CN108586805A - Cable fire-retardant combination and preparation method thereof - Google Patents
Cable fire-retardant combination and preparation method thereof Download PDFInfo
- Publication number
- CN108586805A CN108586805A CN201810499255.5A CN201810499255A CN108586805A CN 108586805 A CN108586805 A CN 108586805A CN 201810499255 A CN201810499255 A CN 201810499255A CN 108586805 A CN108586805 A CN 108586805A
- Authority
- CN
- China
- Prior art keywords
- preparation
- montmorillonite
- fire
- retardant
- retardant combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses a kind of cable fire-retardant combinations and preparation method thereof, the cable fire-retardant combination is using modified montmorillonite as major ingredient, coordinate the flame retardants such as nanoparticle active agent, antimony oxide and ammonium polyphosphate, has the advantages that low cigarette in high fire-retardance, inexpensive, combustion process, and applied to when preparing rubber, it can not only make rubber obtained that there is good low-smoke and flame retardant performance, additionally it is possible to carry out good mechanical performance to rubber strip.And the fire retardant preparation method is simple, raw material is easy to get, and has higher application value.
Description
Technical field
The present invention relates to cable production arts, and in particular, to a kind of cable fire-retardant combination and preparation method thereof.
Background technology
It is exactly to be made of the conductor and external insulating protective layer of one or more mutually insulated for cable is popular, by electric power
Or information is transferred to the conducting wire at another place from one.With the rapid development of economy, more and more places need cable to transmit
Electric power or other information, therefore also have tightened up requirement to the manufacture of cable.The sheath of cable is the indispensable knot of cable
Structure part plays a part of protecting cable, ensures the energization safety of cable, and cable core and water, the isolation of the media such as air is allowed to keep away
Exempt from leaky occur.Resin is material of main part prepared by cable cover(ing), so the property of resin directly determines obtained cable
The property of sheath.
The classification of fire retardant can be divided into halogen system, organic phosphorus and halogen phosphorus system, silicon systems, high purity alumina-magnesia, molybdenum according to element species
System, boron system, nitrogen system etc..Halogenated flame retardant is for a long time with its flame retarding efficiency is high, dosage is few, price is low and well-known.From
The polybrominated diphenyl ethers contained in the product that brominated system burning generates, the double benzdioxans of tetrabromo were found first from Europe in 1986
And double benzofurans of tetrabromo etc. belong to carcinogen, the situation that halogen flame-retardant system rules all the land has received severe choose
The fact that war using bittern-free flame-proof material and product has been trend of the times.Existing inorganic combustion inhibitor (boron system, silicon systems etc.) although
With low toxicity, anti-rotten candle property is inexpensive, in combustion process the advantages that low cigarette, but has the shortcomings that some are very serious, such as low
Flame retarding efficiency and thermal stability cause largely to deteriorate to the physical mechanical property of material.Ammonium polyphosphate is non-toxic and tasteless, no
Etchant gas is generated, hygroscopicity is small, and thermal stability is high, is a kind of non-halogen fire retardant of function admirable.But it is lacked there is also corresponding
Point, since current process polymerisation degree is smaller so having larger hygroscopicity, and very to the Effect on Mechanical Properties of engineering plastics
Greatly.
Therefore, how low cigarette in a kind of less toxic, inexpensive, combustion process is provided, and the mechanical performance of material will not be made to deteriorate
Flame retardant, in cable material, being a technical problem to be solved urgently.
Invention content
The object of the present invention is to provide a kind of cable fire-retardant combination and preparation method thereof, the cable fire-retardant combinations
Using modified montmorillonite as major ingredient, the flame retardants such as cooperation nanoparticle active agent, antimony oxide and ammonium polyphosphate have high resistant
In combustion, inexpensive, combustion process the advantages of low cigarette, and it is good applied to when preparing rubber, rubber obtained can not only have
Low-smoke and flame retardant performance, additionally it is possible to give rubber strip come good mechanical performance.And the fire retardant preparation method is simple, raw material is easy
, there is higher application value.
To achieve the goals above, the present invention provides a kind of preparation method of cable fire-retardant combination, the preparations
Method includes the following steps：(1) mixing is heated into dibastic sodium phosphate and montmorillonite in water, magnesium chloride is then added, be heated to reflux,
Gelatinous mixture is obtained, then pH is adjusted to 8-13；(2) gelatinous mixture is calcined, crushes, obtains phosphate-
The montmorillonite of magnesium-doping vario-property；(3) proportionally by modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate
Mixing.
The present invention also provides a kind of cable fire-retardant combinations being prepared according to previously described preparation method.
Through the above technical solutions, cable fire-retardant combination provided by the invention is matched using modified montmorillonite as major ingredient
The flame retardants such as nanoparticle active agent, antimony oxide and ammonium polyphosphate are closed, there is high fire-retardance, inexpensive, low cigarette in combustion process
Advantage, and applied to when preparing rubber, can not only make rubber obtained that there is good low-smoke and flame retardant performance, additionally it is possible to give rubber
Adhesive tape carrys out good mechanical performance.And the fire retardant preparation method is simple, raw material is easy to get, and has higher application value.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
To achieve the goals above, the present invention provides a kind of preparation method of cable fire-retardant combination, the preparations
Method includes the following steps：(1) mixing is heated into dibastic sodium phosphate and montmorillonite in water, magnesium chloride is then added, be heated to reflux,
Gelatinous mixture is obtained, then pH is adjusted to 8-13；(2) gelatinous mixture is calcined, crushes, obtains phosphate-
The montmorillonite of magnesium-doping vario-property；(3) proportionally by modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate
Mixing.
Through the above technical solutions, cable fire-retardant combination provided by the invention is matched using modified montmorillonite as major ingredient
The flame retardants such as nanoparticle active agent, antimony oxide and ammonium polyphosphate are closed, there is high fire-retardance, inexpensive, low cigarette in combustion process
Advantage, and applied to when preparing rubber, can not only make rubber obtained that there is good low-smoke and flame retardant performance, additionally it is possible to give rubber
Adhesive tape carrys out good mechanical performance.And the fire retardant preparation method is simple, raw material is easy to get, and has higher application value.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that modified montmorillonite, nanoparticle active agent, three oxygen
The mass ratio for changing two antimony and ammonium polyphosphate is 10:1-2:1.5-3:2-3.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that dibastic sodium phosphate, montmorillonite and chlorine in step (1)
The mass ratio for changing magnesium is 3-5:20:2-4.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that the mass ratio of water and montmorillonite in step (1)
For 15-50:1.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that dibastic sodium phosphate, montmorillonite are in water in step (1)
The mixed condition of middle heating includes：Temperature is 60-80 DEG C, time 20-40min.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that it is 90-120 DEG C to be heated to reflux temperature.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that calcination condition includes in step (2)：Temperature is
200-280 DEG C, time 1.5h-3h.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that the substance that pH is adjusted in step (1) is hydrogen-oxygen
Change sodium and/or potassium hydroxide.
In a kind of preferred embodiment of the present invention, there is high fire-retardance in order to obtain and prepared applied to rubber, plastics
In, the fire-retardant combination of good mechanical properties can be carried out for material strips, it is preferable that nanoparticle active agent is nano magnesia, nanometer
It is one or more in aluminium oxide, nm-class boron nitride and nano granular of zinc oxide.
Montmorillonite common saying is also bentonite, and in the above-mentioned technical solutions, montmorillonite can be selected in wider range
It selects, such as sodium-based montmorillonite, calcium-base montmorillonite etc., can meet the requirement of the present invention.For the grain size of montmorillonite, also can compared with
Selection, conventional material filler montmorillonite, such as 200 mesh, 325 mesh, the plurality of specifications such as 1250 mesh in wide scope, can meet this
The requirement of invention in embodiment later, is illustrated with the sodium-based montmorillonite of 325 mesh.
In the above-mentioned technical solutions, for the grinding mode of the substance obtained after calcining in step (2) can there are many choosings
It selects, such as grinds, rolls, ball milling etc., as long as substance after calcining can be made to crush, the present invention can be achieved, in this regard, the present invention is not
Be required, in embodiment later, in order to improve production efficiency, also for obtain can be material strips come more preferable mechanical performance
Fire-retardant combination, in embodiment later, the mode of crushing is carried out with ball milling, it is preferable that the condition of ball milling is：In planet
With the rotating speed ball milling of 220~250r/min 3~6 hours on ball mill, dispersant therein is ethyl alcohol.
The present invention also provides a kind of cable fire-retardant combinations being prepared according to previously described preparation method.
Through the above technical solutions, cable fire-retardant combination provided by the invention is matched using modified montmorillonite as major ingredient
The flame retardants such as nanoparticle active agent, antimony oxide and ammonium polyphosphate are closed, there is high fire-retardance, inexpensive, low cigarette in combustion process
Advantage, and applied to when preparing rubber, can not only make rubber obtained that there is good low-smoke and flame retardant performance, additionally it is possible to give rubber
Adhesive tape carrys out good mechanical performance.And the fire retardant preparation method is simple, raw material is easy to get, and has higher application value.
The present invention will be described in detail by way of examples below.
Embodiment 1
The preparation method of cable fire-retardant combination, includes the following steps：
(1) then in water in 60 DEG C of heating mixing 40min magnesium chloride is added, in 90 DEG C in dibastic sodium phosphate and montmorillonite
It is heated to reflux, obtains gelatinous mixture, then adjusted pH to 13 with sodium hydroxide；Wherein, dibastic sodium phosphate, montmorillonite and chlorination
The mass ratio of magnesium is 3:20:2；Water and the mass ratio of montmorillonite are 15:1；
(2) gelatinous mixture is calcined into 3h, ball mill grinding in 200 DEG C, the illiteracy for obtaining phosphate-magnesium-doping vario-property takes off
Soil；
(3) by modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate according to mass ratio be 10:1:
1.5:2 are mixed；
Wherein, nanoparticle active agent is nano aluminium oxide.
Embodiment 2
The preparation method of cable fire-retardant combination, includes the following steps：
(1) then in water in 80 DEG C of heating mixing 20min magnesium chloride is added, in 120 DEG C in dibastic sodium phosphate and montmorillonite
It is heated to reflux, obtains gelatinous mixture, then adjusted pH to 8 with sodium hydroxide；Wherein, dibastic sodium phosphate, montmorillonite and chlorination
The mass ratio of magnesium is 5:20:4；Water and the mass ratio of montmorillonite are 50:1；
(2) gelatinous mixture is calcined into 1.5h in 280 DEG C, ball mill grinding obtains the illiteracy of phosphate-magnesium-doping vario-property
De- soil；
(3) by modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate according to mass ratio be 10:2:
3:3 are mixed；
Wherein, nanoparticle active agent is nano granular of zinc oxide.
Embodiment 3
The preparation method of cable fire-retardant combination, includes the following steps：
(1) then in water in 70 DEG C of heating mixing 30min magnesium chloride is added, in 105 DEG C in dibastic sodium phosphate and montmorillonite
It is heated to reflux, obtains gelatinous mixture, then adjusted pH to 11 with sodium hydroxide；Wherein, dibastic sodium phosphate, montmorillonite and chlorination
The mass ratio of magnesium is 4:20:3；Water and the mass ratio of montmorillonite are 30:1
(2) gelatinous mixture is calcined into 2h, ball mill grinding in 240 DEG C, the illiteracy for obtaining phosphate-magnesium-doping vario-property takes off
Soil；
(3) by modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate according to mass ratio be 10:
1.5:2:2.5 are mixed；
Wherein, nanoparticle active agent is nano magnesia.
Application examples 1
By fluorubber, fire-retardant combination, molybdenum tetrachloride, -1,2 dihyaroquinoline of 6- ethyoxyl -2,2,4- trimethyls, poly-vinegar
Vinyl acetate, ethyl phosphonic acid diethylester and sulphur the mixing 30min under conditions of 160 DEG C of rotating speeds are 200r/min；Wherein, with weight
Part meter is measured, relative to 100 parts of fluorubber, the dosage of fire-retardant combination is 10 parts, and the dosage of molybdenum tetrachloride is 0.3 part, 6- second
The dosage of oxygroup -2,2,4- trimethyl -1,2 dihyaroquinolines is 0.3 part, and the dosage of polyvinyl acetate is 6 parts, ethyl phosphonic acid
The dosage of diethylester is 5 parts, and the dosage of sulphur is 3 parts；Wherein, fire-retardant combination is the fire-retardant combination in embodiment 1；
Mixing object is subjected to stone roller page, cutting, film is made, by film in 175 DEG C of extrusion moldings, the steam in extrusion
Pressure is controlled in 0.6MPa, then microwave vulcanization, obtains compounded rubber；Wherein microwave vulcanization includes successively：One section of microwave vulcanization, two
Section hot-air cure；One section of microwave vulcanization section temperature is 160 DEG C, and one section of temperature of two sections of hot-air cures is 150 DEG C, two sections of heat
Two sections of temperature of air cure are 135 DEG C.
Flame retardant property test is carried out with reference to national standard GB/T2408-1996：
Horizontal flame retardant property is burnt 20 minutes using 87.9KW coal gas Bunsen burners, and flame is extended to away from coal gas Bunsen burner fire
76 centimetres of flame front end, non smoke generate；Vertical Flame performance is burnt 30 minutes using 154.5KW coal gas Bunsen burners, vertical combustion
Distance is self-extinguish after 1.51 meters, 1.51 meters.Without black smoke and penetrating odor in combustion process.
According to the method tested for tensile strength and elongation at break in national standard GB/T1040-2006, puller system model island
The AG-20KNG of Tianjin company production；Rate of extension is 500mm/min, and test temperature is 23 DEG C, is found after testing, the compounded rubber
Tensile strength be 21.4N/mm2, elongation at break 296.1%.
Application examples 2
By fluorubber, fire-retardant combination, molybdenum pentachloride, 2,2,4- trimethyl 1,2- dihydro quinolines condensate, poly-vinegar acid second
Enester, ethyl phosphonic acid diethylester and sulphur the mixing 20min under conditions of 190 DEG C of rotating speeds are 300r/min；Wherein, with parts by weight
Meter, relative to 100 parts of fluorubber, the dosage of fire-retardant combination is 15 parts, and the dosage of molybdenum pentachloride is 0.8 part, 2,2,4- tri-
Methyl 1, the polymeric dosage of 2- dihydro quinolines are 0.8 part, and the dosage of polyvinyl acetate is 12 parts, ethyl phosphonic acid diethylester
Dosage is 8 parts, and the dosage of sulphur is 8 parts；Wherein, fire-retardant combination is the fire-retardant combination in embodiment 2；
Mixing object is subjected to stone roller page, cutting, film is made, by film in 185 DEG C of extrusion moldings, the steam in extrusion
Pressure is controlled in 0.8MPa, then microwave vulcanization, obtains compounded rubber；Wherein microwave vulcanization includes successively：One section of microwave vulcanization, two
Section hot-air cure；One section of microwave vulcanization section temperature is 180 DEG C, and one section of temperature of two sections of hot-air cures is 160 DEG C, two sections of heat
Two sections of temperature of air cure are 145 DEG C.
Flame retardant property test is carried out with reference to national standard GB/T2408-1996：
Horizontal flame retardant property is burnt 20 minutes using 87.9KW coal gas Bunsen burners, and flame is extended to away from coal gas Bunsen burner fire
65 centimetres of flame front end, non smoke generate；Vertical Flame performance is burnt 30 minutes using 154.5KW coal gas Bunsen burners, vertical combustion
Distance is self-extinguish after 1.36 meters, 1.36 meters.
According to the method tested for tensile strength and elongation at break in national standard GB/T1040-2006, puller system model island
The AG-20KNG of Tianjin company production；Rate of extension is 500mm/min, and test temperature is 23 DEG C, is found after testing, the compounded rubber
Tensile strength be 22.4N/mm2, elongation at break 286.1%.
Without black smoke and penetrating odor in combustion process.
Application examples 3
By fluorubber, fire-retardant combination, dibromo molybdenum dioxide, -1,2 dihyaroquinoline of 6- ethyoxyl -2,2,4- trimethyls,
Polyvinyl acetate, ethyl phosphonic acid diethylester and sulphur the mixing 25min under conditions of 175 DEG C of rotating speeds are 250r/min；Wherein,
In parts by weight, relative to 100 parts of fluorubber, the dosage of fire-retardant combination is 12 parts, and the dosage of dibromo molybdenum dioxide is 0.6
Part, the dosage of 6- ethyoxyls -2,2,4- trimethyl -1,2 dihyaroquinolines is 0.6 part, and the dosage of polyvinyl acetate is 9 parts,
The dosage of ethyl phosphonic acid diethylester is 7 parts, and the dosage of sulphur is 6 parts；Wherein, fire-retardant combination is fire-retardant group in embodiment 3
Close object；
Mixing object is subjected to stone roller page, cutting, film is made, by film in 180 DEG C of extrusion moldings, the steam in extrusion
Pressure is controlled in 0.7MPa, then microwave vulcanization, obtains compounded rubber；Wherein microwave vulcanization includes successively：One section of microwave vulcanization, two
Section hot-air cure；One section of microwave vulcanization section temperature is 170 DEG C, and one section of temperature of two sections of hot-air cures is 155 DEG C, two sections of heat
Two sections of temperature of air cure are 140 DEG C.
Flame retardant property test is carried out with reference to national standard GB/T2408-1996：
Horizontal flame retardant property is burnt 20 minutes using 87.9KW coal gas Bunsen burners, and flame is extended to away from coal gas Bunsen burner fire
71 centimetres of flame front end, non smoke generate；Vertical Flame performance is burnt 30 minutes using 154.5KW coal gas Bunsen burners, vertical combustion
Distance is self-extinguish after 1.41 meters, 1.41 meters.Without black smoke and penetrating odor in combustion process.
According to the method tested for tensile strength and elongation at break in national standard GB/T1040-2006, puller system model island
The AG-20KNG of Tianjin company production；Rate of extension is 500mm/min, and test temperature is 23 DEG C, is found after testing, the compounded rubber
Tensile strength be 23.4N/mm2, elongation at break 298.1%.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail can carry out a variety of simple variants to technical scheme of the present invention within the scope of the technical concept of the present invention, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (10)
1. a kind of preparation method of cable fire-retardant combination, which is characterized in that the preparation method comprises the following steps：
(1) mixing is heated into dibastic sodium phosphate and montmorillonite in water, magnesium chloride is then added, be heated to reflux, it is mixed to obtain gel
Object is closed, then pH is adjusted to 8-13；
(2) gelatinous mixture is calcined, crushes, obtains the montmorillonite of phosphate-magnesium-doping vario-property；
(3) modified montmorillonite, nanoparticle active agent, antimony oxide and ammonium polyphosphate are proportionally mixed.
2. preparation method according to claim 1, wherein modified montmorillonite, nanoparticle active agent, antimony oxide and poly-
The mass ratio of ammonium phosphate is 10:1-2:1.5-3:2-3.
3. preparation method according to claim 2, wherein dibastic sodium phosphate in step (1), montmorillonite and magnesium chloride quality
Than for 3-5:20:2-4.
4. preparation method according to claim 2, wherein water and the mass ratio of montmorillonite are 15-50 in step (1):1.
5. preparation method according to claim 2, wherein mixing is heated in dibastic sodium phosphate, montmorillonite in water in step (1)
Condition include：Temperature is 60-80 DEG C, time 20-40min.
6. preparation method according to claim 2, wherein it is 90-120 DEG C to be heated to reflux temperature.
7. preparation method according to claim 2, wherein calcination condition includes in step (2)：Temperature is 200-280 DEG C,
Time is 1.5h-3h.
8. preparation method according to claim 2, wherein the substance for adjusting pH in step (1) is sodium hydroxide and/or hydrogen
Potassium oxide.
9. according to the preparation method described in any one of claim 1-8, wherein nanoparticle active agent is nano magnesia, nanometer
It is one or more in aluminium oxide, nm-class boron nitride and nano granular of zinc oxide.
10. the cable fire-retardant combination being prepared according to claim 1-9 any one of them preparation methods.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810499255.5A CN108586805A (en) | 2018-05-23 | 2018-05-23 | Cable fire-retardant combination and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810499255.5A CN108586805A (en) | 2018-05-23 | 2018-05-23 | Cable fire-retardant combination and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108586805A true CN108586805A (en) | 2018-09-28 |
Family
ID=63632869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810499255.5A Pending CN108586805A (en) | 2018-05-23 | 2018-05-23 | Cable fire-retardant combination and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108586805A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564002A (en) * | 2019-09-18 | 2019-12-13 | 广西华锑科技有限公司 | Surface modification method of special antimony trioxide for flame-retardant master batch |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556136A (en) * | 2003-12-30 | 2004-12-22 | 上海化工研究院 | Halogen less expansion type polyolefine incombustible agent and its preparation method |
| CN103030879A (en) * | 2011-09-29 | 2013-04-10 | 合肥杰事杰新材料股份有限公司 | Environment-friendly flame retardance permanent antistatic polypropylene material and preparation method of environment-friendly flame retardance permanent antistatic polypropylene material |
| CN103467674A (en) * | 2013-08-23 | 2013-12-25 | 吴江市天源塑胶有限公司 | Flame-retardant ABS plastic |
| CN107033924A (en) * | 2017-04-21 | 2017-08-11 | 常州市好利莱光电科技有限公司 | A kind of preparation method for preventing and treating spontaneous combustionof coal with compound retardant |
| CN107163310A (en) * | 2017-06-07 | 2017-09-15 | 常州苏达欧包装材料有限公司 | A kind of halogen-free fireproof rubber and preparation method thereof |
-
2018
- 2018-05-23 CN CN201810499255.5A patent/CN108586805A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556136A (en) * | 2003-12-30 | 2004-12-22 | 上海化工研究院 | Halogen less expansion type polyolefine incombustible agent and its preparation method |
| CN103030879A (en) * | 2011-09-29 | 2013-04-10 | 合肥杰事杰新材料股份有限公司 | Environment-friendly flame retardance permanent antistatic polypropylene material and preparation method of environment-friendly flame retardance permanent antistatic polypropylene material |
| CN103467674A (en) * | 2013-08-23 | 2013-12-25 | 吴江市天源塑胶有限公司 | Flame-retardant ABS plastic |
| CN107033924A (en) * | 2017-04-21 | 2017-08-11 | 常州市好利莱光电科技有限公司 | A kind of preparation method for preventing and treating spontaneous combustionof coal with compound retardant |
| CN107163310A (en) * | 2017-06-07 | 2017-09-15 | 常州苏达欧包装材料有限公司 | A kind of halogen-free fireproof rubber and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 卢国建: "《高层建筑及大型地下空间火灾防控技术》", 28 February 2014 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564002A (en) * | 2019-09-18 | 2019-12-13 | 广西华锑科技有限公司 | Surface modification method of special antimony trioxide for flame-retardant master batch |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103467832B (en) | Low temperature-resistanflexible flexible crosslinkable halogen-free flame retardant cable and preparation method thereof | |
| CN103232631B (en) | A kind of Halogen-free low-smoke flame-retardant cable sheath material and preparation method thereof | |
| CN100354989C (en) | Environmental protection type fire retardant thermal shrinkage tube without halogen | |
| CN106916362B (en) | Halogen-free flame-retardant polyolefin resin and preparation method thereof | |
| CN102898703B (en) | Flame retardant polyolefin cable material and preparation method thereof | |
| CN108485043A (en) | A kind of halogen-free environmental high fire-retardance temperature-sensing color-changing material and its application | |
| CN105367965B (en) | Fire-resisting cable halogen-free flameproof ceramic cable material of polyolefin and preparation method thereof | |
| CN103642118B (en) | Tube wall bubble-tight irradiation crosslinking halogen-free fire proofing and application during heat shrinkable | |
| CN103319748B (en) | Phosphorus-nitrogen compound fire retardant and its preparation method | |
| CN105385028A (en) | High-flame-retardant polypropylene material and preparation method thereof | |
| CN104513420B (en) | A kind of Halogen no red phosphorus heat-shrinkable T bush and preparation method thereof | |
| CN103102579A (en) | Halogen-free expanded flame retardant cable outer sheath material composition and preparation method thereof | |
| CN103694594B (en) | A kind of fire-resistant cable material | |
| CN108586805A (en) | Cable fire-retardant combination and preparation method thereof | |
| CN108641243A (en) | Fire-retardant compounded rubber of high intensity modified kaolin and preparation method thereof | |
| CN103613831A (en) | Nanometer environmental-protection halogen-free fire-retardation insulation material and preparation method thereof | |
| CN103333403A (en) | Halogen-free intumescent flame retardant polyolefine cable sheath material and preparation method thereof | |
| CN102977467A (en) | Cross-linked low-smoke and zero-halogen flame retardant cable material for nuclear power stations, and its preparation method | |
| CN108623842A (en) | Cable modified kaolin fire-retardant combination and preparation method thereof | |
| CN104262875B (en) | Intumescent flame-retardant cable material taking plant-based active carbon as synergist and preparation method thereof | |
| CN108690302A (en) | Cable modified montmorillonoid fire-retardant combination and preparation method thereof | |
| CN108659417A (en) | Fire-retardant compounded rubber of modified montmorillonoid and preparation method thereof | |
| CN108530805A (en) | High-strength anti-flaming compounded rubber and preparation method thereof | |
| CN108727637A (en) | Cable nontoxic fire-retardant combination and preparation method thereof | |
| CN108690303A (en) | Cable low-smoke and flame retardant composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180928 |