CN108583057B - Document and method for coloring and fixing color thereof - Google Patents
Document and method for coloring and fixing color thereof Download PDFInfo
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- CN108583057B CN108583057B CN201810439587.4A CN201810439587A CN108583057B CN 108583057 B CN108583057 B CN 108583057B CN 201810439587 A CN201810439587 A CN 201810439587A CN 108583057 B CN108583057 B CN 108583057B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D15/00—Printed matter of special format or style not otherwise provided for
- B42D15/0053—Forms specially designed for commercial use, e.g. bills, receipts, offer or order sheets, coupons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/415—Marking using chemicals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
- B42D25/465—Associating two or more layers using chemicals or adhesives
- B42D25/47—Associating two or more layers using chemicals or adhesives using adhesives
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/46—Elements suited for chemical verification or impeding chemical tampering, e.g. by use of eradicators
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Paper (AREA)
- Credit Cards Or The Like (AREA)
Abstract
A method for coloring and fixing color of a document comprises a piece of paper, wherein the paper is provided with encrypted information, the encrypted information comprises an encryption area and an anti-counterfeiting part, the encryption area is provided with the anti-counterfeiting part, the anti-counterfeiting part comprises a liquid storage film A, a liquid inlet hole A, a liquid storage film B, a liquid inlet hole B, a liquid storage film C, a liquid inlet hole C and a sealing part, one side of the liquid storage film A is provided with the liquid inlet hole A, one side of the liquid storage film B is provided with the liquid inlet hole C, the middle parts of the liquid storage film A, the liquid storage film B and the liquid storage film C are respectively provided with a through hole, the through hole is internally connected with the sealing part, the sealing part comprises a sealing column, a liquid outlet hole and a sealing plug, the sealing column is connected in the through hole in a sliding manner, the; the different heights of lifting that can extract sealed post, and then extract different colour developing agent lines to reach the effect that shows different passwords, anti-fake intensity is higher.
Description
Technical Field
The invention relates to a document, in particular to a document and a method for coloring and fixing the document.
Background
The receipt is a written certificate which is obtained or filled in when economic business occurs and specifies the actual conditions of transaction and matters, and is the original material and important basis for accounting. Transacting delivery of goods and payment of payment for goods. The document may indicate whether the exporter is performing, the degree of performing. The imported goods take the document as the right-of-delivery certificate for extracting the goods, and the goods are indicated if the document exists.
However, when documents are manufactured at present, documents are colored and fixed only by a simple coloring and fixing method, and although the method is simple and can quickly manufacture a large batch of documents, the following problems can exist at the same time: firstly, whether the document is real or not can not be directly reflected from paper, and a person taking the document can not directly judge whether the document is a real document or a false document; and secondly, when the person who takes the document judges whether the document is a true document or a false document, the person who takes the document needs to take the document to log in a related website of a national tax bureau or a local tax bureau on a computer, and an invoice code or an invoice number on the document is input, so that the true and false identification of the document can be carried out, and the time spent is long.
Disclosure of Invention
The invention aims to solve the technical problem of providing a document and a method for coloring and fixing color of the document, wherein the document manufactured by the method has good anti-counterfeiting performance, and when a worker takes the invoice manufactured by the method, the worker can judge the authenticity of the invoice through simple operation, so that the operation is simple; and the lifting different heights of the sealing column can be extracted, so that different color developing agent rows are extracted, the effect of displaying different passwords is achieved, and the anti-counterfeiting strength is higher.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: a document comprising a sheet of paper provided with encrypted information.
Encrypted information including encryption district and anti-fake part, install anti-fake part in the encryption district, anti-fake part includes liquid storage membrane A, feed liquor hole A, liquid storage membrane B, feed liquor hole B, liquid storage membrane C, feed liquor hole C7 and sealing, liquid storage membrane A one side is equipped with feed liquor hole A, liquid storage membrane B one side is equipped with feed liquor hole B, liquid storage membrane C one side is equipped with feed liquor hole C7, liquid storage membrane A, liquid storage membrane B and liquid storage membrane C middle part all are equipped with the through-hole, and the through-hole in-connection has sealing, sealing includes sealed post, goes out liquid hole and sealing plug, sealed post sliding connection is in the through-hole, and sealed post middle part is equipped with out the liquid hole, goes out the downthehole dismantlement of liquid and is connected.
The method comprises the following steps:
the method comprises the following steps: coloring the document;
step two: fixing the color of the document;
step three: calendaring treatment;
step four: anti-counterfeiting treatment;
step five: pasting a first layer of anti-counterfeiting film;
step six: sealing treatment;
step seven: sticking a second layer of anti-counterfeiting film;
step eight: pasting a third layer of anti-counterfeiting film;
step nine: and (5) packaging.
The document coloring step comprises the following steps: putting paper into a paper dyeing machine, and adding a colorant to color the document; the document color fixing step comprises: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal; the calendering treatment steps are as follows: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment; the anti-counterfeiting treatment steps are as follows: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice; drawing another piece of re-encryption information in the encryption area by using the pen stained with the crypto agent B, wherein the re-encryption information can be a official seal or a financial seal of a company with an invoice, so that double encryption is achieved; the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is penetrated on the liquid storage film A to form a liquid inlet hole A, and a color developing agent A is injected into the liquid inlet hole A; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A; the sealing treatment steps are as follows: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole; the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B, and water is injected into the liquid inlet hole B; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column; the third layer of anti-counterfeiting film is pasted by the following steps: adhering a liquid storage film C above the liquid storage film B in the seventh step by using glue in a mode of the sixth step or the seventh step, forming a liquid inlet hole C7 by penetrating a small hole in the liquid storage film C, and injecting a color developing agent B into the liquid inlet hole C7; a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column; the packaging processing steps are as follows: and (5) putting the document processed in the step eight into a dryer, adjusting the dryer to have a drying function, and keeping the drying temperature at 60-65 ℃, wherein the drying effect is best, and the liquid storage film A, the liquid storage film B and the liquid storage film C on the paper can be firmly adhered to the paper.
The color developing agent A comprises the following components: potassium iodide, sodium sulfate, phenylfluorone, ethanol, latex, carbon tetrachloride, zinc salicylate resin, hydroxypropyl methyl cellulose, methyl methacrylate, citral, limonene, an antioxidant, a preservative and a color fixing agent; the color developing agent A comprises, by weight, 0-2 parts of potassium iodide, 3-7 parts of sodium sulfate, 1-3 parts of phenylfluorenone, 3-7 parts of ethanol, 1-3 parts of latex, 8-14 parts of carbon tetrachloride, 5-9 parts of zinc salicylate resin, 4-6 parts of hydroxypropyl methyl cellulose, 5-7 parts of methyl methacrylate, 5-7 parts of citral, 10-14 parts of limonene, 2-6 parts of an antioxidant, 5-11 parts of a preservative and 3-5 parts of a color fixing agent.
The color developing agent B comprises the following components: phenolphthalein, citric acid, phenolic resin, diarylethane, talcum powder, zinc salicylate resin, methyl styrene, polyvinyl alcohol, acetamide, paraffin, sodium polyacrylate, antioxidant, preservative and color fixing agent; the color developing agent B comprises, by weight, 0-2 parts of phenolphthalein, 3-7 parts of citric acid, 1-3 parts of phenolic resin, 3-7 parts of diarylethane, 1-3 parts of talcum powder, 8-14 parts of zinc salicylate resin, 5-9 parts of methyl styrene, 4-6 parts of polyvinyl alcohol, 5-7 parts of acetamide, 5-7 parts of paraffin, 10-14 parts of sodium polyacrylate, 2-6 parts of antioxidant, 5-11 parts of preservative and 3-5 parts of color fixing agent.
The antioxidant is bisphenol monoacrylic acid or alkyl diphenylamine; the preservative is sec-butylamine, sodium silicate or methyl hydroxybenzoate wax; the color fixing agent is triethylene tetramine or epoxy chloropropane.
The stealth agent A is a starch solution, and the stealth agent B is a sodium hydroxide solution.
The liquid storage film A, the liquid storage film B and the liquid storage film C are composed of plastic films and rubber films.
The invention provides a document coloring and color fixing method, which has good anti-counterfeiting performance, and when a worker takes an invoice manufactured by the method, the authenticity of the invoice can be judged through simple operation, so that the operation is simple; and the lifting different heights of the sealing column can be extracted, so that different color developing agent rows are extracted, the effect of displaying different passwords is achieved, and the anti-counterfeiting strength is higher.
Drawings
FIG. 1 is a schematic view of a document made by the method of the present invention;
FIG. 2 is an enlarged view A of a portion of FIG. 1 according to the present invention.
Detailed Description
As shown in fig. 1-2, a document comprises a sheet of paper provided with encrypted information.
Encrypted information including encryption district and anti-fake part, install anti-fake part in the encryption district, anti-fake part includes liquid storage membrane A, feed liquor hole A3, liquid storage membrane B, feed liquor hole B, liquid storage membrane C, feed liquor hole C7 and sealing, liquid storage membrane A one side is equipped with feed liquor hole A3, liquid storage membrane B one side is equipped with feed liquor hole B5, liquid storage membrane C one side is equipped with feed liquor hole C7, liquid storage membrane A, liquid storage membrane B and liquid storage membrane C middle part all are equipped with the through-hole, and the through-hole in-connection has sealing, sealing includes sealed post, goes out liquid hole and sealing plug, sealed post sliding connection is in the through-hole, sealed post middle part is equipped with out the liquid hole, goes out the downthehole dismantlement of liquid and is connected with.
The method comprises the following steps:
the method comprises the following steps: coloring the document;
step two: fixing the color of the document;
step three: calendaring treatment;
step four: anti-counterfeiting treatment;
step five: pasting a first layer of anti-counterfeiting film;
step six: sealing treatment;
step seven: sticking a second layer of anti-counterfeiting film;
step eight: pasting a third layer of anti-counterfeiting film;
step nine: and (5) packaging.
The document coloring step comprises the following steps: putting paper into a paper dyeing machine, and adding a colorant to color the document; the document color fixing step comprises: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal; the calendering treatment steps are as follows: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment; the anti-counterfeiting treatment steps are as follows: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice; drawing another piece of re-encryption information in the encryption area by using the pen stained with the crypto agent B, wherein the re-encryption information can be a official seal or a financial seal of a company with an invoice, so that double encryption is achieved; the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is arranged on the liquid storage film A to form a liquid inlet hole A3, and a color developing agent A is injected into the liquid inlet hole A3; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A; the sealing treatment steps are as follows: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole; the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B5, and water is injected into the liquid inlet hole B5; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column; the third layer of anti-counterfeiting film is pasted by the following steps: adhering a liquid storage film C above the liquid storage film B in the seventh step by using glue in a mode of the sixth step or the seventh step, forming a liquid inlet hole C7 by penetrating a small hole in the liquid storage film C, and injecting a color developing agent B into the liquid inlet hole C7; and a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated through by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column.
The color developing agent A comprises the following components: potassium iodide, sodium sulfate, phenylfluorone, ethanol, latex, carbon tetrachloride, zinc salicylate resin, hydroxypropyl methyl cellulose, methyl methacrylate, citral, limonene, an antioxidant, a preservative and a color fixing agent; the color developing agent A comprises, by weight, 0-2 parts of potassium iodide, 3-7 parts of sodium sulfate, 1-3 parts of phenylfluorenone, 3-7 parts of ethanol, 1-3 parts of latex, 8-14 parts of carbon tetrachloride, 5-9 parts of zinc salicylate resin, 4-6 parts of hydroxypropyl methyl cellulose, 5-7 parts of methyl methacrylate, 5-7 parts of citral, 10-14 parts of limonene, 2-6 parts of an antioxidant, 5-11 parts of a preservative and 3-5 parts of a color fixing agent.
The color developing agent B comprises the following components: phenolphthalein, citric acid, phenolic resin, diarylethane, talcum powder, zinc salicylate resin, methyl styrene, polyvinyl alcohol, acetamide, paraffin, sodium polyacrylate, antioxidant, preservative and color fixing agent; the color developing agent B comprises, by weight, 0-2 parts of phenolphthalein, 3-7 parts of citric acid, 1-3 parts of phenolic resin, 3-7 parts of diarylethane, 1-3 parts of talcum powder, 8-14 parts of zinc salicylate resin, 5-9 parts of methyl styrene, 4-6 parts of polyvinyl alcohol, 5-7 parts of acetamide, 5-7 parts of paraffin, 10-14 parts of sodium polyacrylate, 2-6 parts of antioxidant, 5-11 parts of preservative and 3-5 parts of color fixing agent.
The antioxidant is bisphenol monoacrylic acid or alkyl diphenylamine; the preservative is sec-butylamine, sodium silicate or methyl hydroxybenzoate wax; the color fixing agent is triethylene tetramine or epoxy chloropropane.
The stealth agent A is a starch solution, and the stealth agent B is a sodium hydroxide solution.
The liquid storage film A2, the liquid storage film B4 and the liquid storage film C6 are composed of plastic films and rubber films.
The specific implementation process is as follows: when the operator takes the document manufactured by the method and needs to check the authenticity of the document, the operator pulls the sealing plug 10 on the paper 1, and presses the outermost liquid storage film C6 with a finger, when the pressing force reaches a certain degree, the liquid storage film B4 in the liquid storage film C6 is also in a concave state, at this time, the liquid storage film A2 in the liquid storage film B4 starts to deform, finally, the color developing agent A in the liquid storage film A2 flows out from the liquid outlet hole 9 of the sealing column 8, the operator can smear the color developing agent A with the finger and then smear the color developing agent A in the encryption area of the paper 1, at this time, the encryption area can drive the initial encryption information to be displayed from the encryption area because of the reaction of the invisible agent A and the color developing agent A, after the operator records the initial encryption information, the sealing column 8 is pulled until the sealing column 8 moves to the liquid storage film B4, the operator presses the outermost liquid storage film C6 with the finger, when the pressing force reaches a certain degree, the liquid storage film B4 in the liquid storage film C6 is also in a concave state, at the moment, water of the liquid storage film B4 flows out from the liquid outlet hole 9 of the sealing column 8, a worker can use fingers to be smeared with the water in the encryption area to remove the primary encryption information in the encryption area and prevent the leakage of the password, at the moment, the worker pulls the sealing column 8 again until the sealing column 8 moves into the liquid storage film C6 and presses the outermost liquid storage film C6 with the fingers, when the pressing force reaches a certain degree, the color developing agent B in the liquid storage film C6 flows out from the liquid outlet hole 9 of the sealing column 8, the worker can smear the color developing agent B in the encryption area with the fingers, at the moment, the encryption area reacts with the color developing agent B to drive the secondary encryption information to be displayed from the encryption area, the worker can record the secondary encryption information, and according to the combination of the primary encryption information and the secondary encryption information, the staff can confirm the true and false of this document, and it is fast to distinguish, does not need the staff to log in the website and finds out the true and false nature of this document through invoice code or invoice number on the document, and anti-fake intensity is higher and easy operation.
The anti-counterfeiting method has good anti-counterfeiting performance, and when a worker takes the document manufactured by the method, the authenticity of the document can be judged through simple operation, so that the operation is simple; and the different heights of lifting of sealed post 8 can be extracted, and then different color developing agent rows are extracted to reach the effect of showing different passwords, anti-fake intensity is higher.
Examples of the developer A added to the liquid storage film A2 and the developer B added to the liquid storage film B4 are as follows:
the embodiment I of the invention discloses a document coloring and fixing method, which comprises the following steps:
the method comprises the following steps: document coloring, wherein the document coloring step is as follows: putting paper into a paper dyeing machine, and adding a colorant to color the document;
step two: and (3) document color fixation, wherein the document color fixation step is as follows: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal;
step three: calendering, wherein the calendering comprises the following steps: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment;
step four: anti-counterfeiting treatment, which comprises the following steps: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice;
step five: pasting a first layer of anti-counterfeiting film, wherein the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is arranged on the liquid storage film A to form a liquid inlet hole A3, and a color developing agent A is injected into the liquid inlet hole A3; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A;
step six: sealing treatment, wherein the sealing treatment comprises the following steps: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole;
step seven: adhering a second layer of anti-counterfeiting film, wherein the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B5, and water is injected into the liquid inlet hole B5; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column;
step eight: pasting a third layer of anti-counterfeiting film, wherein the step of pasting the third layer of anti-counterfeiting film comprises the following steps: adhering a liquid storage film C above the liquid storage film B in the seventh step by using glue in a mode of the sixth step or the seventh step, forming a liquid inlet hole C7 by penetrating a small hole in the liquid storage film C, and injecting a color developing agent B into the liquid inlet hole C7; a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column;
step nine: packaging processing, wherein the packaging processing step is as follows: and (5) putting the document processed in the step eight into a dryer, adjusting the dryer to have a drying function, and keeping the drying temperature at 60-65 ℃, wherein the drying effect is best, and the liquid storage film A, the liquid storage film B and the liquid storage film C on the paper can be firmly adhered to the paper.
The color developing agent A comprises the following components: potassium iodide, sodium sulfate, phenylfluorone, ethanol, latex, carbon tetrachloride, zinc salicylate resin, hydroxypropyl methyl cellulose, methyl methacrylate, citral, limonene, an antioxidant, a preservative and a color fixing agent; the color developing agent A comprises, by weight, 0 part of potassium iodide, 3 parts of sodium sulfate, 1 part of phenylfluorenone, 3 parts of ethanol, 1 part of latex, 8 parts of carbon tetrachloride, 5 parts of zinc salicylate resin, 4 parts of hydroxypropyl methyl cellulose, 5 parts of methyl methacrylate, 5 parts of citral, 10 parts of limonene, 2 parts of an antioxidant, 5 parts of a preservative and 3 parts of a color fixing agent.
The color developing agent B comprises the following components: phenolphthalein, citric acid, phenolic resin, diarylethane, talcum powder, zinc salicylate resin, methyl styrene, polyvinyl alcohol, acetamide, paraffin, sodium polyacrylate, antioxidant, preservative and color fixing agent; the color developing agent B comprises, by weight, 0 part of phenolphthalein, 3 parts of citric acid, 1 part of phenolic resin, 3 parts of diarylethane, 1 part of talcum powder, 8 parts of zinc salicylate resin, 5 parts of methyl styrene, 4 parts of polyvinyl alcohol, 5 parts of acetamide, 5 parts of paraffin, 10 parts of sodium polyacrylate, 2 parts of antioxidant, 5-11 parts of preservative and 3 parts of color fixing agent.
The second embodiment is a method for coloring and fixing the document, which comprises the following steps:
the method comprises the following steps: document coloring, wherein the document coloring step is as follows: putting paper into a paper dyeing machine, and adding a colorant to color the document;
step two: and (3) document color fixation, wherein the document color fixation step is as follows: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal;
step three: calendering, wherein the calendering comprises the following steps: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment;
step four: anti-counterfeiting treatment, which comprises the following steps: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice;
step five: pasting a first layer of anti-counterfeiting film, wherein the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is arranged on the liquid storage film A to form a liquid inlet hole A3, and a color developing agent A is injected into the liquid inlet hole A3; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A;
step six: sealing treatment, wherein the sealing treatment comprises the following steps: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole;
step seven: adhering a second layer of anti-counterfeiting film, wherein the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B5, and water is injected into the liquid inlet hole B5; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column;
step eight: pasting a third layer of anti-counterfeiting film, wherein the step of pasting the third layer of anti-counterfeiting film comprises the following steps: adhering a liquid storage film C above the liquid storage film B in the seventh step by using glue in a mode of the sixth step or the seventh step, forming a liquid inlet hole C7 by penetrating a small hole in the liquid storage film C, and injecting a color developing agent B into the liquid inlet hole C7; a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column;
step nine: packaging processing, wherein the packaging processing step is as follows: and (5) putting the document processed in the step eight into a dryer, adjusting the dryer to have a drying function, and keeping the drying temperature at 60-65 ℃, wherein the drying effect is best, and the liquid storage film A, the liquid storage film B and the liquid storage film C on the paper can be firmly adhered to the paper.
The color developing agent A comprises the following components: potassium iodide, sodium sulfate, phenylfluorone, ethanol, latex, carbon tetrachloride, zinc salicylate resin, hydroxypropyl methyl cellulose, methyl methacrylate, citral, limonene, an antioxidant, a preservative and a color fixing agent; the color developing agent A comprises, by weight, 1 part of potassium iodide, 5 parts of sodium sulfate, 2 parts of phenylfluorone, 5 parts of ethanol, 2 parts of latex, 11 parts of carbon tetrachloride, 7 parts of zinc salicylate resin, 5 parts of hydroxypropyl methyl cellulose, 6 parts of methyl methacrylate, 6 parts of citral, 12 parts of limonene, 4 parts of an antioxidant, 8 parts of a preservative and 4 parts of a color fixing agent.
The color developing agent B comprises the following components: phenolphthalein, citric acid, phenolic resin, diarylethane, talcum powder, zinc salicylate resin, methyl styrene, polyvinyl alcohol, acetamide, paraffin, sodium polyacrylate, antioxidant, preservative and color fixing agent; the color developing agent B comprises, by weight, 1 part of phenolphthalein, 5 parts of citric acid, 2 parts of phenolic resin, 5 parts of diarylethane, 2 parts of talcum powder, 11 parts of zinc salicylate resin, 7 parts of methyl styrene, 5 parts of polyvinyl alcohol, 6 parts of acetamide, 6 parts of paraffin, 12 parts of sodium polyacrylate, 4 parts of antioxidant, 8 parts of preservative and 4 parts of color fixing agent.
The third embodiment is a method for coloring and fixing the color of the document, which comprises the following steps:
the method comprises the following steps: document coloring, wherein the document coloring step is as follows: putting paper into a paper dyeing machine, and adding a colorant to color the document;
step two: and (3) document color fixation, wherein the document color fixation step is as follows: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal;
step three: calendering, wherein the calendering comprises the following steps: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment;
step four: anti-counterfeiting treatment, which comprises the following steps: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice;
step five: pasting a first layer of anti-counterfeiting film, wherein the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is arranged on the liquid storage film A to form a liquid inlet hole A3, and a color developing agent A is injected into the liquid inlet hole A3; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A;
step six: sealing treatment, wherein the sealing treatment comprises the following steps: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole;
step seven: adhering a second layer of anti-counterfeiting film, wherein the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B5, and water is injected into the liquid inlet hole B5; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column;
step eight: pasting a third layer of anti-counterfeiting film, wherein the step of pasting the third layer of anti-counterfeiting film comprises the following steps: adhering a liquid storage film C above the liquid storage film B in the seventh step by using glue in a mode of the sixth step or the seventh step, forming a liquid inlet hole C7 by penetrating a small hole in the liquid storage film C, and injecting a color developing agent B into the liquid inlet hole C7; a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column;
step nine: packaging processing, wherein the packaging processing step is as follows: and (5) putting the document processed in the step eight into a dryer, adjusting the dryer to have a drying function, and keeping the drying temperature at 60-65 ℃, wherein the drying effect is best, and the liquid storage film A, the liquid storage film B and the liquid storage film C on the paper can be firmly adhered to the paper.
The color developing agent A comprises the following components: potassium iodide, sodium sulfate, phenylfluorone, ethanol, latex, carbon tetrachloride, zinc salicylate resin, hydroxypropyl methyl cellulose, methyl methacrylate, citral, limonene, an antioxidant, a preservative and a color fixing agent; the color developing agent A comprises, by weight, 2 parts of potassium iodide, 7 parts of sodium sulfate, 3 parts of phenylfluorone, 7 parts of ethanol, 3 parts of latex, 14 parts of carbon tetrachloride, 9 parts of zinc salicylate resin, 6 parts of hydroxypropyl methyl cellulose, 7 parts of methyl methacrylate, 7 parts of citral, 14 parts of limonene, 6 parts of an antioxidant, 11 parts of a preservative and 5 parts of a color fixing agent.
The color developing agent B comprises the following components: phenolphthalein, citric acid, phenolic resin, diarylethane, talcum powder, zinc salicylate resin, methyl styrene, polyvinyl alcohol, acetamide, paraffin, sodium polyacrylate, antioxidant, preservative and color fixing agent; the color developing agent A comprises, by weight, 2 parts of phenolphthalein, 7 parts of citric acid, 3 parts of phenolic resin, 7 parts of diarylethane, 3 parts of talcum powder, 14 parts of zinc salicylate resin, 9 parts of methyl styrene, 6 parts of polyvinyl alcohol, 7 parts of acetamide, 7 parts of paraffin, 14 parts of sodium polyacrylate, 6 parts of antioxidant, 11 parts of preservative and 5 parts of color fixing agent.
Use effect experiment: the research examines the product through 100 users and examines the effects of the document 1 which is colored and fixed through the method in all aspects. The test items are the difficulty of distinguishing the true from the false and the definition of the information in the encryption area; the evaluation standard of the test item is as follows: 1. difficulty in distinguishing authenticity: very easy 5 points, easy 4 points, general 3 points, difficult 2 points, very difficult 1 point; 2. definition of encryption zone information: very clear 5 points, clear 4 points, general 3 points, fuzzy 2 points, very fuzzy 1 points
Wherein the common group is a common document 1:
through the document 1 manufactured by the enterprise by using the coloring and color fixing method in the document, the conclusion can be drawn that the document 1 coloring and color fixing method has the advantages of difficulty in distinguishing authenticity and stable definition of information of an encryption area under the condition of the second embodiment, and the components of the color developing agent A and the parts by weight of the components are 1 part of potassium iodide, 5 parts of sodium sulfate, 2 parts of phenylfluorone, 5 parts of ethanol, 2 parts of latex, 11 parts of carbon tetrachloride, 7 parts of zinc salicylate resin, 5 parts of hydroxypropyl methyl cellulose, 6 parts of methyl methacrylate, 6 parts of citral, 12 parts of limonene, 4 parts of antioxidant, 8 parts of preservative and 4 parts of color fixing agent; the color developing agent B is in the most stable state when the components and the parts by weight of the components are 1 part of phenolphthalein, 5 parts of citric acid, 2 parts of phenolic resin, 5 parts of diarylethane, 2 parts of talcum powder, 11 parts of zinc salicylate resin, 7 parts of methyl styrene, 5 parts of polyvinyl alcohol, 6 parts of acetamide, 6 parts of paraffin, 12 parts of sodium polyacrylate, 4 parts of antioxidant, 8 parts of preservative and 4 parts of color fixing agent, the using effect is also the best state, and the encryption area of the paper sheet 1 can display clear information, so that a user can clearly see the information content of the encryption area.
The above-described embodiments are merely preferred embodiments of the present invention, and should not be construed as limiting the present invention, and the scope of the present invention is defined by the claims, and equivalents including technical features described in the claims. I.e., equivalent alterations and modifications within the scope hereof, are also intended to be within the scope of the invention.
Claims (4)
1. A receipt comprises paper and is characterized in that the paper is provided with encryption information, the encryption information comprises an encryption area and anti-counterfeiting components, the anti-counterfeiting components are installed on the encryption area and comprise liquid storage films A, liquid inlet holes A, liquid storage films B, liquid inlet holes B, liquid storage films C, liquid inlet holes C and sealing parts, one sides of the liquid storage films A are provided with the liquid inlet holes A, color developing agents A are contained in the liquid storage films A, one sides of the liquid storage films B are provided with the liquid inlet holes B, water is contained in the liquid storage films B, one sides of the liquid storage films C are provided with the liquid inlet holes C, color developing agents B are contained in the liquid storage films C, through holes are formed in the middle parts of the liquid storage films A, the liquid storage films B and the liquid storage films C, the sealing parts are connected in the through holes and comprise sealing columns, liquid outlet holes and sealing plugs, the sealing columns are connected in the through holes in a, a sealing plug is detachably connected in the liquid outlet hole, the encryption region is respectively drawn with encryption information by using an invisible agent A and an invisible agent B, the invisible agent A is a starch solution, the invisible agent B is a sodium hydroxide solution, the components and parts by weight of the color developing agent A are 0-2 parts of potassium iodide, 3-7 parts of sodium sulfate, 1-3 parts of phenylfluorone, 3-7 parts of ethanol, 1-3 parts of latex, 8-14 parts of carbon tetrachloride, 5-9 parts of zinc salicylate resin, 4-6 parts of hydroxypropyl methyl cellulose, 5-7 parts of methyl methacrylate, 5-7 parts of citral, 10-14 parts of limonene, 2-6 parts of an antioxidant, 5-11 parts of a preservative and 3-5 parts of a color fixing agent, the components and parts by weight of the color developing agent B are 0-2 parts of phenolphthalein, 0-2 parts of the invisible agent B and 3-5 parts of the color fixing agent B, 3-7 parts of citric acid, 1-3 parts of phenolic resin, 3-7 parts of diarylethane, 1-3 parts of talcum powder, 8-14 parts of zinc salicylate resin, 5-9 parts of methyl styrene, 4-6 parts of polyvinyl alcohol, 5-7 parts of acetamide, 5-7 parts of paraffin, 10-14 parts of sodium polyacrylate, 2-6 parts of antioxidant, 5-11 parts of preservative and 3-5 parts of color fixing agent.
2. The document according to claim 1, wherein the antioxidant is bisphenol monoacrylic acid or alkyl diphenylamine; the preservative is sec-butylamine, sodium silicate or methyl hydroxybenzoate wax; the color fixing agent is triethylene tetramine or epoxy chloropropane.
3. A document coloring and color fixing method is characterized by comprising the following steps:
the method comprises the following steps: coloring the document;
step two: fixing the color of the document;
step three: calendaring treatment;
step four: anti-counterfeiting treatment;
step five: pasting a first layer of anti-counterfeiting film;
step six: sealing treatment;
step seven: sticking a second layer of anti-counterfeiting film;
step eight: pasting a third layer of anti-counterfeiting film;
step nine: packaging;
the document coloring step comprises the following steps: putting paper into a paper dyeing machine, and adding a colorant to color the document; the document color fixing step comprises: putting the colored paper in the step one into a dryer, and adjusting the drying temperature of the dryer to 65-85 ℃, wherein the color fixing effect of the paper is optimal; the calendering treatment steps are as follows: the paper subjected to color fixation in the second step is subjected to calendering treatment by a calender, the rotating speed of a press roll of the calender is adjusted to be 220m/min, the temperature of the press roll of the calender is adjusted to be 70-90 ℃, and the calendering effect of the paper is optimal at the moment; the anti-counterfeiting treatment steps are as follows: marking one part of the paper on the paper subjected to the calendaring treatment in the step three as an encryption area, and drawing primary encryption information in the encryption area by using a pen stained with a crypto agent A, wherein the primary encryption information can be the name or address of a company for issuing an invoice; drawing another piece of re-encryption information in the encryption area by using the pen stained with the crypto agent B, wherein the re-encryption information can be a official seal or a financial seal of a company with an invoice, so that double encryption is achieved; the step of pasting the first layer of anti-counterfeiting film comprises the following steps: a liquid storage film A is adhered on the document by glue, a small hole is penetrated on the liquid storage film A to form a liquid inlet hole A, and a color developing agent A is injected into the liquid inlet hole A; a through hole A is formed in the liquid storage film A through a hole, and a sealing ring is additionally arranged in the through hole A; the sealing treatment steps are as follows: inserting a sealing column into the through hole A on the liquid storage film A in the fifth step, punching from the middle part of the sealing column to form a liquid outlet hole, and inserting a sealing plug into the liquid outlet hole; the step of adhering the second layer of anti-counterfeiting film comprises the following steps: a liquid storage film B is adhered above the liquid storage film A in the sixth step by glue in the fifth step, a small hole is formed in the liquid storage film B to form a liquid inlet hole B, and water is injected into the liquid inlet hole B; a through hole B is formed in the liquid storage film B through a perforation, the through hole B is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole B and the sealing column; the third layer of anti-counterfeiting film is pasted by the following steps: adhering a liquid storage membrane C above the liquid storage membrane B in the seventh step by using glue in a mode of the sixth step or the seventh step, penetrating a small hole in the liquid storage membrane C to form a liquid inlet hole C, and injecting a color developing agent B into the liquid inlet hole C; a through hole C is formed in the liquid storage film C through punching, the through hole C is penetrated by the sealing column, and a sealing ring is additionally arranged at the joint of the through hole C and the sealing column; the packaging processing steps are as follows: and (5) putting the document processed in the step eight into a dryer, adjusting the dryer to have a drying function, and keeping the drying temperature at 60-65 ℃, wherein the drying effect is best, and the liquid storage film A, the liquid storage film B and the liquid storage film C on the paper can be firmly adhered to the paper.
4. The method for document fixation of color according to claim 3, wherein the liquid storage film A, the liquid storage film B and the liquid storage film C are composed of plastic film and rubber film.
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| CN1137225C (en) * | 2001-04-30 | 2004-02-04 | 上海复旦天臣新技术有限公司 | Moisture-sensitive allochromatic material and its preparing process |
| CN1202309C (en) * | 2002-09-25 | 2005-05-18 | 康文朝 | Color veiled-image anti-fake paper and its making process |
| DE102004045211B4 (en) * | 2004-09-17 | 2015-07-09 | Ovd Kinegram Ag | Security document with electrically controlled display element |
| GB0714141D0 (en) * | 2007-07-19 | 2007-08-29 | Rue De Int Ltd | security device |
| CN102565054B (en) * | 2011-12-15 | 2013-04-03 | 湖北中信京华彩印股份有限公司 | Material capable of quickly changing color when wetted, preparation method for material and application of material |
| CN106894288B (en) * | 2015-12-19 | 2019-01-04 | 上海西文服饰有限公司 | A kind of anti-fake drop for clothing and preparation method thereof |
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