CN108561756B - Raw coke oven gas pipeline condenses liquid processing device before a kind of primary cooler - Google Patents

Raw coke oven gas pipeline condenses liquid processing device before a kind of primary cooler Download PDF

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Publication number
CN108561756B
CN108561756B CN201810456153.5A CN201810456153A CN108561756B CN 108561756 B CN108561756 B CN 108561756B CN 201810456153 A CN201810456153 A CN 201810456153A CN 108561756 B CN108561756 B CN 108561756B
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CN
China
Prior art keywords
primary cooler
coke oven
raw coke
oven gas
liquid
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Expired - Fee Related
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CN201810456153.5A
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Chinese (zh)
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CN108561756A (en
Inventor
陈文�
胡小建
周建波
崔小莹
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Changsha Medical University
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Changsha Medical University
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Priority to CN201810456153.5A priority Critical patent/CN108561756B/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17DPIPE-LINE SYSTEMS; PIPE-LINES
    • F17D3/00Arrangements for supervising or controlling working operations
    • F17D3/14Arrangements for supervising or controlling working operations for eliminating water
    • F17D3/145Arrangements for supervising or controlling working operations for eliminating water in gas pipelines

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Industrial Gases (AREA)

Abstract

The invention discloses raw coke oven gas pipelines before a kind of primary cooler to condense liquid processing device, the arrival end of raw coke oven gas general pipeline before primary cooler is tilted down and is connected to the gas vent of gas-liquid separator, liquid collection opening is arranged in the total pipe end of raw coke oven gas straight down before primary cooler, liquid collection opening connection row's condensate line, the end for arranging condensate line is connected to tar ammonia pipeline or tar ammonia separator.Compared with prior art, the present invention avoids the blocking of raw coke oven gas pipeline and drain pipe before the increase of flushing liquor system bring low temperature water consumption of raw coke oven gas pipeline high temperature condensate liquid access primary cooler lower section circulation, the increase of primary cooler low-temperature zone heat exchange area, the blocking of lower section circulation flushing liquor system equipment pipeline and primary cooler before primary cooler, reduces the equipment investment of primary cooler;The smooth discharge for ensuring raw coke oven gas pipeline condensate liquid alleviates the Dust Capacity that raw coke oven gas entrainment enters primary cooler, improves raw coke oven gas in the cooling effect of primary cooler.

Description

Raw coke oven gas pipeline condenses liquid processing device before a kind of primary cooler
Technical field
The present invention relates to coking industry technology upgrading and technical field of energy saving and environmental protection, raw coke oven gas before especially a kind of primary cooler Pipeline condenses liquid processing device.
Background technique
During reclaiming clean coke-oven gas, the raw coke oven gas escaped from coke furnace carbonization chamber through tedge first through bridge tube into Enter gas collecting tube, is cooled to 80~84 DEG C by the cyclic ammonia water that tar ammonia separator is sent.Gas collecting tube outlet raw coke oven gas and Tar ammonia mixture is after gas-liquid separator, tar ammonia mixture tar removing ammonium hydroxide separator;Raw coke oven gas enters just cold Device continues cool to 20~22 DEG C.Raw coke oven gas after gas-liquid separator is entrained with the impurity such as coal dust, tar and naphthalene to some extent; High temperature raw coke oven gas pipeline is not kept the temperature before primary cooler, and with environment heat transfer process, saturation water condensation gets off to form height in raw coke oven gas Warm condensate liquid, condensate temperature is close to 80~84 DEG C of raw gas temperature;The impurity such as part coal dust, tar and naphthalene also enter cold together Lime set.Primary cooler generallys use the indirect primary cooler of transverse tube, carries out sub-sectional cooling to raw coke oven gas with industrial circulating water and water at low temperature.It is right Needing to recycle the user that raw coke oven gas waste heat generates high-temperature residual heat water, upper section, middle section, lower section three-stage structure can be used in primary cooler, on Section is cooling with remaining hot water.Disconnected tower tray is set between primary cooler recirculated water section and water at low temperature section.For strengthen primary cooler heat exchange efficiency, Improve the de- naphthalene efficiency of primary cooler, the tar ammonia emulsion that remaining hot water section, recirculated water section are sent with tar ammonia separator It is sprayed, flushing liquor and the disconnected tower tray of gas liquor warp flow to tar ammonia separator certainly;Lower section water at low temperature section lower section The circulation flushing liquor of circulation flushing liquor pumping continuously sprays, oneself flow to lower section through primary cooler bottom for gas liquor and flushing liquor Sprinkling liquid bath, then through lower section circulation flushing liquor be pumped to primary cooler water at low temperature section top circulation sprinkling;Extra condensate liquid by It send after circulation sprinkling liquid pump to tar ammonia separator;The temperature of flushing liquor is recycled at 18~21 DEG C or so.Primary cooler at present Preceding raw coke oven gas high temperature condensate liquid generally accesses primary cooler lower section flushing liquor tank liquor envelope, coal dust, dust and tar slag in condensate liquid Equal impurity have also accessed lower section circulation flushing liquor system together.High temperature condensate liquid is cooled to the heat that circulation flushing liquor temperature is released It is taken out of in primary cooler water at low temperature section by water at low temperature, consumes the dosage and primary cooler low-temperature zone heat exchange area of water at low temperature;Condensate liquid In the impurity such as coal dust, coal dust and tar slag assemble in circulation flushing liquor system, lead to the blocking of equipment and pipeline, reduce Water at low temperature section coal gas cooling effect;Extra condensate liquid is finally pumped to tar ammonia separator through lower section circulation flushing liquor, increases The sendout and power of circulation sprinkling liquid pump are added.The impurity such as coal dust, dust, naphthalene in high temperature condensate liquid are waste easily before primary cooler Assemble in gas piping and Drainage pipe, causes raw coke oven gas pipeline section to be reduced, Drainage pipe blocking and coal gas transporting resistance increase Add.
Summary of the invention
The invention aims to be directed to the deficiencies in the prior art, raw coke oven gas pipeline is cold before providing a kind of primary cooler Lime set processing unit avoids raw coke oven gas pipeline high temperature condensate liquid access primary cooler lower section circulation flushing liquor system before primary cooler from bringing The increase of low temperature water consumption, the increase of primary cooler low-temperature zone heat exchange area, lower section circulation flushing liquor system equipment pipeline it is stifled The blocking of raw coke oven gas pipeline and drain pipe before plug and primary cooler.
In order to achieve the above objectives, the present invention is implemented according to following technical scheme:
Raw coke oven gas pipeline condenses liquid processing device, the gas pipe of the inlet communication including gas-liquid separator before a kind of primary cooler Road, the gas vent of gas-liquid separator connect raw coke oven gas general pipeline before primary cooler, and raw coke oven gas general pipeline passes through before first cold air before primary cooler Raw coke oven gas is in charge of to be connected to horizontal water-tube primary cooler top, and gas-liquid separator liquid outlet passes through tar ammonia pipeline and tar ammonia The connection of separator entrance;The circulation spray line of horizontal water-tube primary cooler lower section recycles sprinkling liquid pump by lower section and lower section circulation is sprayed Liquid bath connection is spilt, the middle section of horizontal water-tube primary cooler is connected to tar ammonia separator entrance, and lower section circulation sprinkling liquid pump goes out Liquid mouth is also connected to tar ammonia separator entrance, and the lower section of horizontal water-tube primary cooler is equipped with gas exit, horizontal water-tube primary cooler Bottom is connected to liquid seal trough, and liquid seal trough top recycles sprinkling liquid bath with lower section and is connected to;By the entrance of raw coke oven gas general pipeline before primary cooler End tilts down and is connected to the gas vent of gas-liquid separator, before first cold air raw coke oven gas be in charge of end tilt down with before primary cooler Raw coke oven gas general pipeline is concentric or pushes up flushconnection, and liquid collection opening, liquid collection opening is arranged in the total pipe end of raw coke oven gas straight down before the primary cooler Connection row's condensate line, the end of row's condensate line is connected to tar ammonia pipeline or tar ammonia separator.
Further technical solution is that there are two condensate line valve is arranged, two rows are cold for setting on row's condensate line Steam blowing pipe is connected on row's condensate line between lime set tube valve.
Further technical solution is that raw coke oven gas general pipeline is in charge of with raw coke oven gas before first cold air and is all connected with before the primary cooler There is hot ammonium hydroxide flushing pipe.
Compared with prior art, present invention process is simple, does not increase new equipment;Avoid raw coke oven gas pipeline before primary cooler high The increase of warm condensate liquid access primary cooler lower section circulation flushing liquor system bring low temperature water consumption, primary cooler low-temperature zone heat-transfer surface The blocking of raw coke oven gas pipeline and drain pipe before the blocking of long-pending increase, lower section circulation flushing liquor system equipment pipeline and primary cooler, The equipment investment for reducing primary cooler reduces the operating cost of primary cooler low-temperature zone circulation sprinkling liquid pump;Ensure raw coke oven gas The smooth discharge of pipeline condensate liquid alleviates the Dust Capacity that raw coke oven gas entrainment enters primary cooler, improves raw coke oven gas in primary cooler Cooling effect.
Detailed description of the invention
Fig. 1 is process flow chart of the invention;
In figure: 1, horizontal water-tube primary cooler, 2, gas-liquid separator, 3, tar ammonia separator, 4, liquid seal trough, 5, lower section follows Ring spray spills liquid bath, 6, lower section circulation sprinkling liquid pump, 7, inhale gas piping, 8, raw coke oven gas general pipeline before primary cooler, and 9, waste before primary cooler Gas manifold, 10, row's condensate line, 11, gas valve, 12, row's condensate line valve, 13, tar ammonia pipeline, 14, low temperature Water heat exchanger tube road, 15, hot ammonium hydroxide flushing pipe, 16, steam blowing pipe, 17, gas exit.
Specific embodiment
The invention will be further described combined with specific embodiments below, in the illustrative examples and explanation of the invention For explaining the present invention, but it is not as a limitation of the invention.
As shown in Figure 1, raw coke oven gas pipeline condenses liquid processing device, existing processing work before a kind of primary cooler of the present embodiment Skill mainly includes the gas piping 7 of the inlet communication of gas-liquid separator 2, before the gas vent of gas-liquid separator 2 connects primary cooler Raw coke oven gas general pipeline 8, raw coke oven gas general pipeline 8 is in charge of 9 by raw coke oven gas before first cold air and connects with 1 top of horizontal water-tube primary cooler before primary cooler Logical, raw coke oven gas is in charge of 9 equipped with gas valve 11 before first cold air, and 2 liquid outlet of gas-liquid separator passes through tar ammonia pipeline 13 It is connected to 3 entrance of tar ammonia separator;The circulation spray line of 1 lower section of horizontal water-tube primary cooler recycles sprinkling liquid pump by lower section 6, which recycle sprinkling liquid bath 5 with lower section, is connected to, and the middle section of horizontal water-tube primary cooler 1 is connected to 3 entrance of tar ammonia separator, lower section The liquid outlet of circulation sprinkling liquid pump 6 is also connected to 3 entrance of tar ammonia separator, and the lower section of horizontal water-tube primary cooler 1 is equipped with coal Gas outlet 17,1 bottom of horizontal water-tube primary cooler is connected to liquid seal trough 4, and 4 top of liquid seal trough recycles sprinkling liquid bath 5 with lower section and is connected to, horizontal It is equipped in the upper section of tubular type primary cooler 1, middle section and lower section for carrying out heat exchange cooling to the coal gas in horizontal water-tube primary cooler 1 Water at low temperature heat exchange pipeline 14;The present embodiment is to tilt down the arrival end of raw coke oven gas general pipeline 8 before primary cooler and gas-liquid separator 2 Gas vent connection, before first cold air raw coke oven gas be in charge of 9 ends tilt down it is concentric or top is put down with raw coke oven gas general pipeline 8 before primary cooler It connects, liquid collection opening, liquid collection opening connection row's condensate line 10, row is arranged in 8 end raw coke oven gas general pipeline straight down before the primary cooler The end of condensate line 10 is connected to tar ammonia pipeline 13 or tar ammonia separator 3, is that will arrange condensation in the present embodiment The end of liquid pipe 10 is directly connected to tar ammonia separator 3, raw coke oven gas pipeline general pipeline 8 and coal waste before first cold air before primary cooler Gas is in charge of the condensate liquid that raw coke oven gas and environment in 9 change thermogenetic condensate liquid, the droplet settling of raw coke oven gas entrainment generates, and passes through row 10 fluid-tight of condensate line accesses the tar ammonia pipeline 13 after tar ammonia separator 3 or gas-liquid separator 2, does not access circulation Liquid bath 5 or liquid seal trough 4 are sprayed, high temperature condensate liquid access primary cooler lower section circulation flushing liquor system bring low temperature water consumption is avoided Increase, primary cooler low-temperature zone heat exchange area increase, lower section circulation flushing liquor system equipment pipeline blocking, reduce just it is cold The equipment investment of device reduces the operating cost of circulation sprinkling liquid pump.
In the above-described embodiments, there are two condensate line valve 12 is arranged, two rows are cold for setting on row's condensate line 10 Steam blowing pipe 16 is connected on row's condensate line 10 between lime set tube valve 12.Periodically two-way cleaning it can arrange condensate line 10 In the impurity such as coal dust, tar and naphthalene, it is ensured that row's 10 condensate discharge of condensate line it is unimpeded.
In the above-described embodiments, raw coke oven gas general pipeline 8 is in charge of on 9 with raw coke oven gas before first cold air and is respectively connected with before the primary cooler Hot ammonium hydroxide flushing pipe 15 can be in charge of the coal assembled in 9 with raw coke oven gas before raw coke oven gas general pipeline 8 before periodic cleaning primary cooler and first cold air The impurity such as powder, tar and naphthalene, it is ensured that raw coke oven gas general pipeline 8 is in charge of the condensate liquid in 9 with raw coke oven gas before first cold air and flow to before primary cooler Condensate line 10 is arranged, mitigates raw coke oven gas entrainment and enters the impurity such as coal dust, tar and the naphthalene of horizontal water-tube primary cooler 1, it is defeated to reduce coal gas Send resistance.
The working principle of the present embodiment are as follows: raw coke oven gas pipeline general pipeline 8 is in charge of in 9 waste with raw coke oven gas before first cold air before primary cooler The condensate liquid that coal gas and environment change thermogenetic condensate liquid, the droplet settling of raw coke oven gas entrainment generates, by arranging condensate line 10 Fluid-tight accesses the tar ammonia pipeline 13 after tar ammonia separator 3 or gas-liquid separator 2, does not access lower section circulation flushing liquor Slot 5 or liquid seal trough 4 avoid the increasing of high temperature condensate liquid access primary cooler lower section circulation flushing liquor system bring low temperature water consumption Add, the increase of primary cooler low-temperature zone heat exchange area, the blocking of lower section circulation flushing liquor system equipment pipeline, reduces primary cooler Equipment investment reduces the operating cost of circulation sprinkling liquid pump.
The limitation that technical solution of the present invention is not limited to the above specific embodiments, it is all to do according to the technique and scheme of the present invention Technology deformation out, falls within the scope of protection of the present invention.

Claims (1)

1. raw coke oven gas pipeline condenses liquid processing device, the coal gas of the inlet communication including gas-liquid separator (2) before a kind of primary cooler Pipeline (7), the gas vent of gas-liquid separator (2) connect raw coke oven gas general pipeline (8) before primary cooler, raw coke oven gas general pipeline before primary cooler (8) it is in charge of (9) by raw coke oven gas before first cold air to be connected to horizontal water-tube primary cooler (1) top, gas-liquid separator (2) liquid outlet is logical Tar ammonia water pipeline (13) is crossed to be connected to tar ammonia separator (3) entrance;The circulation of horizontal water-tube primary cooler (1) lower section is sprayed Pipe recycles sprinkling liquid bath (5) with lower section by lower section circulation sprinkling liquid pump (6) and is connected to, the middle section of horizontal water-tube primary cooler (1) and coke The connection of oily ammonium hydroxide separator (3) entrance, the liquid outlet of lower section circulation sprinkling liquid pump (6) also with tar ammonia separator (3) The lower section of entrance connection, horizontal water-tube primary cooler (1) is equipped with gas exit (17), horizontal water-tube primary cooler (1) bottom and liquid seal trough (4) Connection, liquid seal trough (4) top recycle sprinkling liquid bath (5) with lower section and are connected to, it is characterised in that: by raw coke oven gas general pipeline before primary cooler (8) arrival end is tilted down to be connected to the gas vent of gas-liquid separator (2), before first cold air raw coke oven gas be in charge of (9) end to Lower inclination and raw coke oven gas general pipeline (8) before primary cooler are concentric or push up flushconnection, and raw coke oven gas general pipeline (8) end is vertical before the primary cooler Down-set liquid collection opening, liquid collection opening connection row condensate line (10), the end of row's condensate line (10) and tar ammonia pipe Road (13) or tar ammonia separator (3) connection;There are two arrange condensate line valve for setting on row's condensate line (10) (12), steam blowing pipe (16) are connected on row's condensate line (10) between two rows condensate line valve (12);It is described just cold Raw coke oven gas general pipeline (8) is in charge of on (9) with raw coke oven gas before first cold air before device is respectively connected with hot ammonium hydroxide flushing pipe (15).
CN201810456153.5A 2018-05-14 2018-05-14 Raw coke oven gas pipeline condenses liquid processing device before a kind of primary cooler Expired - Fee Related CN108561756B (en)

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CN109405631A (en) * 2018-12-04 2019-03-01 中冶焦耐(大连)工程技术有限公司 A kind of offline cleaning process of primary cooler lower section and system
CN110013731A (en) * 2019-04-17 2019-07-16 唐钢美锦(唐山)煤化工有限公司 A kind of coking exhaust gas processing device that zero-emission may be implemented and method
CN113203048B (en) * 2021-03-25 2022-07-22 宣化钢铁集团有限责任公司 Safe liquid drainage device and method for gas system at inlet and outlet of aspirator

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JP2007132422A (en) * 2005-11-09 2007-05-31 Keiyo Gas Kk Trapped water removing device of pipe bottom part
CN202265554U (en) * 2011-09-28 2012-06-06 河南宝舜化工科技有限公司 Drainage device for tar oil-circulating ammonia water tank
CN102504851B (en) * 2011-11-03 2013-12-18 河南中鸿集团煤化有限公司 Equipment and process for producing light tar by controlling QI (Quality Index) value of tar
CN105670707A (en) * 2016-01-25 2016-06-15 神木县三江煤化工有限责任公司 Automatic cycle device and method for gas washing water (ammonia water)
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Granted publication date: 20190830