CN108609877A - Cure the method that landfill body prepares clinker using shale gas drilling well solid waste - Google Patents
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste Download PDFInfo
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- CN108609877A CN108609877A CN201810940892.1A CN201810940892A CN108609877A CN 108609877 A CN108609877 A CN 108609877A CN 201810940892 A CN201810940892 A CN 201810940892A CN 108609877 A CN108609877 A CN 108609877A
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- clinker
- solid waste
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- shale gas
- slurry
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/345—Hydraulic cements not provided for in one of the groups C04B7/02 - C04B7/34
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/30—Cements from oil shales, residues or waste other than slag from oil shale; from oil shale residues ; from lignite processing, e.g. using certain lignite fractions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/44—Burning; Melting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The present invention relates to a kind of preparation methods of clinker, cure the method that landfill body prepares clinker in particular with shale gas drilling well solid waste.Including dispensing, cement slurry processed, producing cement clinker, there are 30~75 parts by weight of shale gas drilling well solid waste solidification landfill body, 10~35 parts by weight of diatomite, 10~35 parts by weight of oyster shell whiting, 1~5 parts by weight of sulfate slag in dispensing.The present invention can utilize shale gas drilling well solid waste solidification landfill body to prepare qualified clinker, to realize the recycling of shale gas drilling well solid waste.
Description
Technical field
The present invention relates to a kind of preparation methods of clinker, cure landfill system in particular with shale gas drilling well solid waste
The method of standby clinker.
Background technology
Generate a large amount of drilling well solid waste in shale gas drilling process, including well drilling detritus, discarded slurry, waste water flocculating body and
Other wastes, ingredient are mainly a variety of stable state colloids of the compositions such as clay, drilling cuttings, sewage, chemical treatment regimens and sump oil
Suspension system, harmful components are complicated.At present for shale gas drilling well solid waste, the disposal options generally used are in well site wastewater disposal basin
In solidification landfill stabilization directly carried out by curing agent, which is simple and practicable.Such as Chongqing City's shale gas first stage of the project, two
Lime-ash after water base drilling cuttings, waste water-base mud and the sewage sludge of over one hundred mouthful of well, oil-based drill cuttings de-oiling takes cement solidification
Landfill stabilization, about more than 200, solidification landfill pond, floor space is wide.As it can be seen that the disposal options of solidification landfill occupy a large amount of soil
Ground resource, and this kind of disposal options also have larger security risk.For example Sichuan puguang gas field is leaked because of pond body, no
It obtains not dig out the solid waste of landfill solidification landfill body all and remarket.Current national requirements for environmental protection dynamics increasingly increases, state
Shale gas solid waste is cured landfill body and carries out comprehensive resource profit by gesture high pressure in order to meet increasingly strict environmental protection requirement
With being current and developing direction from now on and trend.
At the same time, the especially traditional construction material industry of the building materials industry in China is that natural mineral resource and energy consumption are high
Industry, 5,000,000,000 tons of various resources will be consumed by producing various construction materials every year, consume 2.3 hundred million tons of standard coals of the energy, give resource
White elephant is brought with environment, cement production enterprise requires own existence and development, it is necessary to establish and contribute for environmental protection
Thought economizes on resources, is energy saving, turning waste into wealth, and makes single cement production enterprise, is transformed into the enterprise of comprehensive utilization of resources
Industry.
It is well known that cement kiln has the characteristics that burning furnace temperature height and processing inventory are big, and cement plant is equipped with
A large amount of environmental protection facility is the strong equipment of the self-purification ability of enviroment.Solid waste is handled using cement rotary kiln, not only has and burns
The volume reduction of method, minimizing feature, and the residue after burning becomes a part for clinker, need not be carried out to burning ash secondary
Processing, is a kind of recycling treatment approach to make the best of both worlds.
Cure the solid waste such as landfill body using shale gas drilling well solid waste and produce clinker, both widens raw material
Source reduces the consumption of a large amount of natural resources, greatly reduces the cost of manufacture of cement, and protects natural environment, is conducive to
Sustainable Development of Cement Industry;Currently, directly curing the side that landfill body does raw material for producing cement chamotte with shale gas drilling well solid waste
Case yet there are no document report.
Invention content
Curing the method that landfill body prepares clinker using shale gas drilling well solid waste the object of the present invention is to provide a kind of,
Shale gas drilling well solid waste solidification landfill body can be utilized to prepare qualified clinker, to realize the money of shale gas drilling well solid waste
Sourceization utilizes.
It is of the present invention to cure the method that landfill body prepares clinker, including following step using shale gas drilling well solid waste
Suddenly:
(1) dispensing:30~75 parts by weight of shale gas drilling well solid waste solidification landfill body, 10~35 parts by weight of diatomite, shell
10~35 parts by weight of powder, 1~5 parts by weight of sulfate slag;
(2) cement slurry processed:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 5~15mm, silicon
Diatomaceous earth is broken into the particle that grain size is 5~15mm, and raw mill is entered together with sulfate slag, and it is more than 53~75 μm of square hole screens to obtain grain size
In 8~15% cement slurry;
(3) producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;
It is slurry more than 53~75 μm of square hole screens 8~15% that oyster shell whiting, which is shell through wet ball grinding into grain size, and oyster shell whiting slurry is aqueous
Rate is 60~80%, and oyster shell whiting slurry is pumped in rotary kiln, is calcined together with the material in rotary kiln, temperature 1300~
1700 DEG C, 35~50 minutes time is to get clinker.
The diatomite is a kind of pure natural nonmetallic mineral, is gradually formed by Diatomeae remains in ocean or lake
Sedimentary rock.
The oyster shell whiting be by scallop shell or/and snail shell through wet ball grinding at slurry.
The oyster shell whiting slurry is pumped to rotary kiln by helicoidal pump, then enters in rotary kiln from rotary kiln.
Since the temperature of rotary kiln is higher than the temperature of rotary kiln end, oyster shell whiting slurry enters rotary kiln from rotary kiln
In can play the role of drying oyster shell whiting slurry.
The grain size of the sulfate slag is 0.1~5mm.
The shale gas drilling well solid waste solidification landfill body is using inorganic silicate reinforcing agent, coagulant, gel breaker, absorption
After agent and pH adjusting agent carry out curing process to shale gas drilling well solid waste, the solids with certain compression strength and water resistance.
I.e. by curing agent --- inorganic silicate reinforcing agent, coagulant, gel breaker, adsorbent and pH adjusting agent and shale gas drilling well solid waste
After carrying out uniform stirring mixed processing, compressive strength of solidified body and leachate meet petrochina company standard《Drilling wastes
Innoxious process for treating specification》Related requirement in QSY XN 0276-2015.
Inorganic silicate reinforcing agent in the curing agent can be portland cement, and coagulant can be CaO, and gel breaker can be
FeCl3, adsorbent can be flyash, and pH adjusting agent can be (NH4)2SO4, and the content of each component is in curing agent:Inorganic silicon
135~155 parts by weight of hydrochlorate reinforcing agent, 60~70 parts by weight of coagulant, 3~7 parts by weight of gel breaker, 65~75 weight of adsorbent
Part, 9~15 parts by weight of pH adjusting agent;When curing process, the addition of curing agent in the shale gas drilling well solid waste per kilostere
It is 280~320 tons.
The beneficial effects of the invention are as follows:
1, the present invention cures landfill body as primary raw material, so as to avoid shale as a result of shale gas drilling well solid waste
Pneumatic drill well solid waste cures landfill stabilization occupying and waste to soil, thoroughly solves shale gas drilling well solid waste solidification landfill stabilization
Existing Environmental security hidden danger afterwards, and secondary pollution, ring will not be caused using the method for the present invention production clinker in the process
Protect remarkable benefit.
2, the present invention realizes clinker production to limited nature since the raw materials such as lime stone, clay, shale are not used
Zero consumption of resource promotes " no pollution, zero power consumption, zero-emission, zero consumption and the negative increasing of solid waste of the production of cement industry enterprise
Length " is implemented, and resource circulation utilization and green ecological cement production, remarkable in economical benefits are realized.
3, the present invention can facilitate using existing dry-process rotary kiln production line equipment and technology, and operability is strong, be conducive to cement and give birth to
Enterprise is produced to environmental type industrial transformation.
Specific implementation mode
Embodiment 1:
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste, includes the following steps:
1, dispensing:Shale gas drilling well solid waste solidification landfill body 750T, diatomite 350T, oyster shell whiting 250T, sulfate slag 50T.
2, system material:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 10mm, diatomite is broken into
Grain size is the particle of 10mm, enters raw mill together with the sulfate slag that grain size is 1.5mm, and it is remaining 12% to be milled into 63 μm of square hole screens
Cement slurry, be sent into homogenizing storehouse.
3, producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shellfish
It is slurry more than 63 μm of square hole screens 12% that shell powder, which is scallop shell through wet ball grinding into grain size, and oyster shell whiting slurry moisture content is
60%, oyster shell whiting slurry is pumped to rotary kiln, then enter in rotary kiln from rotary kiln, with the object in rotary kiln
Material is calcined together, and 1500 DEG C of temperature, 35 minutes time is to get clinker.
Clinker pilot production for three days on end is shown:Raw mill system condition is normal, and quality coal in cement kiln systems operating mode is normal,
On-line checking exhaust gas emission compliance, clinker appearance is normal, and free calcium oxide in cement clinker is on average in 1.4%, cement
Clinker stability is qualified, and quality coal in cement kiln systems yield improves 5.1% on year-on-year basis, and the relatively original common lime stone of one ton of clinker coal consumption glues
Raw material based on soil calcine common clinker reduces by 7.3% on year-on-year basis.Clinker quality testing index average value is shown in Table 1, stability
Qualification is 3 days strong compared with the common clinker statistical average of the common lime stone raw clay calcining of original with 28 days compression strength
0.31% and 0.69% is respectively increased in degree.All things considered cures the clinker items quality testing of landfill body production with drilling well solid waste
Index is suitable with the common clinker that its common lime stone raw clay is calcined.
Embodiment 2:
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste, includes the following steps:
1, dispensing:Shale gas drilling well solid waste solidification landfill body 450T, diatomite 300T, oyster shell whiting 200T, sulfate slag 40T.
2, system material:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 5mm, diatomite is crushed granulating
Diameter is the particle of 5mm, enters raw mill together with the sulfate slag that grain size is 5mm, is milled into the remaining cement 8% of 53 μm of square hole screens
Raw material are sent into homogenizing storehouse.
3, producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shellfish
It is slurry more than 53 μm of square hole screens 8% that shell powder, which is snail shell through wet ball grinding into grain size, and oyster shell whiting slurry moisture content is 80%,
Oyster shell whiting slurry is pumped to rotary kiln, then is entered in rotary kiln from rotary kiln, with the material one in rotary kiln
Calcining is played, 1700 DEG C of temperature, 40 minutes time is to get clinker.
Clinker pilot production for three days on end is shown:Raw mill system condition is normal, and quality coal in cement kiln systems operating mode is normal,
On-line checking exhaust gas emission compliance;Clinker appearance is normal, and free calcium oxide in cement clinker is on average in 1.2%, cement
Clinker stability is qualified, and quality coal in cement kiln systems yield improves 5.6% on year-on-year basis, and the relatively original common lime stone of one ton of clinker coal consumption glues
Raw material based on soil calcine common clinker reduces by 6.1% on year-on-year basis.Clinker quality testing index average value is shown in Table 1, stability
Qualification is 3 days strong compared with the common clinker statistical average of the common lime stone raw clay calcining of original with 28 days compression strength
1.45% and 2.21% is respectively increased in degree.All things considered cures the clinker items quality testing of landfill body production with drilling well solid waste
Index is suitable with the common clinker that its common lime stone raw clay is calcined.
Embodiment 3:
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste, includes the following steps:
1, dispensing:Shale gas drilling well solid waste solidification landfill body 500T, diatomite 250T, oyster shell whiting 350T, sulfate slag 30T.
2, system material:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 15mm, diatomite is broken into
Grain size is the particle of 15mm, enters raw mill together with the sulfate slag that grain size is 3mm, and it is remaining 15% to be milled into 75 μm of square hole screens
Cement slurry is sent into homogenizing storehouse.
3, producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shellfish
It through wet ball grinding at grain size is slurry more than 75 μm of square hole screens 15% that shell powder, which is after scallop shell and snail shell mix in any proportion,
Body, oyster shell whiting slurry moisture content are 70%, oyster shell whiting slurry are pumped to rotary kiln, then enter revolution from rotary kiln
It in kiln kiln, is calcined together with the material in rotary kiln, 1300 DEG C of temperature, 50 minutes time is to get clinker.
Clinker pilot production for three days on end is shown:Raw mill system condition is normal, and quality coal in cement kiln systems operating mode is normal,
On-line checking exhaust gas emission compliance, clinker appearance is normal, and free calcium oxide in cement clinker is on average in 1.3%, cement
Clinker stability is qualified, and quality coal in cement kiln systems yield improves 5.2% on year-on-year basis, and the relatively original common lime stone of one ton of clinker coal consumption glues
Raw material based on soil calcine common clinker reduces by 6.8% on year-on-year basis.Clinker quality testing index average value is shown in Table 1, stability
Qualification is 3 days strong compared with the common clinker statistical average of the common lime stone raw clay calcining of original with 28 days compression strength
0.58% and 1.17% is respectively increased in degree.All things considered cures the clinker items quality testing of landfill body production with drilling well solid waste
Index is suitable with the common clinker that its common lime stone raw clay is calcined.
Embodiment 4:
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste, includes the following steps:
1, dispensing:Shale gas drilling well solid waste solidification landfill body 650T, diatomite 200T, oyster shell whiting 120T, sulfate slag 20T.
2, system material:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 7mm, diatomite is crushed granulating
Diameter is the particle of 7mm, enters raw mill together with the sulfate slag that grain size is 0.1mm, and it is remaining 10% to be milled into 58 μm of square hole screens
Cement slurry is sent into homogenizing storehouse.
3, producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shellfish
It is slurry more than 58 μm of square hole screens 10% that shell powder, which is scallop shell through wet ball grinding into grain size, and oyster shell whiting slurry moisture content is
65%, oyster shell whiting slurry is pumped to rotary kiln, then enter in rotary kiln from rotary kiln, with the object in rotary kiln
Material is calcined together, and 1400 DEG C of temperature, 30 minutes time is to get clinker.
Clinker pilot production for three days on end is shown:Raw mill system condition is normal, and quality coal in cement kiln systems operating mode is normal,
On-line checking exhaust gas emission compliance, clinker appearance is normal, and free calcium oxide in cement clinker is on average in 1.4%, cement
Clinker stability is closed,;Quality coal in cement kiln systems yield improves 5.5% on year-on-year basis, one ton of clinker coal consumption relatively original common lime stone, clay
Based on raw material calcine common clinker and reduce by 5.7% on year-on-year basis.Clinker quality testing index average value is shown in Table 1, and stability is closed
Lattice, the 3 days common clinker statistical average intensity with 28 days compression strength compared with the common lime stone raw clay calcining of original
1.59% and 2.36% is respectively increased.All things considered, the clinker items quality testing for curing landfill body production with drilling well solid waste refer to
It marks suitable with the common clinker that its common lime stone raw clay is calcined.
Embodiment 5:
Cure the method that landfill body prepares clinker using shale gas drilling well solid waste, includes the following steps:
1, dispensing:Shale gas drilling well solid waste solidification landfill body 300T, diatomite 100T, oyster shell whiting 100T, sulfate slag 10T.
2, system material:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 12mm, diatomite is broken into
Grain size be 12mm particle, with grain size be 1mm sulfate slag together with enter raw mill, be milled into 70 μm of square hole screens more than 13% water
Mud raw material are sent into homogenizing storehouse.
3, producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shellfish
It is slurry more than 70 μm of square hole screens 13% that shell powder, which is snail shell through wet ball grinding into grain size, and oyster shell whiting slurry moisture content is
75%, oyster shell whiting slurry is pumped to rotary kiln, then enter in rotary kiln from rotary kiln, with the object in rotary kiln
Material is calcined together, and 1600 DEG C of temperature, 45 minutes time is to get clinker.
Clinker pilot production for three days on end is shown:Raw mill system condition is normal, and quality coal in cement kiln systems operating mode is normal,
On-line checking exhaust gas emission compliance, clinker appearance is normal, and free calcium oxide in cement clinker is on average in 1.5%, cement
Clinker stability is qualified, and quality coal in cement kiln systems yield improves 5.8% on year-on-year basis, and the relatively original common lime stone of one ton of clinker coal consumption glues
Raw material based on soil calcine common clinker reduces by 5.1% on year-on-year basis.Clinker quality testing index average value is shown in Table 1, stability
Qualification is 3 days strong compared with the common clinker statistical average of the common lime stone raw clay calcining of original with 28 days compression strength
1.18% and 2.01% is respectively increased in degree.All things considered cures the clinker items quality testing of landfill body production with drilling well solid waste
Index value is suitable with the common clinker that its common lime stone raw clay is calcined.
1 each embodiment ecology clinker quality testing index average value of table
Claims (5)
1. curing the method that landfill body prepares clinker using shale gas drilling well solid waste, which is characterized in that include the following steps:
(1) dispensing:30~75 parts by weight of shale gas drilling well solid waste solidification landfill body, 10~35 parts by weight of diatomite, oyster shell whiting 10
~35 parts by weight, 1~5 parts by weight of sulfate slag;
(2) cement slurry processed:Shale gas drilling well solid waste is cured into landfill body and is broken into the particle that grain size is 5~15mm, diatomite
It is broken into the particle that grain size is 5~15mm, raw mill is entered together with sulfate slag, it is that 53~75 μm of square hole screens are remaining 8 to obtain grain size
~15% cement slurry;
(3) producing cement clinker:By cement slurry through skewed slot be conveyed into preheater be classified, preheat after send to rotary kiln;Shell
It is slurry more than 53~75 μm of square hole screens 8~15% that powder, which is shell through wet ball grinding into grain size, and oyster shell whiting slurry moisture content is
60~80%, oyster shell whiting slurry is pumped in rotary kiln, is calcined together with the material in rotary kiln, temperature 1300~1700
DEG C, 35~50 minutes time is to get clinker.
2. according to the method described in claim 1, it is characterized in that:The diatomite is a kind of pure natural nonmetallic mineral
Matter, the sedimentary rock gradually formed by Diatomeae remains in ocean or lake.
3. according to the method described in claim 1, it is characterized in that:The oyster shell whiting is by scallop shell or/and snail shell through wet
Method ball milling at slurry.
4. according to the method described in claim 1, it is characterized in that:The oyster shell whiting slurry is pumped to rotary kiln by helicoidal pump
Tail, then enter in rotary kiln from rotary kiln.
5. according to the method described in claim 1, it is characterized in that:The grain size of the sulfate slag is 0.1~5mm.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110357463A (en) * | 2019-06-25 | 2019-10-22 | 成都华寰环保科技有限公司 | A kind of drilling well oil-base mud landwaste wet treatment method |
CN110818291A (en) * | 2019-11-29 | 2020-02-21 | 刘海洋 | Cement fired by using drilling cuttings, method and application |
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2018
- 2018-08-17 CN CN201810940892.1A patent/CN108609877A/en active Pending
Patent Citations (1)
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CN108358477A (en) * | 2018-03-06 | 2018-08-03 | 四川阳森石油技术有限公司 | A method of preparing cement using water-based drilling solid waste |
Non-Patent Citations (2)
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刘小丽等著: "《中国页岩气开发 环境影响评价和监管制度研究》", 31 December 2016, 中国经济出版社 * |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110357463A (en) * | 2019-06-25 | 2019-10-22 | 成都华寰环保科技有限公司 | A kind of drilling well oil-base mud landwaste wet treatment method |
CN110818291A (en) * | 2019-11-29 | 2020-02-21 | 刘海洋 | Cement fired by using drilling cuttings, method and application |
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Application publication date: 20181002 |