K -1 , SOH represents the state of health, ΔI represents the current variation, CR represents the current ratio, AH_spec represents the rated full charge capacity, and K -1 represents a preset offset constant.

本发明的有益的效果在于:通过该控制模组在该电池模组在充电时启动该电池模组的电流的改变,且不需耗费大量时间对该电池模组进行放电,可防止随意对该电池模组放电可能引发的安全问题,且通过利用该校正模组校正该电压变化量因受不同温度影响而产生的误差后,可使该估算处理单元所估测到的该健康状态的准确度有效提升。The beneficial effect of the present invention is that: the control module starts the change of the current of the battery module when the battery module is being charged, and does not need to spend a lot of time to discharge the battery module, which can prevent the random Safety problems that may be caused by the discharge of the battery module, and after correcting the error of the voltage variation due to the influence of different temperatures by using the calibration module, the accuracy of the state of health estimated by the estimation processing unit can be improved. Effective promotion.

附图说明Description of drawings

图1是一个方块图,说明本发明电池健康状态估测装置的实施例与一个电池模组一起使用;FIG. 1 is a block diagram illustrating an embodiment of the battery state of health estimating device of the present invention for use with a battery module;

图2是一个时序图,说明该电池模组的电压与电流;FIG. 2 is a timing diagram illustrating the voltage and current of the battery module;

图3与图4是一个流程图,说明该实施例的该电池健康状态估测装置执行一种电池健康状态估测方法以估测该电池模组的一个健康状态;FIG. 3 and FIG. 4 are a flowchart illustrating that the battery state of health estimating apparatus of the embodiment executes a battery state of health estimating method to estimate a state of health of the battery module;

图5是一个量测图,说明该实施例有执行该电池健康状态估测方法的健康状态误差率对循环寿命的变化;及FIG. 5 is a measurement graph illustrating the variation of the state-of-health error rate on cycle life with the implementation of the battery state-of-health estimation method of the embodiment; and FIG.

图6是一个量测图,说明该实施例没有执行该电池健康状态估测方法的健康状态误差率对循环寿命的变化。FIG. 6 is a measurement graph illustrating the variation of state-of-health error rate versus cycle life for this embodiment without implementing the battery state-of-health estimation method.

具体实施方式Detailed ways

参阅图1与图2,本发明电池健康状态估测装置1的实施例适用于安装在一个载具2中。该载具2包括一个充电模组21、一个电池模组22、一个显示模组23及其它必要元件(图未示)。该电池模组22电连接该充电模组21。该充电模组21用于接收一个交流电源,且将该交流电源转成直流电源并提供给该电池模组22以对该电池模组22进行充电。该充电模组21可操作以调整提供给该电池模组22的直流电源的电量多寡,以改变流过该电池模组22的电流。需说明的是,该载具2可以是纯电动车或复合(hybrid)电动车,且可以呈例如机车、汽车或巴士的形式。Referring to FIG. 1 and FIG. 2 , the embodiment of the battery state of health estimating device 1 of the present invention is suitable for being installed in a carrier 2 . The carrier 2 includes a charging module 21 , a battery module 22 , a display module 23 and other necessary components (not shown). The battery module 22 is electrically connected to the charging module 21 . The charging module 21 is used to receive an AC power source, convert the AC power source into a DC power source, and provide the battery module 22 to charge the battery module 22 . The charging module 21 is operable to adjust the amount of DC power supplied to the battery module 22 to vary the current flowing through the battery module 22 . It should be noted that the vehicle 2 may be a pure electric vehicle or a hybrid electric vehicle, and may be in the form of, for example, a locomotive, a car or a bus.

本实施例的该电池健康状态估测装置1适用于估测该电池模组22的一个健康状态(state of health,SOH)。需说明的是,该健康状态是该电池模组22状况相比于其理想状况的品质因数,且该健康状态的单位是百分比(100%=该电池模组22状况匹配电池规格)。通常,由于该电池模组22的该健康状态理想上在制造出来时为100%,且随着时间及使用而下降。在本实施例中,该电池健康状态估测装置1包含一个控制模组11、一个校正模组12、一个估算处理单元13及一个感测模组14。The battery state of health estimation apparatus 1 of this embodiment is suitable for estimating a state of health (SOH) of the battery module 22 . It should be noted that the state of health is the quality factor of the state of the battery module 22 compared to its ideal state, and the unit of the state of health is a percentage (100%=the state of the battery module 22 matches the battery specification). Typically, the state of health due to the battery module 22 is ideally 100% as manufactured, and declines with time and use. In this embodiment, the battery state of health estimation device 1 includes a control module 11 , a calibration module 12 , an estimation processing unit 13 and a sensing module 14 .

该感测模组14电连接该电池模组22,且定期地(例如连续地)感测该电池模组22的一个电压、一个电流、一个充电状态(state of charge,SOC)及一个温度,以产生一个指示该电池模组的该电压、该电流、该充电状态及该温度的感测信号。The sensing module 14 is electrically connected to the battery module 22, and periodically (eg, continuously) senses a voltage, a current, a state of charge (SOC) and a temperature of the battery module 22, to generate a sensing signal indicating the voltage, the current, the state of charge and the temperature of the battery module.

该控制模组11适用于电连接该充电模组21及该感测模组14,且接收来自该感测模组14的该感测信号。该控制模组11在根据该感测信号所指示的该电池模组22的该电流及该充电状态判断出该电池模组22在充电中且该电池模组22的该充电状态达到一个预设目标值时,输出一个控制信号到该充电模组21,以致该充电模组21改变流过该电池模组22的该电流到一个预设电流值It并维持一段预设测试时间Tt。改变流过该电池模块22的电流为该预设电流值It,使得该电池模组22的该电流的改变并造成该电池模组22的该电压在该段预设测试时间Tt中下降。需说明的是,该预设目标值较佳地在一个从70%到80%的范围内,且在本实施例中是70%。此外,对于该控制信号的不同例子而言,该预设电流值It可以相同或不同。对于该预设电流值It而言,该预设电流值It可以为零,从而该电池模组22既不是在充电中也不是在放电中,即该电池模组22不是在使用中。或者,该预设电流值It可以使得该电池模组22维持在充电中,或使得该电池模组22维持在放电中。The control module 11 is suitable for electrically connecting the charging module 21 and the sensing module 14 and receiving the sensing signal from the sensing module 14 . The control module 11 determines that the battery module 22 is being charged and the charging state of the battery module 22 reaches a preset value according to the current and the charging state of the battery module 22 indicated by the sensing signal. When the target value is reached, a control signal is output to the charging module 21 so that the charging module 21 changes the current flowing through the battery module 22 to a predetermined current value It and maintains a predetermined test time Tt. Changing the current flowing through the battery module 22 to the preset current value It makes the current of the battery module 22 change and causes the voltage of the battery module 22 to drop during the preset test time Tt. It should be noted that the preset target value is preferably in a range from 70% to 80%, and in this embodiment, it is 70%. In addition, for different examples of the control signal, the preset current value It may be the same or different. For the preset current value It, the preset current value It may be zero, so that the battery module 22 is neither in charging nor discharging, that is, the battery module 22 is not in use. Alternatively, the preset current value It can keep the battery module 22 in charging, or can keep the battery module 22 in discharging.

该校正模组12电连接该控制模组11以接收该控制信号,且适用于电连接该感测模组14以接收该感测信号。当接收到该控制信号时,该校正模组12根据该感测信号所指示的该电池模组22的温度,得到该电池模组22在该段预设测试时间中的温度,且根据此温度得到一个电压校正值。需说明的是,该电池模组22在该段预设测试时间Tt中的温度变化很小,因此该电池模组22在该段预设测试时间Tt中的任一个时点被感测到的温度都可以用来得到该电压校正值。The calibration module 12 is electrically connected to the control module 11 to receive the control signal, and is adapted to be electrically connected to the sensing module 14 to receive the sensing signal. When receiving the control signal, the calibration module 12 obtains the temperature of the battery module 22 during the preset test period according to the temperature of the battery module 22 indicated by the sensing signal, and according to the temperature Get a voltage correction value. It should be noted that the temperature change of the battery module 22 during the preset test time Tt is very small, so the temperature of the battery module 22 is sensed at any point in the preset test time Tt. Temperature can be used to derive this voltage correction value.

在本实施例中,该校正模组12根据以下方程式(1)来得到该电压校正值:In this embodiment, the calibration module 12 obtains the voltage calibration value according to the following equation (1):

VC=a×(T1-T0)2-b×(T1-T0)+c 方程式(1),V C =a×(T 1 -T 0 ) 2 -b×(T 1 -T 0 )+c Equation (1),

VC代表该电压校正值,a、b、c各自代表一个预设常数,T1代表该电池模组22在该段预设测试时间中的温度,且T0代表一个预设温度,该预设温度T0相关于下述方程式(3)建立时的预设温度,例如25度。所述预设常数a、b、c会受该电池模组22的该充电状态影响而有不同。举例来说,当该充电状态等于70%时,预设常数a等于2×10-5,预设常数b等于0.0022,预设常数c等于0.0825,因此VC=2×10-5×(T1-T0)2-0.0022×(T1-T0)+0.0825。当该充电状态等于80%时,预设常数a等于3×10-5,预设常数b等于0.0024,预设常数c等于0.0881,因此VC=3×10-5×(T1-T0)2-0.0024×(T1-T0)+0.0881。V C represents the voltage correction value, a, b, c each represent a preset constant, T 1 represents the temperature of the battery module 22 during the preset test time, and T 0 represents a preset temperature, the preset temperature Let the temperature T 0 be related to the preset temperature when the following equation (3) is established, for example, 25 degrees. The preset constants a, b, and c are different depending on the state of charge of the battery module 22 . For example, when the state of charge is equal to 70%, the preset constant a is equal to 2×10 −5 , the preset constant b is equal to 0.0022, and the preset constant c is equal to 0.0825, so V C =2×10 −5 ×(T 1 -T 0 ) 2 -0.0022×(T 1 -T 0 )+0.0825. When the state of charge is equal to 80%, the preset constant a is equal to 3×10 −5 , the preset constant b is equal to 0.0024, and the preset constant c is equal to 0.0881, so V C =3×10 −5 ×(T 1 −T 0 ) 2 -0.0024×(T 1 -T 0 )+0.0881.

值得注意的是,在其它实施例中,可以将本发明的方程式(1)改用方程式(2)来取代以得到该电压校正值,然而以方程式(1)所获得的该电压校正值较为精准。在此情况中,方程式(2)如下:It should be noted that, in other embodiments, equation (1) of the present invention can be replaced by equation (2) to obtain the voltage correction value, but the voltage correction value obtained by equation (1) is more accurate . In this case, equation (2) is as follows:

VC=-d×(T1-T0)+e 方程式(2),V C =-d×(T 1 -T 0 )+e equation (2),

VC、T1、T0的定义与方程式(1)同,d、e各自代表一个预设常数。当该充电状态等于70%或80%时,预设常数d等于0.0008,而预设常数e会受该电池模组22的该充电状态影响而有不同。举例来说,当该充电状态等于70%时,预设常数e等于0.0629,因此VC=-0.0008×(T1-T0)+0.0629。当该充电状态等于80%时,预设常数e等于0.0667,因此VC=-0.0008×(T1-T0)+0.0667。The definitions of V C , T 1 , and T 0 are the same as those of equation (1), and d and e each represent a preset constant. When the state of charge is equal to 70% or 80%, the preset constant d is equal to 0.0008, and the preset constant e varies depending on the state of charge of the battery module 22 . For example, when the state of charge is equal to 70%, the default constant e is equal to 0.0629, so V C =-0.0008×(T 1 −T 0 )+0.0629. When the state of charge is equal to 80%, the preset constant e is equal to 0.0667, so V C =-0.0008×(T 1 −T 0 )+0.0667.

该估算处理单元13电连接该校正模组12及该控制模组11以分别接收该电压校正值VC及该控制信号,且适用于电连接该感测模组14以接收该感测信号。在本实施例中,该估算处理单元13包括一个处理模组131及一个估算模组132。The estimation processing unit 13 is electrically connected to the calibration module 12 and the control module 11 to receive the voltage correction value V C and the control signal respectively, and is adapted to be electrically connected to the sensing module 14 to receive the sensing signal. In this embodiment, the estimation processing unit 13 includes a processing module 131 and an estimation module 132 .

该处理模组131电连接该校正模组12及该控制模组11以分别接收该电压校正值VC及该控制信号,且适用于电连接该感测模组14以接收该感测信号。当接收到该控制信号时,该处理模组131执行以下动作:(1)根据该感测信号所指示的该电池模组22的该电压,得到该电池模组22在该段预设测试时间中的一个电压变化量ΔV;(2)根据该感测信号所指示的该电池模组22的该电流及该预设电流值It,得到该电池模组22在该段预设测试时间中的一个电流变化量ΔI;(3)根据该电压校正值VC校正该电压变化量ΔV因受该温度T1影响而产生的误差,以得到一个电压变化校正值ΔV’;及(4)根据一个描述该电池模组22的一个电流比率(C rate)及该电压变化校正值ΔV’间关系的预设电压映射函式,将该电池模组22的该电压变化校正值ΔV’映射成该电池模组22的该电流比率。需说明的是,该电压变化量ΔV为该电池模组22在该预设测试时间Tt的一个起点t1的电压V1及该预设测试时间Tt的一个终点t2的电压V2间的电压差异(即,V1-V2)。该电流变化量ΔI为该电池模组22在该预设电流值It及紧接改变前的该电流(即,紧接该预设测试时间Tt的该起点t1前所对应的电流)间的电流差异。该电流比率用来表示该电池模组22充放电时电流大小的比率。The processing module 131 is electrically connected to the calibration module 12 and the control module 11 to receive the voltage correction value V C and the control signal respectively, and is adapted to be electrically connected to the sensing module 14 to receive the sensing signal. When receiving the control signal, the processing module 131 performs the following actions: (1) According to the voltage of the battery module 22 indicated by the sensing signal, obtain the preset test time of the battery module 22 in the segment A voltage variation ΔV in the a current variation ΔI; (3) correcting the error of the voltage variation ΔV due to the influence of the temperature T1 according to the voltage correction value VC to obtain a voltage variation correction value ΔV'; and (4) according to a description A preset voltage mapping function of the relationship between a current ratio (C rate) of the battery module 22 and the voltage variation correction value ΔV', mapping the voltage variation correction value ΔV' of the battery module 22 to the battery module This current ratio for group 22. It should be noted that the voltage variation ΔV is the voltage difference between the voltage V1 of the battery module 22 at a starting point t1 of the preset test time Tt and the voltage V2 at an end point t2 of the preset test time Tt (ie, , V1-V2). The current variation ΔI is the current of the battery module 22 between the preset current value It and the current immediately before the change (ie, the current corresponding to the current immediately before the starting point t1 of the preset test time Tt). difference. The current ratio is used to represent the ratio of the magnitude of the current when the battery module 22 is charged and discharged.

在本实施例中,该处理模组131将该电压校正值VC及该电压变化量ΔV相加来得到该电压变化校正值ΔV’(即,ΔV’=VC+ΔV)。该预设电压映射函式表示为,例如,CR=a’×ΔV’+b’,CR代表该电池模组22的该电流比率,且a’及b’是预设常数。该预设电压映射函式可以从与该电池模组22相关联的量测结果推导出。In this embodiment, the processing module 131 adds the voltage correction value VC and the voltage variation ΔV to obtain the voltage variation correction value ΔV' (ie, ΔV'= VC +ΔV). The predetermined voltage mapping function is expressed as, for example, CR=a'×ΔV'+b', CR represents the current ratio of the battery module 22 , and a' and b' are predetermined constants. The predetermined voltage mapping function can be derived from measurement results associated with the battery module 22 .

该估算模组132电连接该处理模组131以接收该电流变化量ΔI及该电流比率CR,且适用于电连接该感测模组14以接收该感测信号,及适用于电连接该显示模组23。该估算模组132根据相关于该电压变化校正值ΔV’的该电流比率CR、该电流变化量ΔI及一个额定完全充电容量来估算该电池模组22的该健康状态,且将该健康状态输出至该显示模组23,以显示在该显示模组23上。The estimation module 132 is electrically connected to the processing module 131 to receive the current variation ΔI and the current ratio CR, and is adapted to be electrically connected to the sensing module 14 to receive the sensing signal, and adapted to be electrically connected to the display Module 23. The estimation module 132 estimates the state of health of the battery module 22 according to the current ratio CR, the current change amount ΔI and a rated full charge capacity relative to the voltage change correction value ΔV', and outputs the state of health to the display module 23 to be displayed on the display module 23 .

在本实施例中,该估算模组132根据以下方程式(3)来估算该电池模组22的该健康状态:In this embodiment, the estimation module 132 estimates the state of health of the battery module 22 according to the following equation (3):

SOH=[(ΔI/CR)/AH_spec]×100%×K-1 方程式(3),SOH=[(ΔI/CR)/AH_spec]×100%×K -1 Equation (3),

SOH代表该电池模组22的该健康状态,AH_spec代表该电池模组22的该额定完全充电容量,且K-1代表一个预设偏移常数。该电池模组22的该额定完全充电容量可以从该电池模组22的规格书中得知。SOH represents the state of health of the battery module 22 , AH_spec represents the rated full charge capacity of the battery module 22 , and K −1 represents a preset offset constant. The rated full charge capacity of the battery module 22 can be known from the specification of the battery module 22 .

参阅图3及图4,其说明该电池健康状态估测装置1执行一种电池健康状态估测方法以估测该电池模组22的健康状态。操作时,先利用该感测模组14感测该电池模组22的温度、电流、电压及充电状态以产生该感测信号(即,步骤30)。接着,该电池健康状态估测装置1再执行该电池健康状态估测方法以估测该电池模组22的该健康状态。最后,利用该显示模组23显示该健康状态(即,步骤36)。在本实施例中,该电池健康状态估测方法包含以下步骤:Referring to FIG. 3 and FIG. 4 , it is illustrated that the battery state of health estimation apparatus 1 executes a battery state of health estimation method to estimate the state of health of the battery module 22 . During operation, the sensing module 14 is used to sense the temperature, current, voltage and charging state of the battery module 22 to generate the sensing signal (ie, step 30 ). Next, the battery state of health estimation apparatus 1 executes the battery state of health estimation method to estimate the state of health of the battery module 22 . Finally, the health status is displayed using the display module 23 (ie, step 36). In this embodiment, the battery state of health estimation method includes the following steps:

步骤31:利用该电池健康状态估测装置1中的该控制模组11来根据该感测信号判断该电池模组22的该充电状态是否达到该预设目标值。若是,则进行步骤32;若否,则进行步骤30。Step 31 : Use the control module 11 in the battery state of health estimating device 1 to determine whether the charging state of the battery module 22 reaches the preset target value according to the sensing signal. If yes, go to step 32; if not, go to step 30.

步骤32:利用该电池健康状态估测装置1中的该控制模组11输出该控制信号,以致该电池模组22的该电流改变到该预设电流值It并维持该段预设测试时间Tt,且电池模组22的电流改变为该预设电流值It,不仅使得该电流改变并造成该电池模组22的该电压在该段预设测试时间Tt中下降。Step 32: Use the control module 11 in the battery state of health estimation device 1 to output the control signal, so that the current of the battery module 22 changes to the preset current value It and maintains the preset test time Tt , and the current of the battery module 22 is changed to the preset current value It, which not only makes the current change but also causes the voltage of the battery module 22 to drop during the preset test time Tt.

步骤33:利用该电池健康状态估测装置1中的该处理模组131根据该感测信号得到该电池模组22在该段预设测试时间Tt中的该电压变化量ΔV及该电流变化量ΔI。Step 33: Using the processing module 131 in the battery state of health estimation device 1 to obtain the voltage variation ΔV and the current variation of the battery module 22 during the preset test time Tt according to the sensing signal ΔI.

步骤34:利用该电池健康状态估测装置1中的该校正模组12根据该感测信号所指示的该电池模组22在该段预设测试时间Tt中的温度得到该电压校正值VCStep 34: Using the calibration module 12 in the battery state of health estimating device 1 to obtain the voltage calibration value V C according to the temperature of the battery module 22 in the preset test time Tt indicated by the sensing signal .

步骤35:利用该电池健康状态估测装置1中的该估算处理单元13根据该电压校正值VC校正该电压变化量ΔV因受该温度影响而产生的误差,以得到该电压变化校正值ΔV’,并根据该电压变化校正值ΔV’、该电流变化量ΔI及该电池模组22的该额定完全充电容量来估算该电池模组22的该健康状态。Step 35: Use the estimation processing unit 13 in the battery state of health estimation device 1 to correct the error of the voltage variation ΔV due to the influence of the temperature according to the voltage correction value VC , so as to obtain the voltage variation correction value ΔV ', and the state of health of the battery module 22 is estimated according to the voltage change correction value ΔV', the current change amount ΔI and the rated full charge capacity of the battery module 22 .

需说明的是,在步骤35中,还进一步包含子步骤351、352的细部流程。It should be noted that, in step 35, the detailed flow of sub-steps 351 and 352 is further included.

子步骤351:利用该电池健康状态估测装置1中的该处理模组131将该电压校正值VC及该电压变化量ΔV相加来得到该电压变化校正值ΔV’,并根据该预设电压映射函式将该电压变化校正值ΔV’映射成该电流比率。Sub-step 351: Use the processing module 131 in the battery state of health estimating device 1 to add the voltage correction value VC and the voltage variation ΔV to obtain the voltage variation correction value ΔV', and according to the preset The voltage mapping function maps the voltage variation correction value ΔV' to the current ratio.

子步骤352:利用该电池健康状态估测装置1中的该估算模组132根据该电流比率、该电流变化量ΔI及该额定完全充电容量来估算该健康状态。Sub-step 352: Use the estimation module 132 in the battery state of health estimation device 1 to estimate the state of health according to the current ratio, the current variation ΔI and the rated full charge capacity.

参阅图5及图6,图5说明该电池健康状态估测装置1有利用该校正模组12校正该电压变化量ΔV因受该温度影响而产生的误差后的量测结果,图6说明没有利用该校正模组12校正该电压变化量ΔV后的量测结果。健康状态误差率定义为将该电池模组22实际去放电而得到的健康状态(实测值)减掉本发明根据方程式(3)得到的该健康状态(理论值)。循环寿命一次的定义是指该电池模组22从完全充饱电的电池放电至电池截止电压。Referring to FIG. 5 and FIG. 6 , FIG. 5 illustrates the measurement result of the battery state of health estimating device 1 using the calibration module 12 to correct the error of the voltage variation ΔV due to the influence of the temperature, and FIG. 6 illustrates the measurement result without The measurement result after correcting the voltage variation ΔV by the correcting module 12 . The state of health error rate is defined as the state of health (measured value) obtained by actually de-discharging the battery module 22 minus the state of health (theoretical value) obtained by the present invention according to equation (3). The definition of one cycle life means that the battery module 22 is discharged from a fully charged battery to a battery cut-off voltage.

由图5可知,有校正该电压变化量ΔV后,健康状态误差率的最大值为4.23%,健康状态误差率的最小值为-0.86%,进而得到健康状态误差率的误差范围为5.09%(即,4.23%-(-0.86%)=5.09%)。此外,平均误差率为2.59%。由图6可知,没有校正该电压变化量ΔV后,健康状态误差率的最大值为6.44%,健康状态误差率的最小值为-0.81%,进而得到健康状态误差率的误差范围为7.25%(即,6.44%-(-0.81%)=7.25%)。此外,平均误差率为3.66%。也就是说,当该电池健康状态估测装置1有利用该校正模组12校正该电压变化量ΔV后,其估测到的该电池模组22的该健康状态更加准确,使得健康状态误差率的误差范围、平均误差率、健康状态误差率的最大值及最小值皆会减少。It can be seen from Figure 5 that after correcting the voltage variation ΔV, the maximum value of the error rate of the state of health is 4.23%, and the minimum value of the error rate of the state of health is -0.86%, and the error range of the error rate of the state of health is 5.09% ( That is, 4.23%-(-0.86%)=5.09%). Furthermore, the average error rate is 2.59%. It can be seen from Figure 6 that after the voltage variation ΔV is not corrected, the maximum value of the error rate of the state of health is 6.44%, and the minimum value of the error rate of the state of health is -0.81%, and the error range of the error rate of the state of health is 7.25% ( That is, 6.44%-(-0.81%)=7.25%). Furthermore, the average error rate is 3.66%. That is to say, when the battery state of health estimating device 1 uses the calibration module 12 to correct the voltage variation ΔV, the estimated state of health of the battery module 22 is more accurate, so that the state of health error rate is increased. The error range, the average error rate, and the maximum and minimum values of the state of health error rate are reduced.

综上所述,上述本实施例具有以下优点:To sum up, the above-mentioned present embodiment has the following advantages:

1.由于本发明该电池健康状态估测装置1可在该电池模组22在充电中时估测该电池模组22的该健康状态,而不需如现有需将可充电电池模组拆卸后才能进行健康状态的估测,因此便于使用者使用。1. Since the battery state of health estimating device 1 of the present invention can estimate the state of health of the battery module 22 when the battery module 22 is being charged, it is not necessary to disassemble the rechargeable battery module as in the prior art The health status can only be estimated after that, so it is convenient for users to use.

2.由于本发明该电池健康状态估测装置1不需耗费大量时间对该电池模组22进行放电即可估测出该电池模组22的该健康状态,可防止随意对该电池模组22放电可能引发的安全问题。2. Since the battery state of health estimation device 1 of the present invention can estimate the state of health of the battery module 22 without spending a lot of time to discharge the battery module 22, it can prevent the battery module 22 from being arbitrarily Safety issues that may arise from discharge.

3.由于本发明该电池健康状态估测装置1是在该电池模组22在充电时启动该充电模组21改变该电池模组22的电流,使的该电池模组22的电压跟着改变,接着利用该校正模组12校正该电池模组22的该电压变化量ΔV以进一步根据上述方程式(3)来得到该电池模组22的该健康状态,所以本发明该电池健康状态估测装置1不需如现有电池健康状态估测装置需使用特殊高频量测仪器量测可充电电池模组的内阻才可估测出可充电电池模组的健康状态。因此,本发明该电池健康状态估测装置1相较于现有电池健康状态估测装置可降低制造成本。3. Since the battery state of health estimating device 1 of the present invention activates the charging module 21 to change the current of the battery module 22 when the battery module 22 is being charged, the voltage of the battery module 22 changes accordingly, Then, the voltage variation ΔV of the battery module 22 is calibrated by the calibration module 12 to obtain the state of health of the battery module 22 according to the above equation (3). Therefore, the battery state of health estimation device 1 of the present invention The state of health of the rechargeable battery module can be estimated without using a special high-frequency measuring instrument to measure the internal resistance of the rechargeable battery module as in the existing battery state of health estimating device. Therefore, the battery state of health estimating device 1 of the present invention can reduce the manufacturing cost compared with the existing battery state of health estimating device.

4.由于该电池模组22在不同温度条件下有不同的活性会造成其本身的电压响应有误差,以致该处理模组131所得到的该电压变化量ΔV跟着也有误差,进而影响估测到的该电池模组22的该健康状态的准确度。因此,本发明该电池健康状态估测装置1通过利用该校正模组12校正该电压变化量ΔV因受不同温度影响而产生的误差后,可使得其所估测到的该电池模组22的该健康状态的准确度有效提升。4. Since the battery module 22 has different activities under different temperature conditions, it will cause an error in its own voltage response, so that the voltage variation ΔV obtained by the processing module 131 also has an error, which further affects the estimated value. The accuracy of the state of health of the battery module 22 . Therefore, the battery state of health estimating device 1 of the present invention can correct the error of the voltage variation ΔV caused by the influence of different temperatures by using the calibration module 12, so that the estimated value of the battery module 22 can be adjusted. The accuracy of this health status is effectively improved.

以上所述者,仅为本发明的实施例而已,当不能以此限定本发明实施的范围,即凡依本发明权利要求书及说明书内容所作的简单的等效变化与修饰,皆仍属本发明的范围。The above are only examples of the present invention, and should not limit the scope of the present invention, that is, any simple equivalent changes and modifications made according to the claims of the present invention and the contents of the description still belong to the present invention. scope of invention.

Claims (13)

1. A battery state of health estimation device is applicable to estimating a state of health of a battery module, and is characterized in that: the battery health state estimation device comprises:
a control module, outputting a control signal when the battery module is in charge and a charge state of the battery module reaches a preset target value, so that a current of the battery module changes to a preset current value and maintains for a preset test time, and a voltage of the battery module is reduced in the preset test time;
the correction module is electrically connected with the control module to receive the control signal, and when the control signal is received, the correction module obtains a temperature of the battery module in the preset test time and obtains a voltage correction value according to the temperature; and
and the estimation processing unit is electrically connected with the correction module and the control module to respectively receive the voltage correction value and the control signal, when the control signal is received, the estimation processing unit obtains a voltage variation and a current variation of the battery module in the preset test time, corrects an error of the voltage variation caused by the influence of the temperature according to the voltage correction value to obtain a voltage variation correction value, and estimates the health state of the battery module according to the voltage variation correction value, the current variation and a rated full charge capacity of the battery module.
2. The battery state of health estimation device of claim 1, wherein: the correction module obtains the voltage correction value according to the following equation:
VC=a×(T1-T0)2-b×(T1-T0)+c,
VCrepresenting the voltage correction value, a, b, c each representing a predetermined constant, T1Represents the temperature, and T0Representing a preset temperature.
3. The battery state of health estimation device of claim 1, wherein: the correction module obtains the voltage correction value according to the following equation:
VC=-d×(T1-T0)+e,
VCrepresenting the voltage correction value, d, e each representing a predetermined constant, T1Represents the temperature, and T0Representing a preset temperature.
4. The battery state of health estimation device of claim 1, wherein: the current variation is a current difference between the preset current value and the current immediately before the change, and the voltage variation is a voltage difference between a voltage of the battery module at a starting point of the preset test time and a voltage at an end point of the preset test time.
5. The battery state of health estimation device of claim 1, wherein: the estimation processing unit includes:
the processing module is electrically connected with the correction module and the control module to respectively receive the voltage correction value and the control signal, and when the control signal is received, the processing module obtains the voltage variation and the current variation, corrects the voltage variation according to the voltage correction value to obtain the voltage variation correction value, and obtains a current ratio of the battery module according to the voltage variation correction value; and
and the estimation module is electrically connected with the processing module to receive the current variation and the current ratio and estimate the health state according to the current ratio, the current variation and the rated full charge capacity.
6. The battery state of health estimation device of claim 5, wherein: the processing module adds the voltage correction value and the voltage variation to obtain the voltage variation correction value, and maps the voltage variation correction value to the current ratio according to a preset voltage mapping function describing the relationship between the current ratio and the voltage variation correction value.
7. The battery state of health estimation device of claim 5, wherein: the estimation module estimates the health state according to the following equation:
SOH=[(ΔI/CR)/AH_spec]×100%×K-1
SOH represents the state of health, Δ I represents the amount of change in the current, CR represents the current ratio, AH _ spec represents the rated full charge capacity, and K-1Representing a predetermined offset constant.
8. The battery state of health estimation device of claim 1, wherein: the battery health state estimation device further comprises:
the sensing module is electrically connected with the battery module, the control module, the correction module and the estimation processing unit and is used for periodically sensing a voltage, a current, a charging state and a temperature of the battery module so as to generate a sensing signal indicating the voltage, the current, the charging state and the temperature of the battery module, the sensing module outputs the sensing signal to the control module, the correction module and the estimation processing unit, the correction module obtains the temperature of the battery module in the preset testing time according to the sensing signal, and the estimation processing unit obtains the voltage variation and the current variation of the battery module in the preset testing time according to the sensing signal.
9. A battery health state estimation method is suitable for estimating a health state of a battery module and is executed by a battery health state estimation device, and is characterized in that: the battery health state estimation method comprises the following steps:
(A) judging whether the charging state of the battery module reaches a preset target value or not by using the battery health state estimation device according to a sensing signal indicating the temperature, the current, the voltage and the charging state of the battery module;
(B) if the judgment result in the step (A) is yes, outputting a control signal by using the battery health state estimation device, so that the current of the battery module is changed to a preset current value and is maintained for a preset test time, and the voltage is reduced in the preset test time;
(C) obtaining a voltage variation and a current variation of the battery module in the preset testing time by using the battery health state estimation device according to the sensing signal;
(D) obtaining a voltage correction value by using the battery health state estimation device according to the temperature of the battery module in the preset test time indicated by the sensing signal; and
(E) and correcting the error of the voltage variation caused by the temperature influence by using the battery health state estimation device according to the voltage correction value to obtain a voltage variation correction value, and estimating the health state of the battery module according to the voltage variation correction value, the current variation and a rated full charge capacity of the battery module.
10. The battery state of health estimation method of claim 9, wherein: in step (D), the battery state of health estimation device obtains the voltage correction value according to the following equation:
VC=a×(T1-T0)2-b×(T1-T0)+c,
VCrepresenting the voltage correction value, a, b, c each representing a predetermined constant, T1Represents the temperature, and T0Representing a preset temperature.
11. The battery state of health estimation method of claim 9, wherein: in step (D), the battery state of health estimation device obtains the voltage correction value according to the following equation:
VC=-d×(T1-T0)+e,
VCrepresenting the voltage correction value, d, e each representing a predetermined constant, T1Represents the temperature, and T0Representing a preset temperature.
12. The battery state of health estimation method of claim 9, wherein: step (E) comprises the sub-steps of:
(E1) adding the voltage correction value and the voltage variation by using the battery health state estimation device to obtain the voltage variation correction value, and mapping the voltage variation correction value into a current ratio according to a preset voltage mapping function; and
(E2) and estimating the state of health by using the battery state of health estimation device according to the current ratio, the current variation and the rated full charge capacity.
13. The battery state of health estimation method of claim 12, wherein: in sub-step (E2), the battery state of health estimation device estimates the state of health according to the following equation:
SOH=[(ΔI/CR)/AH_spec]×100%×K-1
SOH represents the state of health, Δ I represents the amount of change in the current, CR represents the current ratio, AH _ spec represents the rated full charge capacity, and K-1Representing a predetermined offset constant.
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