CN108587021A - A kind of low electrostatic heat-sealing type functional membrane of high-barrier - Google Patents
A kind of low electrostatic heat-sealing type functional membrane of high-barrier Download PDFInfo
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- CN108587021A CN108587021A CN201810440291.4A CN201810440291A CN108587021A CN 108587021 A CN108587021 A CN 108587021A CN 201810440291 A CN201810440291 A CN 201810440291A CN 108587021 A CN108587021 A CN 108587021A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
- C08J2343/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2423/30—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by oxidation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a kind of low electrostatic heat-sealing type functional membranes of high-barrier, are made of the raw material of following parts by weight：40 52 parts of solvent, 20 30 parts of acrylic resin, 14 18 parts of polyvinyl chloride, 12 15 parts of polypropylene, 15 18 parts of ethyl acrylate, 35 parts of vinyltriethoxysilane, 24 parts of oxidic polyethylene, 24 parts of ACR, 24 parts of stearic acid, 35 parts of stabilizer, 8 12 parts of titanium dioxide.Product produced by the invention is nontoxic, high transparency, surface-brightening, impact resistance, tear-proof, do not burn, is nonhygroscopic, heat-sealing is easy, securely, requirement especially suitable for various high speed auto packer tools, the addition of ethyl acrylate and vinyltriethoxysilane forms macromolecule emulsion simultaneously, it is allowed to organically combine with other raw materials, packaging material anti-static function can be assigned, production cost substantially reduces.
Description
Technical field
The present invention relates to function technical field of membrane, and in particular to a kind of low electrostatic heat-sealing type functional membrane of high-barrier.
Background technology
At present film in use, in order to reach the different-effect of product external packaging, the requirement to film is more next
Higher, especially bidirectional stretching polypropylene film (BOPP) is widely used in the outer films such as tobacco packaging, long-term natural
Fold cannot be generated in film surface under environment, the film that existing film production process is produced, chemical resistance is poor, is easy
With the ink of weight color is especially bright red, the chemically reactives such as green and wrinkle, separately have be exactly shrinking percentage inner wrapping rear surface not
The compact appearance for influencing product, heat-sealing temperature height influence its packaging speed, and barrier property is poor.Lead to film when in use always not to the utmost
People's will.
Invention content
The present invention is intended to provide a kind of high-barrier low electrostatic heat-sealing type functional membrane.
The present invention provides the following technical solutions：
A kind of low electrostatic heat-sealing type functional membrane of high-barrier, is made of the raw material of following parts by weight：Solvent 40-52
Part, 20-30 parts of acrylic resin, 14-18 parts of polyvinyl chloride, 12-15 parts of polypropylene, 15-18 parts of ethyl acrylate, vinyl three
3-5 parts of Ethoxysilane, 2-4 parts of oxidic polyethylene, 2-4 parts of ACR, 2-4 parts of stearic acid, 3-5 parts of stabilizer, titanium dioxide 8-
12 parts.
The solvent is mainly carboxylic acid and modified polyorganosiloxane mixture.
The MBS is the terpolymer of methyl methacrylate, butadiene and styrene.
The ACR is acrylate copolymer.
The dispersant is methyl pyrrolidone and palmitic acid according to molar ratio 3：The mixture of 2 compositions.
Compared with prior art, the beneficial effects of the invention are as follows：Product produced by the invention is nontoxic, high transparency, surface light
Bright, impact resistance, tear-proof, do not burn, be nonhygroscopic, heat-sealing be easy, securely, especially suitable for various high speed auto packer tools
It is required that while the addition of ethyl acrylate and vinyltriethoxysilane form macromolecule emulsion, be allowed to other raw materials
Machine combines, and can assign packaging material anti-static function, production cost substantially reduces.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
A kind of low electrostatic heat-sealing type functional membrane of 1 high-barrier of embodiment, is made of the raw material of following parts by weight：Solvent
40 parts, 20 parts of acrylic resin, 14 parts of polyvinyl chloride, 12 parts of polypropylene, 15 parts of ethyl acrylate, vinyltriethoxysilane
3 parts, 2 parts of oxidic polyethylene, 2 parts of ACR, 2 parts of stearic acid, 3 parts of stabilizer, 8 parts of titanium dioxide.
The solvent is mainly carboxylic acid and modified polyorganosiloxane mixture.
The MBS is the terpolymer of methyl methacrylate, butadiene and styrene.
The ACR is acrylate copolymer.
The dispersant is methyl pyrrolidone and palmitic acid according to molar ratio 3：The mixture of 2 compositions.
A kind of low electrostatic heat-sealing type functional membrane of 2 high-barrier of embodiment, is made of the raw material of following parts by weight：Solvent
52 parts, 30 parts of acrylic resin, 18 parts of polyvinyl chloride, 15 parts of polypropylene, 18 parts of ethyl acrylate, vinyltriethoxysilane
5 parts, 4 parts of oxidic polyethylene, 4 parts of ACR, 4 parts of stearic acid, 5 parts of stabilizer, 12 parts of titanium dioxide.
The solvent is mainly carboxylic acid and modified polyorganosiloxane mixture.
The MBS is the terpolymer of methyl methacrylate, butadiene and styrene.
The ACR is acrylate copolymer.
The dispersant is methyl pyrrolidone and palmitic acid according to molar ratio 3：The mixture of 2 compositions.
A kind of low electrostatic heat-sealing type functional membrane of 3 high-barrier of embodiment, is made of the raw material of following parts by weight：Solvent
45 parts, 24 parts of acrylic resin, 16 parts of polyvinyl chloride, 13 parts of polypropylene, 17 parts of ethyl acrylate, vinyltriethoxysilane
4 parts, 3 parts of oxidic polyethylene, 3 parts of ACR, 3 parts of stearic acid, 4 parts of stabilizer, 10 parts of titanium dioxide.
The solvent is mainly carboxylic acid and modified polyorganosiloxane mixture.
The MBS is the terpolymer of methyl methacrylate, butadiene and styrene.
The ACR is acrylate copolymer.
The dispersant is methyl pyrrolidone and palmitic acid according to molar ratio 3：The mixture of 2 compositions.
It is obvious to a person skilled in the art that the present invention is not limited to the details of the exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit require rather than it is described illustrate to limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.In addition, it should be understood that although this specification is described in terms of embodiments, but it is not each
Embodiment only contains an independent technical solution, and this description of the specification is merely for the sake of clarity, this field
Technical staff should consider the specification as a whole, and the technical solutions in the various embodiments may also be suitably combined, form this
The other embodiment that field technology personnel are appreciated that.
Claims (5)
1. a kind of low electrostatic heat-sealing type functional membrane of high-barrier, which is characterized in that it is made of the raw material of following parts by weight：It is molten
40-52 parts of agent, 20-30 parts of acrylic resin, 14-18 parts of polyvinyl chloride, 12-15 parts of polypropylene, 15-18 parts of ethyl acrylate,
3-5 parts of vinyltriethoxysilane, 2-4 parts of oxidic polyethylene, 2-4 parts of ACR, 2-4 parts of stearic acid, 3-5 parts of stabilizer, two
8-12 parts of titanium oxide.
2. a kind of low electrostatic heat-sealing type functional membrane of high-barrier according to claim 1, it is characterised in that：The solvent is main
For carboxylic acid and modified polyorganosiloxane mixture.
3. a kind of low electrostatic heat-sealing type functional membrane of high-barrier according to claim 1, it is characterised in that：The MBS is first
The terpolymer of base methyl acrylate, butadiene and styrene.
4. a kind of low electrostatic heat-sealing type functional membrane of high-barrier according to claim 1, it is characterised in that：The ACR is third
Olefin(e) acid resin copolymer.
5. a kind of low electrostatic heat-sealing type functional membrane of high-barrier according to claim 1, it is characterised in that：The dispersant is
Methyl pyrrolidone and palmitic acid are according to molar ratio 3：The mixture of 2 compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810440291.4A CN108587021A (en) | 2018-05-10 | 2018-05-10 | A kind of low electrostatic heat-sealing type functional membrane of high-barrier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810440291.4A CN108587021A (en) | 2018-05-10 | 2018-05-10 | A kind of low electrostatic heat-sealing type functional membrane of high-barrier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108587021A true CN108587021A (en) | 2018-09-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810440291.4A Pending CN108587021A (en) | 2018-05-10 | 2018-05-10 | A kind of low electrostatic heat-sealing type functional membrane of high-barrier |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987905A (en) * | 2010-10-27 | 2011-03-23 | 界首市天鸿包装材料有限公司 | High-insulation low-static anti-wrinkle heat-seal type functional film |
| US20140017468A1 (en) * | 2005-08-31 | 2014-01-16 | Mitsubishi Plastics, Inc. | Gas barrier multilayer film |
| CN104710707A (en) * | 2013-12-16 | 2015-06-17 | 郝明先 | Antistatic plastic film bag material |
| CN107057502A (en) * | 2017-06-19 | 2017-08-18 | 安徽康瑞高科新材料技术工程有限公司 | A kind of anti-static coatings |
-
2018
- 2018-05-10 CN CN201810440291.4A patent/CN108587021A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140017468A1 (en) * | 2005-08-31 | 2014-01-16 | Mitsubishi Plastics, Inc. | Gas barrier multilayer film |
| CN101987905A (en) * | 2010-10-27 | 2011-03-23 | 界首市天鸿包装材料有限公司 | High-insulation low-static anti-wrinkle heat-seal type functional film |
| CN104710707A (en) * | 2013-12-16 | 2015-06-17 | 郝明先 | Antistatic plastic film bag material |
| CN107057502A (en) * | 2017-06-19 | 2017-08-18 | 安徽康瑞高科新材料技术工程有限公司 | A kind of anti-static coatings |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 801 Jiekang Road, Jieshi Town, Banan District, Chongqing Applicant after: Chongqing China membrane composite material Co., Ltd Address before: 401320 3, 4-2, Shek Gui Road, Jieshi Town, Banan District, Chongqing, 4-2 Applicant before: CHONGQING XINKANGYI DAHL NEW MATERIALS Co.,Ltd. |
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| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180928 |
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| RJ01 | Rejection of invention patent application after publication |