CN108531127A - A kind of high-strength adhesive material and preparation method thereof for the connection of armour gap - Google Patents
A kind of high-strength adhesive material and preparation method thereof for the connection of armour gap Download PDFInfo
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- CN108531127A CN108531127A CN201810158308.7A CN201810158308A CN108531127A CN 108531127 A CN108531127 A CN 108531127A CN 201810158308 A CN201810158308 A CN 201810158308A CN 108531127 A CN108531127 A CN 108531127A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to shellproof technical fields, and in particular to a kind of high-strength adhesive material and preparation method thereof for the connection of armour gap, the quality proportioning of the high-strength adhesive material is as follows：20 30 parts of methyl vinyl silicone, 58 parts of aluminium powder, 20 24 parts of alumina silicate, 10 14 parts of silane coupling agent, 35 parts of dimethyl carbonate, 36 parts of polyvinylpyrrolidone, 10 15 parts of polystyrene dimethione cross-linked copolymer, 30 40 parts of ethyl acetate, 10 15 parts of ethyl alcohol.The present invention solves the problems, such as that existing pointing is difficult to meet armour requirement, has good adhesive strength, stability is good, and impact resistance is good, disclosure satisfy that requirement.
Description
Technical field
The invention belongs to shellproof technical fields, and in particular to a kind of high-strength adhesive material for the connection of armour gap
And preparation method thereof.
Background technology
Currently, the armour as shellproof main body develops via past hard metal panel, high molecular material panel
To ceramic material panel.Ceramic material panel is using material mainly by aluminium oxide, silicon carbide, boron carbide and other composite ceramics
Material.Armour uses fritter splicing panel.Fritter splicing panel has quadrangle or hexagon, its main feature is that dimension precision requirement
It is high.Armour uses fritter splicing panel at present, and fritter splicing panel has quadrangle or hexagon, its main feature is that dimensional accuracy is wanted
Ask high.For the armour of splicing construction, splicing gap is the protection weakness of armour itself, and the protection that can reach whole is wanted
It asks, and does not find good pointing also at present, the requirement can be reached.
Invention content
For the problems of the prior art, the present invention provides a kind of high-strength adhesive material for the connection of armour gap
Material, solves the problems, such as that existing pointing is difficult to meet armour requirement, has good adhesive strength, stability is good, resistance to
Impact is good, disclosure satisfy that requirement.
To realize the above technical purpose, the technical scheme is that：
A kind of high-strength adhesive material for the connection of armour gap, the quality proportioning of the high-strength adhesive material are as follows：
20-30 parts of methyl vinyl silicone, 5-8 parts of aluminium powder, 20-24 parts of alumina silicate, 10-14 parts of silane coupling agent, dimethyl carbonate
3-5 parts, 3-6 parts of polyvinylpyrrolidone, polystyrene-poly diformazan be copolymer 1 0-15 parts silicone cross-linked, ethyl acetate 30-
40 parts, 10-15 parts of ethyl alcohol.
The preparation method of the high-strength adhesive material is in accordance with the following steps：
Step 1, methyl vinyl silicone is added in ethyl acetate, seals ultrasound 10-14min, obtains lysate；
Step 2, aluminium powder and alumina silicate are added into absolute ethyl alcohol, polyvinylpyrrolidone is then added, ultrasonic 1-2h is obtained
Disperse suspension；
Step 3, mechanical agitation is added into dispersion suspension in silane coupling agent and dimethyl carbonate to be mixed to being uniformly mixed
Close liquid；
Step 4, lysate is slowly added dropwise into mixed liquor, mechanical agitation obtains reaction solution to being thoroughly mixed；
Step 5, microwave reaction 50-120min in reaction kettle is added in reaction solution, reaction 20- is evaporated under reduced pressure after natural cooling
50min obtains concentrate；
Step 6, the silicone cross-linked copolymer of polystyrene-poly diformazan is added and is stirred evenly into concentrate, then second
Microwave reaction 30-60min obtains high-strength adhesive material.
The supersonic frequency of sealing ultrasonic reaction in the step 1 is 10-20kHz, and ultrasonic temperature is 40-50 DEG C, pressure
For 0.2-0.4MPa.
The temperature of ultrasonic reaction in the step 2 is 60-70 DEG C, supersonic frequency 40-80kHz.
Churned mechanically speed in the step 3 is 2000-4000r/min.
The speed that is slowly added dropwise in the step 4 is 10-15mL/min, and the churned mechanically mixing speed is 1500-
2500r/min。
The power of microwave reaction in the step 5 is 300-800W, and temperature is 50-60 DEG C.
The temperature of vacuum distillation reaction in the step 5 is 70-80 DEG C, and pressure is the 60-80% of atmospheric pressure, described dense
The concentration of contracting liquid is the 10-15% of reaction solution volume.
The mixing speed stirred evenly in the step 6 is 3000-5000r/min, second of microwave reaction
Microwave power is 300-600W, and temperature is 80-100 DEG C.
The silicone cross-linked copolymer of polystyrene-poly diformazan can not only be formed good protection by the present invention on surface
Effect forms protection the most preliminary, moreover, itself having certain viscosity, helps to connect, while encountering high fever bullet, gather
Styrene-dimethione cross-linked copolymer can quick liquid formed liquid blocking, and with temperature decline to be formed it is secondary
Protection, achievees the effect that make full use of；Inorganic-the metal system being combined using aluminium powder and alumina silicate, is greatly improved shellproof
Connection condensation effect between plate.
The present invention can not only ensure the silicone cross-linked copolymer of polystyrene-poly diformazan and gold by the way of microwave
Category-ceramic complexes are sufficiently mixed, and can also promote the silicone cross-linked copolymer of polystyrene-poly diformazan and methyl ethylene silicon
The hybrid reaction of resin.
The material is added to armour gap, and methyl vinyl silicone and aluminium powder and alumina silicate are formed after spontaneous curing
It is mixed to form, using resin as the frame-like structures of binder, inside forms a large amount of micropores, and micropore is by polystyrene-poly diformazan
Silicone cross-linked copolymer fills up, and forms the shellproof system with favorable elasticity intensity and firmness.
When by bullet impact, when the impact force of bullet is little, when the shellproof plate surface of bullet impact, polystyrene-poly
The favorable elasticity system that the silicone cross-linked copolymer of diformazan is formed with urgent vinyl polysiloxane can utilize the elasticity of itself will
It stops, while aluminium powder and alumina silicate play the role of anti-wear agent, prevent fretting wear；After bullet impact rises, bullet connects
When touching armour, the heat that the silicone cross-linked copolymer of polystyrene-poly diformazan absorbs cartridge belt forms liquefaction in gap
Microcellular structure is formed, methyl vinyl silicone and aluminium powder, alumina silicate form the micro-elasticity porous structure with high intensity, pass through
The blocking layer by layer of porous structure constantly declines bullet velocity, and after the decline of bullet temperature, polystyrene-poly diformazan siloxanes is handed over
Ally the communists polymers, methyl vinyl silicone rubber forms high-tension barrier structure, and aluminium powder and alumina silicate are as dopant and intensity addition
Agent forms the second blocking system, and blocking capability is promoted once again, and after the silicone cross-linked copolymer liquefaction of polystyrene-poly diformazan
Again cure, bullet cladding is got up, secondary protection system is quickly formed, can ensure the shellproof stability of armour, is promoted
It is shellproof quickly restorative.
From the above, it can be seen that the present invention has following advantages：
1. the present invention solves the problems, such as that existing pointing is difficult to meet armour requirement, there is good adhesive strength, surely
Qualitative good, impact resistance is good, disclosure satisfy that requirement.
2. the high-strength adhesive material of the present invention uses organic mineral complex system, there is good protection effect, not only
Good bond effect can be played, and there is good bullet protection effect, the continuity of armour can be formed.
3. the present invention, can be in quick gunslinging using the silicone cross-linked copolymer of polystyrene-poly diformazan as raw material
Liquefaction is formed in the process, and is solidified again after rapid cooling, is reached covered effect, can be formed secondary protection effect.
Specific implementation mode
The present invention will be described in detail in conjunction with the embodiments, but does not do any restriction to the claim of the present invention.
Embodiment 1
A kind of high-strength adhesive material for the connection of armour gap, the quality proportioning of the high-strength adhesive material are as follows：
20 parts of methyl vinyl silicone, 5 parts of aluminium powder, 20 parts of alumina silicate, 10 parts of silane coupling agent, 3 parts of dimethyl carbonate, polyethylene pyrrole
0 part of the silicone cross-linked copolymer 1 of 3 parts of pyrrolidone, polystyrene-poly diformazan, 30 parts of ethyl acetate, 10 parts of ethyl alcohol.
The preparation method of the high-strength adhesive material is in accordance with the following steps：
Step 1, methyl vinyl silicone is added in ethyl acetate, seals ultrasound 10min, obtains lysate；
Step 2, aluminium powder and alumina silicate are added into absolute ethyl alcohol, polyvinylpyrrolidone is then added, ultrasonic 1h is divided
Dissipate suspension；
Step 3, mechanical agitation is added into dispersion suspension in silane coupling agent and dimethyl carbonate to be mixed to being uniformly mixed
Close liquid；
Step 4, lysate is slowly added dropwise into mixed liquor, mechanical agitation obtains reaction solution to being thoroughly mixed；
Step 5, microwave reaction 50min in reaction kettle is added in reaction solution, reaction 20min is evaporated under reduced pressure after natural cooling, is obtained
Concentrate；
Step 6, the silicone cross-linked copolymer of polystyrene-poly diformazan is added and is stirred evenly into concentrate, then second
Microwave reaction 30min obtains high-strength adhesive material.
The supersonic frequency of sealing ultrasonic reaction in the step 1 is 10kHz, and ultrasonic temperature is 40 DEG C, and pressure is
0.2MPa。
The temperature of ultrasonic reaction in the step 2 is 60 DEG C, supersonic frequency 40kHz.
Churned mechanically speed in the step 3 is 2000r/min.
The speed that is slowly added dropwise in the step 4 is 10mL/min, and the churned mechanically mixing speed is 1500r/
min。
The power of microwave reaction in the step 5 is 300W, and temperature is 50 DEG C.
The temperature of vacuum distillation reaction in the step 5 is 70 DEG C, and pressure is the 60% of atmospheric pressure, the concentrate
Concentration is the 10% of reaction solution volume.
The mixing speed stirred evenly in the step 6 is 3000r/min, the microwave work(of second of microwave reaction
Rate is 300W, and temperature is 80 DEG C.
The armour weight is 1.31kg.Using the side NIJ0101.04 of U.S. monomer testing standard to the armour into
Row ballistic performance is tested, and as a result shows that it can resist 10.8g, speed is that 7.62 millimeters of bore all-metals of 869 meter per seconds coat
Bullet.
Embodiment 2
A kind of high-strength adhesive material for the connection of armour gap, the quality proportioning of the high-strength adhesive material are as follows：
30 parts of methyl vinyl silicone, 8 parts of aluminium powder, 24 parts of alumina silicate, 14 parts of silane coupling agent, 5 parts of dimethyl carbonate, polyethylene pyrrole
5 parts of the silicone cross-linked copolymer 1 of 6 parts of pyrrolidone, polystyrene-poly diformazan, 40 parts of ethyl acetate, 15 parts of ethyl alcohol.
The preparation method of the high-strength adhesive material is in accordance with the following steps：
Step 1, methyl vinyl silicone is added in ethyl acetate, seals ultrasound 14min, obtains lysate；
Step 2, aluminium powder and alumina silicate are added into absolute ethyl alcohol, polyvinylpyrrolidone is then added, ultrasonic 2h is divided
Dissipate suspension；
Step 3, mechanical agitation is added into dispersion suspension in silane coupling agent and dimethyl carbonate to be mixed to being uniformly mixed
Close liquid；
Step 4, lysate is slowly added dropwise into mixed liquor, mechanical agitation obtains reaction solution to being thoroughly mixed；
Step 5, microwave reaction 120min in reaction kettle is added in reaction solution, reaction 50min is evaporated under reduced pressure after natural cooling, is obtained
Concentrate；
Step 6, the silicone cross-linked copolymer of polystyrene-poly diformazan is added and is stirred evenly into concentrate, then second
Microwave reaction 60min obtains high-strength adhesive material.
The supersonic frequency of sealing ultrasonic reaction in the step 1 is 20kHz, and ultrasonic temperature is 50 DEG C, and pressure is
0.4MPa。
The temperature of ultrasonic reaction in the step 2 is 70 DEG C, supersonic frequency 80kHz.
Churned mechanically speed in the step 3 is 4000r/min.
The speed that is slowly added dropwise in the step 4 is 15mL/min, and the churned mechanically mixing speed is 2500r/
min。
The power of microwave reaction in the step 5 is 800W, and temperature is 60 DEG C.
The temperature of vacuum distillation reaction in the step 5 is 80 DEG C, and pressure is the 80% of atmospheric pressure, the concentrate
Concentration is the 15% of reaction solution volume.
The mixing speed stirred evenly in the step 6 is 5000r/min, the microwave work(of second of microwave reaction
Rate is 600W, and temperature is 100 DEG C.
The armour weight is 1.28kg.The armour is carried out using the side NIJ0101.04 of U.S. monomer testing standard
Ballistic performance is tested, and as a result shows that it can resist 10.8g, speed is 7.62 millimeters of bore all-metals cladding of 869 meter per seconds
Bullet.
Embodiment 3
A kind of high-strength adhesive material for the connection of armour gap, the quality proportioning of the high-strength adhesive material are as follows：
25 parts of methyl vinyl silicone, 6 parts of aluminium powder, 22 parts of alumina silicate, 12 parts of silane coupling agent, 4 parts of dimethyl carbonate, polyethylene pyrrole
3 parts of the silicone cross-linked copolymer 1 of 4 parts of pyrrolidone, polystyrene-poly diformazan, 35 parts of ethyl acetate, 13 parts of ethyl alcohol.
The preparation method of the high-strength adhesive material is in accordance with the following steps：
Step 1, methyl vinyl silicone is added in ethyl acetate, seals ultrasound 12min, obtains lysate；
Step 2, aluminium powder and alumina silicate are added into absolute ethyl alcohol, polyvinylpyrrolidone is then added, ultrasonic 2h is divided
Dissipate suspension；
Step 3, mechanical agitation is added into dispersion suspension in silane coupling agent and dimethyl carbonate to be mixed to being uniformly mixed
Close liquid；
Step 4, lysate is slowly added dropwise into mixed liquor, mechanical agitation obtains reaction solution to being thoroughly mixed；
Step 5, microwave reaction 80min in reaction kettle is added in reaction solution, reaction 40min is evaporated under reduced pressure after natural cooling, is obtained
Concentrate；
Step 6, the silicone cross-linked copolymer of polystyrene-poly diformazan is added and is stirred evenly into concentrate, then second
Microwave reaction 50min obtains high-strength adhesive material.
The supersonic frequency of sealing ultrasonic reaction in the step 1 is 15kHz, and ultrasonic temperature is 45 DEG C, and pressure is
0.3MPa。
The temperature of ultrasonic reaction in the step 2 is 65 DEG C, supersonic frequency 60kHz.
Churned mechanically speed in the step 3 is 3000r/min.
The speed that is slowly added dropwise in the step 4 is 13mL/min, and the churned mechanically mixing speed is 2000r/
min。
The power of microwave reaction in the step 5 is 600W, and temperature is 55 DEG C.
The temperature of vacuum distillation reaction in the step 5 is 75 DEG C, and pressure is the 70% of atmospheric pressure, the concentrate
Concentration is the 12% of reaction solution volume.
The mixing speed stirred evenly in the step 6 is 4000r/min, the microwave work(of second of microwave reaction
Rate is 500W, and temperature is 90 DEG C.
The armour weight is 1.32kg.The armour is carried out using the side NIJ0101.04 of U.S. monomer testing standard
Ballistic performance is tested, and as a result shows that it can resist 10.8g, speed is 7.62 millimeters of bore all-metals cladding of 869 meter per seconds
Bullet.
In conclusion the present invention has the following advantages：
1. the present invention solves the problems, such as that existing pointing is difficult to meet armour requirement, there is good adhesive strength, surely
Qualitative good, impact resistance is good, disclosure satisfy that requirement.
2. the high-strength adhesive material of the present invention uses organic mineral complex system, there is good protection effect, not only
Good bond effect can be played, and there is good bullet protection effect, the continuity of armour can be formed.
3. the present invention, can be in quick gunslinging using the silicone cross-linked copolymer of polystyrene-poly diformazan as raw material
Liquefaction is formed in the process, and is solidified again after rapid cooling, is reached covered effect, can be formed secondary protection effect.
It is understood that above with respect to the specific descriptions of the present invention, it is merely to illustrate the present invention and is not limited to this
Technical solution described in inventive embodiments.It will be understood by those of ordinary skill in the art that still can be carried out to the present invention
Modification or equivalent replacement, to reach identical technique effect；As long as meet use needs, all protection scope of the present invention it
It is interior.
Claims (9)
1. a kind of high-strength adhesive material for the connection of armour gap, it is characterised in that：The high-strength adhesive material
Quality proportioning is as follows：20-30 parts of methyl vinyl silicone, 5-8 parts of aluminium powder, 20-24 parts of alumina silicate, silane coupling agent 10-14
Part, 3-5 parts of dimethyl carbonate, 3-6 parts of polyvinylpyrrolidone, the silicone cross-linked copolymer 1 0-15 of polystyrene-poly diformazan
Part, 30-40 parts of ethyl acetate, 10-15 parts of ethyl alcohol.
2. a kind of high-strength adhesive material for the connection of armour gap according to claim 1, it is characterised in that：Institute
State the preparation method of high-strength adhesive material in accordance with the following steps：
Step 1, methyl vinyl silicone is added in ethyl acetate, seals ultrasound 10-14min, obtains lysate；
Step 2, aluminium powder and alumina silicate are added into absolute ethyl alcohol, polyvinylpyrrolidone is then added, ultrasonic 1-2h is obtained
Disperse suspension；
Step 3, mechanical agitation is added into dispersion suspension in silane coupling agent and dimethyl carbonate to be mixed to being uniformly mixed
Close liquid；
Step 4, lysate is slowly added dropwise into mixed liquor, mechanical agitation obtains reaction solution to being thoroughly mixed；
Step 5, microwave reaction 50-120min in reaction kettle is added in reaction solution, reaction 20- is evaporated under reduced pressure after natural cooling
50min obtains concentrate；
Step 6, the silicone cross-linked copolymer of polystyrene-poly diformazan is added and is stirred evenly into concentrate, then second
Microwave reaction 30-60min obtains high-strength adhesive material.
3. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The supersonic frequency for stating the sealing ultrasonic reaction in step 1 is 10-20kHz, and ultrasonic temperature is 40-50 DEG C, pressure 0.2-
0.4MPa。
4. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The temperature for stating the ultrasonic reaction in step 2 is 60-70 DEG C, supersonic frequency 40-80kHz.
5. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
It is 2000-4000r/min to state the churned mechanically speed in step 3.
6. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The speed that is slowly added dropwise stated in step 4 is 10-15mL/min, and the churned mechanically mixing speed is 1500-2500r/min.
7. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The power for stating the microwave reaction in step 5 is 300-800W, and temperature is 50-60 DEG C.
8. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The temperature for stating the vacuum distillation reaction in step 5 is 70-80 DEG C, and pressure is the 60-80% of atmospheric pressure, the concentration of the concentrate
It is the 10-15% of reaction solution volume.
9. a kind of high-strength adhesive material for the connection of armour gap according to claim 2, it is characterised in that：Institute
The mixing speed stirred evenly stated in step 6 is 3000-5000r/min, and the microwave power of second of microwave reaction is
300-600W, temperature are 80-100 DEG C.
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|---|---|---|---|
| CN201810158308.7A CN108531127A (en) | 2018-02-25 | 2018-02-25 | A kind of high-strength adhesive material and preparation method thereof for the connection of armour gap |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810158308.7A CN108531127A (en) | 2018-02-25 | 2018-02-25 | A kind of high-strength adhesive material and preparation method thereof for the connection of armour gap |
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Family
ID=63485765
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| CN102559132A (en) * | 2011-12-26 | 2012-07-11 | 吴江德邦科技化工有限公司 | Ceramic binding agent and production method |
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-
2018
- 2018-02-25 CN CN201810158308.7A patent/CN108531127A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559132A (en) * | 2011-12-26 | 2012-07-11 | 吴江德邦科技化工有限公司 | Ceramic binding agent and production method |
| CN102604312A (en) * | 2012-01-13 | 2012-07-25 | 深圳市盛嘉伦橡塑工业有限公司 | Thermoplastic elastomer sealing strip material and preparation method thereof |
| CN105778515A (en) * | 2014-12-26 | 2016-07-20 | 广东生益科技股份有限公司 | Halogen-free and phosphorus-free silicon resin composition and prepreg, laminated board, copper-clad board and printing circuit board using same |
| CN105086919A (en) * | 2015-08-07 | 2015-11-25 | 东莞市新星有机硅科技有限公司 | Nanometer titanium oxide modified organic silicon bonding agent and preparation method thereof |
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| 朱洪法等: "《催化剂手册》", 31 August 2008, 金盾出版社 * |
| 罗文君等: "《大分子设计与实验》", 30 September 2012, 中国地质大学出版社 * |
| 雨录: ""美国研制新型纳米防弹材料"", 《轻兵器》 * |
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Application publication date: 20180914 |