CN108569858A - A kind of special air entraining agent of stable structure type cement - Google Patents

A kind of special air entraining agent of stable structure type cement Download PDF

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Publication number
CN108569858A
CN108569858A CN201810375951.5A CN201810375951A CN108569858A CN 108569858 A CN108569858 A CN 108569858A CN 201810375951 A CN201810375951 A CN 201810375951A CN 108569858 A CN108569858 A CN 108569858A
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China
Prior art keywords
parts
account
accounts
sodium
rosin resin
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CN201810375951.5A
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Chinese (zh)
Inventor
赵亮亮
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Linquan County Kai Sheng Construction Engineering Co Ltd
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Linquan County Kai Sheng Construction Engineering Co Ltd
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Priority to CN201810375951.5A priority Critical patent/CN108569858A/en
Publication of CN108569858A publication Critical patent/CN108569858A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/304Air-entrainers

Abstract

The invention discloses a kind of special air entraining agents of stable structure type cement, are made of following raw material according to parts by weight:Ethylene glycol accounts for 0.3 0.7 parts,Calcium lignosulfonate accounts for 38 parts,Polyacrylamide powder accounts for 15 parts,Sodium hydroxide accounts for 0.3 0.7 parts,Petroleum sodium sulfonate accounts for 14 parts,Beta cyclodextrin accounts for 59 parts,Rosin resin accounts for 26 parts,Lauryl sodium sulfate accounts for 0.2 0.6 parts,Bisphenol-A accounts for 0.1 0.5 parts,Soapberry soap powder accounts for 37 parts,16 parts of polyethylene glycol citric acid,Rosin resin accounts for 7 12 parts,Unsaturated acid anhydride accounts for 0.2 0.6 parts,Pentaerythrite accounts for 0.3 0.8 parts,Methacrylic acid accounts for 15 parts,Gum arabic accounts for 8 15 parts,Tert-butylamine accounts for 0.2 0.7 parts,Sodium lauroyl sarcosine accounts for 15 parts,Sodium carbonate accounts for 27 parts,Coconut oil diethanol amide accounts for 0.3 0.8 parts,Calcium formate accounts for 27 parts,Acrylamide accounts for 28 parts and alkyl phenol polyoxyethylene ether accounts for 0.2 0.6 parts.The present invention has good bleed performance and bubble stability energy, is particularly suitable for the less grinding coagulation soil for being difficult to bleed of concrete and water consumption containing fly ash aggregate.

Description

A kind of special air entraining agent of stable structure type cement
Technical field
The present invention relates to construction correlative technology field more particularly to a kind of special air entraining agents of stable structure type cement.
Background technology
Concrete air-entrainer can be effectively improved the workability of concrete, reduce bleeding performance, while substantially improving mixed The freeze proof anti-permeability performance for coagulating soil, is suitable for the important engineering concrete structure such as airport, harbor work and bridge, severe cold area is spread Concrete Highway, the bridge of cryosel are even more important.In addition, usually being mixed as activity using flyash in the configuration of these concrete And material, to improve the workability of fresh concrete, and reduce the warm contracting cracking trend of mass concrete.But application is found, portion Divide the higher flyash of loss on ignition because containing unburned carbon granules, usually reduces the bleed effect of air entraining agent.
In commerical ready-mixed concrete, the good air entraining agent of performance is remarkably improved plastic concrete and maturing Properties, and the cost of additive and concrete can also be reduced.The research and application of excellent air entraining agent are China's coagulations And its needs and certainty of additive development, exploitation, the promotion and application of air entraining agent are of far-reaching significance, should be Future Development high-performance The indispensable additive of concrete.However mostly presence introducing bubble structure is unreasonable, is unevenly distributed, bubble shakiness for existing air entraining agent Fixed, the deficiencies of size is improper, cannot effective fresh concrete workability, and improve the durability of maturing, with The plyability of other concrete admixtures is poor.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of stable structure type cement proposed Special air entraining agent.
To achieve the goals above, present invention employs following technical solutions:
A kind of special air entraining agent of stable structure type cement is made of according to parts by weight following raw material:Ethylene glycol account for 0.3-0.7 parts, Calcium lignosulfonate account for 3-8 parts, polyacrylamide powder account for 1-5 parts, sodium hydroxide account for 0.3-0.7 parts, petroleum sodium sulfonate account for 1-4 Part, beta-cyclodextrin account for 5-9 parts, rosin resin account for 2-6 parts, lauryl sodium sulfate account for 0.2-0.6 parts, bisphenol-A account for 0.1-0.5 Part, soapberry soap powder account for 3-7 parts, 1-6 parts of polyethylene glycol citric acid, rosin resin account for 7-12 parts, unsaturated acid anhydride account for 0.2-0.6 Part, pentaerythrite account for 0.3-0.8 parts, methacrylic acid account for 1-5 parts, gum arabic account for 8-15 parts, tert-butylamine account for 0.2-0.7 Part, sodium lauroyl sarcosine account for 1-5 parts, sodium carbonate account for 2-7 parts, coconut oil diethanol amide account for 0.3-0.8 parts, calcium formate account for 2- 7 parts, acrylamide accounts for 2-8 parts and alkyl phenol polyoxyethylene ether accounts for 0.2-0.6 parts.
A kind of above-mentioned special air entraining agent of stable structure type cement, is made of according to parts by weight following raw material:Ethylene glycol accounts for 0.3-0.6 parts, calcium lignosulfonate account for 3-7 parts, polyacrylamide powder account for 1-4 parts, sodium hydroxide account for 0.3-0.6 parts, oil Sodium sulfonate account for 1-3 parts, beta-cyclodextrin account for 5-8 parts, rosin resin account for 2-5 parts, lauryl sodium sulfate account for 0.2-0.5 parts, bisphenol-A Account for 0.1-0.4 parts, soapberry soap powder account for 3-6 parts, 1-5 parts of polyethylene glycol citric acid, rosin resin account for 7-11 parts, unsaturated acid anhydride Account for 0.2-0.5 parts, pentaerythrite accounts for 0.3-0.7 parts, methacrylic acid accounts for 1-4 parts, gum arabic accounts for 8-14 parts, tert-butylamine accounts for 0.2-0.6 parts, sodium lauroyl sarcosine account for 1-4 parts, sodium carbonate account for 2-6 parts, coconut oil diethanol amide account for 0.3-0.7 parts, first Sour calcium accounts for 2-6 parts, acrylamide accounts for 2-7 parts and alkyl phenol polyoxyethylene ether accounts for 0.2-0.5 parts.
A kind of above-mentioned special air entraining agent of stable structure type cement, is made of according to parts by weight following raw material:Ethylene glycol accounts for 0.4-0.6 parts, calcium lignosulfonate account for 4-7 parts, polyacrylamide powder account for 2-4 parts, sodium hydroxide account for 0.4-0.6 parts, oil Sodium sulfonate account for 2-3 parts, beta-cyclodextrin account for 6-8 parts, rosin resin account for 3-5 parts, lauryl sodium sulfate account for 0.3-0.5 parts, bisphenol-A Account for 0.2-0.4 parts, soapberry soap powder account for 4-6 parts, 2-5 parts of polyethylene glycol citric acid, rosin resin account for 8-11 parts, unsaturated acid anhydride Account for 0.3-0.5 parts, pentaerythrite accounts for 0.4-0.7 parts, methacrylic acid accounts for 2-4 parts, gum arabic accounts for 9-14 parts, tert-butylamine accounts for 0.3-0.6 parts, sodium lauroyl sarcosine account for 2-4 parts, sodium carbonate account for 3-6 parts, coconut oil diethanol amide account for 0.4-0.7 parts, first Sour calcium accounts for 3-6 parts, acrylamide accounts for 3-7 parts and alkyl phenol polyoxyethylene ether accounts for 0.3-0.5 parts.
A kind of above-mentioned special air entraining agent of stable structure type cement, is made of according to parts by weight following raw material:Ethylene glycol accounts for 0.5 part, calcium lignosulfonate account for 5.5 parts, polyacrylamide powder account for 3 parts, sodium hydroxide account for 0.5 part, petroleum sodium sulfonate account for 2.5 Part, beta-cyclodextrin account for 7 parts, rosin resin account for 4 parts, lauryl sodium sulfate account for 0.4 part, bisphenol-A account for 0.3 part, soapberry soap powder Account for 5 parts, 3.5 parts of polyethylene glycol citric acid, rosin resin account for 9.5 parts, unsaturated acid anhydride account for 0.4 part, pentaerythrite account for 0.55 part, Methacrylic acid account for 3 parts, gum arabic account for 11.5 parts, tert-butylamine account for 0.45 part, sodium lauroyl sarcosine account for 3 parts, sodium carbonate Account for 4.5 parts, coconut oil diethanol amide account for 0.55 part, calcium formate account for 4.5 parts, acrylamide account for 5 parts and alkylphenol-polyethenoxy Ether accounts for 0.4 part.
Compared with prior art, beneficial effects of the present invention are:
A kind of special air entraining agent of stable structure type cement of the present invention has good bleed performance and bubble stability energy, especially suitable The advantageous effects such as the grinding coagulation soil that is difficult to bleed less for the concrete containing fly ash aggregate and water consumption.
Specific implementation mode
Embodiment 1
A kind of special air entraining agent of stable structure type cement is made of according to parts by weight following raw material:Ethylene glycol account for 0.3 part, it is wooden Plain sulfoacid calcium account for 3 parts, polyacrylamide powder account for 1 part, sodium hydroxide account for 0.3 part, petroleum sodium sulfonate account for 1 part, beta-cyclodextrin account for 5 Part, rosin resin account for 2 parts, lauryl sodium sulfate account for 0.2 part, bisphenol-A account for 0.1 part, soapberry soap powder account for 3 parts, polyethylene glycol 1 part of citric acid, rosin resin account for 7 parts, unsaturated acid anhydride account for 0.2 part, pentaerythrite account for 0.3 part, methacrylic acid account for 1 part, Ah Draw primary natural gum account for 8 parts, tert-butylamine account for 0.2 part, sodium lauroyl sarcosine account for 1 part, sodium carbonate account for 2 parts, coconut oil diethanol amide Account for 0.3 part, calcium formate accounts for 2 parts, acrylamide accounts for 2 parts and alkyl phenol polyoxyethylene ether accounts for 0.2 part.
Embodiment 2
A kind of above-mentioned special air entraining agent of stable structure type cement, is made of according to parts by weight following raw material:Ethylene glycol accounts for 0.7 Part, calcium lignosulfonate account for 8 parts, polyacrylamide powder account for 5 parts, sodium hydroxide account for 0.7 part, petroleum sodium sulfonate account for 4 parts, β-ring Dextrin account for 9 parts, rosin resin account for 6 parts, lauryl sodium sulfate account for 0.6 part, bisphenol-A account for 0.5 part, soapberry soap powder account for 7 parts, it is poly- 6 parts of ethylene glycol citric acid, rosin resin account for 12 parts, unsaturated acid anhydride accounts for 0.6 part, pentaerythrite accounts for 0.8 part, methacrylic acid accounts for 5 parts, gum arabic account for 15 parts, tert-butylamine account for 0.7 part, sodium lauroyl sarcosine account for 5 parts, sodium carbonate account for 7 parts, coconut oil diethyl Alkylolamides accounts for 0.8 part, calcium formate accounts for 7 parts, acrylamide accounts for 8 parts and alkyl phenol polyoxyethylene ether accounts for 0.6 part.
Embodiment 3
A kind of above-mentioned special air entraining agent of stable structure type cement, is made of according to parts by weight following raw material:Ethylene glycol accounts for 0.5 Part, calcium lignosulfonate account for 5.5 parts, polyacrylamide powder account for 3 parts, sodium hydroxide account for 0.5 part, petroleum sodium sulfonate account for 2.5 parts, Beta-cyclodextrin account for 7 parts, rosin resin account for 4 parts, lauryl sodium sulfate account for 0.4 part, bisphenol-A account for 0.3 part, soapberry soap powder account for 5 Part, 3.5 parts of polyethylene glycol citric acid, rosin resin account for 9.5 parts, unsaturated acid anhydride account for 0.4 part, pentaerythrite account for 0.55 part, first Base acrylic acid accounts for 3 parts, gum arabic accounts for 11.5 parts, tert-butylamine accounts for 0.45 part, sodium lauroyl sarcosine accounts for 3 parts, sodium carbonate accounts for 4.5 parts, coconut oil diethanol amide account for 0.55 part, calcium formate account for 4.5 parts, acrylamide account for 5 parts and alkyl phenol polyoxyethylene ether Account for 0.4 part.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of special air entraining agent of stable structure type cement, which is characterized in that be made of following raw material according to parts by weight:Ethylene glycol Account for 0.3-0.7 parts, calcium lignosulfonate account for 3-8 parts, polyacrylamide powder account for 1-5 parts, sodium hydroxide account for 0.3-0.7 parts, stone Oily sodium sulfonate account for 1-4 parts, beta-cyclodextrin account for 5-9 parts, rosin resin account for 2-6 parts, lauryl sodium sulfate account for 0.2-0.6 parts, it is double Phenol A account for 0.1-0.5 parts, soapberry soap powder account for 3-7 parts, 1-6 parts of polyethylene glycol citric acid, rosin resin account for 7-12 parts, it is unsaturated Acid anhydrides account for 0.2-0.6 parts, pentaerythrite account for 0.3-0.8 parts, methacrylic acid account for 1-5 parts, gum arabic account for 8-15 parts, tertiary fourth Amine account for 0.2-0.7 parts, sodium lauroyl sarcosine account for 1-5 parts, sodium carbonate account for 2-7 parts, coconut oil diethanol amide account for 0.3-0.8 Part, calcium formate accounts for 2-7 parts, acrylamide accounts for 2-8 parts and alkyl phenol polyoxyethylene ether accounts for 0.2-0.6 parts.
2. a kind of special air entraining agent of stable structure type cement according to claim 1, which is characterized in that have according to parts by weight Following raw material composition:Ethylene glycol account for 0.3-0.6 parts, calcium lignosulfonate account for 3-7 parts, polyacrylamide powder account for 1-4 parts, hydrogen-oxygen Change sodium account for 0.3-0.6 parts, petroleum sodium sulfonate account for 1-3 parts, beta-cyclodextrin account for 5-8 parts, rosin resin account for 2-5 parts, dodecyl sulphur Sour sodium account for 0.2-0.5 parts, bisphenol-A account for 0.1-0.4 parts, soapberry soap powder account for 3-6 parts, 1-5 parts of polyethylene glycol citric acid, rosin tree Fat account for 7-11 parts, unsaturated acid anhydride account for 0.2-0.5 parts, pentaerythrite account for 0.3-0.7 parts, methacrylic acid account for 1-4 parts, it is Arabic Natural gum account for 8-14 parts, tert-butylamine account for 0.2-0.6 parts, sodium lauroyl sarcosine account for 1-4 parts, sodium carbonate account for 2-6 parts, coconut oil diethyl Alkylolamides accounts for 0.3-0.7 parts, calcium formate accounts for 2-6 parts, acrylamide accounts for 2-7 parts and alkyl phenol polyoxyethylene ether accounts for 0.2-0.5 parts.
3. a kind of special air entraining agent of stable structure type cement according to claim 1, which is characterized in that have according to parts by weight Following raw material composition:Ethylene glycol account for 0.4-0.6 parts, calcium lignosulfonate account for 4-7 parts, polyacrylamide powder account for 2-4 parts, hydrogen-oxygen Change sodium account for 0.4-0.6 parts, petroleum sodium sulfonate account for 2-3 parts, beta-cyclodextrin account for 6-8 parts, rosin resin account for 3-5 parts, dodecyl sulphur Sour sodium account for 0.3-0.5 parts, bisphenol-A account for 0.2-0.4 parts, soapberry soap powder account for 4-6 parts, 2-5 parts of polyethylene glycol citric acid, rosin tree Fat account for 8-11 parts, unsaturated acid anhydride account for 0.3-0.5 parts, pentaerythrite account for 0.4-0.7 parts, methacrylic acid account for 2-4 parts, it is Arabic Natural gum account for 9-14 parts, tert-butylamine account for 0.3-0.6 parts, sodium lauroyl sarcosine account for 2-4 parts, sodium carbonate account for 3-6 parts, coconut oil diethyl Alkylolamides accounts for 0.4-0.7 parts, calcium formate accounts for 3-6 parts, acrylamide accounts for 3-7 parts and alkyl phenol polyoxyethylene ether accounts for 0.3-0.5 parts.
4. a kind of special air entraining agent of stable structure type cement according to claim 1, which is characterized in that have according to parts by weight Following raw material composition:Ethylene glycol accounts for 0.5 part, calcium lignosulfonate accounts for 5.5 parts, polyacrylamide powder accounts for 3 parts, sodium hydroxide accounts for 0.5 part, petroleum sodium sulfonate account for 2.5 parts, beta-cyclodextrin account for 7 parts, rosin resin account for 4 parts, lauryl sodium sulfate account for 0.4 part, it is double Phenol A accounts for 0.3 part, soapberry soap powder accounts for 5 parts, 3.5 parts of polyethylene glycol citric acid, rosin resin account for 9.5 parts, unsaturated acid anhydride accounts for 0.4 part, pentaerythrite account for 0.55 part, methacrylic acid account for 3 parts, gum arabic account for 11.5 parts, tert-butylamine account for 0.45 part, bay Acylsarcosine sodium account for 3 parts, sodium carbonate account for 4.5 parts, coconut oil diethanol amide account for 0.55 part, calcium formate account for 4.5 parts, acrylamide It accounts for 5 parts and alkyl phenol polyoxyethylene ether accounts for 0.4 part.
CN201810375951.5A 2018-04-25 2018-04-25 A kind of special air entraining agent of stable structure type cement Withdrawn CN108569858A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110002783A (en) * 2019-04-23 2019-07-12 刘翠芬 A kind of grinding coagulation soil efficient air entraining agent and preparation method thereof
CN115180864A (en) * 2022-07-13 2022-10-14 交通运输部公路科学研究所 Bridge floor flow state concrete rapid plasticizing material

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110002783A (en) * 2019-04-23 2019-07-12 刘翠芬 A kind of grinding coagulation soil efficient air entraining agent and preparation method thereof
CN115180864A (en) * 2022-07-13 2022-10-14 交通运输部公路科学研究所 Bridge floor flow state concrete rapid plasticizing material

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Application publication date: 20180925