CN108569489A - A kind of nonpetroleum warehousing and transportation facilities - Google Patents
A kind of nonpetroleum warehousing and transportation facilities Download PDFInfo
- Publication number
- CN108569489A CN108569489A CN201810595941.2A CN201810595941A CN108569489A CN 108569489 A CN108569489 A CN 108569489A CN 201810595941 A CN201810595941 A CN 201810595941A CN 108569489 A CN108569489 A CN 108569489A
- Authority
- CN
- China
- Prior art keywords
- oil
- fistulae
- nonpetroleum
- warehousing
- petroleum pipeline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003208 petroleum Substances 0.000 claims abstract description 37
- 239000000446 fuel Substances 0.000 claims abstract description 21
- 230000005484 gravity Effects 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims description 65
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 48
- 239000002131 composite material Substances 0.000 claims description 34
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 19
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 14
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 229940106691 bisphenol a Drugs 0.000 claims description 11
- 238000005192 partition Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 7
- 229960004889 salicylic acid Drugs 0.000 claims description 7
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical class O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 claims description 5
- 238000009434 installation Methods 0.000 claims description 4
- 229940059939 kayexalate Drugs 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 241000872931 Myoporum sandwicense Species 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 238000009503 electrostatic coating Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000009825 accumulation Methods 0.000 abstract description 5
- 230000003068 static effect Effects 0.000 abstract description 3
- 230000005611 electricity Effects 0.000 abstract 1
- 238000004880 explosion Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 86
- 239000011248 coating agent Substances 0.000 description 53
- 238000005260 corrosion Methods 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 13
- 239000000243 solution Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 239000003502 gasoline Substances 0.000 description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- 229910000926 A-3 tool steel Inorganic materials 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 230000003405 preventing effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- 206010016717 Fistula Diseases 0.000 description 1
- 108010001336 Horseradish Peroxidase Proteins 0.000 description 1
- 229920000144 PEDOT:PSS Polymers 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 by weight Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/02—Wall construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60P—VEHICLES ADAPTED FOR LOAD TRANSPORTATION OR TO TRANSPORT, TO CARRY, OR TO COMPRISE SPECIAL LOADS OR OBJECTS
- B60P3/00—Vehicles adapted to transport, to carry or to comprise special loads or objects
- B60P3/22—Tank vehicles
- B60P3/224—Tank vehicles comprising auxiliary devices, e.g. for unloading or level indicating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/12—Supports
- B65D90/20—Frames or nets, e.g. for flexible containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/22—Safety features
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/48—Arrangements of indicating or measuring devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/54—Gates or closures
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Transportation (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The present invention relates to petroleum transportation equipment technical fields, more particularly to a kind of nonpetroleum warehousing and transportation facilities, including installing oil tank on the car body, the lower part of oil tank is provided with oil transportation mouth, the defeated oil port is connected with a petroleum pipeline, valve is provided on petroleum pipeline, and the valve downstream pipe outer wall of petroleum pipeline is arranged with an anti-fistulae being detachably connected, leakproof bottom of the tube is closed and is communicated with the fuel reserve tank of a fixation on the car body by a gravity flow hose, fuel reserve tank bottom is provided with a pressure inductor, the lateral wall of fuel reserve tank is provided with a controller, the warning lamp that can be observed by the rearview mirror on car body is provided with along the side wall at oil tank length direction rear portion, warning lamp and pressure inductor are electrically connected with controller；In addition, being additionally provided with antistatic backing in oil tank.The present invention can be such that driver finds in time and handle Oil spills situation；It is also avoided that accumulation of static electricity in oil tank simultaneously, fundamentally avoids leakage and the explosion equivalent risk of oil truck.
Description
Technical field
The present invention relates to petroleum transportation equipment technical fields, and in particular to a kind of nonpetroleum warehousing and transportation facilities.
Background technology
Steady, fast-developing with China's economy, crude oil consumption amount sharply increases, and the whole world is more next to the demand of oil
Bigger, oil occupies more and more important position in international economy and politics.Oil has only transported demand after mining
Place can just be effectively utilized, the means of transportation of oil has pipeline transportation, waterway transportation, railway transportation and highway at present
Transport.Wherein highway transportation has the characteristics that transport is flexible, has irreplaceable role in oil movement and storage and processing.
Highway transportation generally uses vehicle-mounted oil tank to carry out, and oil is transported to by oil transportation mouth in oil tank, purpose is transported to
It is come out again from oil transportation mouth by oil transportation behind ground.And after the folding use of the components over time such as valve of oil transportation mouth, leakproofness is big
It is big to reduce, it is easy to cause Oil spills, when oil tank oil transportation mouth occurs leaking and driver cannot discover in time, will be brought to driving
Prodigious security risk, and will also result in oil waste.
Also, in existing oil tank, vehicle traveling causes oil and tank skin, air relative motion friction in tank, is easy production
Raw electrostatic charge, leads to the quiet raising of inner tank wall, when the electrostatic charge over-limit condition of accumulation, oil truck just easily burns
Even explode.In the prior art, general using adding a large amount of metal particles in tank body coating so that materials conductive, and pass through painting
Electrostatic is imported the earth by the access of material-tank skin-ground connection drag chain, to solve the problems, such as static charge accumulation.But the increasing of metal particle
Adding can make tank body material be more easy to be corroded, and Leakage is often more serious.Meanwhile as oil product is to tank body metal material
Corrosion, metal material cure as combustible material, further increase the risk of burning.
In the prior art, it also has tried to prepare antistatic coating, such as publication No. using PEDOT-PSS aqueous dispersions
For：CN106752939A, although improving the static conductive ability of coating, film-formation result is undesirable, can not effectively prevent tank body
It is corroded.
Invention content
Present invention aims at providing a kind of nonpetroleum warehousing and transportation facilities, during being avoided that petroleum transportation Oil spills go out
It goes, and driver can have found oil oil transportation mouth leakage problem in time, avoid the wave of the security risk and oil in driving conditions
Take；The present invention also aims to provide a kind of oil tank vehicle tank coating of the anti-vulcanization of Anti-static anti-corrosion, increase the resistance to of tank body
Corrode anti-curing capacity, avoid the accumulation of electrostatic charge on tank body, fundamentally solves the problems, such as oil truck oil leak, inflammable and explosive.
To achieve the above object, the technical solution adopted in the present invention is：Including installing oil tank on the car body, the oil
The lower part of tank is provided with oil transportation mouth, and the defeated oil port is connected with a petroleum pipeline, and valve, and oil transportation are provided on the petroleum pipeline
The valve downstream pipe outer wall of pipe is arranged with an anti-fistulae being detachably connected, and the leakproof bottom of the tube closing is simultaneously soft by a gravity flow
Pipe is communicated with the fuel reserve tank of a fixation on the car body, and the fuel reserve tank bottom is provided with a pressure inductor, car body or fuel reserve tank
Lateral wall be provided with a controller, being provided with along the side wall at oil tank length direction rear portion can be seen by the rearview mirror on car body
The warning lamp measured, the warning lamp and pressure inductor are electrically connected with controller.
When Oil spills occurs, oil is leaked to from from petroleum pipeline nozzle in anti-fistulae, and the oil in anti-fistulae is from pipe
It is flowed into fuel reserve tank at road, when the pressure inductor in fuel reserve tank senses the pressure of oil, signal is transmitted to controller, controlled
Device processed control warning lamp lights, driver can by rearview mirror observes warning lamp the case where parking process.
Further, the petroleum pipeline is connect with anti-fistulae by a quick-release connector, and the quick-release connector includes that setting exists
The pressure ring of anti-fistulae upper end, there are two opposite spacing block set, pressure ring lower sections to be provided with two for the pressure ring lower outside setting
It is hinged on the connecting rod of anti-fistulae madial wall, a spring for being fixed on anti-fistulae madial wall, the bullet are provided with below the connecting rod
Spring is fixedly connected with connecting rod, is provided with a sealing ring below spring, the anti-fistulae madial wall below the sealing ring is inwardly arranged
There are convex edge, petroleum pipeline lateral wall to be provided with the groove being inserted into for connecting rod one end.When installation, petroleum pipeline is inserted into anti-fistulae, defeated
The bottom of oil pipe just resists the convex edge on anti-fistulae madial wall, and petroleum pipeline is made to be unlikely to be inserted into the bottom of anti-fistulae, there are
Certain space, connecting rod are just inserted into groove, and the connecting rod on both sides is just clamped anti-fistulae and do not fallen down, and fistulae anti-so just covers
It is connected on petroleum pipeline, when needing to remove anti-fistulae, it is only necessary to it is firmly pressed downward pressure ring, pressure ring gives connecting rod one downward power,
Connecting rod skids off groove, and connecting rod just does not cause to clamp to anti-fistulae, and fistulae anti-in this way can be removed easily, such structure setting
So that anti-fistulae can not influence normal defeated, operation of draining the oil with Quick Release fast-assembling.
Further, the partition board arranged in a crossed manner along its length for having two pieces to be arranged at X-shaped in the oil tank, partition board are located at oil
Tank middle and upper part is simultaneously fixed on by fixed link on two side.Oil is in transportational process, when car body is turned, oil in oil tank to
Outside centrifugal direction movement, easily makes body gravity unstable, and the danger overturned occurs, and such be provided with is conducive in turning,
The power that oil shakes outward can be distributed to all directions by partition board, it is ensured that the stationarity of the center of gravity of vehicle avoids overturning
Danger.
Further, it is connected with a sealing cover at the petroleum pipeline nozzle position.Petroleum pipeline can be further increased in this way
The leak preventing effect of mouth.
Further, be provided with antistatic backing on the oil tank madial wall, the antistatic backing by epoxy resin bisphenol-A and
The anti-static coatings of PEDOT-PSS composite materials composition are prepared；In mass ratio, the epoxy resin bisphenol-A：PEDOT-
Composite material=4 PSS:3~7.
Further, the PEDOT-PSS composite materials include by weight：3~6 parts of 3,4- ethylenedioxythiophenes, 2~4
Part kayexalate, 0.1~0.3 part of salicylic acid, 12~16 parts of NaIO4。
Further, the PEDOT-PSS composite materials include by weight：5 parts of 3,4- ethylenedioxythiophenes, 3 parts of polyphenyl
Vinyl sulfonic acid sodium, 0.2 part of salicylic acid, 14 parts of NaIO4。
Further, the processing method of the anti-static coatings is：
(1) PEDOT-PSS composite materials are prepared：3,4- ethylenedioxythiophenes and kayexalate are dissolved completely in
In deionized water, HCl adjusts pH value to 2, and salicylic acid, NaIO is added4, 16h is reacted at 20 DEG C, obtains PEDOT-PSS composite materials；
(2) anti-static coatings are prepared：By epoxy resin bisphenol-A, PEDOT-PSS composite material mixings, anti-static coatings are obtained.
Further, the preparation method of the antistatic backing is：In the anti-static coatings, addition weight is antistatic
After the TA-70 of coating weight 6~9%, 3~10min of vibration at high speed, it is coated onto rapidly on oil tank madial wall, it is solid at 50 DEG C
Change >=20min is to get antistatic backing.
Further, the addition weight of the TA-70 be anti-static coatings weight 7.5%, the vibration at high speed when
Between be 5min.
The beneficial effects of the invention are as follows：
The configuration of the present invention is simple, by setting up defences fistulae in petroleum pipeline outer sheath, and the fuel reserve tank being connected with anti-fistulae, prevent
Only in Oil spills to environment, pressure inductor and being used cooperatively for warning lamp can make driver find Oil spills feelings in time
Condition, timely parking process avoid the waste of the security risk and oil in driving conditions.Anti- fistulae can be with Quick Release fast-assembling, no
Influence normal defeated, operation of draining the oil.
One layer is also coated in the oil truck inner tank wall of the present invention to be made of the coating of the anti-vulcanization of Anti-static anti-corrosion
Antistatic backing, the coating have good conductive property, and can effectively avoid the accumulation of electrostatic charge in tank body；Meanwhile because in coating
EDOT itself do not reacted with the sulfur component in oil, so the coating also have the good corrosion resistance of resistance to vulcanization；More
Importantly, the coating hydrophilicity and filming performance are excellent, it can be effectively prevent the leakage of oil product in tank body, fundamentally solved
Oil truck oil leak, it is inflammable and explosive the problems such as.
Description of the drawings
Fig. 1 is the overall schematic of the present invention；
Fig. 2 is close-up schematic view of the present invention；
Reference numeral：1. oil tank, 2. oil transportation mouths, 3. petroleum pipelines, 4. anti-fistulaes, 5. sealing covers, 6. valves, 7. fuel reserve tanks,
8. pipeline, 9. controllers, 10. sealing rings, 11. pressure inductors, 12. partition boards, 13. antistatic backings, 14. spacing block sets, 15. polices
Show lamp, 301. grooves, 401. pressure rings, 402. connecting rods, 403. springs, 404. convex edges.
Specific implementation mode
Referring to Fig.1,2, which includes the oil tank 1 of installation on the car body, and the lower part of oil tank 1 is provided with oil transportation
Mouthfuls 2, a petroleum pipeline 3 is connected at the oil transportation mouth 2, and valve, and the valve downstream of petroleum pipeline 3 are provided on the petroleum pipeline 3
Pipe outer wall is arranged with an anti-fistulae 4 being detachably connected, and 4 bottom lock of anti-fistulae is simultaneously communicated with by a gravity flow hose 8
One fixes fuel reserve tank 7 on the car body, and 7 bottom of the fuel reserve tank is provided with a pressure inductor 11, and the lateral wall of fuel reserve tank 7 is set
It is equipped with a controller 10, being provided with along the side wall at 1 length direction rear portion of oil tank can be observed by the rearview mirror on car body
Warning lamp 15, the warning lamp 15 and pressure inductor 11 are electrically connected with controller 9.
Operation principle：When Oil spills occurs, oil leaks to from 3 nozzle of petroleum pipeline in anti-fistulae 4, anti-fistulae 4
In oil flowed into fuel reserve tank 7 from pipeline 8, when the pressure inductor 11 in fuel reserve tank 7 senses the pressure of oil,
Signal is transmitted to controller 9, and controller 9 controls warning lamp 15 and lights, and driver can observe warning lamp 15 by rearview mirror
Situation and parking process.
Warning lamp 15 can be arranged two, and two values, a upper limit value and a lower limiting value is arranged in controller 9, right respectively
Corresponding warning lamp 15, lower limiting value is answered to refer to the pressure that Oil spills can just incude, the oil that upper limit value refers to leakage fills storage soon
Pressure value when fuel tank 7, when driver find Oil spills, but by prevailing circumstances influenced to have no idea timely processing when, because thus
When the oil that leaks in fuel reserve tank 7, do not leak into outside environment, be temporarily safe from danger, can continue to travel, save
Haulage time reduces the workload of driver, and when the oil of leakage fills fuel reserve tank 7 soon, another warning lamp 15 lights, at this moment
It just must parking process.
The configuration of the present invention is simple, by setting up defences fistulae 4 in 3 outer sheath of petroleum pipeline, and the fuel reserve tank being connected with anti-fistulae 4
7, it prevents in Oil spills to environment, pressure inductor 11 can make driver find oil in time with being used cooperatively for warning lamp 15
Leakage situation, timely parking process avoid the waste of the security risk and oil in driving conditions.
It advanced optimizes on this basis, the petroleum pipeline 3 is connect with anti-fistulae 4 by a quick-release connector, the quick change
Connector includes the pressure ring 401 being arranged in 4 upper end of anti-fistulae, and there are two opposite limit convexes for the setting of 401 lower outside of the pressure ring
Block 14,401 lower section of pressure ring are provided with two connecting rods 402 for being hinged on 4 madial wall of anti-fistulae, and 402 lower section of the connecting rod is provided with
One is fixed on the spring 403 of 4 madial wall of anti-fistulae, and the spring 403 is fixedly connected with connecting rod 402, and 403 lower section of spring is provided with
4 madial wall of anti-fistulae of one sealing ring 10,10 lower section of the sealing ring is inwardly provided with convex edge 404, the setting of 3 lateral wall of petroleum pipeline
There is the groove 301 being inserted into for 402 one end of connecting rod.When installation, petroleum pipeline 3 is inserted into anti-fistulae 4, and the bottom of petroleum pipeline 3 is just
The convex edge 404 on 4 madial wall of anti-fistulae is resisted, makes petroleum pipeline 4 be unlikely to be inserted into the bottom of anti-fistulae 3, there are certain skies
Between, connecting rod 402 is just inserted into groove 301, and the connecting rod 402 on both sides is just clamped anti-fistulae 4 and do not fallen down, so anti-fistulae 4
It is just socketed on petroleum pipeline 3, when needing to remove anti-fistulae 4, it is only necessary to firmly be pressed downward pressure ring 401, pressure ring 401 gives connecting rod
402 1 downward power, connecting rod 402 skid off groove 301, and connecting rod 402 just does not cause to clamp to anti-fistulae 4, and anti-fistulae 4 is just in this way
It can easily remove, such structure setting makes anti-fistulae 4 that can not influence normal defeated, operation of draining the oil with Quick Release fast-assembling.
Further, the partition board 12 arranged in a crossed manner for there are two pieces to be arranged at X-shaped is provided in the oil tank 1 along its length,
Partition board 12 is located at 1 middle and upper part of oil tank and is fixed on two side by fixed link.Oil is in transportational process, when car body is turned,
Centrifugal direction moves oil in oil tank 1 outward, easily makes body gravity unstable, and the danger overturned occurs.Such setting
Be conducive in turning, the power that oil shakes outward can be distributed to all directions by partition board 12, it is ensured that the center of gravity of vehicle
Stationarity avoids the danger of overturning.A sealing cover 5 can also be connected at 3 nozzle position of the petroleum pipeline.It in this way can be with
Further increase the leak preventing effect of oil transportation nozzle.
In the present embodiment, such as Fig. 1, an antistatic backing 13 is provided on 1 madial wall of oil tank, the antistatic backing 13 is by anti-quiet
Electrocoating paint is prepared.The preparation method of the anti-static coating 13 is：
1, in parts by weight, by 3~6 parts of 3,4- ethylenedioxythiophenes (EDOT) and 2~4 parts of kayexalates
(PSS) it is dissolved into 800 parts of deionized waters, is adjusted pH value to 2 with HCl, be added 0.1~0.3 part of salicylic acid (catalyst), 12
~16 parts of NaIO4(oxidant) reacts 16h at 20 DEG C, obtains PEDOT-PSS composite materials.
2, effective weight ratio, epoxy resin bisphenol-A are pressed：Composite material=4 PEDOT-PSS:3~7, mixing obtains required painting
Material；Add weight be coating weight 6~9% TA-70 (alicyclic ring amine hardener), open high-speed microwave shake table, vibration 3~
After ten minutes, material is coated on 1 madial wall of oil tank, cures 10~60 minutes at 50 DEG C to get required coating.
With reference to specific experiment, further explaination is done to the preparation of anti-static coating.
(1) control group is prepared
1) control group 1：PEDOT- is replaced using commercially available PEDOT-PSS aqueous solutions (Baytron P, Bayer AG companies)
PSS composite materials, by weight, epoxy resin bisphenol-A：Aqueous solution=4 PEDOT-PSS:5, mixing to get control group 1 painting
Material.The TA-70 that weight is coating weight 7.5% is added, high-speed microwave shake table is opened, vibration after five minutes, is applied to rapidly
On A3 steel plates, cure 20 minutes coatings to get control group 1 at 50 DEG C.
2) control group 2：5 parts of EDOT and 3 part of PSS are dissolved into 800 parts of deionized waters, are adjusted pH value to 2 with HCl,
0.2 part of horseradish peroxidase (HRP, catalyst) is added, 26 parts of hydrogen peroxide (oxidant) are reacted 16h at 4 DEG C, must be compareed
The PEDOT-PSS composite materials of group 2.By weight, epoxy resin bisphenol-A：Composite material=4 PEDOT-PSS:5, mixing, i.e.,
Obtain the coating of control group 2.The TA-70 that weight is coating weight 7.5% is added, high-speed microwave shake table is opened, is vibrated 5 minutes
Afterwards, cure 20 minutes at 50 DEG C, be applied to rapidly on A3 steel plates to get the coating of control group 2.
(2) 1 is tested：It is preferred that preparing the parameter of PEDOT-PSS composite materials
1) according to above-mentioned preparation method, 11 groups of PEDOT-PSS composite materials of equivalent are prepared, by effective weight ratio, asphalt mixtures modified by epoxy resin
Fat bisphenol-A：Composite material=4 PEDOT-PSS:5, each group PEDOT-PSS composite materials are mixed with epoxy resin bisphenol-A respectively
It is even to get required coating.The TA-70 (alicyclic ring amine hardener) that weight is coating weight 7.5% is added in each group coating again,
High-speed microwave shake table is opened, vibration after five minutes, is coated on A3 steel plates, cures 20 minutes at 50 DEG C to get each group coating.
In each group PEDOT-PSS composite materials, the specific parts by weight of each component are as shown in table 1.
Table 1PEDOT-PSS composite material preparation parameters
2) each materials conductive performance test
Using high insulation measurement instrument and digital four-point probe to the PEDOT-PSS composite materials of above-mentioned each group
Carry out conductivity test.The results are shown in Table 2.
The conductivity of 2 each group PEDOT-PSS composite materials of table
| Group | Conductivity (S/m) |
| Group 1 | 41.02 |
| Group 2 | 52.10 |
| Group 3 | 57.88 |
| Group 4 | 55.64 |
| Group 5 | 53.30 |
| Group 6 | 53.13 |
| Group 7 | 30.16 |
| Group 8 | 56.19 |
| Group 9 | 33.56 |
| Group 10 | 46.98 |
| Group 11 | 53.69 |
| Control group 1 | 10.11 |
| Control group 2 | 20.28 |
As can be seen from the above table：PEDOT-PSS composite materials are prepared using technical solution of the present invention, conductivity pole is better than general
Logical PEDOT-PSS composite materials, wherein the PEDOT-PSS composite materials prepared using group 3, electric conductivity are best.
3) corrosion resistance is tested
Prepare 5%HCl aqueous solutions, 10%NaOH aqueous solutions, three groups of solution of No. 90 gasoline purchased in market, respectively the above-mentioned each group of clip
Coating material 1cm2, above-mentioned three groups of solution is immersed respectively, 240h is impregnated at 25 DEG C, after taking-up is dried, observes appearance of coat situation,
The results are shown in Table 3.
The corrosion resistance of 3 each group coating material of table
As can be seen from the above table：Under acid, alkali, gasoline environment, coating prepared by technical solution of the present invention does not all blister, table
Face flawless, it was demonstrated that the corrosion resistance of the coating, film forming can meet the need of more severe use environment in oil tank vehicle tank
It asks.
According to above-mentioned experiment, the parameter of PEDOT-PSS composite materials preferably group 3 is prepared.
(2) 2 are tested：It is preferred that preparing the parameter of coating/coating
1) method for pressing 1 group 3 of above-mentioned experiment prepares 15 groups of PEDOT-PSS composite materials, then 15 parts of epoxy resin are double
Phenol A and each group PEDOT-PSS composite material mixings, obtain required coating；It is added in each group coating and is separately added into TA-70, opened
High-speed microwave shake table after vibration, each group material is coated on A3 steel plates rapidly, solidification is to get each group coating at 50 DEG C
The coating of preparation.The design parameter for preparing each group coating/coating is as shown in table 4.
4 coating of table/coating preparation parameter
2) viscosity performance is tested.Test the cementability after the initial cementability of each group coating, and vulcanization.Vulcanization process：
Each group material is placed in the carbon disulfide solution (a concentration of 0.46mol/L of the sulfur chloride in carbon disulfide) of sulfur chloride and is impregnated
10d.The viscosity performance of each group is as shown in table 5.
5 each group viscosity performance of table
As can be seen from the above table, in technical solution of the present invention, viscosity performance variation is little, and does not almost cure, sulphur
The viscosity performance for changing front and back material is approximate.Meanwhile coating material prepared by the present invention, sulfidation-resistance can be substantially better than using common
PEDOT-PSS aqueous dispersions prepare coating material, this may be because common PE DOT-PSS aqueous dispersions in, respectively
The mainly non-covalent bond connection with intermolecular force, leads to its structure defective tightness between component, can not effective protection coating.
3) conducting performance test.Using high insulation measurement instrument and digital four-point probe to each group coating material
Carry out the test of resistivity.The results are shown in Table 6.
The electric conductivity of 6 each group coating material of table
| Group | Conductivity (S/m) |
| Group 1 | 31.22 |
| Group 2 | 42.09 |
| Group 3 | 41.98 |
| Group 4 | 39.99 |
| Group 5 | 40.01 |
| Group 6 | 37.93 |
| Group 7 | 35.95 |
| Group 8 | 38.29 |
| Group 9 | 42.01 |
| Group 10 | 42.08 |
| Group 11 | 39.88 |
| Group 12 | 42.08 |
| Group 13 | 42.09 |
| Group 14 | 43.10 |
| Group 15 | 42.09 |
| Control group 1 | 4.25 |
| Control group 2 | 5.38 |
As can be seen from the above table, when additive amount is relatively low, conductive coating performance with the increase of PEDOT-PSS composite materials and
Increase, when PEDOT-PSS composite materials increase to 7.5, electric conductivity is best.
4) corrosion-resistant, osmotic-pressure-tolerant can be tested
Corrosion-resistant test：Prepare 5%HCl aqueous solutions, 10%NaOH aqueous solutions, three groups of solution of No. 90 gasoline purchased in market, respectively
The coating 1cm of clip above-mentioned each group coating and control group2, above-mentioned three groups of solution is immersed respectively, impregnates 240h at 25 DEG C, taking-up is dried in the air
After dry, visual condition is observed, the results are shown in Table 7.
Resistance to penetration testing：Each coating is placed in 10h in High Purity Nitrogen simultaneously to deoxygenate, then while difference sealed soak is in purchased in market
In No. 90 gasoline, and it is continually fed into CO2With H2S, respectively at 5h, 22h, 100h and 240h of immersion, each group coating is taken by 78 DEG C
Go out, washes off the gasoline of coating surface successively with deionized water and ethyl alcohol, the corrosion potential of each group is tested after dry, as a result such as
Shown in table 7.
The corrosion-resistant osmotic-pressure-tolerant energy of 7 each group of table
As can be seen from the above table, using technical solution of the present invention prepare coating, corrode through the long period, still without
Bubble, crackle, situations such as falling off, occur；And over time, corrosion potential varies less, it was demonstrated that coating efficiently avoids
Carrier is corroded by acid, alkali, petroleum derivative, and corrosion-resistant osmotic-pressure-tolerant can be good.And the coating material of control group 1 is in No. 90 gasoline
Foaming phenomena, and the constantly negative shifting over time of its corrosion potential have occurred under environment, illustrates that the coating of control group 1 can not
Fully against the leakage of No. 90 gasoline, corrosion slowly occurs under coating.
Claims (10)
1. a kind of nonpetroleum warehousing and transportation facilities includes the oil tank (1) of installation on the car body, it is characterised in that：The oil tank (1)
Lower part is provided with oil transportation mouth (2), and a petroleum pipeline (3) is connected at the oil transportation mouth (2), valve is provided on the petroleum pipeline (3)
Door, and the valve downstream pipe outer wall of petroleum pipeline (3) is arranged with an anti-fistulae (4) being detachably connected, anti-fistulae (4) bottom
It closes and the fuel reserve tank (7) of a fixation on the car body, fuel reserve tank (7) the bottom setting is communicated with by a gravity flow hose (8)
There is a pressure inductor (11), the lateral wall of car body or fuel reserve tank (7) is provided with a controller (9), along oil tank (1) length direction
Being provided on the side wall at rear portion can be by the warning lamp (15) that the rearview mirror on car body observes, the warning lamp (15) and pressure
Inductor (11) is electrically connected with controller (9).
2. a kind of nonpetroleum warehousing and transportation facilities according to claim 1, it is characterised in that：The petroleum pipeline (3) and leakproof
It manages (4) to be socketed by a quick-release connector, the quick-release connector includes pressure ring (401) of the setting in anti-fistulae (4) upper end, the pressure
There are two opposite spacing block set (14), pressure ring (401) lower sections to be provided with two and be hinged on leakproof for the setting of ring (401) lower outside
The connecting rod (402) of (4) madial wall is managed, a spring for being fixed on anti-fistulae (4) madial wall is provided with below the connecting rod (402)
(403), it is fixedly connected in the middle part of the spring (403) and connecting rod (402) one end far from anti-fistulae madial wall, under spring (403)
Side is provided with a sealing ring (10), and anti-fistulae (4) madial wall below the sealing ring (10) is provided with convex edge to inner ring
(404), petroleum pipeline (3) lateral wall is provided with the groove (301) being inserted into for connecting rod (402) one end, and petroleum pipeline (3) is successively from pressure
Ring (401), sealing ring (403) are inserted into anti-fistulae (4).
3. a kind of nonpetroleum warehousing and transportation facilities according to claim 1, it is characterised in that：Along length in the oil tank (1)
The direction partition board arranged in a crossed manner for having two pieces to be arranged at X-shaped (12), partition board (12) are located at oil tank (1) middle and upper part and are fixed by fixed link
On two side.
4. a kind of nonpetroleum warehousing and transportation facilities according to claim 1, it is characterised in that：Petroleum pipeline (3) the nozzle position
The place of setting is connected with a sealing cover (5).
5. a kind of nonpetroleum warehousing and transportation facilities according to claim 1, it is characterised in that：On oil tank (1) madial wall
It is provided with antistatic backing (13), the antistatic backing (13) is made of anti-epoxy resin bisphenol-A and PEDOT-PSS composite materials
Electrostatic coatings are prepared；In mass ratio, the epoxy resin bisphenol-A：Composite material=4 PEDOT-PSS:3~7.
6. a kind of nonpetroleum warehousing and transportation facilities according to claim 5, it is characterised in that：The PEDOT-PSS composite woods
Material include by weight：3~6 parts of 3,4- ethylenedioxythiophenes, 2~4 parts of kayexalates, 0.1~0.3 part of salicylic acid, 12
~16 parts of NaIO4。
7. according to a kind of nonpetroleum warehousing and transportation facilities described in claim 6, it is characterised in that：The PEDOT-PSS is compound
Material includes by weight：5 parts of 3,4- ethylenedioxythiophenes, 3 parts of kayexalates, 0.2 part of salicylic acid, 14 parts of NaIO4。
8. a kind of nonpetroleum warehousing and transportation facilities according to claim 5~7 any one, it is characterised in that：It is described anti-
The processing method of electrostatic coatings is：
(1) PEDOT-PSS composite materials are prepared：By 3,4- ethylenedioxythiophenes and kayexalate be dissolved completely in from
In sub- water, HCl adjusts pH value to 2, and salicylic acid, NaIO is added4, 16h is reacted at 20 DEG C, obtains PEDOT-PSS composite materials；
(2) anti-static coatings are prepared：By epoxy resin bisphenol-A, PEDOT-PSS composite material mixings, anti-static coatings are obtained.
9. a kind of nonpetroleum warehousing and transportation facilities according to claim 8, it is characterised in that：The system of the antistatic backing (13)
Preparation Method is：In the anti-static coatings, be added weight be anti-static coatings weight 6~9% TA-70, vibration at high speed 3~
After 10min, it is coated onto rapidly on oil tank (1) madial wall, solidification >=20min is to get antistatic backing (13) at 50 DEG C.
10. a kind of nonpetroleum warehousing and transportation facilities according to claim 9, it is characterised in that：The addition weight of the TA-70
It is the 7.5% of anti-static coatings weight, the time of the vibration at high speed is 5min.
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