CN108609731A - A kind of nitrogenous effluent treatment method - Google Patents
A kind of nitrogenous effluent treatment method Download PDFInfo
- Publication number
- CN108609731A CN108609731A CN201810393007.2A CN201810393007A CN108609731A CN 108609731 A CN108609731 A CN 108609731A CN 201810393007 A CN201810393007 A CN 201810393007A CN 108609731 A CN108609731 A CN 108609731A
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- CN
- China
- Prior art keywords
- nitrogenous effluent
- nitrogenous
- biochemical unit
- treatment method
- microbe stuffing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
Abstract
The present invention relates to technical field of waste water processing more particularly to a kind of nitrogenous effluent treatment methods comprising following steps:Preposition processing is carried out to nitrogenous effluent;Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing and activated sludge are provided in biochemical unit, includes acclimated microorganism bacterium colony in microbe stuffing;Nitrogenous effluent is handled in biochemical unit, and at least partly microbe stuffing generates vibration by driving during nitrogenous effluent is processed;The water discharge after processing is up to standard.This kind of nitrogenous effluent treatment method, without putting into carbon source, it is not necessary that aerator is arranged, and effectively avoids pipeline from blocking the appearance with flow dead zone during handling waste water.
Description
Technical field
The present invention relates to technical field of waste water processing more particularly to a kind of nitrogenous effluent treatment methods.
Background technology
Current industrial is quickly grown, and incident environmental pollution has become increasingly serious, many industrial wastewaters are processed into
Main problem, and, the nitrogenous effluent extremely difficult processing of especially high concentration even more so in face of nitrogenous effluent, even if last water outlet reaches
Mark is also required to very high processing cost, and traditional processing method takes up a large area, and treatment effeciency is low, and process is complicated.
Traditional denitrogenation of waste water mode is generally AAO, this mode firstly the need of to the object difficult to degrade in nitrogenous effluent into
Row degradation, is then handled nitrogenous effluent by putting into the form of carbon source and reflux.In the method, it needs to put into carbon
Source, carbon source are of high cost;It needs to flow back, a high proportion of reflux is easy to impact the Bacterial community of leading portion and can make each section molten
It solves oxygen and generates fluctuation, influence the state of anaerobic pond;It needs that powerful aerator is arranged, energy consumption is higher;Meanwhile each anti-
Ying Chizhong is susceptible to the problem of pipeline blocking or flow dead zone, and operating condition is bad.
For this reason, it may be necessary to propose to improve for problems of the prior art
Invention content
(1) technical problems to be solved
In order to solve the above problem of the prior art, the present invention provides a kind of processing method of nitrogenous effluent, processing
Without putting into carbon source during nitrogenous effluent, it is not necessary that aerator is arranged, and pipeline is effectively avoided to block and flow dead zone
Occur.
(2) technical solution
To achieve the above object, the main technical schemes that the present invention uses include:
The present invention provides a kind of nitrogenous effluent treatment methods comprising following steps:Preposition place is carried out to nitrogenous effluent
Reason;Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing is provided in the biochemical unit and activity is dirty
Mud, the interior microbe stuffing includes acclimated microorganism bacterium colony;Nitrogenous effluent is handled in the biochemical unit, nitrogenous
At least partly described microbe stuffing generates vibration by driving during waste water is processed;The water row after processing is up to standard
Go out.
Further, the preposition processing includes suspended solids content, pH values and the biochemistry poison adjusted in nitrogenous effluent
Property.
Further, the suspended solids content in nitrogenous effluent is made to be not more than 800mg/L, pH in the preposition processing
Value is 5.5-9.5.
Further, before injecting nitrogenous effluent to the biochemical unit, tap water is injected to the biochemical unit, originally
Glucose or sodium acetate are added in water.
Further, before injecting nitrogenous effluent to the biochemical unit, anaerobism ammonia oxygen is added into the activated sludge
Change bacterium.
Further, the part microbe stuffing is fixed in the biochemical unit, the part microbe stuffing
It is vibrated by driving.
Further, the resonant frequency for detecting the microbe stuffing makes the microbe stuffing in its resonant frequency
Lower vibration.
Further, include ferrous metals or magnetisable material in at least partly described microbe stuffing, to micro- life
Region where object filler applies variable magnetic field.
Further, multiple biochemical units vertically arranged are set, it is single convenient for the biochemistry positioned at upper layer
Water body in member, which can drop, to be flowed in the biochemical unit of lower layer.
Further, lifting device is set, and the lifting device promotes the water body in the biochemical unit of lower layer
To in the biochemical unit of upper layer.
(3) advantageous effect
The beneficial effects of the invention are as follows:
(1) when handling nitrogenous effluent, activated sludge makes attached microbial bacterium colony on microbe stuffing, microorganism
Bacterium colony handles nitrogenous effluent;By using the means of vibration the surface boundary layer of the liquid level of water body is disturbed,
So that the oxygen in air is easier to dissolve in the surface of water body, and the microbe stuffing of the underclad portion of water body is contacted with biochemical unit
Region dissolved oxygen amount it is smaller, make to form aerobic zone, anoxic zone and anaerobic zone in biochemical unit, pass through the biochemistry in three regions
It reacts to make nitrogenous effluent be cleaned, realizes the processing to nitrogenous effluent;
(2) vibration can to form microchannel in microbe stuffing so that microbe colony in microbe stuffing with contain
Preferably contact occurs for nitrogen waste water, improves the treatment effeciency to nitrogenous effluent;
(3) vibration can make the water body in biochemical unit form disturbance, improve the mobility of water body, prevent flow dead zone
Occur, since the case where being not necessarily to setting reflux, not having line clogging occurs;
(4) dissolved oxygen amount is improved by way of vibration without setting aerator, meanwhile, compared to aerator, shake
Energy consumption needed for dynamic device is smaller, more energy efficient;
(5) through experiment, in the processing method, without put into the carbon source system also can stable operation, operating cost is relatively low;
(6) in the preferred scheme, the multiple biochemical units vertically arranged are set, evolution can be formed from top to down
Formula microbe colony, each section can be achieved different purification functions, and whole system has better stability and impact resistance, together
When, during stream drops in water body from top to bottom, in conjunction with the effect of vibration, more oxygen can be allowed to dissolve in water body, to height
The nitrogenous effluent of COD has better treatment effect.
Specific implementation mode
In order to preferably explain the present invention, in order to understand, below by specific embodiment, present invention work is retouched in detail
It states.
The present invention provides a kind of nitrogenous effluent treatment methods comprising following steps:
Biochemical unit is set, is provided with microbe stuffing in biochemical unit, activated sludge is added in biochemical unit, preferably
Ground first injects tap water in biochemical unit, makes to tame out for handling the micro- of nitrogenous effluent in the microbe stuffing of biochemical unit
Biological bacterium colony.For injection tap water and activated sludge is added without precedence requirement.It is of course also possible to first be added without originally
Water, but recycling microorganism bacterium colony when follow-up addition nitrogenous effluent, but domestication speed and domestication effect be not slightly good enough.
Preposition processing is carried out to nitrogenous effluent, which makes the content of the suspended solid in nitrogenous effluent specific
In value range, make the pH value of nitrogenous effluent in a specific range, and makes in nitrogenous effluent without causing pole to microbe colony
The substance of major injury prevents nitrogenous effluent from keeping microbe colony unbalance.
Preposition treated nitrogenous effluent is injected biochemical unit.
Nitrogenous effluent is handled in biochemical unit, at least partly microbe stuffing during nitrogenous effluent is processed
Vibration is generated by driving.When processing, it can be the water up to standard that marginal not enters that the output of nitrogenous effluent side is handled well, i.e., constantly have new
Nitrogenous effluent is injected, while also constantly having the water up to standard handled well to be discharged;Can also be to contain after injection nitrogenous effluent
Nitrogen waste water stops the regular hour in biochemical unit, the water one up to standard handled well in biochemical unit after a period of time
Play discharge.At least partly microbe stuffing generates vibration by driving, and it can be that whole microbe stuffings are all driven to refer to
Movable property life vibration can also be that a part of microbe stuffing generates vibration by driving, specifically will be explained below.
The water discharge after processing is up to standard.
Based on above-mentioned method and step, nitrogenous effluent treatment method provided by the present invention is handled to nitrogenous effluent
When, activated sludge makes attached microbial bacterium colony on microbe stuffing, microbe colony handle nitrogenous effluent;By using
The means of vibration make the surface boundary layer of the liquid level of water body disturb so that the oxygen in air is easier to dissolve in the table of water body
Face, and the region dissolved oxygen amount that the microbe stuffing of the underclad portion of water body is contacted with biochemical unit is smaller, makes shape in biochemical unit
At aerobic zone, anoxic zone and anaerobic zone, so that nitrogenous effluent is cleaned by the biochemical reaction in three regions, realizes to containing
The processing of nitrogen waste water;Vibration can to form microchannel in microbe stuffing so that microbe colony in microbe stuffing with
Preferably contact occurs for nitrogenous effluent, improves the treatment effeciency to nitrogenous effluent;Vibration can make the water body shape in biochemical unit
At disturbance, the mobility of water body is improved, prevents the appearance of flow dead zone;Due to being not necessarily to setting reflux, line clogging is not had
It happens;Dissolved oxygen amount is improved by way of vibration without setting aerator, meanwhile, compared to aerator, vibration
Energy consumption needed for device is smaller, more energy efficient;Through experiment, in the processing method, it can also stablize fortune without putting into the carbon source system
Row, operating cost are relatively low.
Preferably, the suspended solids content in nitrogenous effluent is made to be not more than 800mg/L in preposition processing, pH value is
5.5-9.5.Adjusting suspended solids content can be handled by putting into the modes such as flocculant or air supporting, and adjusting pH value can lead to
Addition acid-base reagent is crossed to be handled, nitrogenous effluent is processed to meet above-mentioned requirements after, then be input in biochemical unit.Into one
Step preferably pH value is 7.
Preferably, before injecting nitrogenous effluent to biochemical unit, tap water is injected to biochemical unit, Portugal is added in tap water
Grape sugar or sodium acetate;Above-mentioned substance, which is added, can improve the domestication speed of initial stage microbe colony.
Preferably, before injecting nitrogenous effluent to biochemical unit, anaerobic ammonia oxidizing bacteria is added into activated sludge;Addition is detested
Anaerobic ammonium oxidation bacterium can reduce the acclimation period of microbe colony, improve the denitrification ability of biochemical unit.
Preferably, when nitrogenous effluent is handled in biochemical unit, part microbe stuffing is fixed in biochemical unit,
Part microbe stuffing is vibrated by driving.During biochemical unit handles nitrogenous effluent, in fixed microbe stuffing
With by driving vibration microbe stuffing between nitrogenous effluent can be promoted to circulate, so that nitrogenous effluent is more fully located
Reason.
Preferably, the resonant frequency for detecting microbe stuffing makes microbe stuffing be vibrated under its resonant frequency.It can be with
Vibrating data collection device is set in biochemical unit, acquires and calculate the resonant frequency of microbe stuffing, control driving vibration
Vibrating device vibration frequency, the vibration frequency for making vibrating device is consistent with the resonant frequency of microbe stuffing, generate altogether
The consumption of energy can be reduced after shaking.Meanwhile the microorganism for being attached with microbe colony is collected during follow-up operation
After the real-time vibration frequency of filler, the microorganism in current microbe stuffing can be obtained by the real-time vibration frequency conversion
The quantity situation of bacterium colony.
Certainly, the vibration frequency of vibrating device is also not necessarily required to as the resonant frequency of microbe stuffing.According to not
Same situation can adjust the disturbance width of the surface boundary layer of the liquid level of water body by changing the vibration frequency of vibrating device
Degree, to adjust the dissolved oxygen amount of water body.Preferably, vibration is it is required that the upper end dissolved oxygen of biochemical unit reaches 2-5mg/L.
Preferably, include ferrous metals or magnetisable material at least partly microbe stuffing, to where microbe stuffing
Region apply variable magnetic field, make ferrous metals or magnetisable material that at least partly microbe stuffing be driven to vibrate.By additional
Variable magnetic field makes the microbe stuffing vibrate.
Preferably, multiple biochemical units vertically arranged are set, convenient in the biochemical unit of upper layer
Water body, which can drop, to be flowed in the biochemical unit of lower layer, and water body is contacted with oxygen to increase in water body during dropping stream
Dissolved oxygen amount.In the preferred scheme, the multiple biochemical units vertically arranged are set, evolution can be formed from top to down
Formula microbe colony, each section can be achieved different purification functions, and whole system has better stability and impact resistance, together
When, during stream drops in water body from top to bottom, in conjunction with the effect of vibration, more oxygen can be allowed to dissolve in water body, to height
The nitrogenous effluent of COD has better treatment effect.
Further preferably, lifting device is set, and lifting device carries the water body in the biochemical unit of lower layer
It is raised in the biochemical unit of upper layer.The drop flowing water body of biochemical unit positioned at lower layer is promoted again on relatively
In the biochemical unit of layer, better treatment effect is had for the nitrogenous effluent of high nitrogen concentration or high chemical oxygen demand.
In the absence of conflict, the feature in the above embodiments and embodiment can be combined with each other.
It is to be appreciated that describing the skill simply to illustrate that the present invention to what specific embodiments of the present invention carried out above
Art route and feature, its object is to allow those skilled in the art to can understand the content of the present invention and implement it accordingly, but
The present invention is not limited to above-mentioned specific embodiments.Every various change made within the scope of the claims is repaiied
Decorations should all be covered within the scope of the present invention.
Claims (10)
1. a kind of nitrogenous effluent treatment method, it is characterised in that include the following steps:
Preposition processing is carried out to nitrogenous effluent;
Preposition treated nitrogenous effluent is injected biochemical unit, microbe stuffing is provided in the biochemical unit and activity is dirty
Mud, the interior microbe stuffing includes acclimated microorganism bacterium colony;
Nitrogenous effluent is handled in the biochemical unit, at least partly described microorganism during nitrogenous effluent is processed
Filler generates vibration by driving;
The water discharge after processing is up to standard.
2. nitrogenous effluent treatment method according to claim 1, it is characterised in that:The preposition processing includes that adjusting is nitrogenous
Suspended solids content, pH value in waste water and biochemical toxicity.
3. nitrogenous effluent treatment method according to claim 2, it is characterised in that:Make in the preposition processing nitrogenous useless
Suspended solids content in water is not more than 800mg/L, pH value 5.5-9.5.
4. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is nitrogenous being injected to the biochemical unit
Before waste water, tap water is injected to the biochemical unit, glucose or sodium acetate is added in tap water.
5. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is nitrogenous being injected to the biochemical unit
Before waste water, anaerobic ammonia oxidizing bacteria is added into the activated sludge.
6. nitrogenous effluent treatment method according to claim 1, it is characterised in that:The part microbe stuffing is fixed
In the biochemical unit, the part microbe stuffing is vibrated by driving.
7. nitrogenous effluent treatment method according to claim 1, it is characterised in that:Detect being total to for the microbe stuffing
Vibration frequency makes the microbe stuffing be vibrated under its resonant frequency.
8. according to the nitrogenous effluent treatment method described in claim 1 or 6 or 7, it is characterised in that:At least partly described microorganism
Include ferrous metals or magnetisable material in filler, variable magnetic field is applied to the region where the microbe stuffing.
9. nitrogenous effluent treatment method according to claim 1, it is characterised in that:It is arranged and multiple vertically arranges
The biochemical unit flows to convenient for the water body drop in the biochemical unit of upper layer in the biochemical unit of lower layer.
10. nitrogenous effluent treatment method according to claim 9, it is characterised in that:Lifting device, the promotion dress are set
It sets and the water body in the biochemical unit of lower layer is promoted in the biochemical unit of upper layer.
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CN201810393007.2A CN108609731B (en) | 2018-04-27 | 2018-04-27 | Treatment method of nitrogen-containing wastewater |
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CN201810393007.2A CN108609731B (en) | 2018-04-27 | 2018-04-27 | Treatment method of nitrogen-containing wastewater |
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CN108609731B CN108609731B (en) | 2020-07-28 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109761338A (en) * | 2019-03-05 | 2019-05-17 | 东北大学 | A kind of reinforced electric catalysis biological filler and its application method |
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CN104512963A (en) * | 2014-11-29 | 2015-04-15 | 北京工业大学 | Integral multistage simultaneous nitrification and denitrification biological membrane system denitrification method and device |
CN104529091A (en) * | 2015-01-08 | 2015-04-22 | 北京中瑞佳亿环境科技有限公司 | Sewage treatment device and method for micro-power multi-medium fixed biological filter |
CN106542655A (en) * | 2017-01-23 | 2017-03-29 | 中蓝连海设计研究院 | A kind of efficient denitrification microbial bacterial agent rapid biofilm method |
CN107108293A (en) * | 2015-01-19 | 2017-08-29 | 水翼株式会社 | The denitrogenation method and nitrogen rejection facility of nitrogenous effluent |
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2018
- 2018-04-27 CN CN201810393007.2A patent/CN108609731B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN2369999Y (en) * | 1999-05-07 | 2000-03-22 | 同济大学 | Three-in-one water processor for precipitation fitation and aeration |
CN104512963A (en) * | 2014-11-29 | 2015-04-15 | 北京工业大学 | Integral multistage simultaneous nitrification and denitrification biological membrane system denitrification method and device |
CN104529091A (en) * | 2015-01-08 | 2015-04-22 | 北京中瑞佳亿环境科技有限公司 | Sewage treatment device and method for micro-power multi-medium fixed biological filter |
CN107108293A (en) * | 2015-01-19 | 2017-08-29 | 水翼株式会社 | The denitrogenation method and nitrogen rejection facility of nitrogenous effluent |
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Cited By (1)
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CN109761338A (en) * | 2019-03-05 | 2019-05-17 | 东北大学 | A kind of reinforced electric catalysis biological filler and its application method |
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