CN108612924A - A kind of fuel charger anti-static rubber tube and preparation method - Google Patents

A kind of fuel charger anti-static rubber tube and preparation method Download PDF

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Publication number
CN108612924A
CN108612924A CN201611131385.0A CN201611131385A CN108612924A CN 108612924 A CN108612924 A CN 108612924A CN 201611131385 A CN201611131385 A CN 201611131385A CN 108612924 A CN108612924 A CN 108612924A
Authority
CN
China
Prior art keywords
carbon black
fuel charger
rubber tube
layer
static rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611131385.0A
Other languages
Chinese (zh)
Inventor
修德欣
蒲鹤
丁莉丽
王振中
张健中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
Original Assignee
China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Qingdao Safety Engineering Institute filed Critical China Petroleum and Chemical Corp
Priority to CN201611131385.0A priority Critical patent/CN108612924A/en
Publication of CN108612924A publication Critical patent/CN108612924A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00Hoses, i.e. flexible pipes
    • F16L11/04Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L11/08Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

The present invention relates to antistatic aids, specifically fuel charger anti-static rubber tube and preparation method.A kind of fuel charger anti-static rubber tube, is followed successively by antistatic backing, inner glue layer, braiding layer and outer glue-line from the inside to the outside.The fuel charger anti-static rubber tube of the present invention has the advantages that compared with prior art:Carbon black PTFE antistatic backings are increased on the basis of common sebific duct, antistatic backing has the characteristics that not adhere to, it is small to rub, and it is added to the conductive nano carbon black materials after dispersion, effectively increase the static conductive ability of internal layer, it can electrify to avoid oil product, and effectively guide already present electrostatic charge of oil charge.

Description

A kind of fuel charger anti-static rubber tube and preparation method
Technical field
The present invention relates to antistatic aids, specifically fuel charger anti-static rubber tube and preparation method.
Background technology
In fuel charger refueling process, fuel oil is pumped out from sunken tankers, flow through buried pipeline, fuel charger gut line, The components such as filter, flowmeter, petroleum vapor recovery regulating valve, sebific duct and refueling nozzle, during fuel flow in these equipment Wall friction will produce electrostatic, especially nonmetal structure, such as filter and sebific duct.
The electrostatic risk of fuel charger is that gas station needs the security risk paid close attention to, but is advised in previous Safety of Gas Station In fixed, antistatic more focuses on the ground connection of equipment and releasing for static electricity on human body, smaller to the concern of electrostatic charge of oil.Actually work as oil When between case mouth and refueling nozzle without forming effectively bridging, oil product charge density is higher in refueling process, can be exported in refueling nozzle Place forms potential difference, generates static discharge phenomenon.
Under increasing operated pressure, there is an urgent need to the means such as improve oiling flow velocity and refuel in emptying for gas station The sales volume in the unit interval is improved, these demands also propose stern challenge to the electrostatic safety of gas station.
Steel wire braid is all usually added in current fuel charger sebific duct, improves anti-rolling performance, while reinforcing hose is led Electrically.A kind of " the fuel charger sebific duct for carrying braiding layer " is elaborated if ZL201320349221.0, such hose assembly is usual Resistance is in 4 Ω hereinafter, the conducting of fuel-servicing equipment can be realized effectively.But in refueling process, oil product and steel wire braid are not It is in direct contact, sebific duct internal layer is usually nitrile rubber, and the electric conductivity and antistatic property of interior glue are poor, the oil that can still flow through Product are rubbed to carry a large amount of charges.
Invention content
In order to solve the problems, such as to easy to produce a large amount of electrostatic in existing fuel charger sebific duct, the present invention is at sebific duct using anti- Electrostatic designs can effectively reduce the charge density for flowing through sebific duct oil product, prevent the generation of electric discharge phenomena, can effective guarantee add The safety of oily process lays the foundation the technological means such as to increase oiling flow velocity and refueling in emptying.
The present invention solve its technical problem the technical solution adopted is that:A kind of fuel charger anti-static rubber tube, from the inside to the outside according to Secondary is antistatic backing, inner glue layer, braiding layer and outer glue-line.
The antistatic backing is formed by adding nano carbon black powder in base PTFE.
The present invention also provides a kind of preparation method of fuel charger anti-static rubber tube simultaneously, and this approach includes the following steps:
(1)Carbon black powder is disperseed using polyurethane ball-milling pot zirconium oxide balls, Ball-milling Time 20-24 hours, ball milling turns Speed is 8000-11000r/min, system pH 7-9, obtains stable carbon black slurry;
(2)Carbon black slurry is added in PTFE emulsion, carbon black additive amount is 1.5-2.0wt%, and stirring at low speed obtains stable carbon black PTFE mixed liquors;
(3)Extrusion aid is added into mixed liquor, using paste extrusion molding, squeezes out PTFE layers of carbon black, i.e. antistatic backing;
(4)Inner glue layer is processed in mixer, is squeezed out and is coated on antistatic backing;
(5)By braider, braiding layer is coated in inner glue layer outer wall;
(6)Outer glue-line is processed in mixer, is squeezed out and is coated in braiding layer;
(7)Vulcanizing treatment is carried out to pipe, curing temperature is 150-160 DEG C, vulcanization time 100-110min.
The fuel charger anti-static rubber tube of the present invention has the advantages that compared with prior art:In common sebific duct On the basis of increase carbon black PTFE antistatic backings, antistatic backing has the characteristics that not adhere to, it is small to rub, and after being added to dispersion Conductive nano carbon black materials effectively increase the static conductive ability of internal layer, can electrify to avoid oil product, and effectively guide existing Electrostatic charge of oil charge.The preparation method step of the present invention is simple, technical maturity.
Description of the drawings
Fig. 1 is the structural schematic diagram of the fuel charger anti-static rubber tube of the present invention.
Specific implementation mode
As shown in Figure 1, the fuel charger anti-static rubber tube of the present invention, is followed successively by carbon black PTFE antistatic backings 1, interior from the inside to the outside Glue-line 2, braiding layer 3, outer glue-line 4.Inner glue layer material is nitrile rubber, and outer glue-line is neoprene, braiding layer using steel wire and Fiber shuffling.
The fuel charger anti-static rubber tube of the present invention, is prepared by following steps:
(1)Carbon black powder is disperseed using polyurethane ball-milling pot zirconium oxide balls, Ball-milling Time 22 hours, rotational speed of ball-mill is 9000r/min, system pH 8 obtain stable carbon black slurry;
(2)Carbon black slurry is added in PTFE emulsion, carbon black additive amount is 1.7wt%, and stirring at low speed obtains stable carbon black PTFE Mixed liquor;
(3)Extrusion aid is added into mixed liquor, using paste extrusion molding, squeezes out PTFE layers of carbon black, i.e. antistatic backing;
(4)Inner glue layer is processed in mixer, is squeezed out and is coated on antistatic backing;
(5)By braider, braiding layer is coated in inner glue layer outer wall;
(6)Outer glue-line is processed in mixer, is squeezed out and is coated in braiding layer;
(7)Vulcanizing treatment is carried out to pipe, curing temperature is 150 DEG C, vulcanization time 100min.
The fuel charger anti-static rubber tube of the present invention, antistatic backing is using the polytetrafluoroethylene (PTFE) for adding conductive nano carbon powder PTFE material, PTFE have surface tension minimum in solid material, do not adhere to any substance, can reduce in oil product and sebific duct Frictional force when wall contacts.Meanwhile the addition of carbon black improves the electric conductivity of internal layer, can be improved using conductive nano carbon black Dispersibility of the conductive black in PTFE, the electric conductivity of material can be effectively improved by adding a small amount of carbon black, avoid excessive addition Material property caused by carbon black reduces and poor processability.

Claims (3)

1. a kind of fuel charger anti-static rubber tube, it is characterised in that:Be followed successively by from the inside to the outside antistatic backing, inner glue layer, braiding layer and Outer glue-line.
2. fuel charger anti-static rubber tube according to claim 1, it is characterised in that:The antistatic backing is by base It adds nano carbon black powder in layer PTFE and is formed.
3. a kind of preparation method of fuel charger anti-static rubber tube, it is characterised in that:This approach includes the following steps:
(1)Carbon black powder is disperseed using polyurethane ball-milling pot zirconium oxide balls, Ball-milling Time 20-24 hours, ball milling turns Speed is 8000-11000r/min, system pH 7-9, obtains stable carbon black slurry;
(2)Carbon black slurry is added in PTFE emulsion, carbon black additive amount is 1.5-2.0wt%, and stirring at low speed obtains stable carbon black PTFE mixed liquors;
(3)Extrusion aid is added into mixed liquor, using paste extrusion molding, squeezes out PTFE layers of carbon black, i.e. antistatic backing;
(4)Inner glue layer is processed in mixer, is squeezed out and is coated on antistatic backing;
(5)By braider, braiding layer is coated in inner glue layer outer wall;
(6)Outer glue-line is processed in mixer, is squeezed out and is coated in braiding layer;
(7)Vulcanizing treatment is carried out to pipe, curing temperature is 150-160 DEG C, vulcanization time 100-110min.
CN201611131385.0A 2016-12-09 2016-12-09 A kind of fuel charger anti-static rubber tube and preparation method Pending CN108612924A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611131385.0A CN108612924A (en) 2016-12-09 2016-12-09 A kind of fuel charger anti-static rubber tube and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611131385.0A CN108612924A (en) 2016-12-09 2016-12-09 A kind of fuel charger anti-static rubber tube and preparation method

Publications (1)

Publication Number Publication Date
CN108612924A true CN108612924A (en) 2018-10-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611131385.0A Pending CN108612924A (en) 2016-12-09 2016-12-09 A kind of fuel charger anti-static rubber tube and preparation method

Country Status (1)

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CN (1) CN108612924A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113154144A (en) * 2020-12-28 2021-07-23 苏州华仁科技有限公司 HRS silicone tube and 52+ -5-degree weaving process thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7445030B2 (en) * 2003-10-17 2008-11-04 Technip France Flexible tubular pipe, especially for oil production, having a PTFE winding
CN202640737U (en) * 2012-07-13 2013-01-02 董过房 Polytetrafluoroethylene paste extruder
CN203131241U (en) * 2013-03-26 2013-08-14 赵炜 Antistatic anticorrosion pipeline
CN103836275A (en) * 2014-02-26 2014-06-04 无锡二橡胶股份有限公司 Ethylene propylene diene monomer (EPDM) environment-friendly rubber tube and manufacturing method thereof
CN203718183U (en) * 2013-06-18 2014-07-16 中国石油化工股份有限公司 Refueling machine rubber pipe with knitted layer
CN105001801A (en) * 2015-08-25 2015-10-28 安徽省元琛环保科技有限公司 High-temperature resistant conductive polytetrafluoroethylene hot melting adhesive tape and production method thereof
CN105126649A (en) * 2015-08-25 2015-12-09 安徽省元琛环保科技有限公司 Preparation method for fireproof antistatic polytetrafluoroethylene film

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7445030B2 (en) * 2003-10-17 2008-11-04 Technip France Flexible tubular pipe, especially for oil production, having a PTFE winding
CN202640737U (en) * 2012-07-13 2013-01-02 董过房 Polytetrafluoroethylene paste extruder
CN203131241U (en) * 2013-03-26 2013-08-14 赵炜 Antistatic anticorrosion pipeline
CN203718183U (en) * 2013-06-18 2014-07-16 中国石油化工股份有限公司 Refueling machine rubber pipe with knitted layer
CN103836275A (en) * 2014-02-26 2014-06-04 无锡二橡胶股份有限公司 Ethylene propylene diene monomer (EPDM) environment-friendly rubber tube and manufacturing method thereof
CN105001801A (en) * 2015-08-25 2015-10-28 安徽省元琛环保科技有限公司 High-temperature resistant conductive polytetrafluoroethylene hot melting adhesive tape and production method thereof
CN105126649A (en) * 2015-08-25 2015-12-09 安徽省元琛环保科技有限公司 Preparation method for fireproof antistatic polytetrafluoroethylene film

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
凌玲等: "纳米导电炭黑防静电PTFE涂层的研究", 《上海涂料》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113154144A (en) * 2020-12-28 2021-07-23 苏州华仁科技有限公司 HRS silicone tube and 52+ -5-degree weaving process thereof

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Application publication date: 20181002