CN108559198A - A kind of polyvinyl chloride heat proof cable material and preparation method thereof - Google Patents

A kind of polyvinyl chloride heat proof cable material and preparation method thereof Download PDF

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Publication number
CN108559198A
CN108559198A CN201711447823.9A CN201711447823A CN108559198A CN 108559198 A CN108559198 A CN 108559198A CN 201711447823 A CN201711447823 A CN 201711447823A CN 108559198 A CN108559198 A CN 108559198A
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CN
China
Prior art keywords
totm
bisphenol
corvic
polyvinyl chloride
heat proof
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711447823.9A
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Chinese (zh)
Inventor
吴昌皂
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Jiangsu Pengcheng Chemical Co Ltd
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Jiangsu Pengcheng Chemical Co Ltd
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Priority to CN201711447823.9A priority Critical patent/CN108559198A/en
Publication of CN108559198A publication Critical patent/CN108559198A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)

Abstract

A kind of polyvinyl chloride heat proof cable material of the present invention and preparation method thereof, is grouped as by the group of following parts by weight:Corvic 80 110;Trioctyl trimellitate (TOTM) 30 40;Lead stearate 0.7 1.2;Bisphenol-A 0.2 0.8;Calcinated argil 27.The present invention have the characteristics that it is wear-resisting, be not easy to flatten, good insulation preformance.The present invention is heat-resist, non-aging, fall off, and avoids the generation of fire, meanwhile, it has been also convenient for the normal operation that outdoor construction is laid with cable.

Description

A kind of polyvinyl chloride heat proof cable material and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of polyvinyl chloride heat proof cable material and its preparation side Method.
Background technology
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and which includes a variety of product such as rubber, plastics, nylon Kind.CABLE MATERIALS manufacturing enterprise is with cable manufacturing enterprise for user, there is the market of CABLE MATERIALS as long as live wire cabling requirements.Electricity In line cable product insulating layer mouth is almost required in addition to the bare wires product such as steel-cored aluminium strand, electromagnetic wire.But due to China Edge is vast, and the north and south temperature difference is big, if cable poor heat resistance, is easy for aging, falls off, and not only causes the difficulty of repair in this way, disappears More resources are consumed, can also cause cable work abnormal, easily cause fire, meanwhile, if easy to aging also bring shadow to construction operation It rings, is unfavorable for the improvement of people's living standards.
Invention content
The purpose of the present invention is overcoming the deficiencies of existing technologies, provide it is a kind of it is wear-resisting, be not easy to flatten, good insulation preformance it is poly- Vinyl chloride heat proof cable material and preparation method thereof.
For this purpose, the present invention provides a kind of polyvinyl chloride heat proof cable material, its main feature is that, it is grouped by the group of following parts by weight At:Corvic 80-110;Trioctyl trimellitate (TOTM) 30-40;Lead stearate 0.7-1.2;Bisphenol-A 0.2-0.8;It forges Burn clay 2-7;Preparation method includes the following steps:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
Preferably, being grouped as by the group of following parts by weight:Corvic 80;Trioctyl trimellitate (TOTM) 30;Firmly Resin acid lead 0.7;Bisphenol-A 0.2;Calcinated argil 2.
Preferably, being grouped as by the group of following parts by weight:Corvic 110;Trioctyl trimellitate (TOTM) 40;Firmly Resin acid lead 1.2;Bisphenol-A 0.8;Calcinated argil 7.
Preferably, being grouped as by the group of following parts by weight:Corvic 100;Trioctyl trimellitate (TOTM) 38;Firmly Resin acid lead 1.1;Bisphenol-A 0.6;Calcinated argil 6.
Beneficial effects of the present invention:The present invention have the characteristics that it is wear-resisting, be not easy to flatten, good insulation preformance.The present invention is heat-resisting Property it is good, it is non-aging, fall off, avoid the generation of fire, meanwhile, be also convenient for the normal operation that outdoor construction is laid with cable.
Specific implementation mode
With reference to embodiment, the present invention is furture elucidated.
Embodiment 1:
A kind of polyvinyl chloride heat proof cable material is present embodiments provided, is grouped as by the group of following parts by weight:Corvic 80-110;Trioctyl trimellitate (TOTM) 30-40;Lead stearate 0.7-1.2;Bisphenol-A 0.2-0.8;Calcinated argil 2-7;It is made Preparation Method includes the following steps:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
The trioctyl trimellitate (TOTM) can be used as plasticizer;Lead stearate can be used as stabilizer so that product has good Lubricity;Add bisphenol-A, it is ensured that CABLE MATERIALS inner core-body is not easy to be corroded.
Embodiment 2:
A kind of polyvinyl chloride heat proof cable material is present embodiments provided, is grouped as by the group of following parts by weight:Corvic 80;Trioctyl trimellitate (TOTM) 30;Lead stearate 0.7;Bisphenol-A 0.2;Calcinated argil 2;Preparation method, including walk as follows Suddenly:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
Embodiment 3:
A kind of polyvinyl chloride heat proof cable material is present embodiments provided, is grouped as by the group of following parts by weight:Corvic 110;Trioctyl trimellitate (TOTM) 40;Lead stearate 1.2;Bisphenol-A 0.8;Calcinated argil 7;Preparation method, including walk as follows Suddenly:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
Embodiment 4:
A kind of polyvinyl chloride heat proof cable material is present embodiments provided, is grouped as by the group of following parts by weight:Corvic 100;Trioctyl trimellitate (TOTM) 38;Lead stearate 1.1;Bisphenol-A 0.6;Calcinated argil 6;Preparation method, including walk as follows Suddenly:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
The foregoing examples are only illustrative of the present invention, does not constitute the limitation to protection scope of the present invention, all Be with the present invention it is same or analogous design all belong to the scope of protection of the present invention within.

Claims (4)

1. a kind of polyvinyl chloride heat proof cable material, which is characterized in that be grouped as by the group of following parts by weight:
Corvic 80-110;Trioctyl trimellitate (TOTM) 30-40;Lead stearate 0.7-1.2;Bisphenol-A 0.2-0.8; Calcinated argil 2-7;
Preparation method includes the following steps:
(1)Prepare slurry:Trioctyl trimellitate (TOTM), lead stearate, bisphenol-A and calcinated argil are mixed into slurry, slurry is made;
(2)Slurry obtained by step is mediated with Corvic, is refined through open type plastic purificating set, enters pelleter afterwards into granulating Material, you can be made.
2. a kind of polyvinyl chloride heat proof cable material as described in claim 1, which is characterized in that be grouped by the group of following parts by weight At:Corvic 80;Trioctyl trimellitate (TOTM) 30;Lead stearate 0.7;Bisphenol-A 0.2;Calcinated argil 2.
3. a kind of polyvinyl chloride heat proof cable material as described in claim 1, which is characterized in that be grouped by the group of following parts by weight At:Corvic 110;Trioctyl trimellitate (TOTM) 40;Lead stearate 1.2;Bisphenol-A 0.8;Calcinated argil 7.
4. a kind of polyvinyl chloride heat proof cable material as described in claim 1, which is characterized in that be grouped by the group of following parts by weight At:Corvic 100;Trioctyl trimellitate (TOTM) 38;Lead stearate 1.1;Bisphenol-A 0.6;Calcinated argil 6.
CN201711447823.9A 2017-12-27 2017-12-27 A kind of polyvinyl chloride heat proof cable material and preparation method thereof Pending CN108559198A (en)

Priority Applications (1)

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CN201711447823.9A CN108559198A (en) 2017-12-27 2017-12-27 A kind of polyvinyl chloride heat proof cable material and preparation method thereof

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CN201711447823.9A CN108559198A (en) 2017-12-27 2017-12-27 A kind of polyvinyl chloride heat proof cable material and preparation method thereof

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Publication Number Publication Date
CN108559198A true CN108559198A (en) 2018-09-21

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289252A (en) * 2013-06-25 2013-09-11 张宇 A fatigue-resistant PVC insulated cable material
CN103319802A (en) * 2013-06-18 2013-09-25 张宇 Low-smoke flame-retardant PVC (polyvinyl chloride) cable material and preparation method thereof
KR20160073615A (en) * 2014-12-17 2016-06-27 엘에스전선 주식회사 Polyvinylchloride composition for sheath of cable and cable comprising a sheath prepared from the same
CN105924826A (en) * 2016-05-03 2016-09-07 安徽九华金润铜业有限公司 Cold and high temperature resistant PVC cable material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103319802A (en) * 2013-06-18 2013-09-25 张宇 Low-smoke flame-retardant PVC (polyvinyl chloride) cable material and preparation method thereof
CN103289252A (en) * 2013-06-25 2013-09-11 张宇 A fatigue-resistant PVC insulated cable material
KR20160073615A (en) * 2014-12-17 2016-06-27 엘에스전선 주식회사 Polyvinylchloride composition for sheath of cable and cable comprising a sheath prepared from the same
CN105924826A (en) * 2016-05-03 2016-09-07 安徽九华金润铜业有限公司 Cold and high temperature resistant PVC cable material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
尹汝生等: "耐热105℃PVC电线电缆绝缘料配方和性能", 《塑料工业》 *
陈长明等: "《精细化学品配方工艺及原料分析》", 31 July 2002, 北京工业大学出版社 *

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Application publication date: 20180921