CN108546381A - A kind of aviation cable jacket material and preparation method thereof - Google Patents

A kind of aviation cable jacket material and preparation method thereof Download PDF

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Publication number
CN108546381A
CN108546381A CN201810517438.5A CN201810517438A CN108546381A CN 108546381 A CN108546381 A CN 108546381A CN 201810517438 A CN201810517438 A CN 201810517438A CN 108546381 A CN108546381 A CN 108546381A
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parts
cable jacket
powder
jacket material
aviation
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夏森
陈大龙
黄耀
操瑞
谢荣婷
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Anhui Nicola Electronic Technology Co Ltd
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Anhui Nicola Electronic Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H01B3/445Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18Homopolymers or copolymers of tetrafluoroethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of aviation cable jacket material and preparation method thereof, and the aviation cable jacket material includes following raw material:Polytetrafluoroethylene (PTFE), Kynoar, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine, liquid silica gel, diisononyl phthalate, terephthalate, stearic acid;Preparation method includes the following steps:S1, prepare raw material;S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine disperse in liquid silica gel;S3, mixing;S4, it extrusion, is molded, is drying to obtain.Cable jacket material proposed by the present invention, formula is reasonable, and preparation process raw material easily disperses, cable jacket material obtained has excellent mechanical property, flame retardant property and anti-aging property, fire retardant additive amount is few, and service life grows favorable reproducibility between close batch, is suitable for industrialized production.

Description

A kind of aviation cable jacket material and preparation method thereof
Technical field
The present invention relates to cable jacket field of material technology more particularly to a kind of aviation cable jacket material and its preparations Method.
Background technology
Cable is the general designation of optical cable, cable and other items, and there are many uses of the cable, is mainly used for control installation, connection is set It is standby, the multiple actions such as transmit electric power, be a common and indispensable thing in daily life.In order to improve the use of cable Service life and security performance, it will usually which external in cable is arranged protective case, cable jacket material used in different field and field Requirement be also not quite similar, and cable for aerospace sheath material is due to the use of the special of field, therefore to cable jacket material The requirement of material is also higher than traditional cable jacket material, for example is wanted in the requirement of high temperature resistant, rub resistance and weight etc. Far above traditional cable jacket material.The elasticity of mesh but current aviation cable jacket is relatively low, and tension and anti-extrusion ability are simultaneously It is undesirable, and a large amount of fire retardant would generally be added in order to improve flame retardant effect, therefore seriously affected aviation and protected with cable The tensile property of cover material.Based on the deficiencies in the prior art, the present invention propose a kind of aviation cable jacket material and Preparation method.
Invention content
The purpose of the present invention is to solve the elastic low of existing cable jacket material, tension and anti-extrusion energy force difference, resistance The big deficiency of combustion agent dosage, and a kind of aviation cable jacket material and preparation method thereof proposed.
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of aviation cable jacket material, includes the raw material of following parts by weight:80~100 parts of polytetrafluoroethylene (PTFE) gathers partially 20~40 parts of vinyl fluoride, 1~5 part of sericite in powder, 2~6 parts of clay powder, 1~3 part of zinc oxide, 0.5~1.5 part of antimony oxide, 1~3 part of melamine, 3~8 parts of liquid silica gel, 0.2~0.6 part of diisononyl phthalate, terephthalate 0.1~ 0.3 part, 0.5~1.5 part of stearic acid.
Preferably, the mass ratio of the clay powder and zinc oxide is 2:1.
Preferably, the mass ratio of the antimony oxide and melamine is 1:2.
Preferably, the aviation cable jacket material includes the raw material of following parts by weight:85~95 parts of polytetrafluoroethylene (PTFE), 25~35 parts of Kynoar, 2~4 parts of sericite in powder, 3~5 parts of clay powder, 1~3 part of zinc oxide, antimony oxide 0.8~ 1.2 parts, 1.6~2.4 parts of melamine, 4~8 parts of liquid silica gel, 0.2~0.6 part of diisononyl phthalate, terephthaldehyde 0.1~0.3 part of acid esters, 0.8~1.2 part of stearic acid.
Preferably, the aviation cable jacket material includes the raw material of following parts by weight:90 parts of polytetrafluoroethylene (PTFE) gathers partially 30 parts of vinyl fluoride, 3 parts of sericite in powder, 4 parts of clay powder, 2 parts of zinc oxide, 1 part of antimony oxide, 2 parts of melamine, liquid silica gel 6,0.4 part of diisononyl phthalate, 0.2 part of terephthalate, 1 part of stearic acid.
The invention also provides a kind of aviation preparation methods of cable jacket material, include the following steps:
S1, according to 80~100 parts of polytetrafluoroethylene (PTFE), 20~40 parts of Kynoar, 1~5 part of sericite in powder, clay powder 2 ~6 parts, 1~3 part of zinc oxide, 0.5~1.5 part of antimony oxide, 1~3 part of melamine, 3~8 parts of liquid silica gel, adjacent benzene two 0.2~0.6 part of formic acid dinonyl, 0.1~0.3 part of terephthalate, 0.5~1.5 part of stearic acid weigh each raw material, standby With;
S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine are added in liquid silica gel and grind 5 ~10min, re-ultrasonic dispersion is uniform to obtain mixture A;
S3, it polytetrafluoroethylene (PTFE) and Kynoar is added in kneader is kneaded, then step S2 prepared mixed Conjunction object A and step S1 weighs diisononyl phthalate, terephthalate and stearic acid agent and is added sequentially to kneader In, continue to be kneaded to uniformly to get mixture B;
S4, mixture B made from step S3 is added in screw extruder, it is extruded, be molded, be drying to obtain aviation With cable jacket material.
Cable jacket material provided by the invention, compared with prior art advantage be:Cable jacket proposed by the present invention Material, formula is reasonable, and preparation process raw material easily disperses, and cable jacket material obtained has excellent mechanical property, anti-flammability Energy and anti-aging property, fire retardant additive amount is few, and service life grows favorable reproducibility between close batch, is suitable for industrialized production; Using polytetrafluoroethylene (PTFE) and Kynoar as major ingredient, assign cable jacket material excellent corrosion resistance, by adding sericite Powder and a certain proportion of clay powder and zinc oxide to ensure that cable jacket material has excellent wearability performance, and are matched Close antimony oxide, melamine and the liquid silica gel of rational proportion, diisononyl phthalate, terephthalate and Stearic acid significantly improves the tensile strength and elongation at break of cable jacket material, and tests prove that line prepared by the present invention The anti-aging property and flame retardant property of cable sheath material are apparently higher than commercial goods, and the invention also provides a kind of operation letters The method of the preparation aviation cable jacket material single, stock dispersion effect is good, will first be not easy sericite in powder, the clay of mixing Powder, zinc oxide, antimony oxide, melamine are heated to be ground in liquid silica gel, with improve its in polytetrafluoroethylene (PTFE) and Mixing in Kynoar is prepared for later stage production performance uniformity, stability height.
Specific implementation mode
The present invention is made further to explain with reference to specific embodiment.
Embodiment 1
A kind of aviation cable jacket material proposed by the present invention, includes the raw material of following parts by weight:Polytetrafluoroethylene (PTFE) 80 Part, 20 parts of Kynoar, 1 part of sericite in powder, 2 parts of clay powder, 1 part of zinc oxide, 0.5 part of antimony oxide, melamine 1 Part, 3 parts of liquid silica gel, 0.2 part of diisononyl phthalate, 0.1 part of terephthalate, 0.5 part of stearic acid;
Preparation method includes the following steps:
S1, according to 80 parts of polytetrafluoroethylene (PTFE), 20 parts of Kynoar, 1 part of sericite in powder, 2 parts of clay powder, 1 part of zinc oxide, 0.5 part of antimony oxide, 1 part of melamine, 3 parts of liquid silica gel, 0.2 part of diisononyl phthalate, terephthalate 0.1 part, 0.5 part of stearic acid weigh each raw material, it is spare;
S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine are added in liquid silica gel and are ground 5min, re-ultrasonic dispersion is uniform to obtain mixture A;
S3, it polytetrafluoroethylene (PTFE) and Kynoar is added in kneader is kneaded, then step S2 prepared mixed Conjunction object A and step S1 weighs diisononyl phthalate, terephthalate and stearic acid agent and is added sequentially to kneader In, continue to be kneaded to uniformly to get mixture B;
S4, mixture B made from step S3 is added in screw extruder, it is extruded, be molded, be drying to obtain aviation With cable jacket material.
Embodiment 2
A kind of aviation cable jacket material proposed by the present invention, includes the raw material of following parts by weight:Polytetrafluoroethylene (PTFE) 90 Part, 30 parts of Kynoar, 3 parts of sericite in powder, 4 parts of clay powder, 2 parts of zinc oxide, 1 part of antimony oxide, 2 parts of melamine, Liquid silica gel 6,0.4 part of diisononyl phthalate, 0.2 part of terephthalate, 1 part of stearic acid;
Preparation method includes the following steps:
S1, according to 90 parts of polytetrafluoroethylene (PTFE), 30 parts of Kynoar, 3 parts of sericite in powder, 4 parts of clay powder, 2 parts of zinc oxide, 1 part of antimony oxide, 2 parts of melamine, liquid silica gel 6,0.4 part of diisononyl phthalate, terephthalate 0.2 Part, 1 part of stearic acid weigh each raw material, spare;
S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine are added in liquid silica gel and are ground 8min, re-ultrasonic dispersion is uniform to obtain mixture A;
S3, it polytetrafluoroethylene (PTFE) and Kynoar is added in kneader is kneaded, then step S2 prepared mixed Conjunction object A and step S1 weighs diisononyl phthalate, terephthalate and stearic acid agent and is added sequentially to kneader In, continue to be kneaded to uniformly to get mixture B;
S4, mixture B made from step S3 is added in screw extruder, it is extruded, be molded, be drying to obtain aviation With cable jacket material.
Embodiment 3
Embodiment 1
A kind of aviation cable jacket material proposed by the present invention, includes the raw material of following parts by weight:Polytetrafluoroethylene (PTFE) 100 Part, 40 parts of Kynoar, 5 parts of sericite in powder, 6 parts of clay powder, 3 parts of zinc oxide, 1.5 parts of antimony oxide, melamine 3 Part, 8 parts of liquid silica gel, 0.6 part of diisononyl phthalate, 0.3 part of terephthalate, 1.5 parts of stearic acid;
Preparation method includes the following steps:
S1, according to 100 parts of polytetrafluoroethylene (PTFE), 40 parts of Kynoar, 5 parts of sericite in powder, 6 parts of clay powder, zinc oxide 3 Part, 1.5 parts of antimony oxide, 3 parts of melamine, 8 parts of liquid silica gel, 0.6 part of diisononyl phthalate, terephthalic acid (TPA) 0.3 part of ester, 1.5 parts of stearic acid weigh each raw material, spare;
S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine are added in liquid silica gel and are ground 10min, re-ultrasonic dispersion is uniform to obtain mixture A;
S3, it polytetrafluoroethylene (PTFE) and Kynoar is added in kneader is kneaded, then step S2 prepared mixed Conjunction object A and step S1 weighs diisononyl phthalate, terephthalate and stearic acid agent and is added sequentially to kneader In, continue to be kneaded to uniformly to get mixture B;
S4, mixture B made from step S3 is added in screw extruder, it is extruded, be molded, be drying to obtain aviation With cable jacket material.
The cable jacket material and commercially available cable jacket material prepared to Examples 1 to 3 is tested for the property respectively, is tied Fruit is as follows:
1, performance test before aging, it is as a result as follows:
Test event Embodiment 1 Embodiment 2 Embodiment 3 It is commercially available
Tensile strength MPa 35 44 38 26
Elongation at break % 451 482 474 247
Flame retardant rating V-0 V-0 V-0 V-2
2, thermal aging test, 313 ± 3 DEG C of test temperature, ageing time 120h, test result is as follows:
Test event Embodiment 1 Embodiment 2 Embodiment 3 It is commercially available
Variation in tensile strength % 3.6 4.1 3.2 10.4
Elongation at break change rate % 3.2 4.2 2.0 11.6
Above-mentioned test result shows that the flame retardant rating of cable jacket material prepared by Examples 1 to 3 is UL-94V0 grades, in fact A Zhang Qiangdu Gao Jun are applied in 30MPa or more, elongation at break greatly 450 or more, and change rate exists after thermal aging test 5% hereinafter, and under same test condition, the tensile strength of commercially available cable jacket material is 26MPa, elongation at break only has 457%, show that the flame retardant property, tensile strength, elongation at break of cable jacket material proposed by the present invention are significantly increased, And cable jacket material property prepared by Examples 1 to 3 is close, shows the preparation weight of cable jacket material proposed by the present invention Existing property is good, is suitable for industrialized production.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of aviation cable jacket material, which is characterized in that include the raw material of following parts by weight:Polytetrafluoroethylene (PTFE) 80~ 100 parts, 20~40 parts of Kynoar, 1~5 part of sericite in powder, 2~6 parts of clay powder, 1~3 part of zinc oxide, antimony oxide 0.5~1.5 part, 1~3 part of melamine, 3~8 parts of liquid silica gel, 0.2~0.6 part of diisononyl phthalate, to benzene two 0.1~0.3 part of formic acid esters, 0.5~1.5 part of stearic acid.
2. a kind of aviation cable jacket material according to claim 1, which is characterized in that the clay powder and zinc oxide Mass ratio be 2:1.
3. a kind of aviation cable jacket material according to claim 1, which is characterized in that the antimony oxide and three The mass ratio of poly cyanamid is 1:2.
4. a kind of aviation cable jacket material according to claim 1, which is characterized in that the aviation cable jacket Material includes the raw material of following parts by weight:85~95 parts of polytetrafluoroethylene (PTFE), 25~35 parts of Kynoar, sericite in powder 2~4 Part, 3~5 parts of clay powder, 1~3 part of zinc oxide, 0.8~1.2 part of antimony oxide, 1.6~2.4 parts of melamine, liquid silica gel 4~8 parts, 0.2~0.6 part of diisononyl phthalate, 0.1~0.3 part of terephthalate, 0.8~1.2 part of stearic acid.
5. a kind of aviation cable jacket material according to claim 1 or 2 or 3, which is characterized in that the aviation line Cable sheath material includes the raw material of following parts by weight:90 parts of polytetrafluoroethylene (PTFE), 30 parts of Kynoar, 3 parts of sericite in powder, clay 4 parts of powder, 2 parts of zinc oxide, 1 part of antimony oxide, 2 parts of melamine, liquid silica gel 6,0.4 part of diisononyl phthalate, 0.2 part of terephthalate, 1 part of stearic acid.
6. a kind of aviation preparation method of cable jacket material, which is characterized in that include the following steps:
S1, according to 80~100 parts of polytetrafluoroethylene (PTFE), 20~40 parts of Kynoar, 1~5 part of sericite in powder, clay powder 2~6 Part, 1~3 part of zinc oxide, 0.5~1.5 part of antimony oxide, 1~3 part of melamine, 3~8 parts of liquid silica gel, phthalic acid 0.2~0.6 part of dinonyl, 0.1~0.3 part of terephthalate, 0.5~1.5 part of stearic acid weigh each raw material, spare;
S2, sericite in powder, clay powder, zinc oxide, antimony oxide, melamine are added in liquid silica gel grinding 5~ 10min, re-ultrasonic dispersion is uniform to obtain mixture A;
S3, polytetrafluoroethylene (PTFE) and Kynoar are added in kneader to the mixture A being kneaded, then step S2 is prepared And step S1 weighs diisononyl phthalate, terephthalate and stearic acid agent and is added sequentially in kneader, after It is continuous to be kneaded to uniformly to get mixture B;
S4, mixture B made from step S3 is added in screw extruder, it is extruded, be molded, be drying to obtain aviation line Cable sheath material.
CN201810517438.5A 2018-05-25 2018-05-25 A kind of aviation cable jacket material and preparation method thereof Pending CN108546381A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007314639A (en) * 2006-05-24 2007-12-06 Daikin Ind Ltd Flame-retardant material, and electric wire jacket and lan cable made thereof
CN105175959A (en) * 2015-07-14 2015-12-23 安徽春辉仪表线缆集团有限公司 Heatproof corrosion-resistant cable material for urban rail transport and preparation method thereof
CN106221090A (en) * 2016-08-30 2016-12-14 李兆源 A kind of pump valve modified plastic material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007314639A (en) * 2006-05-24 2007-12-06 Daikin Ind Ltd Flame-retardant material, and electric wire jacket and lan cable made thereof
CN105175959A (en) * 2015-07-14 2015-12-23 安徽春辉仪表线缆集团有限公司 Heatproof corrosion-resistant cable material for urban rail transport and preparation method thereof
CN106221090A (en) * 2016-08-30 2016-12-14 李兆源 A kind of pump valve modified plastic material

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