CN108546965A - A kind of production method of hydrometallurgy anode plate handle - Google Patents

A kind of production method of hydrometallurgy anode plate handle Download PDF

Info

Publication number
CN108546965A
CN108546965A CN201810171827.7A CN201810171827A CN108546965A CN 108546965 A CN108546965 A CN 108546965A CN 201810171827 A CN201810171827 A CN 201810171827A CN 108546965 A CN108546965 A CN 108546965A
Authority
CN
China
Prior art keywords
die casting
anode plate
casting machine
lead
mould
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810171827.7A
Other languages
Chinese (zh)
Inventor
贾天将
陆帅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NINGXIA TIANYUAN MANGANESE Ltd Co
Original Assignee
NINGXIA TIANYUAN MANGANESE Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NINGXIA TIANYUAN MANGANESE Ltd Co filed Critical NINGXIA TIANYUAN MANGANESE Ltd Co
Priority to CN201810171827.7A priority Critical patent/CN108546965A/en
Publication of CN108546965A publication Critical patent/CN108546965A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34—Constructional details or accessories or operation thereof
    • B03C3/40—Electrode constructions
    • B03C3/45—Collecting-electrodes
    • B03C3/47—Collecting-electrodes flat, e.g. plates, discs, gratings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C11/00—Alloys based on lead
    • C22C11/06—Alloys based on lead with tin as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/10—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of chromium or manganese
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/30—Electrolytic production, recovery or refining of metals by electrolysis of melts of manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

The invention belongs to anode plate manufacture fields, and in particular to a kind of production method of hydrometallurgy anode plate handle；A kind of production method of hydrometallurgy anode plate handle, specific production procedure are as follows：Smelting, mould of die casting machine release agent spraying, embedded copper bar, injection lead-containing alloy solution, die cast, the finishing of lead-containing alloy solution；The present invention is designed into the making of anode plate handle, using die casting machine die cast, improve the castability of the degree of automation and anode plate handle of anode plate production, improve anode plate handle castability, reduce stomata, and be that lower process welding sequence has accomplished fluently Process ba- sis, the effective service life for improving anode plate.

Description

A kind of production method of hydrometallurgy anode plate handle
Technical field：
The invention belongs to anode plate manufacture fields, and in particular to a kind of production method of hydrometallurgy anode plate handle.
Background technology：
Anode plate is the core component of electric precipitator, the acceptance criteria of anode plate：It is straight, intensity is high, rigidity is strong, is not easy to turn round It is bent.Electrolytic anode plate, by anode hangers, transition row, mainboard sequence be formed by welding, it is characterized in that transition row by tin, silver, cobalt, silicon, Antimony, lead, mainboard are mixed in a certain ratio by calcium, aluminium, silver, tin, lead, and trace rare-earth element is separately added, respectively through dissolving, mixing, Casting, cold pressing, shearing, stamping making.Antiseptic property is good, is used for electrolytic manganese.Anode plate connects the cathode of high-voltage DC power supply High voltage electric field is formed between line and the anode plate of ground connection, since corona discharge occurs for cathode, gas is ionized, electronegative gas Ion, under the action of electric field force, plate moves on the sunny side, collides during exercise with dust particles, then makes grit lotus with negative electricity, charged Grit afterwards is under the action of electric field force, also to anode movement, after reaching anode, releases negative electrical charge, grit is then deposited on anode On plate, and outside the gas discharge dust excluder being purified
For ease of use, handle is set on anode plate.The method that the handle of general anode plate all uses gravity casting, The product air holes that this method is produced are more, and density is not high.Cause with anode plate grid weld there are weld defect, welding Of poor quality, anode plate service life is short, is often broken from commissure.
Invention content：
The present invention provides a kind of production method of anode plate handle, improves anode plate handle castability, reduces stomata, is Anode plate welding sequence is laid a solid foundation, and anode plate service life is improved.
A kind of production method of hydrometallurgy anode plate handle, specific production procedure are as follows：
The first step：Lead-containing alloy solution is made in waste and old metal pole plate calcining fusing by the smelting of lead-containing alloy solution, It will be transported in holding furnace after the processing of lead-containing alloy solution homogenizing, wherein the temperature of lead-containing alloy solution is 400 DEG C -500 DEG C, is protected Temperature in warm stove is 400 DEG C -500 DEG C；
Second step：Mould of die casting machine release agent spraying opens mould of die casting machine, releasing agent even application is existed by spraying machine Intracavitary in mould of die casting machine, wherein the flue gas of intracavitary is collected by smoke gas collecting apparatus in mould of die casting machine；
Third walks：Embedded copper bar, manipulator grip copper bar and copper bar are embedded in die casting machine dies cavity, and mould of die casting machine closes Mould；
4th step：Lead-containing alloy solution is injected, lead-containing alloy solution is taken from holding furnace by soup feeding machine and is poured into die casting In machine dies cavity, the lead-containing alloy liquid of melting is under the action of shooting system pressure, intracavitary in injection to mould of die casting machine, Middle shooting system pressure is 75-125MPa；
5th step：Die cast keeps mould of die casting machine chamber pressure constant, until lead-containing alloy solution is fully cured into For anode plate handle product, the wherein pressure of mould of die casting machine inner cavity is 75-125MPa；
6th step：Finishing, by the anode plate handle product after die cast by manipulator from mould of die casting machine inner cavity It takes out, send to bead cutter, bead cutter places the mouth of a river, cutting burrs on conveyer, stacking machine is by finished product stacking for next procedure It uses.
Preferably, lead-containing alloy main chemical compositions：Sn 3%-5%, Ag 0.08%-0.1%, Sb 1%-2%, As 0.6%-0.8%, Pb 92.1%-95.32%.
Preferably, lead-containing alloy main chemical compositions：Sn 3%, Ag 0.08%, Sb 1%, As 0.6%, Pb 92.1%.
Preferably, the flue gas in the flue dust and holding furnace of die casting machine is sent into fume collection in workshop by gas collection system Pipeline.
The present invention is designed into the making of anode plate handle, using die casting machine die cast, improves anode plate production oneself The castability of dynamicization degree and anode plate handle improves anode plate handle castability, reduces stomata, and is lower process welding Process has accomplished fluently Process ba- sis, the effective service life for improving anode plate.
Specific embodiment：
Embodiment one：
A kind of production method of hydrometallurgy anode plate handle, specific production procedure are as follows：
The first step：Lead-containing alloy solution is made in waste and old metal pole plate calcining fusing by the smelting of lead-containing alloy solution, It will be transported in holding furnace after the processing of lead-containing alloy solution homogenizing, wherein the temperature of lead-containing alloy solution is 400 DEG C, in holding furnace Temperature be 400 DEG C；
Second step：Mould of die casting machine release agent spraying opens mould of die casting machine, releasing agent even application is existed by spraying machine Intracavitary in mould of die casting machine, wherein the flue gas of intracavitary is collected by smoke gas collecting apparatus in mould of die casting machine；
Third walks：Embedded copper bar, manipulator grip copper bar and copper bar are embedded in die casting machine dies cavity, and mould of die casting machine closes Mould；
4th step：Lead-containing alloy solution is injected, lead-containing alloy solution is taken from holding furnace by soup feeding machine and is poured into die casting In machine dies cavity, the lead-containing alloy liquid of melting is under the action of shooting system pressure, intracavitary in injection to mould of die casting machine, Middle shooting system pressure is 75MPa；
5th step：Die cast keeps mould of die casting machine chamber pressure constant, until lead-containing alloy solution is fully cured into For anode plate handle product, the wherein pressure of mould of die casting machine inner cavity is 75MPa；
6th step：Finishing, by the anode plate handle product after die cast by manipulator from mould of die casting machine inner cavity It takes out, send to bead cutter, bead cutter places the mouth of a river, cutting burrs on conveyer, stacking machine is by finished product stacking for next procedure It uses.
Wherein, the flue gas in the flue dust and holding furnace of die casting machine is sent into fume collection pipe in workshop by gas collection system Road.Lead-containing alloy main chemical compositions：Sn 3%, Ag 0.08%, Sb 1%, As 0.6%, Pb 92.1%.
Embodiment two：
A kind of production method of hydrometallurgy anode plate handle, specific production procedure are as follows：
The first step：Lead-containing alloy solution is made in waste and old metal pole plate calcining fusing by the smelting of lead-containing alloy solution, It will be transported in holding furnace after the processing of lead-containing alloy solution homogenizing, wherein the temperature of lead-containing alloy solution is 450 DEG C, in holding furnace Temperature be 450 DEG C；
Second step：Mould of die casting machine release agent spraying opens mould of die casting machine, releasing agent even application is existed by spraying machine Intracavitary in mould of die casting machine, wherein the flue gas of intracavitary is collected by smoke gas collecting apparatus in mould of die casting machine；
Third walks：Embedded copper bar, manipulator grip copper bar and copper bar are embedded in die casting machine dies cavity, and mould of die casting machine closes Mould；
4th step：Lead-containing alloy solution is injected, lead-containing alloy solution is taken from holding furnace by soup feeding machine and is poured into die casting In machine dies cavity, the lead-containing alloy liquid of melting is under the action of shooting system pressure, intracavitary in injection to mould of die casting machine, Middle shooting system pressure is 90MPa；
5th step：Die cast keeps mould of die casting machine chamber pressure constant, until lead-containing alloy solution is fully cured into For anode plate handle product, the wherein pressure of mould of die casting machine inner cavity is 90MPa；
6th step：Finishing, by the anode plate handle product after die cast by manipulator from mould of die casting machine inner cavity It takes out, send to bead cutter, bead cutter places the mouth of a river, cutting burrs on conveyer, stacking machine is by finished product stacking for next procedure It uses.
Wherein, the flue gas in the flue dust and holding furnace of die casting machine is sent into fume collection pipe in workshop by gas collection system Road.Lead-containing alloy main chemical compositions：Sn 4%, Ag 0.09%, Sb 1.5%, As 0.7%, Pb 93.5%.
Implement three：
A kind of production method of hydrometallurgy anode plate handle, specific production procedure are as follows：
The first step：Lead-containing alloy solution is made in waste and old metal pole plate calcining fusing by the smelting of lead-containing alloy solution, It will be transported in holding furnace after the processing of lead-containing alloy solution homogenizing, wherein the temperature of lead-containing alloy solution is 500 DEG C, in holding furnace Temperature be 500 DEG C；
Second step：Mould of die casting machine release agent spraying opens mould of die casting machine, releasing agent even application is existed by spraying machine Intracavitary in mould of die casting machine, wherein the flue gas of intracavitary is collected by smoke gas collecting apparatus in mould of die casting machine；
Third walks：Embedded copper bar, manipulator grip copper bar and copper bar are embedded in die casting machine dies cavity, and mould of die casting machine closes Mould；
4th step：Lead-containing alloy solution is injected, lead-containing alloy solution is taken from holding furnace by soup feeding machine and is poured into die casting In machine dies cavity, the lead-containing alloy liquid of melting is under the action of shooting system pressure, intracavitary in injection to mould of die casting machine, Middle shooting system pressure 125MPa；
5th step：Die cast keeps mould of die casting machine chamber pressure constant, until lead-containing alloy solution is fully cured into For anode plate handle product, the wherein pressure of mould of die casting machine inner cavity is 125MPa；
6th step：Finishing, by the anode plate handle product after die cast by manipulator from mould of die casting machine inner cavity It takes out, send to bead cutter, bead cutter places the mouth of a river, cutting burrs on conveyer, stacking machine is by finished product stacking for next procedure It uses.
Wherein, the flue gas in the flue dust and holding furnace of die casting machine is sent into fume collection pipe in workshop by gas collection system Road.Lead-containing alloy main chemical compositions：Sn 5%, Ag 0.1%, Sb 2%, As 0.8%, Pb 95.32%.

Claims (4)

1. a kind of production method of hydrometallurgy anode plate handle, it is characterised in that：A kind of system of hydrometallurgy anode plate handle Make method, specific production procedure is as follows：
The first step：Lead-containing alloy solution is made, by lead in waste and old metal pole plate calcining fusing by the smelting of lead-containing alloy solution It is transported in holding furnace after the processing of based alloy solution homogenizing, wherein the temperature of lead-containing alloy solution is 400 DEG C -500 DEG C, holding furnace In temperature be 400 DEG C -500 DEG C；
Second step：Mould of die casting machine release agent spraying opens mould of die casting machine, by spraying machine by releasing agent even application in die casting In machine dies cavity, wherein the flue gas of intracavitary is collected by smoke gas collecting apparatus in mould of die casting machine；
Third walks：Embedded copper bar, manipulator grip copper bar and copper bar are embedded in die casting machine dies cavity, mould of die casting machine molding；
4th step：Lead-containing alloy solution is injected, lead-containing alloy solution is taken from holding furnace by soup feeding machine and is poured into die casting machine mould Intracavitary in tool, the lead-containing alloy liquid of melting is under the action of shooting system pressure, intracavitary in injection to mould of die casting machine, wherein penetrating Material system pressure is 75-125MPa；
5th step：Die cast keeps mould of die casting machine chamber pressure constant, until lead-containing alloy solution is fully cured as sun Pole plate handle product, the wherein pressure of mould of die casting machine inner cavity are 75-125MPa；
6th step：Finishing takes out the anode plate handle product after die cast by manipulator from mould of die casting machine inner cavity, It send to bead cutter, bead cutter places the mouth of a river, cutting burrs on conveyer, and stacking machine uses finished product stacking for next procedure.
2. a kind of production method of hydrometallurgy anode plate handle according to claim 1, it is characterised in that：The lead Based alloy main chemical compositions：Sn 3%-5%, Ag 0.08%-0.1%, Sb 1%-2%, As 0.6%-0.8%, Pb 92.1%-95.32%.
3. a kind of production method of hydrometallurgy anode plate handle according to claim 2, it is characterised in that：The lead Based alloy main chemical compositions：Sn 3%, Ag 0.08%, Sb 1%, As 0.6%, Pb 92.1%.
4. a kind of production method of hydrometallurgy anode plate handle according to claim 1, it is characterised in that：Die casting machine Flue gas in flue dust and holding furnace is sent into fume collection pipeline in workshop by gas collection system.
CN201810171827.7A 2018-03-01 2018-03-01 A kind of production method of hydrometallurgy anode plate handle Pending CN108546965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810171827.7A CN108546965A (en) 2018-03-01 2018-03-01 A kind of production method of hydrometallurgy anode plate handle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810171827.7A CN108546965A (en) 2018-03-01 2018-03-01 A kind of production method of hydrometallurgy anode plate handle

Publications (1)

Publication Number Publication Date
CN108546965A true CN108546965A (en) 2018-09-18

Family

ID=63516009

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810171827.7A Pending CN108546965A (en) 2018-03-01 2018-03-01 A kind of production method of hydrometallurgy anode plate handle

Country Status (1)

Country Link
CN (1) CN108546965A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114535540A (en) * 2020-11-19 2022-05-27 金川集团股份有限公司 Automatic plate lifting system and method for nickel sulfide anode plate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105543892A (en) * 2015-12-10 2016-05-04 沈阳弘圣鑫电解技术研发有限公司 Lead-silver alloy anode plate for zinc electrolysis and manufacturing method of lead-silver alloy anode plate
CN107419299A (en) * 2017-04-17 2017-12-01 晋宁理工恒达科技有限公司 It is a kind of to reclaim method of the Zinc electrolysis with the useless plate of palisading type aluminium base alloy lead anode

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105543892A (en) * 2015-12-10 2016-05-04 沈阳弘圣鑫电解技术研发有限公司 Lead-silver alloy anode plate for zinc electrolysis and manufacturing method of lead-silver alloy anode plate
CN107419299A (en) * 2017-04-17 2017-12-01 晋宁理工恒达科技有限公司 It is a kind of to reclaim method of the Zinc electrolysis with the useless plate of palisading type aluminium base alloy lead anode

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘云薄等: "《发动机铸造工艺及装备调试》", 30 June 2015, 西南交通大学出版社 *
吴春苗: "《压铸实用技术》", 31 May 2003, 广东科技出版社 *
王香等: "《材料加工过程控制技术》", 30 August 2006, 哈尔滨工业大学出版社 *
许发樾: "《实用模具设计与制造手册》", 31 October 2000, 机械工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114535540A (en) * 2020-11-19 2022-05-27 金川集团股份有限公司 Automatic plate lifting system and method for nickel sulfide anode plate

Similar Documents

Publication Publication Date Title
CN102689921B (en) The preparation method for the Pb nm-class oxide powders for reclaiming and manufacturing for lead-acid accumulator
CN102689922B (en) Lead compound nano-powder preparation method for recovery and manufacture of lead-acid battery
CN102689923B (en) The preparation method of lead-acid battery PbO nano-powder
CN101488597B (en) Method for waste lead-acid cell resourcization and lead-acid cell cyclic production
CN101622739B (en) Negative electrode active material for nickel-metal hydride battery and nickel-metal hydride battery using the same, and method for treating negative electrode active material for nickel-metal hydride
CN103184340B (en) Method for recovering lead plaster of negative pole of disused lead acid storage battery and application of recovered lead plaster
CN105057679B (en) Method for manufacturing aluminum alloy anode metal plate of aluminum-air battery
CN102534225A (en) Treatment method for anode mud
CN1913053A (en) Preparation method of high corrosion resistance sintered neodymium iron boron
CN103374658A (en) Ultrafine lead oxide prepared from desulfurated lead plaster by means of three-stage process and method thereof
CN108546965A (en) A kind of production method of hydrometallurgy anode plate handle
CN105714329B (en) A kind of method of Direct Electrolysis scrap
CN109585798A (en) Graphene lead composite material and its preparation method and application and anode diachylon, cathode lead plaster
CN106435653B (en) A kind of Zinc electrolysis commercial bronze aluminium conductive transition part preparation method
CN107312935A (en) A kind of processing method of reducing slag after lead anode slurry melting
CN105861842B (en) A kind of method that lead is reclaimed from lead-containing material
Cole et al. Recovery of lead from battery sludge by electrowinning
CN104611571B (en) A kind of converter nitre slag melting technique
CN115323435A (en) Electrochemical metallurgy method for extracting metal and sulfur from metal sulfide
CN107502768A (en) A kind of siller tin oxide tungsten carbide composite electric contact material preparation method and products thereof
CN107841765A (en) A kind of Zinc electrolysis anode material and preparation method thereof
CN104810567B (en) Accumulator pole board waste material alloy reuse method
CN208066549U (en) A kind of anode plate handle
CN103757465B (en) A kind of corrosion-resistant easy cutting Cu alloy material and preparation method thereof
JPH1186871A (en) Copper foil-made current collector for secondary battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180918