CN108546488A - A kind of composite plate high temperature resistant interleaving agent and preparation method thereof - Google Patents
A kind of composite plate high temperature resistant interleaving agent and preparation method thereof Download PDFInfo
- Publication number
- CN108546488A CN108546488A CN201810449525.1A CN201810449525A CN108546488A CN 108546488 A CN108546488 A CN 108546488A CN 201810449525 A CN201810449525 A CN 201810449525A CN 108546488 A CN108546488 A CN 108546488A
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- CN
- China
- Prior art keywords
- interleaving agent
- composite plate
- high temperature
- temperature resistant
- alumina powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B47/00—Auxiliary arrangements, devices or methods in connection with rolling of multi-layer sheets of metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Abstract
The invention belongs to interleaving agent technical fields, more particularly to a kind of composite plate high temperature resistant interleaving agent and preparation method thereof, the interleaving agent is mixed by alumina powder and Phenolic resin powder with water, and the additive amount of the Phenolic resin powder is the 0.01 10% of alumina powder weight.Phenolic resin content is too small to make Alumina build-up inferior capabilities；Excessively high interleaving agent during heating of plate blank of resin content can largely be deflated, and zirconium steel bond quality is influenced.Interleaving agent prepared by present invention dispersibility, ductility are good, and adhesive ability is strong.
Description
Technical field
The invention belongs to interleaving agent technical fields, and in particular to a kind of composite plate high temperature resistant interleaving agent and its preparation side
Method.
Background technology
With the development of the industries such as petrochemical industry, marine building, medicine, to the wear-resisting, corrosion-resistant of material, high temperature resistant, knot
Structure intensity requirement is higher and higher, and single metal even alloy can not provide good comprehensive performance, and metal composite technology
Solves the problems, such as this in the case of very big.Composite plate common are titanium-steel composite board, Stainless Steel Steel Clad Plate, Copper steel cladding
The advantages of plate, titanium nickel compound board, nickel steel composite plate, copper-aluminum composite board, ambrose alloy composite plate, zirconium clad steel plate etc., composite metal plate
For：The cladding of plank and base respectively undertake different functions in use so that composite plate has excellent comprehensive
Energy；Compared with single metal material or alloy material, metallic composite has very high economy.Such as titanium steel composite board
The operating mode that is faced of titanium layer it is relatively high to corrosion resistance requirement, and the operating mode that steel layer is faced generally requires very corrosion resistance
Low, the presence of steel layer provides very high structural strength with very low cost to titanium steel composite board.
Composite metal plate produces generally use Hot rolling, and it is wherein heavy to organize material process during Hot rolling production composite plate
The link wanted generally uses symmetry rolling, symmetry rolling structure is as schemed to ensure plied timber deformation synchronous with base material
Shown in 1, wherein 1 is substrate layer, three be made of two layers of compound plate layer 2 and one layer of release agent layer 3 are equipped between two-layer substrate layer 1
Mingzhi's sandwich.The effect of release agent layer 3 is in order to avoid the back adhesive and surface wrinkling of compound plate layer 2 in the operation of rolling.
Generally use aluminium oxide cooks interleaving agent at present, and aluminium oxide has high-temperature stability, good dispersibility, ductility.
But aluminium oxide cooks interleaving agent the shortcomings that there are bad adhesions, easy to fall off during composite plate assembly, mistake of the assembly in carrying
Aggregation is easy in journey due to vibrations etc., opening is not easy after causing composite plate to roll.
Chinese publication CN104311144A discloses a kind of containing the stratiform for aligning whisker perpendicular to bed boundary
Aluminium oxide-epoxy resin composite material imitates " Mineralogical Digital Museum " structure of shell pearl layer, similar in ceramic layered middle formation structure
" whisker bridge " structure of " Mineralogical Digital Museum " is prepared a kind of containing by the stratiform oxidation for aligning whisker perpendicular to bed boundary direction
Aluminium-epoxy resin composite ceramics, to realize the mesh for further increasing strong, the tough performance of stratiform aluminium oxide-epoxy resin composite material
, belong to technology field of ceramic matrix composite material, different field is adhered to separately with the interleaving agent in this case.
Chinese publication CN104311144A discloses a kind of preparation method of antibacterial flame-retardant epoxy resin adhesive,
Using epoxy resin as base-material, modified nano-alumina is added, this adhesive is unsuitable for composite board and bonds isolation use.
Invention content
Invention broadly provides a kind of composite plate high temperature resistant interleaving agent and preparation method thereof, the interleaving agent of preparation disperses
Property, ductility are good, and adhesive ability is strong.Its technical solution is as follows：
A kind of composite plate high temperature resistant interleaving agent, the interleaving agent are mixed by alumina powder and Phenolic resin powder with water
It forms, the additive amount of the Phenolic resin powder is the 0.01-10% of alumina powder weight.Phenolic resin content is too small to be made
Alumina build-up inferior capabilities；Excessively high interleaving agent during heating of plate blank of resin content can largely be deflated, and zirconium steel combination is influenced
Quality.
Preferably, the additive amount of water is 1-10 times of alumina powder weight.
Preferably, the grain size of the alumina powder is 1-100 μm.
A kind of preparation method of above-mentioned composite plate high temperature resistant interleaving agent, the method is, in the alumina powder of formula ratio
The Phenolic resin powder of formula ratio is added in end and is stirred evenly, and alumina powder weight 1-10 is added into above-mentioned mixed-powder
Water again, is sprayed at composite plate blanks surface after mixing, air-dries.
Preferably, it is 1-2mm that the interleaving agent, which is sprayed at the thickness in composite plate,.
Using the above scheme, the present invention has the following advantages：
After high temperature resistant interleaving agent prepared by the present invention is coated in composite plate, in composite metal plate production process, with
The extension of plank, the same even variation of release agent layer illustrate that the interleaving agent has good ductility, and the interleaving agent is mixed with water
It easily forms suspension and is not easy to precipitate, dispersion performance is good；In use, will not be led because of collision in slab carrying, the operation of rolling
It causes interleaving agent to fall off, illustrates that interleaving agent adhesive ability is strong.
Description of the drawings
Fig. 1 is composite plate symmetry rolling structure chart.
Wherein, 1 is substrate layer, and 2 be compound plate layer, and 3 be separation layer.
Specific implementation mode
Experimental method in following embodiment is conventional method unless otherwise required, involved experiment reagent and material
Material is conventional biochemical reagent and material unless otherwise required.
Embodiment 1
1. a kind of composite plate high temperature resistant interleaving agent, the interleaving agent are mixed by alumina powder and Phenolic resin powder with water
It closes, the additive amount of the Phenolic resin powder is the 10% of alumina powder weight, and the additive amount of water is alumina powder
10 times of weight.The grain size of the alumina powder is 1-100 μm.
2. the preparation method of above-mentioned interleaving agent is：
The Phenolic resin powder of formula ratio is added in the alumina powder of formula ratio and is stirred evenly, to above-mentioned mixed powder
The water that formula ratio is added in end, is sprayed at composite plate blanks surface, coating thickness 2mm, natural air drying or heating after mixing
It air-dries.
Embodiment 2
1. a kind of composite plate high temperature resistant interleaving agent, the interleaving agent are mixed by alumina powder and Phenolic resin powder with water
It closes, the additive amount of the Phenolic resin powder is the 0.01% of alumina powder weight, and the additive amount of water is alumina powder
1 times of last weight.The grain size of the alumina powder is 1-100 μm.
2. the preparation method of above-mentioned interleaving agent is：
The Phenolic resin powder of formula ratio is added in the alumina powder of formula ratio and is stirred evenly, to above-mentioned mixed powder
The water that formula ratio is added in end, is sprayed at composite plate blanks surface, coating thickness 1mm, natural air drying or heating after mixing
It air-dries.
Embodiment 3
1. a kind of composite plate high temperature resistant interleaving agent, the interleaving agent are mixed by alumina powder and Phenolic resin powder with water
It closes, the additive amount of the Phenolic resin powder is the 1% of alumina powder weight, and the additive amount of water is alumina powder weight
5 times of amount.The grain size of the alumina powder is 1-100 μm.
2. the preparation method of above-mentioned interleaving agent is：
The Phenolic resin powder of formula ratio is added in the alumina powder of formula ratio and is stirred evenly, to above-mentioned mixed powder
The water that formula ratio is added in end is sprayed at composite plate blanks surface, coating thickness 1.5mm, natural air drying or warm after mixing
Gas air-dries.
Disperse sex expression
During embodiment 1-3 prepares interleaving agent, performance of the mixed-powder when being mixed with water, discovery and water are observed
It when mixing, is easy to form suspension and is not easy to form precipitation, illustrate that the dispersion performance of the interleaving agent is good.
Extension sex expression
The composite plate with interleaving agent prepared in Example 1-3, rolls composite plate, finds to give birth in composite plate
During production, with the extension of plank, the same even variation of release agent layer, do not occur release agent layer it is hardened be one piece, milling train grind
Fragmentation during pressure cannot play the case where buffer action and occur.
Bond sex expression
The composite plate with interleaving agent prepared in embodiment 1-3 repeatedly carry, is hit, isolation is found no
Agent obscission illustrates that interleaving agent adhesive property is good.
It will be apparent to those skilled in the art that technical solution that can be as described above and design, make various other
Corresponding change and deformation, and all these changes and deformation should all belong to the protection domain of the claims in the present invention
Within.
Claims (5)
1. a kind of composite plate high temperature resistant interleaving agent, it is characterised in that：The interleaving agent is by alumina powder and phenol-formaldehyde resin powder
End is mixed with water, and the additive amount of the Phenolic resin powder is the 0.01-10% of alumina powder weight.
2. composite plate according to claim 1 high temperature resistant interleaving agent, it is characterised in that：The additive amount of water is alumina powder
1-10 times of last weight.
3. composite plate according to claim 1 high temperature resistant interleaving agent, it is characterised in that：The grain size of the alumina powder
It is 1-100 μm.
4. a kind of preparation method of composite plate as described in claim 1 high temperature resistant interleaving agent, it is characterised in that：The method
To add the Phenolic resin powder of formula ratio in the alumina powder of formula ratio and stirring evenly, into above-mentioned mixed-powder
The water for adding 1-10 times of alumina powder weight, is sprayed at composite plate blanks surface after mixing, air-dries.
5. the composite plate according to claim 4 preparation method of high temperature resistant interleaving agent, it is characterised in that：The interleaving agent
The thickness being sprayed in composite plate is 1-2mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810449525.1A CN108546488A (en) | 2018-05-11 | 2018-05-11 | A kind of composite plate high temperature resistant interleaving agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810449525.1A CN108546488A (en) | 2018-05-11 | 2018-05-11 | A kind of composite plate high temperature resistant interleaving agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108546488A true CN108546488A (en) | 2018-09-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810449525.1A Pending CN108546488A (en) | 2018-05-11 | 2018-05-11 | A kind of composite plate high temperature resistant interleaving agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113930090A (en) * | 2021-10-18 | 2022-01-14 | 张家港宏昌钢板有限公司 | Isolating agent for non-vacuum pack rolling and preparation and use methods thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1641200A (en) * | 1999-09-08 | 2005-07-20 | 埃里安特技术体系股份有限公司 | Elastomerized phenolic resin ablative insulation for rocket motors |
| CN105238216A (en) * | 2015-10-30 | 2016-01-13 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for obtaining release agent layer on base plate and composite material containing base plate and release agent layer |
| CN105482243A (en) * | 2014-09-19 | 2016-04-13 | 中国石油化工股份有限公司 | Phenolic resin composition and foaming material and moulding material prepared therefrom |
| CN107009090A (en) * | 2016-01-27 | 2017-08-04 | 鞍钢股份有限公司 | A kind of production method of stainless steel clad plate |
| CN107446304A (en) * | 2016-05-30 | 2017-12-08 | 陈精明 | The method of phenolic resin preimpregnation material and its manufacture phenolic composite |
-
2018
- 2018-05-11 CN CN201810449525.1A patent/CN108546488A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1641200A (en) * | 1999-09-08 | 2005-07-20 | 埃里安特技术体系股份有限公司 | Elastomerized phenolic resin ablative insulation for rocket motors |
| CN105482243A (en) * | 2014-09-19 | 2016-04-13 | 中国石油化工股份有限公司 | Phenolic resin composition and foaming material and moulding material prepared therefrom |
| CN105238216A (en) * | 2015-10-30 | 2016-01-13 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for obtaining release agent layer on base plate and composite material containing base plate and release agent layer |
| CN107009090A (en) * | 2016-01-27 | 2017-08-04 | 鞍钢股份有限公司 | A kind of production method of stainless steel clad plate |
| CN107446304A (en) * | 2016-05-30 | 2017-12-08 | 陈精明 | The method of phenolic resin preimpregnation material and its manufacture phenolic composite |
Non-Patent Citations (1)
| Title |
|---|
| 孙红镱等: "《油田非金属压力管道技术》", 31 August 2014, 哈尔滨工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113930090A (en) * | 2021-10-18 | 2022-01-14 | 张家港宏昌钢板有限公司 | Isolating agent for non-vacuum pack rolling and preparation and use methods thereof |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20191107 Address after: 211164, Jiangsu Province, Nanjing city street, industrial concentration zone, 116 North Road, Qing margin Applicant after: Nanjing Youtian Metal Technology Co., Ltd. Address before: 211161 Xiaozhuang Industrial Park, ningqiao North Road, Jiangning District, Jiangning, Nanjing, Jiangsu Applicant before: Nanjing Ningfeng Chemical Equipment Co., Ltd. |
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Application publication date: 20180918 |
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