CN108608788A - Decoration coating, its production method with multicolor patterns and appearance member - Google Patents

Decoration coating, its production method with multicolor patterns and appearance member Download PDF

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Publication number
CN108608788A
CN108608788A CN201611074872.8A CN201611074872A CN108608788A CN 108608788 A CN108608788 A CN 108608788A CN 201611074872 A CN201611074872 A CN 201611074872A CN 108608788 A CN108608788 A CN 108608788A
Authority
CN
China
Prior art keywords
cured resin
ultraviolet light
light
decoration coating
mass percentage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611074872.8A
Other languages
Chinese (zh)
Inventor
陈薇婷
马宏俊
江承祖
廖育麟
李汉隆
许义忠
张志荣
戴丰源
刘日成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hongfujin Precision Industry Shenzhen Co Ltd
Hon Hai Precision Industry Co Ltd
Original Assignee
Hongfujin Precision Industry Shenzhen Co Ltd
Hon Hai Precision Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hongfujin Precision Industry Shenzhen Co Ltd, Hon Hai Precision Industry Co Ltd filed Critical Hongfujin Precision Industry Shenzhen Co Ltd
Priority to CN201611074872.8A priority Critical patent/CN108608788A/en
Publication of CN108608788A publication Critical patent/CN108608788A/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of decoration coating with multicolor patterns, for being decorated to an appearance member, including：Film layer is transferred, the transfer film layer is formed by curing by ultraviolet light (UV) light-cured resin mixture, and the ultraviolet light light-cured resin mixture includes at least：Acrylic copolymer, propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester and trimethylbenzene；And pattern layer, transfer film surface is formed in by ink-jet mode.Further include a kind of production method of the above-mentioned decoration coating with multicolor patterns and includes the appearance member of the decoration coating with multicolor patterns.

Description

Decoration coating, its production method with multicolor patterns and appearance member
Technical field
The present invention relates to a kind of decoration coating and preparation method thereof more particularly to a kind of decorating films with multicolor patterns Layer, its production method and appearance member.
Background technology
Decoration coating uses intaglio plate or wire mark mode to make more, if but client just have to pass through when having multicolor patterns design Multiple working procedure carries out chromatography and has chromatography yield and precision problem, unfavorable production.
Invention content
In view of this, it is necessary to provide a kind of decoration coating, its production method and appearance member with multicolor patterns, uses Spray printing mode forms multicolor patterns, saves process and improves production capacity and yield.
A kind of decoration coating with multicolor patterns, for being decorated to an appearance member, including：Film layer is transferred, it is described Transfer film layer is formed by curing by ultraviolet light light-cured resin mixture, and the ultraviolet light light-cured resin mixture includes at least： Acrylic copolymer, propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester and trimethylbenzene；And pattern layer, by ink-jet mode shape At in transfer film surface.
A kind of production method of the decoration coating with multicolor patterns, including：One film support plate, the film support plate are provided Including a release surface；One ultraviolet light light-cured resin mixture is provided, the ultraviolet light light-cured resin mixture is coated In in the release surface of the film support plate, film layer is transferred to form one on the film support plate, wherein the ultraviolet light Light-cured resin mixture includes at least：Acrylic copolymer, propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester and three Toluene；The transfer film layer is coated on an appearance piece surface together with the film support plate；Cure the transfer by ultraviolet light Film layer removes the film support plate later；And pattern layer is formed in the transfer film surface by the form of ink-jet.
A kind of appearance member, including substrate and be formed in the substrate surface such as the above-mentioned decorating film with multicolor patterns Layer, wherein the transfer film layer is formed directly into the substrate surface.
Compared with the prior art, the decoration coating with multicolor patterns of the technical program offer, its production method and outer Part is seen by the direct spray printing of the pattern of design in transferring in film layer, multiple tracks chromatography process can be saved and improves production capacity and promotes yield, And the transfer film layer reliability that the ultraviolet light light-cured resin mixture formed by special formulation is formed by curing is preferable.
Description of the drawings
Fig. 1 is the sectional view of the decoration coating with multicolor patterns of first embodiment of the invention offer.
Fig. 2 be the decoration coating with multicolor patterns of second embodiment of the invention offer production method in provide it is thin The sectional view of film support plate.
Fig. 3 be the decoration coating with multicolor patterns of second embodiment of the invention offer production method in provide The film support plate of Fig. 2 forms the sectional view after transfer film layer.
Fig. 4 be the decoration coating with multicolor patterns of second embodiment of the invention offer production method in provide The transfer film layer of Fig. 3 is formed in the sectional view after an appearance piece surface.
Fig. 5 be the decoration coating with multicolor patterns of second embodiment of the invention offer production method in the general that provides Sectional view after film support plate removal total Fig. 4.
Fig. 6 be the decoration coating with multicolor patterns of second embodiment of the invention offer production method in provide The transfer film surface of Fig. 5 forms the sectional view after pattern layer.
Main element symbol description
Decoration coating 100 with multicolor patterns
Transfer film layer 10
Pattern layer 20
First surface 101
Second surface 102
Film support plate 30
Release surface 31
Appearance member 50
Substrate 51
Following specific implementation mode will be further illustrated the present invention in conjunction with above-mentioned attached drawing.
Specific implementation mode
Referring to Fig. 1, the present invention provides a kind of decoration coating 100 with multicolor patterns, including transfer film layer 10 and figure Pattern layer 20.The decoration coating 100 with multicolor patterns can be used to form in the table of an appearance member such as mobile phone shell, packing box etc. Face, for being decorated to the appearance member.
The transfer film layer 10 is formed by curing by ultraviolet light light-cured resin mixture, and the ultraviolet light light-cured resin is mixed Closing object includes：Acrylic copolymer (Acrylic copolymer), propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester (Propylene Glycol Monomethyl Ether Propionate), trimethylbenzene (Trimethylbenzene), toner And silicone analog assistant.
Wherein it is preferred to which mass percentage of the acrylic copolymer in the ultraviolet light light-cured resin is About 50% to about 70%, it is highly preferred that being 60% or so；The propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester is in institute It is about 5% to about 20% to state the mass percentage in ultraviolet light light-cured resin, it is highly preferred that being 12% or so；Described three Mass percentage of the toluene in the ultraviolet light light-cured resin is about 7% to about 25%, it is highly preferred that left for 12% It is right；Mass percentage of the toner in the ultraviolet light light-cured resin is about 3% to about 15%, it is highly preferred that being 5% or so；Mass percentage of the silicone analog assistant in the ultraviolet light light-cured resin is about 0.05% to about 10%, it is highly preferred that being 5% or so.
The toner can be the toner of a variety of colors, the transfer film layer 10 for obtaining various predetermined colors, for example, institute It can be metallochrome toner to state toner.
In other embodiments, the ultraviolet light light-cured resin mixture further includes a small amount of pearl powder, so as to To the transfer film layer 10 with pearly luster.
The first surface 101 and second surface 102 for transferring film layer 10 and including opposite, wherein the first surface 101 Can be used for directly connecting with the appearance member, can be formed on the second surface 102 it is textured, such as imitation leather texture, imitative cloth texture Deng.
The pattern layer 20 is formed directly into the second surface 102, and the pattern layer 20 is formed by ink-jet.The pattern Layer 20 can be rendered as various patterns.
The present invention also provides a kind of methods making the above-mentioned decoration coating 100 with multicolor patterns, including step：
S1, referring to Fig. 1, providing a film support plate 30, the film support plate 30 includes a release surface 31.
Preferably, the film support plate 30 is made of polyolefin (polyolefine, PO) material.In the present embodiment, also By way of heating compacting or the compacting of UV lines texture is formed in the release surface 31.
S2 mixes the ultraviolet light light-cured resin referring to Fig. 2, providing a ultraviolet light light-cured resin mixture Object is coated in the release surface 31 of the film support plate 30, to form a transfer film layer 10 on the film support plate 30.
Wherein, the ultraviolet light light-cured resin mixture includes：Acrylic copolymer, propylene glycol list dimethyl propylene glycol Monomethyl ether propionic ester, trimethylbenzene, toner, silicone analog assistant and pearl powder.
Wherein it is preferred to which mass percentage of the acrylic copolymer in the ultraviolet light light-cured resin is About 50% to about 70%, it is highly preferred that being 60% or so；The propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester is in institute It is about 5% to about 20% to state the mass percentage in ultraviolet light light-cured resin, it is highly preferred that being 12% or so；Described three Mass percentage of the toluene in the ultraviolet light light-cured resin is about 7% to about 25%, it is highly preferred that left for 12% It is right；Mass percentage of the toner in the ultraviolet light light-cured resin is about 3% to about 15%, it is highly preferred that being 5% or so；Mass percentage of the silicone analog assistant in the ultraviolet light light-cured resin is about 0.05% to about 10%, it is highly preferred that being 5% or so.
S3, referring to Fig. 3, by vacuum hot transferred mode, by the transfer film layer 10 together with the film support plate 30 It is coated on 51 surface of substrate of an appearance member, the transfer film layer 10 is made to be bonded in the surface of the substrate 51.
S4 please refers to Fig. 4-5, cures the transfer film layer 10 by ultraviolet light, later, removes the film support plate 30.
Wherein, the transfer film layer 10 includes opposite first surface 101 and second surface 102, the first surface 101 Directly connect with the appearance member, it is textured because being formed in the release surface 31 in the present embodiment, therefore, remove the film After support plate 30, by transferring shape on the transfer surface namely the second surface 102 of the film layer 10 far from the substrate 51 At textured.
S5, referring to Fig. 6, according to designed pattern, by the form of UV ink-jets in the 10 surface shape of transfer film layer At the pattern layer 20, to form the decoration coating 100 with multicolor patterns on 51 surface of the substrate.
Wherein, the pattern layer 20 is that UV ink is formed by curing under the irradiation of UV light.
It is appreciated that the transfer film layer 10 can not also be cured in S4 steps, and the cured pattern layer in S5 steps When 20, while curing the transfer film layer 10.
Referring to Fig. 6, the present invention provides also a kind of appearance member 50 for including, the appearance member 50 includes substrate 51 and shape At in the decoration coating 100 with multicolor patterns on 51 surface of substrate.The decoration coating 100 with multicolor patterns includes turning Die layer 10 and pattern layer 20.
The transfer film layer 10 is formed by curing by ultraviolet light light-cured resin mixture, and the ultraviolet light light-cured resin is mixed Closing object includes：Acrylic copolymer (Acrylic copolymer), propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester (Propylene Glycol Monomethyl Ether Propionate), trimethylbenzene (Trimethylbenzene), toner And silicone analog assistant.
Wherein it is preferred to which mass percentage of the acrylic copolymer in the ultraviolet light light-cured resin is About 50% to about 70%, it is highly preferred that being 60% or so；The propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester is in institute It is about 5% to about 20% to state the mass percentage in ultraviolet light light-cured resin, it is highly preferred that being 12% or so；Described three Mass percentage of the toluene in the ultraviolet light light-cured resin is about 7% to about 25%, it is highly preferred that left for 12% It is right；Mass percentage of the toner in the ultraviolet light light-cured resin is about 3% to about 15%, it is highly preferred that being 5% or so；Mass percentage of the silicone analog assistant in the ultraviolet light light-cured resin is about 0.05% to about 10%, it is highly preferred that being 5% or so.
The toner can be the toner of a variety of colors, the transfer film layer 10 for obtaining various predetermined colors, for example, institute It can be metallochrome toner to state toner.
In other embodiments, the ultraviolet light light-cured resin mixture further includes a small amount of pearl powder, so as to To the transfer film layer 10 with pearly luster.
The first surface 101 and second surface 102 for transferring film layer 10 and including opposite, wherein the first surface 101 Can be used for directly connecting with the substrate 51, can be formed on the second surface 102 it is textured, such as imitation leather texture, imitative cloth texture Deng.
The pattern layer 20 is formed directly into the second surface 102, and the pattern layer 20 is formed by ink-jet.The pattern Layer 20 can be rendered as various patterns.
Embodiment 1
The production method of one decoration coating with multicolor patterns, including：
A film support plate is provided, the film support plate includes a release surface, and the film support plate uses polyolefine material It is made, is formed in the release surface textured.
Later, a ultraviolet light light-cured resin mixture is provided, the ultraviolet light light-cured resin mixture is coated on In the release surface of the film support plate, to form a transfer film layer on the film support plate；Wherein, the ultraviolet light light Solidified resin mixture includes：Acrylic copolymer that mass percentage is 60%, mass percentage are the third the two of 12% Trimethylbenzene that alcohol list dimethyl propylene glycol monomethyl ether propionic ester, mass percentage are 12%, mass percentage are 5% Blue toner, the silicone analog assistant that mass percentage is 5% and a small amount of pearl powder.
Later, by vacuum hot transferred mode, the transfer film layer is coated on an appearance together with the film support plate The substrate surface of part makes the transfer film layer be bonded in the surface of the substrate.
Later, the transfer film layer is cured by ultraviolet light, removes the film support plate.
Later, according to designed pattern, by the form of UV ink-jets in the presumptive area shape for transferring film surface At pattern layer, to form the decoration coating with multicolor patterns in the substrate surface.
Embodiment 2
One decoration coating with multicolor patterns is made, the decoration with multicolor patterns by the method for embodiment 1 Film layer is generally blue and has pearly luster, and the decoration coating subregion with multicolor patterns is formed with polychrome figure Case.
Wherein, the performance test results of the decoration coating with multicolor patterns join table 1, by table 1 it is found that the tool There is the decoration coating of multicolor patterns that there is preferable adhesive force and preferable hardness, also, its acid and alkali-resistance, solvent resistant, heat-proof water Immersion, perspiration resistance corrosivity are also preferable.
Table 1
The decoration coating with multicolor patterns of offer of the embodiment of the present invention, the transfer film layer of its production method and appearance member Reliability is preferable, and by the direct spray printing of the pattern of design in transfer film layer on, multiple tracks chromatography process can be saved and improve production capacity and Promote yield；If in addition, carrying out spray printing directly on decoration merely in prior art, band gold can not be had by being limited to ink-jet properties The effect of category or pearl powder gloss, therefore must be accepted or rejected in technological design, and film layer is transferred described in this case to be had Various colors and metal or pearly luster effect have preferable decorating feature.
It is understood that for those of ordinary skill in the art, can be conceived with the technique according to the invention and be done Go out various other corresponding changes and deformation, and all these changes and deformation should all belong to the protection model of the claims in the present invention It encloses.

Claims (16)

1. a kind of decoration coating with multicolor patterns, for being decorated to an appearance member, including：
Film layer is transferred, the transfer film layer is formed by curing by ultraviolet light light-cured resin mixture, the ultraviolet light photocuring tree Lipoprotein mixture includes at least：Acrylic copolymer, propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester and trimethylbenzene；And
Pattern layer is formed in transfer film surface by ink-jet mode.
2. the decoration coating with multicolor patterns as described in claim 1, which is characterized in that the ultraviolet light light-cured resin Mixture further includes pearl powder.
3. the decoration coating with multicolor patterns as described in claim 1, which is characterized in that the acrylic copolymer is in institute It is 50% to 70% to state the mass percentage in ultraviolet light light-cured resin；The propylene glycol list dimethyl propylene glycol monomethyl Mass percentage of the ether propionic ester in the ultraviolet light light-cured resin is 5% to 20%；The trimethylbenzene is in the purple Mass percentage in outer smooth light-cured resin is 7% to 25%.
4. the decoration coating with multicolor patterns as claimed in claim 3, which is characterized in that the acrylic copolymer is in institute It is 60% to state the mass percentage in ultraviolet light light-cured resin；The propylene glycol list dimethyl propylene glycol monomethyl ether propionic acid Mass percentage of the ester in the ultraviolet light light-cured resin is 12%；The trimethylbenzene is in the ultraviolet light photocuring tree Mass percentage in fat is 12%.
5. the decoration coating with multicolor patterns as described in claim 1, which is characterized in that also include silicone auxiliary agent, it is described Mass percentage of the silicone auxiliary agent in the ultraviolet light light-cured resin is 0.05% to 10%.
6. the decoration coating with multicolor patterns as described in claim 1, which is characterized in that also include toner, the toner Mass percentage in the ultraviolet light light-cured resin is 3% to 15%.
7. the decoration coating with multicolor patterns as described in claim 1, which is characterized in that the transfer film layer includes opposite First surface and second surface, the first surface formed on the second surface for directly connecting with the appearance member Textured, the pattern layer is formed directly into the second surface.
8. a kind of production method of the decoration coating with multicolor patterns, including：
A film support plate is provided, the film support plate includes a release surface；
One ultraviolet light light-cured resin mixture is provided, the ultraviolet light light-cured resin mixture is carried coated on the film In the release surface of plate, to form a transfer film layer on the film support plate, wherein the ultraviolet light light-cured resin is mixed Object is closed to include at least：Acrylic copolymer, propylene glycol list dimethyl propylene glycol monomethyl ether propionic ester and trimethylbenzene；
The transfer film layer is coated on an appearance member substrate surface together with the film support plate；
Cure the transfer film layer by ultraviolet light, later, removes the film support plate；And
By way of ink-jet pattern layer is formed in the transfer film surface.
9. the production method of the decoration coating with multicolor patterns as claimed in claim 8, which is characterized in that the ultraviolet light Light-cured resin mixture further includes pearl powder.
10. the production method of the decoration coating with multicolor patterns as claimed in claim 9, which is characterized in that the propylene Mass percentage of the acid copolymer in the ultraviolet light light-cured resin is 50% to 70%；The propylene glycol list dimethyl Mass percentage of the propylene glycol monomethyl ether propionic ester in the ultraviolet light light-cured resin is 5% to 20%；Described three Mass percentage of the toluene in the ultraviolet light light-cured resin is 7% to 25%.
11. the production method of the decoration coating with multicolor patterns as claimed in claim 9, which is characterized in that the propylene Mass percentage of the acid copolymer in the ultraviolet light light-cured resin is 60%；The propylene glycol list dimethyl propylene glycol Mass percentage of the monomethyl ether propionic ester in the ultraviolet light light-cured resin is 12%；The trimethylbenzene is in the purple Mass percentage in outer smooth light-cured resin is 12%.
12. the production method of the decoration coating with multicolor patterns as claimed in claim 8, which is characterized in that also include silicon Ketone auxiliary agent, mass percentage of the silicone auxiliary agent in the ultraviolet light light-cured resin are 0.05% to 10%.
13. the production method of the decoration coating with multicolor patterns as claimed in claim 8, which is characterized in that also include color Powder, mass percentage of the toner in the ultraviolet light light-cured resin are 3% to 15%.
14. the production method of the decoration coating with multicolor patterns as claimed in claim 8, which is characterized in that the film Formed textured in the release surface of support plate, the transfer film layer includes opposite first surface and second surface, and described second Surface is affixed to be also formed with texture with the release surface, and the first surface with the substrate for directly connecting, institute It states pattern layer and is formed directly into the second surface.
15. the production method of the decoration coating with multicolor patterns as claimed in claim 8, which is characterized in that pass through vacuum The transfer film layer is coated on the appearance piece surface by the mode of thermal transfer together with the film support plate.
16. a kind of appearance member, including substrate and be formed in the substrate surface as described in 1 to 7 any one of the claims The decoration coating with multicolor patterns, wherein the transfer film layer is formed directly into the substrate surface.
CN201611074872.8A 2016-11-29 2016-11-29 Decoration coating, its production method with multicolor patterns and appearance member Pending CN108608788A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611074872.8A CN108608788A (en) 2016-11-29 2016-11-29 Decoration coating, its production method with multicolor patterns and appearance member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611074872.8A CN108608788A (en) 2016-11-29 2016-11-29 Decoration coating, its production method with multicolor patterns and appearance member

Publications (1)

Publication Number Publication Date
CN108608788A true CN108608788A (en) 2018-10-02

Family

ID=63643093

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611074872.8A Pending CN108608788A (en) 2016-11-29 2016-11-29 Decoration coating, its production method with multicolor patterns and appearance member

Country Status (1)

Country Link
CN (1) CN108608788A (en)

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Application publication date: 20181002