CN108597865A - Low square resistance metallized film and evaporation process - Google Patents

Low square resistance metallized film and evaporation process Download PDF

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Publication number
CN108597865A
CN108597865A CN201810346865.1A CN201810346865A CN108597865A CN 108597865 A CN108597865 A CN 108597865A CN 201810346865 A CN201810346865 A CN 201810346865A CN 108597865 A CN108597865 A CN 108597865A
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CN
China
Prior art keywords
metallized film
square resistance
low square
metal coated
coated strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810346865.1A
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Chinese (zh)
Inventor
钱锦绣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qian Liwen
Original Assignee
Qian Liwen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qian Liwen filed Critical Qian Liwen
Priority to CN201810346865.1A priority Critical patent/CN108597865A/en
Publication of CN108597865A publication Critical patent/CN108597865A/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/33Thin- or thick-film capacitors 
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • H01G4/008Selection of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/14Organic dielectrics

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

A kind of low square resistance metallized film of the present invention, including basement membrane (1), it is vaporized on that the metal coated strip (2) of side longitudinal central axis is deposited in basement membrane and blank stays sideband (3), the sheet resistance of the metal coated strip (2) is 0.35~0.85 Ω/.The low square resistance metallized film that the present invention is deposited can use under the extreme environmental conditions such as temperature change dramatically, high temperature, strong vibration and high radiation environment, weightlessness and microgravity, and have very high reliability.

Description

Low square resistance metallized film and evaporation process
Technical field
The present invention relates to thin film capacitor manufacturing metallized film materials, more particularly to a kind of low square resistance metal Change film and evaporation process.
Background technology
For thin film capacitor because it is used widely with good resistance to pressure and self-healing property, metallized film is thin-film electro The important materials of container production manufacture, by high purity metal(Such as AL, ZN)It melts, evaporate under high vacuum state, being deposited to Jie On matter basement membrane, the film after medium membrane surface forms one layer of very thin coat of metal is exactly metallized film;It metallizes thin The resistance value of the unit square area of the coat of metal on film is known as sheet resistance(That is square resistance is indicated with Ω/), metal-plated The thickness and sheet resistance value of layer are inversely proportional, i.e., sheet resistance is lower, and metal layer thickness is bigger;The sheet resistance of Conventional metallization film is 2~4 Ω/□;Under the conditions of general atmosphere, what such metallized film use was applicable in, but in temperature change dramatically, high temperature, strong vibration Under the extreme environmental conditions such as high radiation environment, weightlessness and microgravity, then it can not ensure the reliability of the capacitor of its manufacture.
Invention content
The purpose of the present invention is being directed to the deficiencies in the prior art, a kind of low square resistance metallized film and vapor deposition are provided Technique, can be under the extreme environmental conditions such as temperature change dramatically, high temperature, strong vibration and high radiation environment, weightlessness and microgravity It uses, and has very high reliability.
Technical solution
To achieve the above object, present invention employs following technical schemes:A kind of side's low square resistance metallized film, including basement membrane, The metal coated strip and blank for being vaporized on basement membrane vapor deposition side longitudinal central axis stay sideband;The sheet resistance of the metal coated strip is 0.35 ~0.85 Ω/, and the sheet resistance of metallized film metal coated strip can only achieve 2~4 Ω/ usually under technical conditions, i.e., it is golden The thickness of categoryization film metal coating band is 7 times or so of usual technical conditions metal membrane metal coated strip, and metallization is thin The thickness of film metal coated strip significantly thickens, it is meant that in vacuum evaporation, to precipitate on inherent basement membrane at the same time More metals, and more precipitated metals also bring more heats to scald organic basement membrane in basement membrane, influence metallized film Performance.
Further, the coat of metal carrying material is fine aluminium.
Further, a kind of side's low square resistance metallized film includes following evaporation process:
1. the vacuum degree in plated film intracavitary portion is -4 × 10-3mbar;
2. evaporation rate is 2 meter per seconds;
3. the temperature of the main drum of cooling is -25 DEG C.
The beneficial effects of the present invention are
The low square resistance metallized film produced through above-mentioned evaporation process:It can be in temperature change dramatically, high temperature, strong vibration and high spoke It penetrates under the extreme environmental conditions such as environment, weightlessness and microgravity and uses, and have very high reliability.
Description of the drawings
Fig. 1 is sectional view of the present invention.
In figure, 1 basement membrane, 2 metal coated strips, 3 blank stay sideband.
Specific implementation mode
As shown in Figure 1, a kind of low square resistance metallized film of the present invention, including basement membrane (1), to be vaporized on basement membrane vapor deposition side longitudinal The metal coated strip (2) and blank of axis stay sideband (3);The sheet resistance of the metal coated strip (2) be 0.35~0.85 Ω/ , and the sheet resistance of metallized film metal coated strip (2) can only achieve 2~4 Ω/ usually under technical conditions, that is, metallize thin The thickness of film metal coated strip (2) is 7 times or so of usual technical conditions metal membrane metal coated strip (2), and metallization is thin The thickness of film metal coated strip (2) significantly thickens, it is meant that in vacuum evaporation, to sink on inherent basement membrane at the same time Form sediment more metals, and more precipitated metals also bring more heats to scald organic basement membrane (2) in basement membrane (1), influence gold The performance of categoryization film;
Metal coated strip (2) material is fine aluminium;
A kind of side's low square resistance metallized film includes following evaporation process:
1. the vacuum degree in plated film intracavitary portion is -4 × 10-3mbar;
2. evaporation rate is 2 meter per seconds;
3. the temperature of the main drum of cooling is -25 DEG C.

Claims (3)

1. a kind of low square resistance metallized film, including basement membrane (1), the metal coated strip for being vaporized on basement membrane vapor deposition side longitudinal central axis (2) and blank stays sideband (3), it is characterised in that the sheet resistance of the metal coated strip (2) is 0.35~0.85 Ω/.
2. a kind of low square resistance metallized film according to claim 1, it is characterised in that metal coated strip (2) material For fine aluminium.
3. a kind of low square resistance metallized film according to claim 1, it is characterised in that including following evaporation process:
The vacuum degree in A plated film intracavitary portion is -4 × 10-3mbar;
B evaporation rates are 2 meter per seconds;
The temperature that C cools down main drum is -25 DEG C.
CN201810346865.1A 2018-04-18 2018-04-18 Low square resistance metallized film and evaporation process Withdrawn CN108597865A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810346865.1A CN108597865A (en) 2018-04-18 2018-04-18 Low square resistance metallized film and evaporation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810346865.1A CN108597865A (en) 2018-04-18 2018-04-18 Low square resistance metallized film and evaporation process

Publications (1)

Publication Number Publication Date
CN108597865A true CN108597865A (en) 2018-09-28

Family

ID=63613544

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810346865.1A Withdrawn CN108597865A (en) 2018-04-18 2018-04-18 Low square resistance metallized film and evaporation process

Country Status (1)

Country Link
CN (1) CN108597865A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101295581A (en) * 2007-04-28 2008-10-29 上海奥移电器有限公司 All-aluminum thickened thin film for metalized capacitor
CN103077821A (en) * 2013-01-09 2013-05-01 铜陵市东市电子有限责任公司 Ultralow-sheet-resistance metal aluminum film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101295581A (en) * 2007-04-28 2008-10-29 上海奥移电器有限公司 All-aluminum thickened thin film for metalized capacitor
CN103077821A (en) * 2013-01-09 2013-05-01 铜陵市东市电子有限责任公司 Ultralow-sheet-resistance metal aluminum film

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Application publication date: 20180928