CN108579780A - A kind of quick catalysis decomposes the processing method of rubbish from cooking - Google Patents

A kind of quick catalysis decomposes the processing method of rubbish from cooking Download PDF

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Publication number
CN108579780A
CN108579780A CN201810000928.8A CN201810000928A CN108579780A CN 108579780 A CN108579780 A CN 108579780A CN 201810000928 A CN201810000928 A CN 201810000928A CN 108579780 A CN108579780 A CN 108579780A
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China
Prior art keywords
catalyst
rubbish
added
processing method
mixed
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CN201810000928.8A
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Chinese (zh)
Inventor
李振华
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Guangdong Jiarong Environmental Protection Equipment Co Ltd
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Guangdong Jiarong Environmental Protection Equipment Co Ltd
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Priority to CN201810000928.8A priority Critical patent/CN108579780A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/232Carbonates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • C05F9/04Biological compost
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to the processing methods that a kind of quick catalysis decomposes rubbish from cooking, include the following steps:S1:A certain amount of iron powder and aluminium powder are mixed, acetum is added and is dissolved so that the concentration of iron is maintained at 90~93g/L;S2:It heats while stirring, ammonium hydroxide is added when solution boils;S3:Precipitation of calcium carbonate is added, drying precipitate is obtained into Fe Al Si K catalyst bases;S4:It is mixed with carrier, catalyst is made;S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, heating, and are kept the temperature;S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation is handled through low-temperature catalytic burning;S7:Catalyst circulation uses, by dead catalyst compost treatment.The advantage of the invention is that:It is efficient, overall treatment can be carried out to the kitchen garbage of various complicated forms, rubbish is turned waste into wealth, by-product is processed and is recycled, not will produce secondary pollution before and after the processing, and processing procedure is simple to operation.

Description

A kind of quick catalysis decomposes the processing method of rubbish from cooking
Technical field
The present invention relates to kitchen garbage technical field, especially a kind of quick catalysis decomposes the processing method of rubbish from cooking.
Background technology
With the growth of national economy and the sustainable development of catering industry, the yield of China's kitchen garbage is also constantly increasing It is long.Kitchen garbage contains the perishabilities substance such as starch, cellulose, protein, fat, and thus caused environmental problem also causes Extensive concern both domestic and external.It was estimated in China Statistical Yearbook according to 2012, the annual kitchen garbage in the city of China in 2011 Output is about 4000~50,000,000 tons.How to handle these kitchen garbages becomes China's solid waste resource in recent years Change an important topic in research on utilization field.
Currently, in all parts of the country increasingly pay attention to the processing of kitchen garbage, kitchen garbage is come into effect from house refuse Separate individually receive fortune measure, kitchen garbage separated from house refuse be its recycling premise.It is same with this When, domestic garbage treatment plant and kitchen garbage treatment plant etc. are gradually built in various regions, instead of original refuse landfill, rubbish Resource utilization utilizes the Main way for becoming garbage disposal from now on.
The effective way of changing food waste into resources processing is anaerobic fermentation Biogas.The major defect of anaerobic fermentation processing It is long processing period (more than for 24 hours), treating capacity is small, sometimes along with the generation of sour suppression in processing procedure, influences to detest The progress of aerobe fermentation.At the same time, cost of investment and processing cost are high.
Invention content
It is an object of the invention to overcome the prior art, a kind of processing of quick catalysis decomposition rubbish from cooking is provided Method accelerates the resolution process of kitchen garbage by preparing catalyst, efficient, can be to the kitchen garbage of various complicated forms Overall treatment is carried out, rubbish is turned waste into wealth, by-product is processed and is recycled, not will produce secondary pollution before and after the processing, and locate Reason process is simple to operation.
The purpose of the present invention is achieved through the following technical solutions:A kind of quick catalysis decomposes the processing side of rubbish from cooking Method includes the following steps:
S1:A certain amount of iron powder and aluminium powder are mixed, the acetum of addition a concentration of 28~32% is dissolved so that The concentration of iron is maintained at 90~93g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils;
S3:Precipitation of calcium carbonate is added, sediment is dried into 22~26h in 100~110 DEG C of environment, obtains Fe-Al- Si-K catalyst bases;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with carrier, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 160~180 DEG C, and keep the temperature 4~6h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalyzed Burning is handled;
S7:After catalyst circulation uses 25~35 times, by dead catalyst compost treatment.
Further, in step S1, iron powder and aluminium powder are 100 in mass ratio:0.2~0.4 is mixed.
Further, in step S2, a concentration of 4~6mol/L of ammonium hydroxide is added.
Further, in step S3, the amount that calcium carbonate is added is 12~15g/L.
Further, in step S4, the carrier is sawdust.
The present invention has the following advantages:
1, accelerate the resolution process of kitchen garbage by preparing catalyst, it is efficient, it can be to the meal of various complicated forms Kitchen rubbish carries out overall treatment, and rubbish is turned waste into wealth, and by-product is processed and is recycled, not will produce secondary dirt before and after the processing Dye, and processing procedure is simple to operation.
Specific implementation mode
With reference to embodiment, the present invention will be further described, but protection scope of the present invention is not limited to following institute It states.
【Embodiment 1】:
A kind of quick catalysis decomposes the processing method of rubbish from cooking, includes the following steps:
S1:It is 100 in mass ratio by a certain amount of iron powder and aluminium powder:0.2 is mixed, and a concentration of 32% acetic acid is added Solution is dissolved so that the concentration of iron is maintained at 93g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils, a concentration of 6mol/L of ammonium hydroxide is added;
S3:Precipitation of calcium carbonate is added, sediment in 110 DEG C of environment is dried 22h, obtained by addition 12g/L Fe-Al-Si-K catalyst bases;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with sawdust, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 180 DEG C, and keep the temperature 6h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalyzed Burning is handled;
S7:After catalyst circulation uses 35 times, by dead catalyst compost treatment.
【Embodiment 2】:
A kind of quick catalysis decomposes the processing method of rubbish from cooking, includes the following steps:
S1:It is 100 in mass ratio by a certain amount of iron powder and aluminium powder:0.3 is mixed, and a concentration of 30% acetic acid is added Solution is dissolved so that the concentration of iron is maintained at 92g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils, a concentration of 5mol/L of ammonium hydroxide is added;
S3:Precipitation of calcium carbonate is added, addition 13g/L, drying for 24 hours, obtains in 105 DEG C of environment by sediment Fe-Al-Si-K catalyst bases;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with sawdust, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 170 DEG C, and keep the temperature 5h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalyzed Burning is handled;
S7:After catalyst circulation uses 30 times, by dead catalyst compost treatment.
The embodiment is most preferred embodiment.
【Embodiment 3】:
A kind of quick catalysis decomposes the processing method of rubbish from cooking, includes the following steps:
S1:It is 100 in mass ratio by a certain amount of iron powder and aluminium powder:0.3 is mixed, and a concentration of 30% acetic acid is added Solution is dissolved so that the concentration of iron is maintained at 90g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils, a concentration of 5mol/L of ammonium hydroxide is added;
S3:Precipitation of calcium carbonate is added, addition 15g/L, drying for 24 hours, obtains in 105 DEG C of environment by sediment Fe-Al-Si-K catalyst bases;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with sawdust, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 160 DEG C, and keep the temperature 5h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalyzed Burning is handled;
S7:After catalyst circulation uses 30 times, by dead catalyst compost treatment.
【Embodiment 4】:
A kind of quick catalysis decomposes the processing method of rubbish from cooking, includes the following steps:
S1:It is 100 in mass ratio by a certain amount of iron powder and aluminium powder:0.4 is mixed, and a concentration of 28% acetic acid is added Solution is dissolved so that the concentration of iron is maintained at 90g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils, a concentration of 4mol/L of ammonium hydroxide is added;
S3:Precipitation of calcium carbonate is added, sediment is dried 26h by addition 15g/L in 100~110 DEG C of environment, Obtain Fe-Al-Si-K catalyst bases;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with sawdust, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 160 DEG C, and keep the temperature 4h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalyzed Burning is handled;
S7:After catalyst circulation uses 25 times, by dead catalyst compost treatment.
After kitchen garbage is handled according to the processing method multiplicating of embodiment 2, condensed water and dead catalyst are obtained.Its Middle condensation water constituent is as shown in table 1, and dead catalyst ingredient is as shown in table 2.
The ingredient of 1 condensed water of table
Test event Unit Test result Test event Unit Test result
BOD mg/L 2700 PCBs mg/L It is not detected
COD mg/L 1200 Salinity % 0.002
pH - 3.0 Cr mg/L 0.11
Escherichia coli A/mL < 30 Zn mg/L 0.56
Coloration Degree 390 Hg mg/L It is not detected
Nitrogen mg/L 34.5 As mg/L It is not detected
Phosphorus mg/L 0.36 Pb mg/L It is not detected
Grease type mg/L 8.2 Tetrachloro-ethylene mg/L It is not detected
The ingredient of 2 dead catalyst of table
Test event Unit Test result
Lead mg/L It is not detected
Copper mg/L 0.574
Arsenic mg/L 0.113
Mercury mg/L It is not detected
Cr VI mg/L 1.20
Cadmium mg/L 0.058
Organophosphor mg/L It is not detected
Grease mg/L 4.89
Tetrachloro-ethylene mg/L It is not detected
Trichloro ethylene mg/L It is not detected
Cyano mg/L It is not detected
According to Tables 1 and 2 it is found that generating pollution to environment without containing PCBs, Hg, As, Pb, tetrachloro-ethylene etc. in condensed water Pollutant, the pollution that lead, mercury, tetrachloro-ethylene, trichloro ethylene, cyano etc. generate environment pollution is not contained in dead catalyst yet Object, the byproduct obtained after processing can be safe to use, not will produce secondary pollution.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of quick catalysis decomposes the processing method of rubbish from cooking, it is characterised in that:Include the following steps:
S1:A certain amount of iron powder and aluminium powder are mixed, the acetum of addition a concentration of 28~32% is dissolved so that iron Concentration is maintained at 90~93g/L;
S2:It heats while stirring, ammonium hydroxide is added when solution boils;
S3:Precipitation of calcium carbonate is added, sediment is dried into 22~26h in 100~110 DEG C of environment, obtains Fe-Al-Si-K Catalyst base;
S4:It takes above-mentioned Fe-Al-Si-K catalyst bases to be mixed with carrier, catalyst is made;
S5:The catalyst and kitchen garbage for taking equivalent are stirred in a kettle, are heated to 160~180 DEG C, and keep the temperature 4~ 6h;
S6:The condensate water collecting that reaction generates is got up, liquid fertilizer is used for after dilution, the exhaust gas of generation to be through low-temperature catalytic burning Processing;
S7:After catalyst circulation uses 25~35 times, by dead catalyst compost treatment.
2. a kind of quick catalysis decomposes the processing method of rubbish from cooking according to claim 1, it is characterised in that:Step S1 In, iron powder and aluminium powder are 100 in mass ratio:0.2~0.4 is mixed.
3. a kind of quick catalysis decomposes the processing method of rubbish from cooking according to claim 1, it is characterised in that:Step S2 In, a concentration of 4~6mol/L of ammonium hydroxide is added.
4. a kind of quick catalysis decomposes the processing method of rubbish from cooking according to claim 1, it is characterised in that:Step S3 In, the amount that calcium carbonate is added is 12~15g/L.
5. a kind of quick catalysis decomposes the processing method of rubbish from cooking according to claim 1, it is characterised in that:Step S4 In, the carrier is sawdust.
CN201810000928.8A 2018-01-02 2018-01-02 A kind of quick catalysis decomposes the processing method of rubbish from cooking Pending CN108579780A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109627131A (en) * 2019-02-27 2019-04-16 上海市园林科学规划研究院 A kind of method for making plant quickly absorb organic wet garbage and fertilizer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101890423A (en) * 2010-04-30 2010-11-24 郭东平 Recycling method for cleaning and processing kitchen waste
CN103877980A (en) * 2014-03-19 2014-06-25 中国科学院过程工程研究所 Catalyst for lightening tar by catalytic pyrolysis and preparation method of catalyst
CN105567264A (en) * 2015-12-21 2016-05-11 中国科学院过程工程研究所 Modular equipment using solid waste catalytic pyrolysis to prepare high-value fuel gas
CN106215878A (en) * 2016-08-30 2016-12-14 西南化工研究设计院有限公司 The extraordinary desulfurizing agent of a kind of food waste deodorization process and deodorization process
CN107459126A (en) * 2017-09-22 2017-12-12 广东产品质量监督检验研究院 A kind of kitchen garbage, waste-water COD minimizing technology and system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101890423A (en) * 2010-04-30 2010-11-24 郭东平 Recycling method for cleaning and processing kitchen waste
CN103877980A (en) * 2014-03-19 2014-06-25 中国科学院过程工程研究所 Catalyst for lightening tar by catalytic pyrolysis and preparation method of catalyst
CN105567264A (en) * 2015-12-21 2016-05-11 中国科学院过程工程研究所 Modular equipment using solid waste catalytic pyrolysis to prepare high-value fuel gas
CN106215878A (en) * 2016-08-30 2016-12-14 西南化工研究设计院有限公司 The extraordinary desulfurizing agent of a kind of food waste deodorization process and deodorization process
CN107459126A (en) * 2017-09-22 2017-12-12 广东产品质量监督检验研究院 A kind of kitchen garbage, waste-water COD minimizing technology and system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109627131A (en) * 2019-02-27 2019-04-16 上海市园林科学规划研究院 A kind of method for making plant quickly absorb organic wet garbage and fertilizer

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