CN108546399A - A kind of noctilucence mouse case material and preparation method thereof - Google Patents
A kind of noctilucence mouse case material and preparation method thereof Download PDFInfo
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- CN108546399A CN108546399A CN201810382338.6A CN201810382338A CN108546399A CN 108546399 A CN108546399 A CN 108546399A CN 201810382338 A CN201810382338 A CN 201810382338A CN 108546399 A CN108546399 A CN 108546399A
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- parts
- powder
- noctilucence
- mouse case
- tossa
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- 239000000463 material Substances 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 81
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002994 raw material Substances 0.000 claims abstract description 29
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 26
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 26
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 26
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 26
- 239000004425 Makrolon Substances 0.000 claims abstract description 21
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 21
- 241001122767 Theaceae Species 0.000 claims abstract description 20
- 229920005560 fluorosilicone rubber Polymers 0.000 claims abstract description 20
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 20
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003365 glass fiber Substances 0.000 claims abstract description 19
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 19
- 229920002545 silicone oil Polymers 0.000 claims abstract description 19
- -1 β phenylacrylic acids methyl esters Chemical class 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 238000001291 vacuum drying Methods 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 8
- 150000002466 imines Chemical class 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 7
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 7
- 239000008188 pellet Substances 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 3
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
- UXKQNCDDHDBAPD-UHFFFAOYSA-N 4-n,4-n-diphenylbenzene-1,4-diamine Chemical group C1=CC(N)=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 UXKQNCDDHDBAPD-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 6
- 235000019837 monoammonium phosphate Nutrition 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 150000004645 aluminates Chemical class 0.000 description 5
- 229920006351 engineering plastic Polymers 0.000 description 4
- GQTXKEVAUZYHGE-UHFFFAOYSA-N methyl 2-phenylprop-2-enoate Chemical class COC(=O)C(=C)C1=CC=CC=C1 GQTXKEVAUZYHGE-UHFFFAOYSA-N 0.000 description 4
- 239000005909 Kieselgur Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000000686 essence Substances 0.000 description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical class CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000003181 co-melting Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of noctilucence mouse case materials and preparation method thereof, are related to mouse Material Field, include the raw material of following parts by weight meter：1.5 2.5 parts of 30 40 parts of makrolon, 20 30 parts of fluorine silicone rubber, 8 15 parts of polycaprolactone, 36 parts of tributyl citrate, 5 10 parts of tossa, 5 10 parts of diatomite, 48 parts of glass fibre, 5 10 parts of profound spar powder, 48 parts of luminescent powder, 36 parts of nanometer silicon carbide, 24 parts of β phenylacrylic acids methyl esters, 24 parts of tea seed cake powder, 36 parts of silicone oil, 1.2 2.4 parts of silane coupling agent, 1.2 1.8 parts of antiseptic and antioxidant；Mouse quality of materials of the present invention is light, intensity is high, excellent anti-corrosion performance, has self light emission function, the position of mouse can be clearly distinguished in dark, facility is brought to people and life.
Description
Technical field
The present invention relates to mouse Material Fields, and in particular to a kind of Luminous casing mouse material and preparation method thereof
Background technology
Mouse is a kind of very common and common computer input apparatus, it can carry out quota to the vernier on current screen
Day, and operated by the screen elements that button and roller devices pass through vernier.Most of mouse material is No. seven modelings
Expect that polycarbonate resin is a kind of thermoplastic engineering plastic of function admirable, there is excellent impact resistance, heat-resisting and cold resistance,
Creep resistant and dimensional stability, and be the material uniquely in five large-engineering plastics with good transparency, due to poly- carbonic acid
Particularity on ester structure has become the general engineering plastic that growth rate is most fast in five large-engineering plastics.
In recent years, occurring many Noctilucent plastic products in succession, such as luminous switch, luminous plastics measurer, luminous plastics
Optical fiber, luminous plastics toy, luminous plastics ornament materials etc..Luminous plastics natural light or energy after the irradiation of other artificial light sources
Enough energy of storage light irradiation, then slowly discharge the energy of storage in the form of visible light again in the dark.Noctilucence at present
The adusk illumination indicative function of plastics has brought great convenience, while also having the work of energy saving beautification life
With.But the field of mouse that Noctilucent material is applied in the prior art is seldom, is the project that current mouse Material Field can be studied
One of.
Invention content
For problems of the prior art, the present invention provides a kind of Luminous casing mouse material and its preparation sides
Method, mouse quality of materials of the present invention is light, intensity is high, excellent anti-corrosion performance, has self light emission function, can be clearly in dark
The position for distinguishing mouse brings facility to people and life.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
30-40 parts of makrolon, 20-30 parts of fluorine silicone rubber, 8-15 parts of polycaprolactone, 3-6 parts of tributyl citrate, jute
5-10 parts of fiber, 5-10 parts of diatomite, 4-8 parts of glass fibre, 5-10 parts of profound spar powder, 4-8 parts of luminescent powder, nanometer silicon carbide 3-
6 parts, 2-4 parts of beta-phenyl methyl acrylate, 2-4 parts of tea seed cake powder, 3-6 parts of silicone oil, 1.2-2.4 parts of silane coupling agent, antiseptic
1.2-1.8 1.5-2.5 parts of part and antioxidant.
Preferably, include the raw material of following parts by weight meter：33-37 parts of makrolon, gathers in oneself 24-26 parts of fluorine silicone rubber
10-13 parts of fat, 4-5 parts of tributyl citrate, 7-9 parts of tossa, 7-9 parts of diatomite, 5-7 parts of glass fibre, profound spar powder
7-9 parts, 5-7 parts of luminescent powder, 4-5 parts of nanometer silicon carbide, 2.5-3.5 parts of beta-phenyl methyl acrylate, 2.5-3.5 parts of tea seed cake powder,
1.8-2.2 parts of 4-5 parts of silicone oil, 1.8-2.1 parts of silane coupling agent, 1.4-1.6 parts of antiseptic and antioxidant.
Preferably, include the raw material of following parts by weight meter：35 parts of makrolon, 25 parts of fluorine silicone rubber, 12 parts of polycaprolactone,
4.5 parts of tributyl citrate, 8 parts of diatomite, 6 parts of glass fibre, 8 parts of profound spar powder, 6 parts of luminescent powder, is received 8 parts of tossa
4.5 parts of silicon carbide of rice, 3 parts of beta-phenyl methyl acrylate, 3 parts of tea seed cake powder, 4.5 parts of silicone oil, 2.0 parts of silane coupling agent, antiseptic
1.5 parts and 2.1 parts of antioxidant.
Preferably, the luminescent powder is alkali earth metal aluminate or manosil AS strontium.
Preferably, the silane coupling agent is gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl front three
Oxysilane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilanes and N- (β-aminoethyl)-gamma-aminopropyl-triethoxy silicon
One or more of alkane combines.
Preferably, the antiseptic is zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Preferably, the antioxidant is N, N- diphenyl-para-phenylene diamines, N, bis- (2, the 4- diaminodiphenyl ether) imines of N-
It is combined with one or more of bis- (2,4- diiminos diphenyl ether) imines of N-.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present invention, specifically, including following step
Suddenly：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 10-15 hours, after being rinsed well repeatedly with clear water,
It is placed in 80-90 degrees Celsius of vacuum drying oven dry ester moisture and is less than 1%, be placed in pulverizer and crush, mistake
200-500 mesh sieves, and obtains tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 100-120 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material
1；
(4) tossa powder and mixed material 1 are added in high-speed mixer, temperature control is to 60-70 degrees Celsius, 3-5 points
Silane coupling agent is added in Zhong Hou, and makrolon, fluorine silicone rubber, polycaprolactone, citric acid is added after 5-10 minutes in mixed at high speed
Tributyl, beta-phenyl methyl acrylate, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed obtain mixed after 10-20 minutes
Close material 2；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 180-190 degrees Celsius of extrusion temperature, spiral shell
80-100 revs/min of bar rotating speed, pellet are cooled to room temperature to get the noctilucence mouse case material.
The present invention has following advantageous effect：
(1) mouse quality of materials of the present invention is light, intensity is high, excellent anti-corrosion performance, has self light emission function, can in dark
Clearly to distinguish the position of mouse, facility is brought to people and life.
(2) present invention is using makrolon, fluorine silicone rubber and three kinds of polymer of polycaprolactone are co-melting prepares material, fluorine silicon rubber
Glue can make up the shortcomings that makrolon is intolerant to highly basic strong acid, the performance of polycarbafil, and polycaprolactone has good life
Object compatibility and good biological degradability, can promote the compatibility between polymer and amalgamation, be material character and knot
Structure is more stablized.
(3) profound spar powder is added in raw material of the present invention, profound spar powder is a kind of mineral drug gypsum crystal, containing abundant
Medical substance, be added in material, can be with antibacterial, the bactericidal property of reinforcing material, be beneficial to man health.
(4) tributyl citrate is added in raw material of the present invention, it is heat-resisting fast light water-fast, have with resin good compatible
Property, to be plasticized the preferable plasticizer of efficiency；Antibacterium of also having does not grow bacterium, nonirritant, anti-flammability and degradability again.
(5) it is added with beta-phenyl methyl acrylate and tea seed cake powder in raw material of the present invention, has the function of essence, material can be made
Material releases faint scent.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
30 parts of makrolon, 20 parts of fluorine silicone rubber, 8 parts of polycaprolactone, 3 parts of tributyl citrate, 5 parts of tossa, silicon
5 parts of diatomaceous earth, 4 parts of glass fibre, 5 parts of profound spar powder, 4 parts of luminescent powder, 3 parts of nanometer silicon carbide, 2 parts of beta-phenyl methyl acrylate,
1.5 parts of 2 parts of tea seed cake powder, 3 parts of silicone oil, 1.2 parts of silane coupling agent, 1.2 parts of antiseptic and antioxidant.
Luminescent powder is alkali earth metal aluminate.
Silane coupling agent is gamma-aminopropyl-triethoxy-silane.
Antiseptic is zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Antioxidant is N, N- diphenyl-para-phenylene diamines.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present embodiment, specifically, including it is following
Step：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 10 hours, after being rinsed well repeatedly with clear water, is set
Dry ester moisture is less than 1% in 80 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, and crosses 200 mesh sieve,
Obtain tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 100 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 are added in high-speed mixer, temperature control to after 60 degrees Celsius, 3 minutes,
Silane coupling agent is added, after five minutes, makrolon, fluorine silicone rubber, polycaprolactone, tributyl citrate, β-is added in mixed at high speed
Phenylacrylic acid methyl esters, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed after ten minutes, obtain mixed material 2；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 180 degrees Celsius of extrusion temperature, screw rod turns
80 revs/min of speed, pellet is cooled to room temperature to get the noctilucence mouse case material.
Embodiment 2
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
40 parts of makrolon, 30 parts of fluorine silicone rubber, 15 parts of polycaprolactone, 6 parts of tributyl citrate, 10 parts of tossa,
10 parts of diatomite, 8 parts of glass fibre, 10 parts of profound spar powder, 8 parts of luminescent powder, 6 parts of nanometer silicon carbide, beta-phenyl methyl acrylate 4
Part, 4 parts of tea seed cake powder, 6 parts of silicone oil, 2.4 parts of silane coupling agent, 1.8 parts of antiseptic and 2.5 parts of antioxidant.
Luminescent powder is manosil AS strontium.
Silane coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane.
Antiseptic is zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Antioxidant is N, bis- (2,4- diaminodiphenyl ethers) imines of N-.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present embodiment, specifically, including it is following
Step：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 15 hours, after being rinsed well repeatedly with clear water, is set
Dry ester moisture is less than 1% in 90 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, and crosses 500 mesh sieve,
Obtain tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 120 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 being added in high-speed mixer, temperature control is to 70 degrees Celsius, after five minutes,
Be added silane coupling agent, mixed at high speed after ten minutes, be added makrolon, fluorine silicone rubber, polycaprolactone, tributyl citrate,
Beta-phenyl methyl acrylate, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed after twenty minutes, obtain mixed material 2；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 190 degrees Celsius of extrusion temperature, screw rod turns
100 revs/min of speed, pellet is cooled to room temperature to get the noctilucence mouse case material.
Embodiment 3
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
33 parts of makrolon, 24 parts of fluorine silicone rubber, 10 parts of polycaprolactone, 4 parts of tributyl citrate, 7 parts of tossa, silicon
7 parts of diatomaceous earth, 5 parts of glass fibre, 7 parts of profound spar powder, 5 parts of luminescent powder, 4 parts of nanometer silicon carbide, beta-phenyl methyl acrylate 2.5
Part, 2.5 parts of tea seed cake powder, 4 parts of silicone oil, 1.8 parts of silane coupling agent, 1.4 parts of antiseptic and 1.8 parts of antioxidant.
Luminescent powder is alkali earth metal aluminate.
Silane coupling agent is N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane.
Antiseptic is zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Antioxidant is bis- (the 2,4- diiminos diphenyl ether) imines of N-.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present embodiment, specifically, including it is following
Step：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 12 hours, after being rinsed well repeatedly with clear water, is set
Dry ester moisture is less than 1% in 85 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, and crosses 300 mesh sieve,
Obtain tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 108 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 are added in high-speed mixer, temperature control to after 65 degrees Celsius, 4 minutes,
Silane coupling agent is added, makrolon, fluorine silicone rubber, polycaprolactone, tributyl citrate, β-is added after 8 minutes in mixed at high speed
Phenylacrylic acid methyl esters, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed obtain mixed material 2 after 15 minutes；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 185 degrees Celsius of extrusion temperature, screw rod turns
90 revs/min of speed, pellet is cooled to room temperature to get the noctilucence mouse case material.
Embodiment 4
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
37 parts of makrolon, 26 parts of fluorine silicone rubber, 13 parts of polycaprolactone, 5 parts of tributyl citrate, 9 parts of tossa, silicon
9 parts of diatomaceous earth, 7 parts of glass fibre, 9 parts of profound spar powder, 7 parts of luminescent powder, 5 parts of nanometer silicon carbide, beta-phenyl methyl acrylate 3.5
Part, 3.5 parts of tea seed cake powder, 5 parts of silicone oil, 2.1 parts of silane coupling agent, 1.6 parts of antiseptic and 2.2 parts of antioxidant.
Luminescent powder is alkali earth metal aluminate.
Silane coupling agent is N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane.
State antiseptic be zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Antioxidant is bis- (the 2,4- diiminos diphenyl ether) imines of N-.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present embodiment, specifically, including it is following
Step：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 14 hours, after being rinsed well repeatedly with clear water, is set
Dry ester moisture is less than 1% in 88 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, and crosses 300 mesh sieve,
Obtain tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 115 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 being added in high-speed mixer, temperature control is to 68 degrees Celsius, after five minutes,
Silane coupling agent is added, makrolon, fluorine silicone rubber, polycaprolactone, tributyl citrate, β-is added after 8 minutes in mixed at high speed
Phenylacrylic acid methyl esters, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed obtain mixed material 2 after 17 minutes；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 188 degrees Celsius of extrusion temperature, screw rod turns
95 revs/min of speed, pellet is cooled to room temperature to get the noctilucence mouse case material.
Embodiment 5
A kind of Luminous casing mouse material includes the raw material of following parts by weight meter：
35 parts of makrolon, 25 parts of fluorine silicone rubber, 12 parts of polycaprolactone, 4.5 parts of tributyl citrate, 8 parts of tossa,
8 parts of diatomite, 6 parts of glass fibre, 8 parts of profound spar powder, 6 parts of luminescent powder, 4.5 parts of nanometer silicon carbide, beta-phenyl methyl acrylate 3
Part, 3 parts of tea seed cake powder, 4.5 parts of silicone oil, 2.0 parts of silane coupling agent, 1.5 parts of antiseptic and 2.1 parts of antioxidant.
Luminescent powder is alkali earth metal aluminate.
Silane coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane.
Antiseptic is zinc oxide, ammonium dihydrogen phosphate and lithium carbonate according to mass ratio 1:2:2 mixing compositions.
Antioxidant is N, and N- diphenyl-para-phenylene diamines and bis- (2,4- diaminodiphenyl ethers) imines of N, N- are according to mass ratio
1:1 mixing composition.
A kind of preparation method of above-mentioned noctilucence mouse case material is also disclosed in the present embodiment, specifically, including it is following
Step：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 13 hours, after being rinsed well repeatedly with clear water, is set
Dry ester moisture is less than 1% in 86 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, and crosses 400 mesh sieve,
Obtain tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven,
It is dried in the environment of 110 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 are added in high-speed mixer, temperature control to after 68 degrees Celsius, 4 minutes,
Silane coupling agent is added, makrolon, fluorine silicone rubber, polycaprolactone, tributyl citrate, β-is added after 8 minutes in mixed at high speed
Phenylacrylic acid methyl esters, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed obtain mixed material 2 after 18 minutes；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 185 degrees Celsius of extrusion temperature, screw rod turns
90 revs/min of speed, pellet is cooled to room temperature to get the noctilucence mouse case material.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of noctilucence mouse case material, which is characterized in that including following raw material by weight：Makrolon 30-40
Part, 20-30 parts of fluorine silicone rubber, 8-15 parts of polycaprolactone, 3-6 parts of tributyl citrate, 5-10 parts of tossa, diatomite 5-10
Part, 4-8 parts of glass fibre, 5-10 parts of profound spar powder, 4-8 parts of luminescent powder, 3-6 parts of nanometer silicon carbide, beta-phenyl methyl acrylate
2-4 parts, 2-4 parts of tea seed cake powder, 3-6 parts of silicone oil, 1.2-2.4 parts of silane coupling agent, 1.2-1.8 parts of antiseptic and antioxidant 1.5-
2.5 part.
2. noctilucence mouse case material according to claim 1, which is characterized in that include the raw material of following parts by weight meter：
33-37 parts of makrolon, 24-26 parts of fluorine silicone rubber, 10-13 parts of polycaprolactone, 4-5 parts of tributyl citrate, tossa 7-9
Part, 7-9 parts of diatomite, 5-7 parts of glass fibre, 7-9 parts of profound spar powder, 5-7 parts of luminescent powder, 4-5 parts of nanometer silicon carbide, beta-phenyl
2.5-3.5 parts of methyl acrylate, 2.5-3.5 parts of tea seed cake powder, 4-5 parts of silicone oil, 1.8-2.1 parts of silane coupling agent, antiseptic 1.4-
1.6 parts and 1.8-2.2 parts of antioxidant.
3. noctilucence mouse case material according to claim 1, which is characterized in that include the raw material of following parts by weight meter：
35 parts of makrolon, 25 parts of fluorine silicone rubber, 12 parts of polycaprolactone, 4.5 parts of tributyl citrate, 8 parts of tossa, diatomite 8
Part, 6 parts of glass fibre, 8 parts of profound spar powder, 6 parts of luminescent powder, 4.5 parts of nanometer silicon carbide, 3 parts of beta-phenyl methyl acrylate, tea seed cake
2.1 parts of 3 parts of powder, 4.5 parts of silicone oil, 2.0 parts of silane coupling agent, 1.5 parts of antiseptic and antioxidant.
4. noctilucence mouse case material according to claim 1, which is characterized in that the luminescent powder is alkaline-earth metal aluminic acid
Salt or manosil AS strontium.
5. noctilucence mouse case material according to claim 1, which is characterized in that the silane coupling agent is γ-ammonia third
Ethyl triethoxy silicane alkane, γ-glycidyl ether oxygen propyl trimethoxy silicane, N- (β-aminoethyl)-γ-aminopropyl trimethoxies
One or more of silane and N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane combine.
6. noctilucence mouse case material according to claim 1, which is characterized in that the antiseptic is zinc oxide, phosphoric acid
Ammonium dihydrogen and lithium carbonate are according to mass ratio 1:2:2 mixing compositions.
7. noctilucence mouse case material according to claim 1, which is characterized in that the antioxidant is N, N- diphenyl
P-phenylenediamine, N, bis- (2,4- diaminodiphenyl ethers) imines of N- and one kind in bis- (the 2,4- diiminos diphenyl ether) imines of N- or
Several combinations.
8. a kind of preparation method of such as claim 1-7 any one of them noctilucence mouse case materials, which is characterized in that including
Following steps：
(1) each raw material is weighed according to the raw material weight number of noctilucence mouse case material；
(2) tossa is put into sodium hydroxide solution, after impregnating 10-15 hours, after being rinsed well repeatedly with clear water, is placed in
Dry ester moisture is less than 1% in 80-90 degrees Celsius of vacuum drying oven, is placed in pulverizer and crushes, crosses 200-500
Mesh sieves, and obtains tossa powder；
(3) diatomite, glass fibre, profound spar powder, luminescent powder, nanometer silicon carbide are respectively put into vacuum drying oven, in 100-
It is dried in the environment of 120 degrees Celsius after being less than 1% to moisture, it is uniform to be put into stirrer for mixing, obtains mixed material 1；
(4) tossa powder and mixed material 1 are added in high-speed mixer, temperature control to after 60-70 degrees Celsius, 3-5 minutes,
Silane coupling agent is added, makrolon, fluorine silicone rubber, polycaprolactone, three fourth of citric acid is added after 5-10 minutes in mixed at high speed
Ester, beta-phenyl methyl acrylate, tea seed cake powder, silicone oil, antiseptic and antioxidant, mixed at high speed obtain mixture after 10-20 minutes
Material 2；
(5) mixed material 2 is put into double screw extruder and carries out extruding pelletization, 180-190 degrees Celsius of extrusion temperature, screw rod turns
Fast 80-100 revs/min, pellet is cooled to room temperature to get the noctilucence mouse case material.
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| CN112210170A (en) * | 2020-10-15 | 2021-01-12 | 上海新帆实业股份有限公司 | Fragrant plastic seal and preparation method thereof |
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| CN106977897A (en) * | 2017-05-23 | 2017-07-25 | 东至县科创塑料制品有限公司 | A kind of high performance engineering plastics |
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| CN104262937A (en) * | 2014-09-18 | 2015-01-07 | 东莞市雄林新材料科技股份有限公司 | High-transparency TPU (thermoplastic polyurethane) film used as keyboard film and preparation method thereof |
| CN106977897A (en) * | 2017-05-23 | 2017-07-25 | 东至县科创塑料制品有限公司 | A kind of high performance engineering plastics |
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