CN108579439A - A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution - Google Patents

A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution Download PDF

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Publication number
CN108579439A
CN108579439A CN201810674771.7A CN201810674771A CN108579439A CN 108579439 A CN108579439 A CN 108579439A CN 201810674771 A CN201810674771 A CN 201810674771A CN 108579439 A CN108579439 A CN 108579439A
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China
Prior art keywords
filter
membrane
electric field
membrane module
filter housings
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Pending
Application number
CN201810674771.7A
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Chinese (zh)
Inventor
吴涛
翟丁
高从堦
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Huzhou Research Institute Of Membrane Separation And Water Treatment Co Innovation Center Zhejiang University Of Technology
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Huzhou Research Institute Of Membrane Separation And Water Treatment Co Innovation Center Zhejiang University Of Technology
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Priority to CN201810674771.7A priority Critical patent/CN108579439A/en
Publication of CN108579439A publication Critical patent/CN108579439A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/427Electro-osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08Prevention of membrane fouling or of concentration polarisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4698Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electro-osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/06Pressure conditions
    • C02F2301/066Overpressure, high pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Urology & Nephrology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention relates to a kind of membrane filters, in particular to a kind of general-purpose highly effective anti-pollution to block up electric field membrane filter.The present invention includes membrane module, filter housings, wherein membrane module is installed in filter housings, is placed conductive plastics electrode centers pipe at filter housings center, is connected with power cathode, filter housings internal edge places one layer of conductive plastics electrode grid, connects positive pole;Membrane module is fixed by top filter core positioning compression plate;Water inlet, water outlet are offered on filter housings, the water inlet of water inlet is filtered out of shell into membrane module by cathode electric field pipe network, later by membrane module central collection treatment fluid, is flowed out finally by the water outlet of filter housings.It is an advantage of the invention that overcoming concentration polarization phenomenon, fouling membrane situation is effectively improved so that greatly increase filtration flux through the seepage flow of filter membrane and be improved.

Description

A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution
Technical field
The present invention relates to a kind of membrane filters, in particular to a kind of general-purpose highly effective anti-pollution to block up electric field membrane filter, specifically Applied to water-treatment technology field.
Background technology
The mechanism of membrane filtration is mainly not have phase transformation and secondary pollution in mechanical grading process and membrane filtration, therefore quilt It is taken seriously extensively, and has been applied to the concentration and separation process in the fields such as chemical industry, biochemistry medicine, food.But due to film surface Concentration polarization and film surface deposition and fouling membrane phenomenon, membrane filtration rate at any time it is rapid decay be still asking for generally existing Topic, it is only 1/10 when new film just works, separation that is even lower while can also making film that it, which often results in the membrane filtration rate in production, Performance declines, the reduced service life of film.For the phenomenon that membrane filtration rate decays rapidly at any time during membrane filtration, put forth effort to develop It is a kind of can improve membrane filtration rate, contain fouling membrane optimum organization filter membrane by being important.
After DC electric field is then added inside and outside membrane module makes the particle generation that is trapped with net deposit charge in filter chamber deviate from The electrophoretic migration of film surface moves.This electrophoretic action can be reduced so that preventing from being trapped deposition of the particle to film surface, you can gram It takes concentration polarization phenomenon and improves fouling membrane situation.At the same time additional electric field can also make liquid production of the infiltration in filter membrane hole The mobile phenomenon through hole of raw orientation this imitates different from the seepage flow through filter membrane caused by pressure difference but a kind of electric osmose It answers.
Invention content
A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution, production method is to install several membrane modules into filtering In device shell, the conductive plastics electrode centers pipe that a carbon modeling Polymer Synthesizing is placed at filter housings center is used for connecting electricity Source cathode, the conductive plastics electrode grid that filter housings internal edge places one layer of flexible carbon modeling Polymer Synthesizing are used for Positive pole is connected, membrane module is fixed by top filter core positioning compression plate and connects power supply;By compression pump in filter Housing inlet squeezes into accessing pending water solution, is filtered into membrane module out of shell by anode electric field pipe network, Zhi Houtong Membrane module central collection treatment fluid is crossed, is flowed out finally by the water outlet of filter housings.
The present invention is achieved by following technical proposals:
A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution, including membrane module, filter housings, it is characterised in that film group Part is installed in filter housings, is placed conductive plastics electrode centers pipe at filter housings center, is connected with power cathode, mistake Filter shell internal edge places one layer of conductive plastics electrode grid, connects positive pole;
Membrane module is fixed by top filter core positioning compression plate;Water inlet, water outlet are offered on filter housings, The water inlet of water inlet is filtered out of shell into membrane module by anode electric field pipe network, passes through membrane module central collection later Treatment fluid is flowed out finally by the water outlet of filter housings.
Preferably, a kind of above-mentioned general-purpose highly effective anti-pollution block up membrane module described in electric field membrane filter be winded filtering core, Spray welding filter element, inorganic ceramic membrane filter or foldable filter element, used diaphragm are the seperation film that aperture is 0.01~0.1 μm.
Preferably, a kind of above-mentioned general-purpose highly effective anti-pollution blocks up the upper position in filter housings in electric field membrane filter Circulation port is offered, sewage draining exit is offered in the lower part of filter housings.
Preferably, a kind of above-mentioned general-purpose highly effective anti-pollution block up conductive plastics electrode centers pipe in electric field membrane filter be by Carbon is moulded made of Polymer Synthesizing.
It is placed preferably, a kind of above-mentioned general-purpose highly effective anti-pollution blocks up filter housings internal edge in electric field membrane filter The conductive plastics pipe composition electrode grid of several flexible carbon modeling Polymer Synthesizings is used for connecting positive pole, the electrode network Lattice include top filter core positioning compression plate.
Preferably, a kind of above-mentioned general-purpose highly effective anti-pollution, which blocks up water inlet in electric field membrane filter, passes through compression pump and raw water Case connects, and accessing pending water solution is entered by water inlet in the membrane module in filter head housings body, circulating backwater passes through circulation port Into raw water box, the treatment fluid that conductive plastics electrode centers pipe is entered by membrane module is flowed out by water outlet, and sewage mouth excludes Remain aqueous solution.
The application moulds conductive plastics electrode and the company of Polymer Synthesizing by being equipped with the carbon of elasticity in filter housings Power positive cathode is connect, forms electric field in the filter.
Membrane module is installed in the pressure-bearing filter shell with terminal stud, putamina is passed through direct current by external power supply Electricity, direct current anode pass through the terminal stud jointed anode electric field pipe network (anode) on anode electric field pipe network (anode), direct current Cathode connects cathode electric field central tube (cathode) by the terminal stud on pressure plate.It is intake in filter housings by compression pump Mouth squeezes into accessing pending water solution, is filtered into membrane module out of shell by cathode electric field pipe network, passes through membrane module later Central collection treatment fluid is flowed out finally by the water outlet of filter housings.
Affiliated membrane module includes winded filtering core, spray welding filter element, inorganic ceramic membrane filter and foldable filter element, used diaphragm The separating. functional layer material polyethylene, polypropylene, polytetrafluoroethylene (PTFE), Kynoar, poly- for being 0.01~0.1 μm for pore diameter range Sulfone, polyether sulfone and its polymer-modified microporous barrier using macromolecule non-woven fabrics as backing material, anode electric field pipe network is (just Pole) and cathode electric field central tube (cathode) material be carbon mould Polymer Synthesizing conductive plastics.
Advantageous effect:
The application compared with prior art, has the advantages that:Since band is net after adding corresponding DC electric field The particle generation that is trapped for depositing charge is trapped deposition of the particle to film surface away from the electrophoretic migration movement of film surface so that preventing, It overcomes concentration polarization phenomenon and effectively improves fouling membrane situation, at the same time additional electric field can also make infiltration in filter membrane hole Liquid generate the mobile phenomenon through hole of orientation the seepage flow through filter membrane made to greatly increase filtration flux and be carried It is high.
Description of the drawings
The internal structure schematic diagram of Fig. 1 present invention
The electric field membrane filter particle mass transfer schematic diagram of Fig. 2 present invention
The flow diagram of Fig. 3 present invention in the application
Specific implementation mode
Below in conjunction with the accompanying drawings, the specific implementation of the application is illustrated:
Embodiment 1
Structure as shown in Figure 1 assembles a kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution, including membrane module, filter Shell, it is characterised in that membrane module 4 is installed in filter housings 10, and conductive plastics electrode is placed at 10 center of filter housings Central tube 11 is connected with power cathode 1, and power cathode 1 connects negative terminals 2;10 internal edge of filter housings places one Layer conductive plastics electrode grid, connects positive pole 3, and positive pole 3 is connect with positive terminal 9;It is positioned by top filter core Pressure plate 8 fixes membrane module 4;Water inlet 5, water outlet 6 are offered on filter housings 10, the water inlet of water inlet 5 is passed through Anode electric field pipe network is filtered out of shell into membrane module, later by 4 central collection treatment fluid of membrane module, finally by The water outlet 6 of filter housings flows out.
Membrane module is installed in filter housings, a carbon is placed at filter housings center and moulds leading for Polymer Synthesizing Electric plastic electrode central tube is used for connecting power cathode, and filter housings internal edge places one layer of flexible carbon and moulds macromolecule The conductive plastics electrode grid of synthesis is used for connecting positive pole, which includes top filter core positioning compression plate.Putamina passes through External power supply is passed through direct current, and direct current anode passes through the terminal stud jointed anode field tube on anode electric field pipe network (anode) Net (anode), direct current cathode connect cathode electric field central tube (cathode) by the terminal stud on pressure plate.Pass through compression pump Accessing pending water solution is squeezed into filter housings water inlet, was carried out into membrane module out of shell by cathode electric field pipe network Filter is flowed out later by membrane module central collection treatment fluid finally by the water outlet of filter housings.Membrane module used, packet Winded filtering core, spray welding filter element, inorganic ceramic membrane filter and foldable filter element are included, diaphragm is pore diameter range used in filter core and filter core For 0.05 μm of separating. functional layer material polyethylene, polypropylene, polytetrafluoroethylene (PTFE), Kynoar, polysulfones, polyether sulfone and its change The microporous barrier using macromolecule non-woven fabrics as backing material of property polymer.
After normal operation, the signal of whole service process inside and outside membrane module as shown in Fig. 2, then add DC electric field Afterwards.The particle that is trapped with net deposit charge in filter chamber is set to generate the electrophoretic migration movement for deviating from film surface.This electrophoretic action can be with It reduces so that preventing from being trapped deposition of the particle to film surface, you can overcome concentration polarization phenomenon and improve fouling membrane situation.With this Additional electric field can also make liquid of the infiltration in filter membrane hole generate the mobile phenomenon through hole oriented simultaneously.This is different from The seepage flow through filter membrane caused by pressure difference but a kind of electroosmotic effect.
Embodiment 2
Structure as shown in Figure 1 assembles a kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution, including membrane module, filter Shell, it is characterised in that membrane module 4 is installed in filter housings 10, and conductive plastics electrode is placed at 10 center of filter housings Central tube 11 is connected with power cathode 1, and 10 internal edge of filter housings places one layer of conductive plastics electrode grid, connection electricity Source anode 3;Membrane module is fixed by top filter core positioning compression plate 8;Water inlet 5 is offered on filter housings 10, is gone out The water inlet at the mouth of a river 6, water inlet 5 is filtered out of shell into membrane module by anode electric field pipe network, passes through membrane module 4 later Central collection treatment fluid is flowed out finally by the water outlet 6 of filter housings.It is offered in the upper position of filter housings 10 Circulation port 7 offers sewage draining exit 12 in the lower part of filter housings 10.Membrane module is installed in filter housings, is being filtered The conductive plastics electrode centers pipe that device casing center places a carbon modeling Polymer Synthesizing is used for connecting power cathode, filter head housings The conductive plastics electrode grid that body internal edge places one layer of flexible carbon modeling Polymer Synthesizing is used for connecting positive pole, should Grid includes top filter core positioning compression plate.Putamina is passed through direct current by external power supply, and direct current anode passes through anode electric field Terminal stud jointed anode electric field pipe network (anode) on pipe network (anode), direct current cathode pass through the terminal stud on pressure plate Connect cathode electric field central tube (cathode).Accessing pending water solution is squeezed into filter housings water inlet by compression pump, by the moon Pole electric field pipe network is filtered out of shell into membrane module, later by membrane module central collection treatment fluid, finally by mistake The water outlet of filter shell flows out.Membrane module used, including winded filtering core, spray welding filter element, inorganic ceramic membrane filter and folding filter Diaphragm used in core, filter core and filter core be the separating. functional layer material polyethylene that pore diameter range is 0.01~10 μm, polypropylene, Polytetrafluoroethylene (PTFE), Kynoar, polysulfones, polyether sulfone and its polymer-modified using macromolecule non-woven fabrics as backing material Microporous barrier.After normal operation, good effect can be equally obtained.
Embodiment 3
Structure as shown in Figure 1 assembles a kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution, including membrane module, filter Shell, it is characterised in that membrane module 4 is installed in filter housings 10, and conductive plastics electrode is placed at 10 center of filter housings Central tube 11 is connected with power cathode 1, and 10 internal edge of filter housings places one layer of conductive plastics electrode grid, connection electricity Source anode 3;Membrane module is fixed by top filter core positioning compression plate 8;Water inlet 5 is offered on filter housings 10, is gone out The water inlet at the mouth of a river 6, water inlet 5 is filtered out of shell into membrane module by anode electric field pipe network, passes through membrane module 4 later Central collection treatment fluid is flowed out finally by the water outlet 6 of filter housings.It is offered in the upper position of filter housings 10 Circulation port 7 offers sewage draining exit 12 in the lower part of filter housings 10.Conductive plastics electrode centers pipe 11 in the present embodiment is Made of carbon modeling Polymer Synthesizing.10 internal edge of filter housings places several flexible carbon and moulds Polymer Synthesizing Conductive plastics pipe composition electrode grid is used for connecting positive pole 3, which includes top filter core positioning compression plate 8;Such as Shown in Fig. 3, in application process, water inlet 5 is connect by compression pump with raw water box, and accessing pending water solution is passed through water inlet 5 Into in the membrane module 4 in filter housings 10, circulating backwater enters raw water box by circulation port 7, is entered by membrane module 4 and is led The treatment fluid of electric plastic electrode central tube 11 is flowed out by water outlet 6, and sewage mouth 12 excludes residual aqueous solution.
Membrane module is installed in filter housings, a carbon is placed at filter housings center and moulds leading for Polymer Synthesizing Electric plastic electrode central tube is used for connecting power cathode, and filter housings internal edge places one layer of flexible carbon and moulds macromolecule The conductive plastics electrode grid of synthesis is used for connecting positive pole, which includes top filter core positioning compression plate.Putamina passes through External power supply is passed through direct current, and direct current anode passes through the terminal stud jointed anode field tube on anode electric field pipe network (anode) Net (anode), direct current cathode connect cathode electric field central tube (cathode) by the terminal stud on pressure plate.Pass through compression pump Accessing pending water solution is squeezed into filter housings water inlet, was carried out into membrane module out of shell by cathode electric field pipe network Filter is flowed out later by membrane module central collection treatment fluid finally by the water outlet of filter housings.Membrane module used, packet Winded filtering core, spray welding filter element, inorganic ceramic membrane filter and foldable filter element are included, diaphragm is pore diameter range used in filter core and filter core For 0.01~10 μm of separating. functional layer material polyethylene, polypropylene, polytetrafluoroethylene (PTFE), Kynoar, polysulfones, polyether sulfone and Its polymer-modified microporous barrier using macromolecule non-woven fabrics as backing material.After normal operation, can equally it obtain good Good effect.

Claims (6)

1. a kind of general-purpose highly effective anti-pollution blocks up electric field membrane filter, including membrane module (4), filter housings (10), feature exists It is installed in filter housings (10) in membrane module (4), conductive plastics electrode centers pipe is placed at filter housings (10) center (11), it is connected with power cathode (1), filter housings (10) internal edge places one layer of conductive plastics electrode grid, connection electricity Source anode (3);
Membrane module is fixed by top filter core positioning compression plate (8);Offered on filter housings (10) water inlet (5), The water inlet of water outlet (6), water inlet (5) is filtered out of shell into membrane module (4) by anode electric field pipe network, Zhi Houtong Membrane module (4) central collection treatment fluid is crossed, is flowed out finally by the water outlet (6) of filter housings.
2. a kind of general-purpose highly effective anti-pollution according to claim 1 blocks up electric field membrane filter, which is characterized in that the film group Part (4) is winded filtering core, spray welding filter element, inorganic ceramic membrane filter or foldable filter element, used diaphragm be aperture be 0.01~ 0.1 μm of seperation film.
3. a kind of general-purpose highly effective anti-pollution according to claim 1 blocks up electric field membrane filter, which is characterized in that in filter The upper position of shell (10) offers circulation port (7), and sewage draining exit (12) is offered in the lower part of filter housings (10).
4. a kind of general-purpose highly effective anti-pollution according to claim 1 blocks up electric field membrane filter, which is characterized in that conductive plastics Electrode centers pipe (11) is made of carbon modeling Polymer Synthesizing.
5. a kind of general-purpose highly effective anti-pollution according to claim 1 blocks up electric field membrane filter, which is characterized in that filter head housings The conductive plastics pipe composition electrode grid that body (10) internal edge places several flexible carbon modeling Polymer Synthesizings is used for connecting Positive pole (3) is connect, which includes top filter core positioning compression plate (8).
6. a kind of general-purpose highly effective anti-pollution according to claim 3 blocks up electric field membrane filter, which is characterized in that water inlet (5) connect with raw water box by compression pump, by accessing pending water solution by water inlet (5) enter filter housings (10) in film In component (4), circulating backwater enters raw water box by circulation port (7), enters conductive plastics electrode centers pipe by membrane module (4) (11) treatment fluid is flowed out by water outlet (6), and sewage mouth (12) excludes residual aqueous solution.
CN201810674771.7A 2018-06-27 2018-06-27 A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution Pending CN108579439A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0950977A (en) * 1995-05-31 1997-02-18 Shin Etsu Handotai Co Ltd Device and method for cleaning semiconductor substrate
CN108136293A (en) * 2015-08-10 2018-06-08 水技术国际有限责任公司 For mitigating the method and apparatus of biological fouling in reverse osmosis membrane
CN208493836U (en) * 2018-06-27 2019-02-15 浙江工业大学膜分离与水处理协同创新中心湖州研究院 A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0950977A (en) * 1995-05-31 1997-02-18 Shin Etsu Handotai Co Ltd Device and method for cleaning semiconductor substrate
CN108136293A (en) * 2015-08-10 2018-06-08 水技术国际有限责任公司 For mitigating the method and apparatus of biological fouling in reverse osmosis membrane
CN208493836U (en) * 2018-06-27 2019-02-15 浙江工业大学膜分离与水处理协同创新中心湖州研究院 A kind of stifled electric field membrane filter of general-purpose highly effective anti-pollution

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
冯春宇, 成都:电子科技大学出版社 *

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