CN108557957B - Stone processing integrated sewage treatment device and treatment method thereof - Google Patents

Stone processing integrated sewage treatment device and treatment method thereof Download PDF

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Publication number
CN108557957B
CN108557957B CN201810693545.3A CN201810693545A CN108557957B CN 108557957 B CN108557957 B CN 108557957B CN 201810693545 A CN201810693545 A CN 201810693545A CN 108557957 B CN108557957 B CN 108557957B
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water
water inlet
pipeline
valve
washing
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CN108557957A (en
Inventor
吴振华
张轶凡
张舒阳
张健富
伊泽
杨帅
朱冠宇
李红霞
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TIANJIN CARING TECHNOLOGY DEVELOPMENT CO LTD
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TIANJIN CARING TECHNOLOGY DEVELOPMENT CO LTD
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18Use of gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/03Pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses an integrated sewage treatment device for stone processing, which comprises: the device comprises a water inlet tank, a water inlet valve, a water inlet pressure gauge, macroporous membrane equipment, a water outlet valve, a concentrated water valve, a gas washing assembly, a water outlet and backwashing water tank, a water inlet pipeline, a water outlet pipeline, a concentrated water pipeline, a water washing pipeline and a gas washing pipeline, wherein the water inlet tank is connected with the macroporous membrane equipment through the water inlet pipeline, and the water inlet valve and the water inlet pressure gauge are arranged on the water inlet pipeline; the water inlet tank is connected with macroporous membrane equipment through a concentrated water pipeline, and a concentrated water valve is arranged on the concentrated water pipeline; the water outlet pipeline is respectively connected with the macroporous membrane equipment and the water outlet and backwashing water tank, and is provided with a water outlet valve; the water washing component is connected with the macroporous membrane equipment and the effluent and backwash water tank through a water washing pipeline; the air washing component is connected with the macroporous membrane equipment through an air washing pipeline; the invention also discloses a stone processing integrated sewage treatment method, and the sewage treated by the method has higher water yield.

Description

Stone processing integrated sewage treatment device and treatment method thereof
Technical Field
The invention relates to the technical field of environmental protection, in particular to a stone processing integrated sewage treatment device and a treatment method thereof.
Background
In recent years, along with the gradual increase of stone processing enterprises, the discharge water amount is gradually increased, and most stone processing enterprises adopt large-scale cutting machines to process stone plates, so as to prolong the service lives of cutters and grinding tools in the processing processThe method of cooling the cutter and the grinding tool by using clear water to remove scraps and residues, thereby generating a large amount of sewage. The sewage contains a large amount of stone powder, and the main component comprises silicon dioxide (SiO 2 ) Calcium carbonate (CaCO) 3 ) And other inorganic oxides, small amounts of diamond grains, abrasive grains, and also including silt and product packaging material fragments, etc., washed from the shop floor. Generally, the suspended matter content in sewage is 2000 mg/L-4000 mg/L, and the highest suspended matter content can reach 7000mg/L, and although sewage treatment enterprises carry out multiple upgrading and reconstruction projects, the condition that SS exceeds standard still exists in drainage indexes, and the downstream beach culture enterprises and the surrounding ecological environment are seriously affected. Especially, the central environment-friendly supervision group feeds back opinion to improve the processing standard reaching capability of the sewage treatment plant of the stone processing park, perfects an emergency processing guarantee system, stops the accidental discharge of the sewage of the park and protects the beach culture environment of the coastal sea area.
At present, the basic methods of treating the sewage in stone slab processing mainly comprise a physical treatment method, a chemical treatment method and a biochemical treatment method, and the pollutants contained in the sewage are separated, removed, recycled or converted into harmless substances so as to purify the water. Generally, pollutants with larger particle sizes can be removed by a conventional chemical flocculation strengthening method, and the pollutants with the particle sizes of 3-5 um are researched as main exceeding standard parts in drainage, so that the pollutant with smaller particle sizes in the range can form a stable colloid-like state in sewage, and cannot be removed by a conventional coagulating sedimentation process and device.
Accordingly, the inventors of the present invention have demanded to devise a new technique for improving the problems thereof.
Disclosure of Invention
In order to solve the technical problems, the invention provides an integrated sewage treatment device for stone processing and a treatment method thereof.
The technical scheme of the invention is as follows:
a stone processing integrated sewage treatment device, comprising: the water inlet device comprises a water inlet tank, a water inlet valve, a water inlet pressure gauge, macroporous membrane equipment, a water outlet valve, a concentrated water valve, a gas washing assembly, a water outlet and backwashing water tank, a water inlet pipeline, a water outlet pipeline, a concentrated water pipeline, a water washing pipeline and a gas washing pipeline, wherein the water inlet tank is connected with the macroporous membrane equipment through the water inlet pipeline, and the water inlet valve and the water inlet pressure gauge are arranged on the water inlet pipeline; the water inlet tank is connected with the macroporous membrane equipment through the concentrated water pipeline, and the concentrated water valve is arranged on the concentrated water pipeline; the water outlet pipeline is respectively connected with the macroporous membrane equipment and the water outlet and backwashing water tank, and the water outlet valve is arranged on the water outlet pipeline; the water washing component is connected with the macroporous membrane equipment and the water outlet and backwashing water tank through a water washing pipeline; the air washing component is connected with the macroporous membrane equipment through the air washing pipeline.
Preferably, the air washing assembly comprises an air washing valve, an air washing fan and an air washing pressure gauge.
Preferably, the water washing assembly comprises a water washing valve, a water washing pressure gauge and a water washing pump.
Preferably, the water inlet pump is communicated with the water inlet pipeline.
Preferably, the pore diameter of the macroporous membrane equipment is 3-5 um.
The treatment method based on the stone processing integrated sewage treatment device comprises the following steps:
s1: opening a water inlet valve, a water outlet valve and a concentrated water valve;
s2: conveying sewage to macroporous membrane equipment through a water inlet pipeline;
s3: the macroporous membrane equipment filters sewage;
s4: the water reaching the treatment standard is discharged to the water outlet and backwashing water tank and then is discharged to the downstream receiving water body; and returning the water which does not reach the standard to the water inlet tank through a concentrated water pipeline.
Preferably, the method further comprises the following pretreatment steps:
s01: checking the value of the water inlet pressure gauge, and when the value reaches a first water inlet pressure threshold value, entering a step S02; otherwise, enter step S1;
s02: keeping the water inlet valve and the water inlet pump in an open state, closing the water outlet valve, opening the air washing valve, and opening the air washing fan to perform air washing operation;
s03: after the air washing is finished, checking the numerical value of the water inlet pressure gauge again, and entering step S04 when the numerical value reaches a second water inlet pressure threshold value; otherwise, enter step S1;
s04: and closing the water inlet pump and the water inlet valve, opening the water washing valve and the water washing pump, and performing water washing operation, wherein the pressure value of the water washing pressure gauge is controlled to be smaller than the first water inlet pressure threshold or the second water inlet pressure threshold in the water washing operation process.
Preferably, the first inlet water pressure threshold and/or the second inlet water pressure threshold is 0.3Mpa.
Preferably, the method comprises: the air washing operation time is 10-20 s, and the water washing operation time is 1-2 min.
Preferably, the step S2 specifically includes: and starting the water inlet pump, and pumping the sewage from the water inlet tank to the macroporous membrane equipment through the water inlet pump.
By adopting the technical scheme, the invention at least comprises the following beneficial effects:
according to the stone processing integrated sewage treatment device and the stone processing integrated sewage treatment method, any medicament is not required to be added, and the sewage with the exceeding standard of the stone processing tail end can directly enter equipment, so that repeated medicament adding and circulating are avoided, the SS of effluent is less than 1mg/L, the water return level is achieved, and the cost of operating medicaments is saved.
Drawings
FIG. 1 is a schematic diagram of a stone processing integrated sewage treatment device according to the present invention;
FIG. 2 shows a stone processing integrated sewage treatment device according to the invention;
fig. 3 is a view showing a stone processing integrated sewage treatment device according to the present invention.
Wherein: the water tank 1, the water inlet pump 2, the water inlet valve 3, the water inlet pressure gauge 4, the macroporous membrane equipment 5, the water outlet valve 6, the concentrate valve 7, the air washing valve 8, the air washing pressure gauge 9, the air washing fan 10, the water washing pressure gauge 11, the water washing pump 12, the water washing valve 13, the water outlet and backwashing water tank 14.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
As shown in fig. 1, the present invention provides an integrated sewage treatment device for stone processing, comprising: the water inlet tank 1 is connected with the macroporous membrane device 5 through the water inlet pipeline, and the water inlet valve 3 and the water inlet pressure meter 4 are arranged on the water inlet pipeline; the water inlet tank 1 is connected with the macroporous membrane equipment 5 through the concentrated water pipeline, and the concentrated water valve 7 is arranged on the concentrated water pipeline; the water outlet pipeline is respectively connected with the macroporous membrane equipment 5 and the water outlet and backwashing water tank 14, and the water outlet pipeline is provided with the water outlet valve 6; the water washing component is connected with the macroporous membrane equipment 5 and the water outlet and backwashing water tank 14 through a water washing pipeline; the air washing component is connected with the macroporous membrane equipment 5 through the air washing pipeline.
Preferably, the air washing assembly comprises an air washing valve 8, an air washing fan 10 and an air washing pressure gauge 9.
Preferably, the water washing assembly comprises a water washing valve 13, a water washing pressure gauge 11 and a water washing pump 12.
Preferably, the water inlet pump 2 is further included, and the water inlet pump 2 is communicated with the water inlet pipeline.
Preferably, the pore size of the macroporous membrane equipment 5 is 3-5 um.
As shown in fig. 2, the treatment method of the stone processing integrated sewage treatment device according to the present invention comprises the following steps:
s1: opening the water inlet valve 3, the water outlet valve 6 and the concentrate valve 7;
s2: delivering the sewage to the macroporous membrane equipment 5 through a water inlet pipeline;
s3: the macroporous membrane equipment 5 is used for filtering sewage;
s4: the water reaching the treatment standard is discharged to the water outlet and backwashing water tank 14 and then discharged to the downstream receiving water body; the water which does not reach the standard is returned to the water inlet tank 1 through a concentrated water pipeline.
Preferably, the method further comprises the following pretreatment steps:
s01: checking the value of the water inlet pressure gauge 4, and when the value reaches a first water inlet pressure threshold value, entering a step S02; otherwise, enter step S1;
s02: keeping the water inlet valve 3 and the water inlet pump 2 in an open state, closing the water outlet valve 6, opening the air washing valve 8, and opening the air washing fan 10 to perform air washing operation;
s03: after the air washing is finished, checking the numerical value of the water inlet pressure gauge 4 again, and entering the step S04 when the numerical value reaches a second water inlet pressure threshold value; otherwise, enter step S1;
s04: and closing the water inlet pump 2 and the water inlet valve 3, opening the water washing valve 13 and the water washing pump 12, and performing water washing operation, wherein the pressure value of the water washing pressure gauge 11 is controlled to be smaller than the first water inlet pressure threshold value or the second water inlet pressure threshold value during the water washing operation.
Preferably, the first inlet water pressure threshold and/or the second inlet water pressure threshold is 0.3Mpa.
Preferably, the method comprises: the air washing operation time is 10-20 s, and the water washing operation time is 1-2 min.
Preferably, the step S2 specifically includes: the water inlet pump 2 is started, and sewage is pumped from the water inlet tank to the macroporous membrane equipment 5 through the water inlet pump 2.
The water yield of the stone processing sewage treatment integrated equipment can reach 90%, namely, the water inflow of 90% proportion can reach the standard and be discharged or recycled according to the water inflow, only 10% of concentrated water can be generated in the process, and the part of concentrated water can return to a raw water inflow pool for continuous treatment.
However, with the increase of the service life of the membrane equipment, when the pressure of the water inlet pressure gauge 4 is increased to 0.3Mpa, gas backwashing is required, and the specific operation process is that the water inlet valve 3 and the water inlet pump 2 are kept in an open state, the water outlet valve 6 is closed, the gas washing valve 8 is opened, then the gas washing fan 10 is opened, the gas washing pressure gauge 9 is controlled to be smaller than 0.1Mpa in the gas washing process, and gas washing is stopped when suspended substances SS of water inlet and water outlet are felt to be almost in a macroscopic state, and the gas washing process is generally considered to last for 10-20 s. When the air washing effect is found to be poor, namely the air washing is finished, the water inlet pressure gauge 4 is still about 0.3Mpa when water is fed again, water washing is needed at the moment, the specific water washing process is that the water inlet pump 2 is closed, the water inlet valve 3 is closed, the water washing valve 13 is opened, the pressure of the water washing pressure gauge 11 is controlled to be less than 0.3Mpa in the process of opening the water washing pump 12, and the water is washed for 1-2 min.
The stone processing sewage is large in water quantity, the main pollutants are solid suspended solids SS and a small amount of organic matter cutting cooling liquid, a horizontal sedimentation tank is mainly selected as a conventional treatment process, a large amount of coagulating sedimentation agents are added in the treatment process, a large amount of sludge is generated in the sedimentation process due to the fact that suspended solids SS in sewage are very high, coagulant aid is required to be added again in a dewatering link, press drainage is required to return to inflow water for retreatment, different types of sedimentation agents are continuously circulated in a sewage treatment system, so that the effluent suspended solids SS, particularly fine particles with the particle size of 3-5 um, form a stable state, are not easy to settle, and the flocculation effect is hardly caused by adding the sedimentation agents again at the tail end, and even the effluent turbidity of a sewage treatment facility is increased. The stone processing sewage integrated treatment device adopts main equipment such as a water inlet pump 2, a macroporous membrane device 5, an air washing blower 10, a water washing pump 12 and the like. The production of the phenomena can be avoided by combining a sewage collecting tank, a water inlet pump 2 room, a vertical flow sedimentation tank, a horizontal flow sedimentation tank, a sewage regulating tank, a plate and frame sludge regulating tank, a plate and frame filter press, a sludge centrifugal regulating tank, a sludge centrifugal machine and the like and combining the process steps shown in the figure 3. In fig. 3, solid arrows indicate waterways, and broken arrows indicate mud paths, which are known.
The invention has the main advantages that:
(1) The stone processing tail end standard exceeding sewage can directly enter equipment without adding any medicament, so that repeated medicament adding and circulating are avoided, the effluent SS is less than 1mg/L, the grade of reuse water is achieved, and the cost of operating the medicament is saved;
(2) Compared with the traditional membrane product, the membrane has high water yield and low ton water investment cost;
(3) The flocculation effect is good, so that the filtering effect is obviously better than that of the traditional physical filtering equipment (such as sand filtering equipment);
(4) Compared with the traditional gravity flow filtration or pressureless flow filtration system, the device adopts pressure filtration, belongs to pressurized flow, can manually control the water inflow, and is used as an emergency control system when the water inflow fluctuates and the water inflow is greatly increased in rainy seasons.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (4)

1. The utility model provides a processing method of stone material processing integration sewage treatment plant which characterized in that, this stone material processing integration sewage treatment plant includes: the water inlet device comprises a water inlet tank, a water inlet valve, a water inlet pressure gauge, macroporous membrane equipment, a water outlet valve, a concentrated water valve, a gas washing assembly, a water outlet and backwashing water tank, a water inlet pipeline, a water outlet pipeline, a concentrated water pipeline, a water washing pipeline and a gas washing pipeline, wherein the water inlet tank is connected with the macroporous membrane equipment through the water inlet pipeline, and the water inlet valve and the water inlet pressure gauge are arranged on the water inlet pipeline; the water inlet tank is connected with the macroporous membrane equipment through the concentrated water pipeline, and the concentrated water valve is arranged on the concentrated water pipeline; the water outlet pipeline is respectively connected with the macroporous membrane equipment and the water outlet and backwashing water tank, and the water outlet valve is arranged on the water outlet pipeline; the water washing component is connected with the macroporous membrane equipment and the water outlet and backwashing water tank through a water washing pipeline; the air washing component is connected with the macroporous membrane equipment through the air washing pipeline; the processing method based on the device comprises the following steps:
s1: opening a water inlet valve, a water outlet valve and a concentrated water valve;
s2: conveying sewage to macroporous membrane equipment through a water inlet pipeline;
s3: the macroporous membrane equipment filters sewage;
s4: the water reaching the treatment standard is discharged to the water outlet and backwashing water tank and then is discharged to the downstream receiving water body; returning the water which does not reach the standard to the water inlet tank through a concentrated water pipeline;
the method also comprises the following pretreatment steps:
s01: checking the value of the water inlet pressure gauge, and when the value reaches a first water inlet pressure threshold value, entering a step S02; otherwise, enter step S1;
s02: keeping the water inlet valve and the water inlet pump in an open state, closing the water outlet valve, opening the air washing valve, and opening the air washing fan to perform air washing operation;
s03: after the air washing is finished, checking the numerical value of the water inlet pressure gauge again, and entering step S04 when the numerical value reaches a second water inlet pressure threshold value; otherwise, enter step S1;
s04: and closing the water inlet pump and the water inlet valve, opening the water washing valve and the water washing pump, and performing water washing operation, wherein the pressure value of the water washing pressure gauge is controlled to be smaller than the first water inlet pressure threshold or the second water inlet pressure threshold in the water washing operation process.
2. The method for treating the stone processing integrated sewage treatment device according to claim 1, wherein: the first inlet water pressure threshold and/or the second inlet water pressure threshold is 0.3Mpa.
3. The method for treating the stone processing integrated sewage treatment device according to claim 1, wherein: the air washing operation time is 10-20 s, and the water washing operation time is 1-2 min.
4. A method for treating a stone processing integrated sewage treatment device according to any one of claims 1 to 3, characterized in that: the step S2 specifically includes: and starting the water inlet pump, and pumping the sewage from the water inlet tank to the macroporous membrane equipment through the water inlet pump.
CN201810693545.3A 2018-06-29 2018-06-29 Stone processing integrated sewage treatment device and treatment method thereof Active CN108557957B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0131119A1 (en) * 1983-05-27 1985-01-16 C.P.C. Engineering Corp. Cross-flow microfiltration lime softener
CN2639286Y (en) * 2003-07-31 2004-09-08 马志新 Sewage purification equipment for ceramic processing
JP2007245059A (en) * 2006-03-17 2007-09-27 Fuji Electric Systems Co Ltd Backwashing method and apparatus of filtration membrane
KR101036001B1 (en) * 2010-12-07 2011-05-23 (주)대림그린엔택 Wastwater treatment method and system using dynamic flow and submerged membrane
WO2014079253A1 (en) * 2012-11-26 2014-05-30 海尔集团技术研发中心 Laundry water cyclic utilization apparatus, cleaning method thereof, and water-saving washing control method
CN104402094A (en) * 2014-12-17 2015-03-11 北京碧水源膜科技有限公司 Energy-saving and pollution-resisting water treatment system provided with RO (reverse osmosis) membranes and application of water treatment system
CN104492265A (en) * 2014-12-31 2015-04-08 天津大学 Ultrafiltration membrane device with on-line medicament backwashing and blowdown device
CN105217733A (en) * 2015-10-12 2016-01-06 北京碧水源膜科技有限公司 A kind of nanometer filtering film water treatment system of two-way flow and method
CN208500438U (en) * 2018-06-29 2019-02-15 天津凯英科技发展股份有限公司 A kind of processing of stone integrated sewage treating apparatus

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0131119A1 (en) * 1983-05-27 1985-01-16 C.P.C. Engineering Corp. Cross-flow microfiltration lime softener
CN2639286Y (en) * 2003-07-31 2004-09-08 马志新 Sewage purification equipment for ceramic processing
JP2007245059A (en) * 2006-03-17 2007-09-27 Fuji Electric Systems Co Ltd Backwashing method and apparatus of filtration membrane
KR101036001B1 (en) * 2010-12-07 2011-05-23 (주)대림그린엔택 Wastwater treatment method and system using dynamic flow and submerged membrane
WO2014079253A1 (en) * 2012-11-26 2014-05-30 海尔集团技术研发中心 Laundry water cyclic utilization apparatus, cleaning method thereof, and water-saving washing control method
CN104402094A (en) * 2014-12-17 2015-03-11 北京碧水源膜科技有限公司 Energy-saving and pollution-resisting water treatment system provided with RO (reverse osmosis) membranes and application of water treatment system
CN104492265A (en) * 2014-12-31 2015-04-08 天津大学 Ultrafiltration membrane device with on-line medicament backwashing and blowdown device
CN105217733A (en) * 2015-10-12 2016-01-06 北京碧水源膜科技有限公司 A kind of nanometer filtering film water treatment system of two-way flow and method
CN208500438U (en) * 2018-06-29 2019-02-15 天津凯英科技发展股份有限公司 A kind of processing of stone integrated sewage treating apparatus

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