CN108545849A - A method of phenol wastewater produced by processing needle coke production technology - Google Patents
A method of phenol wastewater produced by processing needle coke production technology Download PDFInfo
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- CN108545849A CN108545849A CN201810441836.3A CN201810441836A CN108545849A CN 108545849 A CN108545849 A CN 108545849A CN 201810441836 A CN201810441836 A CN 201810441836A CN 108545849 A CN108545849 A CN 108545849A
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- Prior art keywords
- phenol
- production technology
- needle coke
- waste water
- coke production
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
- C02F2101/345—Phenols
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The present invention relates to a kind of methods of phenol wastewater produced by processing needle coke production technology.Waste water caused by needle coke production technology mainly contains phenol and nitrogen amide, and concentration is higher, and pH is close to 10.Such waste water nature determines that conventional method is difficult to realize detach except phenol condition is harsher.The present invention innovatively uses the mixed fillers of the macroporous absorbent resin that skeleton is polystyrene and the strong-base anion-exchange resin that skeleton is polystyrene to adsorb the aldehydes matter in waste water.Since the resin of aldehydes matter and polystyrene all has benzene ring structure, specific binding can be formed by π π interactions between the two, in addition, the ion exchange between phenol ion and anion exchange resin so that this mixed fillers can reach removes phenol effect well.Discharge standard is fully achieved in waste water after this flow processing, and present invention process flow is simple, at low cost, effect is good and environmentally protective.
Description
Technical field
The present invention relates to technical field of waste water processing, and specifically, being that a kind of processing needle coke production technology is produced contains phenol
The method of waste water.
Background technology
Needle coke is a kind of good carbon raw materials, and surface is in apparent strip lines, mostly strip needle when being crushed
Fibrous structure, thus referred to as needle coke can be observed in shape fragment under the microscope.Needle coke is production high power graphite electrode
With the raw material of ultra high power graphite electrode, the graphite electrode made of needle coke have thermal shock resistance strong, high mechanical strength,
The advantages that current density that oxidation susceptibility is good, consumption of electrode is low and allows is big.Needle coke with oil refinery's heavy distillate or
Person's coal tar, pitch are raw material, will produce volatile phenol and the amic waste water of nitrogen containing higher concentration, and its pH in production process
It is higher, close to 10.
Phenol wastewater is extremely serious to environmental disruption, and phenolic compound is a kind of strong neurotoxic substance again, has corrosion
Property, it is harmful to biology, therefore the hot spot that people study sewage disposal is had become to the processing of phenol wastewater.Locate both at home and abroad at present
The method of reason phenol wastewater mainly has:Leather follows the example of, biochemical process, liquid-film method and active carbon adsorption, but all there are some defects, than
Such as the problems such as complicated for operation, energy consumption is big, of high cost, and handle the ineffective of this kind of needle coke waste water.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide contain produced by a kind of processing needle coke production technology
The method of phenol waste water.
The purpose of the present invention is achieved through the following technical solutions:
A method of phenol wastewater produced by processing needle coke production technology, the specific steps are:
(1) filtered wastewater removes suspended matter and solid impurity therein;
(2) by the mixed fillers after activation loaded in glass column or stainless steel column;
(1) with constant flow pump control waste water flow through resin column carry out absorption remove phenol;
(3) resin column is impregnated with eluant, eluent, is reused after zeolite regeneration.
As an optimization, in above-mentioned steps (2), using the macroporous absorbent resin and polystyrene skeleton of polystyrene skeleton
The mixed fillers of strong-base anion-exchange resin.
As an optimization, in above-mentioned steps (2), volume ratio shared by macroporous absorbent resin is 70~85%.
As an optimization, in above-mentioned steps (3), it is 4~6 times of column volume/hours that constant flow pump, which controls waste water flow velocity,.
As an optimization, in above-mentioned steps (4), eluant, eluent is absolute ethyl alcohol, and soaking time is 1~3 hour, is impregnated twice.
This method is suitable for processing and contains phenol and nitrogen amide, and concentration is higher, waste water of the pH close to 10.
Compared with prior art, the positive effect of the present invention is:
In the processing scheme for the phenol wastewater that needle coke production technology provided by the present invention generates, used macropore is inhaled
Attached resin and strong-base anion-exchange resin are using styrenic as skeleton.Aldehydes matter and styrene skeleton it
Between π-π interaction and the electrostatic interaction between phenol and anion exchange resin so that mixed fillers are this severe
There is fabulous adsorption effect under conditions of quarter to aldehydes matter office.Mixed fillers regenerating easily can follow bad utilization, and elute
Agent dosage is only 0.5 times of column volume, and the organic contamination of generation is few.Present invention process is simple, economical and efficient, environmentally protective.
Description of the drawings
Fig. 1 is the liquid chromatogram before waste water absorption;
Fig. 2 is the liquid chromatogram after waste water absorption;
Fig. 3 is to adsorb breakthrough curve for the first time;
Fig. 4 is second of absorption breakthrough curve;
Fig. 5 is third time absorption breakthrough curve;
Specific implementation mode
The specific embodiment party of the method for phenol wastewater produced by a kind of processing needle coke production technology of the present invention presented below
Formula.
Embodiment 1
A method of phenol wastewater produced by processing needle coke production technology, the specific steps are:
(1) filtered wastewater removes suspended matter and solid impurity therein;
(2) by the mixed fillers after activation loaded in glass column or stainless steel column;
(1) with constant flow pump control waste water flow through resin column carry out absorption remove phenol;
(3) resin column is impregnated with eluant, eluent, is reused after zeolite regeneration.
It is cloudy using the macroporous absorbent resin of polystyrene skeleton and the strong basicity of polystyrene skeleton in above-mentioned steps (2)
The mixed fillers of ion exchange resin.
In above-mentioned steps (2), volume ratio shared by macroporous absorbent resin is 70~85%.
In above-mentioned steps (3), it is 4~6 times of column volume/hours that constant flow pump, which controls waste water flow velocity,.
In above-mentioned steps (4), eluant, eluent is absolute ethyl alcohol, and soaking time is 1~3 hour, is impregnated twice.
This method is suitable for processing and contains phenol and nitrogen amide, and concentration is higher, waste water of the pH close to 10.
The method of Phenol-Containing Wastewater Treatment of the present invention, specific experiment process are as follows:
Refer to attached drawing 1,2,3,4,5, waste water is extracted with constant flow pump, 5 μm of filter plate is flowed it through, it is miscellaneous to be filtered to remove solid
Matter.By the mixed fillers after activation, (macroporous absorbent resin selects HZ-16 type resins, strong-base anion-exchange resin to select
D201 type resins;It is 20%) to fill column in diameter that wherein volume shared by HZ-16 types resin, which is volume shared by 80%, D201 type resins,
15mm, in the glass column of height 360mm.It is adsorbed by resin column with the flow velocity of 5mL/min with constant flow pump control waste water, often
Adsorption liquid is collected every 10min, the content of phenol in adsorption liquid is measured by high performance liquid chromatography.
Etc. resin adsorptions saturation after, i.e. when the phenol changes of contents of liquid chromatogram measuring is little stop absorption, made with constant flow pump
Absolute ethyl alcohol is pumped into glass column, until glass column bottom stops when having liquid outflow, closes valve, absolute ethyl alcohol is made to be impregnated in column
Then 1h is blown out whole liquid with air pump.This step 1 time is repeated, resin regeneration is completed.The eluting agent that the process uses
30mL (0.5 times of column volume) is only needed, organic contamination that is simple for process, generating is small, environmentally protective.
It repeats the above adsorption and desorption step twice, draws breakthrough curve.Breakthrough curve is according in different time adsorption liquid
The concentration of object is drawn.Can visually see the adsorption capacity and adsorption effect of mixed fillers from breakthrough curve.
This experiment carries out identification and with high performance liquid chromatography to phenol using gas chromatography combined with mass spectrometry to waste component
Content carries out quantitative calculating.
Gas chromatography combined with mass spectrometry is the results show that mainly contain phenol, 2- methylphenols, 2-aminotoluene, 4- in waste water
Methylphenol.
The front and back liquid chromatogram of comparison absorption can be seen that by the way that after mixed fillers column, Phenol for Waste Water substance is almost
It is adsorbed completely.
The present invention is fine to the adsorption effect of Phenol for Waste Water it can be seen from three breakthrough curve figures, and adsorption capacity is big, and
And there is no weaken for the effect after resin zeolite regeneration.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make several improvements and modifications, these improvements and modifications also should be regarded as
In protection scope of the present invention.
Claims (6)
1. a kind of method of phenol wastewater produced by processing needle coke production technology, which is characterized in that use polystyrene skeleton
Macroporous absorbent resin and polystyrene skeleton strong-base anion-exchange resin mixed fillers absorption remove phenol.
2. the method for phenol wastewater, feature produced by a kind of processing needle coke production technology according to claim 1 exist
In, the specific steps are:
(1) filtered wastewater removes suspended matter and solid impurity therein;
(2) by the mixed fillers after activation loaded in glass column or stainless steel column;
Mixed fillers are the strong-base anion-exchange resin of the macroporous absorbent resin and polystyrene skeleton of polystyrene skeleton;
(3) with constant flow pump control waste water flow through resin column carry out absorption remove phenol;
(4) resin column is impregnated with eluant, eluent, is reused after zeolite regeneration.
3. the method for phenol wastewater, feature produced by a kind of processing needle coke production technology according to claim 2 exist
In volume ratio shared by macroporous absorbent resin is 70~85%.
4. the method for phenol wastewater, feature produced by a kind of processing needle coke production technology according to claim 2 exist
In in above-mentioned steps (3), it is 4~6 times of column volume/hours that constant flow pump, which controls waste water flow velocity,.
5. the method for phenol wastewater, feature produced by a kind of processing needle coke production technology according to claim 2 exist
In in above-mentioned steps (4), eluant, eluent is absolute ethyl alcohol, and soaking time is 1~3 hour, is impregnated twice.
6. the method for phenol wastewater, feature produced by a kind of processing needle coke production technology according to claim 1 exist
It is suitable for processing in, this method and contains phenol and nitrogen amide, concentration is higher, waste water of the pH close to 10.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100263689A1 (en) * | 2009-04-21 | 2010-10-21 | Ecolab Usa Inc. | Methods and apparatus for controlling water hardness |
CN104024168A (en) * | 2011-11-30 | 2014-09-03 | 罗门哈斯公司 | Coking wastewater treatment |
CN106732447A (en) * | 2016-12-03 | 2017-05-31 | 华莉君 | A kind of macroporous absorbent resin for containing phenol industrial wastewater for processing and preparation method thereof |
-
2018
- 2018-05-10 CN CN201810441836.3A patent/CN108545849A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100263689A1 (en) * | 2009-04-21 | 2010-10-21 | Ecolab Usa Inc. | Methods and apparatus for controlling water hardness |
CN104024168A (en) * | 2011-11-30 | 2014-09-03 | 罗门哈斯公司 | Coking wastewater treatment |
CN106732447A (en) * | 2016-12-03 | 2017-05-31 | 华莉君 | A kind of macroporous absorbent resin for containing phenol industrial wastewater for processing and preparation method thereof |
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Application publication date: 20180918 |