CN108609731A - A kind of nitrogenous effluent treatment method - Google Patents

A kind of nitrogenous effluent treatment method Download PDF

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Publication number
CN108609731A
CN108609731A CN201810393007.2A CN201810393007A CN108609731A CN 108609731 A CN108609731 A CN 108609731A CN 201810393007 A CN201810393007 A CN 201810393007A CN 108609731 A CN108609731 A CN 108609731A
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China
Prior art keywords
nitrogenous effluent
nitrogenous
biochemical unit
treatment method
microbe stuffing
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CN201810393007.2A
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Chinese (zh)
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CN108609731B (en
Inventor
张阔
朱彤
王有昭
王瑶
吕力婷
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Northeastern University China
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Northeastern University China
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

Abstract

The present invention relates to technical field of waste water processing more particularly to a kind of nitrogenous effluent treatment methods comprising following steps:Preposition processing is carried out to nitrogenous effluent;Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing and activated sludge are provided in biochemical unit, includes acclimated microorganism bacterium colony in microbe stuffing;Nitrogenous effluent is handled in biochemical unit, and at least partly microbe stuffing generates vibration by driving during nitrogenous effluent is processed;The water discharge after processing is up to standard.This kind of nitrogenous effluent treatment method, without putting into carbon source, it is not necessary that aerator is arranged, and effectively avoids pipeline from blocking the appearance with flow dead zone during handling waste water.

Description

A kind of nitrogenous effluent treatment method
Technical field
The present invention relates to technical field of waste water processing more particularly to a kind of nitrogenous effluent treatment methods.
Background technology
Current industrial is quickly grown, and incident environmental pollution has become increasingly serious, many industrial wastewaters are processed into Main problem, and, the nitrogenous effluent extremely difficult processing of especially high concentration even more so in face of nitrogenous effluent, even if last water outlet reaches Mark is also required to very high processing cost, and traditional processing method takes up a large area, and treatment effeciency is low, and process is complicated.
Traditional denitrogenation of waste water mode is generally AAO, this mode firstly the need of to the object difficult to degrade in nitrogenous effluent into Row degradation, is then handled nitrogenous effluent by putting into the form of carbon source and reflux.In the method, it needs to put into carbon Source, carbon source are of high cost;It needs to flow back, a high proportion of reflux is easy to impact the Bacterial community of leading portion and can make each section molten It solves oxygen and generates fluctuation, influence the state of anaerobic pond;It needs that powerful aerator is arranged, energy consumption is higher;Meanwhile each anti- Ying Chizhong is susceptible to the problem of pipeline blocking or flow dead zone, and operating condition is bad.
For this reason, it may be necessary to propose to improve for problems of the prior art
Invention content
(1) technical problems to be solved
In order to solve the above problem of the prior art, the present invention provides a kind of processing method of nitrogenous effluent, processing Without putting into carbon source during nitrogenous effluent, it is not necessary that aerator is arranged, and pipeline is effectively avoided to block and flow dead zone Occur.
(2) technical solution
To achieve the above object, the main technical schemes that the present invention uses include:
The present invention provides a kind of nitrogenous effluent treatment methods comprising following steps:Preposition place is carried out to nitrogenous effluent Reason;Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing is provided in the biochemical unit and activity is dirty Mud, the interior microbe stuffing includes acclimated microorganism bacterium colony;Nitrogenous effluent is handled in the biochemical unit, nitrogenous At least partly described microbe stuffing generates vibration by driving during waste water is processed;The water row after processing is up to standard Go out.
Further, the preposition processing includes suspended solids content, pH values and the biochemistry poison adjusted in nitrogenous effluent Property.
Further, the suspended solids content in nitrogenous effluent is made to be not more than 800mg/L, pH in the preposition processing Value is 5.5-9.5.
Further, before injecting nitrogenous effluent to the biochemical unit, tap water is injected to the biochemical unit, originally Glucose or sodium acetate are added in water.
Further, before injecting nitrogenous effluent to the biochemical unit, anaerobism ammonia oxygen is added into the activated sludge Change bacterium.
Further, the part microbe stuffing is fixed in the biochemical unit, the part microbe stuffing It is vibrated by driving.
Further, the resonant frequency for detecting the microbe stuffing makes the microbe stuffing in its resonant frequency Lower vibration.
Further, include ferrous metals or magnetisable material in at least partly described microbe stuffing, to micro- life Region where object filler applies variable magnetic field.
Further, multiple biochemical units vertically arranged are set, it is single convenient for the biochemistry positioned at upper layer Water body in member, which can drop, to be flowed in the biochemical unit of lower layer.
Further, lifting device is set, and the lifting device promotes the water body in the biochemical unit of lower layer To in the biochemical unit of upper layer.
(3) advantageous effect
The beneficial effects of the invention are as follows:
(1) when handling nitrogenous effluent, activated sludge makes attached microbial bacterium colony on microbe stuffing, microorganism Bacterium colony handles nitrogenous effluent;By using the means of vibration the surface boundary layer of the liquid level of water body is disturbed, So that the oxygen in air is easier to dissolve in the surface of water body, and the microbe stuffing of the underclad portion of water body is contacted with biochemical unit Region dissolved oxygen amount it is smaller, make to form aerobic zone, anoxic zone and anaerobic zone in biochemical unit, pass through the biochemistry in three regions It reacts to make nitrogenous effluent be cleaned, realizes the processing to nitrogenous effluent;
(2) vibration can to form microchannel in microbe stuffing so that microbe colony in microbe stuffing with contain Preferably contact occurs for nitrogen waste water, improves the treatment effeciency to nitrogenous effluent;
(3) vibration can make the water body in biochemical unit form disturbance, improve the mobility of water body, prevent flow dead zone Occur, since the case where being not necessarily to setting reflux, not having line clogging occurs;
(4) dissolved oxygen amount is improved by way of vibration without setting aerator, meanwhile, compared to aerator, shake Energy consumption needed for dynamic device is smaller, more energy efficient;
(5) through experiment, in the processing method, without put into the carbon source system also can stable operation, operating cost is relatively low;
(6) in the preferred scheme, the multiple biochemical units vertically arranged are set, evolution can be formed from top to down Formula microbe colony, each section can be achieved different purification functions, and whole system has better stability and impact resistance, together When, during stream drops in water body from top to bottom, in conjunction with the effect of vibration, more oxygen can be allowed to dissolve in water body, to height The nitrogenous effluent of COD has better treatment effect.
Specific implementation mode
In order to preferably explain the present invention, in order to understand, below by specific embodiment, present invention work is retouched in detail It states.
The present invention provides a kind of nitrogenous effluent treatment methods comprising following steps:
Biochemical unit is set, is provided with microbe stuffing in biochemical unit, activated sludge is added in biochemical unit, preferably Ground first injects tap water in biochemical unit, makes to tame out for handling the micro- of nitrogenous effluent in the microbe stuffing of biochemical unit Biological bacterium colony.For injection tap water and activated sludge is added without precedence requirement.It is of course also possible to first be added without originally Water, but recycling microorganism bacterium colony when follow-up addition nitrogenous effluent, but domestication speed and domestication effect be not slightly good enough.
Preposition processing is carried out to nitrogenous effluent, which makes the content of the suspended solid in nitrogenous effluent specific In value range, make the pH value of nitrogenous effluent in a specific range, and makes in nitrogenous effluent without causing pole to microbe colony The substance of major injury prevents nitrogenous effluent from keeping microbe colony unbalance.
Preposition treated nitrogenous effluent is injected biochemical unit.
Nitrogenous effluent is handled in biochemical unit, at least partly microbe stuffing during nitrogenous effluent is processed Vibration is generated by driving.When processing, it can be the water up to standard that marginal not enters that the output of nitrogenous effluent side is handled well, i.e., constantly have new Nitrogenous effluent is injected, while also constantly having the water up to standard handled well to be discharged;Can also be to contain after injection nitrogenous effluent Nitrogen waste water stops the regular hour in biochemical unit, the water one up to standard handled well in biochemical unit after a period of time Play discharge.At least partly microbe stuffing generates vibration by driving, and it can be that whole microbe stuffings are all driven to refer to Movable property life vibration can also be that a part of microbe stuffing generates vibration by driving, specifically will be explained below.
The water discharge after processing is up to standard.
Based on above-mentioned method and step, nitrogenous effluent treatment method provided by the present invention is handled to nitrogenous effluent When, activated sludge makes attached microbial bacterium colony on microbe stuffing, microbe colony handle nitrogenous effluent;By using The means of vibration make the surface boundary layer of the liquid level of water body disturb so that the oxygen in air is easier to dissolve in the table of water body Face, and the region dissolved oxygen amount that the microbe stuffing of the underclad portion of water body is contacted with biochemical unit is smaller, makes shape in biochemical unit At aerobic zone, anoxic zone and anaerobic zone, so that nitrogenous effluent is cleaned by the biochemical reaction in three regions, realizes to containing The processing of nitrogen waste water;Vibration can to form microchannel in microbe stuffing so that microbe colony in microbe stuffing with Preferably contact occurs for nitrogenous effluent, improves the treatment effeciency to nitrogenous effluent;Vibration can make the water body shape in biochemical unit At disturbance, the mobility of water body is improved, prevents the appearance of flow dead zone;Due to being not necessarily to setting reflux, line clogging is not had It happens;Dissolved oxygen amount is improved by way of vibration without setting aerator, meanwhile, compared to aerator, vibration Energy consumption needed for device is smaller, more energy efficient;Through experiment, in the processing method, it can also stablize fortune without putting into the carbon source system Row, operating cost are relatively low.
Preferably, the suspended solids content in nitrogenous effluent is made to be not more than 800mg/L in preposition processing, pH value is 5.5-9.5.Adjusting suspended solids content can be handled by putting into the modes such as flocculant or air supporting, and adjusting pH value can lead to Addition acid-base reagent is crossed to be handled, nitrogenous effluent is processed to meet above-mentioned requirements after, then be input in biochemical unit.Into one Step preferably pH value is 7.
Preferably, before injecting nitrogenous effluent to biochemical unit, tap water is injected to biochemical unit, Portugal is added in tap water Grape sugar or sodium acetate;Above-mentioned substance, which is added, can improve the domestication speed of initial stage microbe colony.
Preferably, before injecting nitrogenous effluent to biochemical unit, anaerobic ammonia oxidizing bacteria is added into activated sludge;Addition is detested Anaerobic ammonium oxidation bacterium can reduce the acclimation period of microbe colony, improve the denitrification ability of biochemical unit.
Preferably, when nitrogenous effluent is handled in biochemical unit, part microbe stuffing is fixed in biochemical unit, Part microbe stuffing is vibrated by driving.During biochemical unit handles nitrogenous effluent, in fixed microbe stuffing With by driving vibration microbe stuffing between nitrogenous effluent can be promoted to circulate, so that nitrogenous effluent is more fully located Reason.
Preferably, the resonant frequency for detecting microbe stuffing makes microbe stuffing be vibrated under its resonant frequency.It can be with Vibrating data collection device is set in biochemical unit, acquires and calculate the resonant frequency of microbe stuffing, control driving vibration Vibrating device vibration frequency, the vibration frequency for making vibrating device is consistent with the resonant frequency of microbe stuffing, generate altogether The consumption of energy can be reduced after shaking.Meanwhile the microorganism for being attached with microbe colony is collected during follow-up operation After the real-time vibration frequency of filler, the microorganism in current microbe stuffing can be obtained by the real-time vibration frequency conversion The quantity situation of bacterium colony.
Certainly, the vibration frequency of vibrating device is also not necessarily required to as the resonant frequency of microbe stuffing.According to not Same situation can adjust the disturbance width of the surface boundary layer of the liquid level of water body by changing the vibration frequency of vibrating device Degree, to adjust the dissolved oxygen amount of water body.Preferably, vibration is it is required that the upper end dissolved oxygen of biochemical unit reaches 2-5mg/L.
Preferably, include ferrous metals or magnetisable material at least partly microbe stuffing, to where microbe stuffing Region apply variable magnetic field, make ferrous metals or magnetisable material that at least partly microbe stuffing be driven to vibrate.By additional Variable magnetic field makes the microbe stuffing vibrate.
Preferably, multiple biochemical units vertically arranged are set, convenient in the biochemical unit of upper layer Water body, which can drop, to be flowed in the biochemical unit of lower layer, and water body is contacted with oxygen to increase in water body during dropping stream Dissolved oxygen amount.In the preferred scheme, the multiple biochemical units vertically arranged are set, evolution can be formed from top to down Formula microbe colony, each section can be achieved different purification functions, and whole system has better stability and impact resistance, together When, during stream drops in water body from top to bottom, in conjunction with the effect of vibration, more oxygen can be allowed to dissolve in water body, to height The nitrogenous effluent of COD has better treatment effect.
Further preferably, lifting device is set, and lifting device carries the water body in the biochemical unit of lower layer It is raised in the biochemical unit of upper layer.The drop flowing water body of biochemical unit positioned at lower layer is promoted again on relatively In the biochemical unit of layer, better treatment effect is had for the nitrogenous effluent of high nitrogen concentration or high chemical oxygen demand.
In the absence of conflict, the feature in the above embodiments and embodiment can be combined with each other.
It is to be appreciated that describing the skill simply to illustrate that the present invention to what specific embodiments of the present invention carried out above Art route and feature, its object is to allow those skilled in the art to can understand the content of the present invention and implement it accordingly, but The present invention is not limited to above-mentioned specific embodiments.Every various change made within the scope of the claims is repaiied Decorations should all be covered within the scope of the present invention.

Claims (10)

1. a kind of nitrogenous effluent treatment method, it is characterised in that include the following steps:
Preposition processing is carried out to nitrogenous effluent;
Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing is provided in the biochemical unit and activity is dirty Mud, the interior microbe stuffing includes acclimated microorganism bacterium colony;
Nitrogenous effluent is handled in the biochemical unit, at least partly described microorganism during nitrogenous effluent is processed Filler generates vibration by driving;
The water discharge after processing is up to standard.
2. nitrogenous effluent treatment method according to claim 1, it is characterised in that:The preposition processing includes that adjusting is nitrogenous Suspended solids content, pH value in waste water and biochemical toxicity.
3. nitrogenous effluent treatment method according to claim 2, it is characterised in that:Make in the preposition processing nitrogenous useless Suspended solids content in water is not more than 800mg/L, pH value 5.5-9.5.
4. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is nitrogenous being injected to the biochemical unit Before waste water, tap water is injected to the biochemical unit, glucose or sodium acetate is added in tap water.
5. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is nitrogenous being injected to the biochemical unit Before waste water, anaerobic ammonia oxidizing bacteria is added into the activated sludge.
6. nitrogenous effluent treatment method according to claim 1, it is characterised in that:The part microbe stuffing is fixed In the biochemical unit, the part microbe stuffing is vibrated by driving.
7. nitrogenous effluent treatment method according to claim 1, it is characterised in that:Detect being total to for the microbe stuffing Vibration frequency makes the microbe stuffing be vibrated under its resonant frequency.
8. according to the nitrogenous effluent treatment method described in claim 1 or 6 or 7, it is characterised in that:At least partly described microorganism Include ferrous metals or magnetisable material in filler, variable magnetic field is applied to the region where the microbe stuffing.
9. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is arranged and multiple vertically arranges The biochemical unit flows to convenient for the water body drop in the biochemical unit of upper layer in the biochemical unit of lower layer.
10. nitrogenous effluent treatment method according to claim 9, it is characterised in that:Lifting device, the promotion dress are set It sets and the water body in the biochemical unit of lower layer is promoted in the biochemical unit of upper layer.
CN201810393007.2A 2018-04-27 2018-04-27 Treatment method of nitrogen-containing wastewater Active CN108609731B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109761338A (en) * 2019-03-05 2019-05-17 东北大学 A kind of reinforced electric catalysis biological filler and its application method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2369999Y (en) * 1999-05-07 2000-03-22 同济大学 Three-in-one water processor for precipitation fitation and aeration
CN104512963A (en) * 2014-11-29 2015-04-15 北京工业大学 Integral multistage simultaneous nitrification and denitrification biological membrane system denitrification method and device
CN104529091A (en) * 2015-01-08 2015-04-22 北京中瑞佳亿环境科技有限公司 Sewage treatment device and method for micro-power multi-medium fixed biological filter
CN106542655A (en) * 2017-01-23 2017-03-29 中蓝连海设计研究院 A kind of efficient denitrification microbial bacterial agent rapid biofilm method
CN107108293A (en) * 2015-01-19 2017-08-29 水翼株式会社 The denitrogenation method and nitrogen rejection facility of nitrogenous effluent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2369999Y (en) * 1999-05-07 2000-03-22 同济大学 Three-in-one water processor for precipitation fitation and aeration
CN104512963A (en) * 2014-11-29 2015-04-15 北京工业大学 Integral multistage simultaneous nitrification and denitrification biological membrane system denitrification method and device
CN104529091A (en) * 2015-01-08 2015-04-22 北京中瑞佳亿环境科技有限公司 Sewage treatment device and method for micro-power multi-medium fixed biological filter
CN107108293A (en) * 2015-01-19 2017-08-29 水翼株式会社 The denitrogenation method and nitrogen rejection facility of nitrogenous effluent
CN106542655A (en) * 2017-01-23 2017-03-29 中蓝连海设计研究院 A kind of efficient denitrification microbial bacterial agent rapid biofilm method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109761338A (en) * 2019-03-05 2019-05-17 东北大学 A kind of reinforced electric catalysis biological filler and its application method

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