CN108531058A - A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor - Google Patents

A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor Download PDF

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Publication number
CN108531058A
CN108531058A CN201810345422.0A CN201810345422A CN108531058A CN 108531058 A CN108531058 A CN 108531058A CN 201810345422 A CN201810345422 A CN 201810345422A CN 108531058 A CN108531058 A CN 108531058A
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China
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parts
skidding
aqueous polyurethane
fireproof coating
pack system
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CN201810345422.0A
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Chinese (zh)
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邹奇峰
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Individual
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, and raw material includes following components by weight:80 100 parts of polyaminoester emulsion, 15 25 parts of titanium dioxide, 10 20 parts of diamond dust, 35 parts of hydroxyethyl cellulose, 13 parts of pentaerythrite, 35 parts of melamine, 25 parts of phosphoric acid dihydro amine, 12 parts of dispersant, 0.2 0.5 parts of surfactant, 13 parts of coalescents, 13 parts of thickener, 0.1 0.3 parts of antilubricant, 0.5 0.8 parts of antifoaming agent, 0.2 0.5 parts of levelling agent, 0.2 0.5 parts of antifreezing agent, 30 50 parts of deionized water.The anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor not only has many advantages, such as good low-temperature stability, water resistance, alkali resistance, abrasion resistance, weatherability, polluting proofing property and ageing resistance, and with wear-resisting antiskid, fire resistant flame retardant.

Description

A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor
Technical field
The present invention relates to a kind of coating, and in particular to a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor.
Background technology
Non-skid coating:It prevents from slipping when walking for various public places, the deck of ship, workshop ground, family, garden etc. A kind of anti-skidding building materials.Its advantage is that adhesive force is good, it is coarse and can be effectively anti-skidding.Skid resistance is the essential characteristic of non-skid coating, It is a kind of property possessed by film.Non-skid coating mainly contains the substances such as anti-skidding pellet, film-forming resin, and anti-skidding pellet is In order to improve the additive of paint film non-skid property, paint film skid resistance is assigned, prevents personnel from slipping tumble injury;Film-forming resin has solid The effect of fixed anti-skidding pellet, while ground being protected not to be damaged.The most successful application of non-skid coating is in aircraft carrier and carrier-borne On deck, coating increases the friction coefficient on deck, avoids sliding, and when aircraft carrier navigates by water, coating can prevent aircraft and vehicle from existing It is slided on deck, just because of these special purposes, the development of non-skid coating is made to advance by leaps and bounds.Non-skid coating has skid resistance Can, this is a kind of specific function possessed by film, is determined according to requirements.As the deck of ships and aircraft carrier, Coating is required with enough non-skid properties used in the nearly drainage facility such as platform, pontoon bridge of offshore, in order to walk And job safety;The for another example iron aerial structure such as high-voltage power transmission tower, Wave Iron Tower, worker usually need to maintain and examine up and down It repaiies, if coating used is then easy to make one to slip without certain non-skid property, with danger;Furthermore industrial floor(Such as The wetland face in food workshop, slaughterhouse etc.), stadium, sports equipments ground, library, the hospital such as land arena etc. build The ground built, it is also desirable to it is appropriate anti-skidding, with falling-resistant.
Fireproof coating is exactly by that on the surface of those combustible materials, can improve the refractory ability of material, subtract paint brush Slow propagation of flame spread speed, or can prevent to burn within a certain period of time, this kind of coating is known as fireproof coating, or is called fire-retardant Coating.Fireproof coating is to be used for flammable substrates surface, can reduce by the combustibility of painting material surface, block the rapid climing of fire Prolong, to improve by a kind of sapecial coating of painting material fire endurance.It is applied to flammable substrates surface, to change material table Face combustion characteristics, retardance fire are spread rapidly;Or be applied on building element, the extraordinary of fire endurance to improve component applies Material claims fireproof coating.
Non-skid coating and fireproof coating type are various, are widely used in many fields.It is big in existing coating Part is all that the coating of single effect is relatively more, there are no it is a it is qualified, security performance is high, existing non-skid property also has and prevents The sale of the coating of the multifunctional usage of fiery performance.
Invention content
The purpose of the present invention provides a kind of anti-skidding fire prevention in aqueous polyurethane one pack system floor and applies aiming at existing issue Material, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor is using the polyaminoester emulsion of one pack system as film forming matter, addition Titanium dioxide, diamond dust, hydroxyethyl cellulose, pentaerythrite, melamine, di(2-ethylhexyl)phosphate with non-skid property and fire protecting performance Simultaneously part of auxiliary is added in hydrogen amine, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor being prepared.The one kind is aqueous The anti-skidding fireproof coating in polyurethane monocomponent floor not only have good low-temperature stability, water resistance, alkali resistance, abrasion resistance, Weatherability, polluting proofing property and ageing resistance, and have many advantages, such as wear-resisting antiskid, fire resistant flame retardant.
In order to solve the above technical problems, the technical solution used in the present invention is:
A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, raw material include following components by weight:Polyurethane breast 80-100 parts of liquid, 15-25 parts of titanium dioxide, 10-20 parts of diamond dust, 3-5 parts of hydroxyethyl cellulose, 1-3 parts of pentaerythrite, trimerization 3-5 parts of cyanamide, 2-5 parts of phosphoric acid dihydro amine, 1-2 parts of dispersant, 0.2-0.5 parts of surfactant, 1-3 parts of coalescents, thickening 1-3 parts of agent, 0.1-0.3 parts of antilubricant, 0.5-0.8 parts of antifoaming agent, 0.2-0.5 parts of levelling agent, 0.2-0.5 parts of antifreezing agent, go from Sub- water 30-50 parts.
Further, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
Further, the dispersant is hydrophobically modified dispersant.
Further, the coalescents are propylene glycol.
Further, the antifoaming agent is modified polyether ester.
Further, the antifreezing agent is ethylene glycol.
A kind of preparation method of the anti-skidding fireproof coating in aqueous polyurethane one pack system floor of the present invention can pass through following step It is rapid to prepare gained:--- --- --- --- -- --- -- discharging ----is spare for neutralization for-batch mixing for-dispensing for-grinding for weighing.
It is compared with the prior art, the invention has the advantages that:
1, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor of the invention uses polyaminoester emulsion for film forming binder, It is added to diamond dust and antilubricant with non-skid property to cooperate, reaches good skid-resistant performance so that practical application Floor has the function and effect of wear-resisting antiskid;
2, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor of the invention uses polyaminoester emulsion for film forming binder, Be added to pentaerythrite with fire protecting performance, melamine, phosphoric acid dihydro amine and cooperate with main fire retardant, improve flame retardant property and The anti-oxidant index of coating and oxidation-resistance property delay the transmission speed of heat, reduce the discharge of smog in air;
3, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor of the invention uses polyaminoester emulsion for film forming binder, It is added to titanium dioxide, diamond dust, hydroxyethyl cellulose, pentaerythrite, melamine, phosphorus with non-skid property and fire protecting performance Simultaneously part of auxiliary is added in acid dihydride amine, the anti-skidding fireproof coating in a kind of aqueous polyurethane one pack system floor being prepared.The one kind The anti-skidding fireproof coating in aqueous polyurethane one pack system floor not only has good low-temperature stability, water resistance, alkali resistance, washability Property, weatherability, polluting proofing property and ageing resistance, and have many advantages, such as wear-resisting antiskid, fire resistant flame retardant.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, this is opposed below in conjunction with specific implementation mode Invention is described in further detail.
Embodiment 1
A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, raw material include following components by weight:Polyurethane breast 80 parts of liquid, 15 parts of titanium dioxide, 10 parts of diamond dust, 3 parts of hydroxyethyl cellulose, 1 part of pentaerythrite, 3 parts of melamine, biphosphate 2 parts of amine, 1 part of dispersant, 0.2 part of surfactant, 1 part of coalescents, 1 part of thickener, 0.1 part of antilubricant, antifoaming agent 0.5 Part, 0.2 part of levelling agent, 0.2 part of antifreezing agent, 30 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 100 μm.
The dispersant is hydrophobically modified dispersant.
The coalescents are propylene glycol.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
Embodiment 2
A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, raw material include following components by weight:Polyurethane breast 100 parts of liquid, 25 parts of titanium dioxide, 20 parts of diamond dust, 5 parts of hydroxyethyl cellulose, 3 parts of pentaerythrite, 5 parts of melamine, di(2-ethylhexyl)phosphate 5 parts of hydrogen amine, 2 parts of dispersant, 0.5 part of surfactant, 3 parts of coalescents, 3 parts of thickener, 0.3 part of antilubricant, antifoaming agent 0.8 Part, 0.5 part of levelling agent, 0.5 part of antifreezing agent, 50 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 150 μm.
The dispersant is hydrophobically modified dispersant.
The coalescents are propylene glycol.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
Embodiment 3
A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, raw material include following components by weight:Polyurethane breast 90 parts of liquid, 20 parts of titanium dioxide, 15 parts of diamond dust, 4 parts of hydroxyethyl cellulose, 2 parts of pentaerythrite, 4 parts of melamine, biphosphate 3 parts of amine, 1.5 parts of dispersant, 0.4 part of surfactant, 2 parts of coalescents, 2 parts of thickener, 0.2 part of antilubricant, antifoaming agent 0.6 Part, 0.4 part of levelling agent, 0.3 part of antifreezing agent, 40 parts of deionized water.
The titanium dioxide is rutile type titanium white, and grain size is 120 μm.
The dispersant is hydrophobically modified dispersant.
The coalescents are propylene glycol.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (6)

1. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor, which is characterized in that its raw material includes following by weight Component:80-100 parts of polyaminoester emulsion, 15-25 parts of titanium dioxide, 10-20 parts of diamond dust, 3-5 parts of hydroxyethyl cellulose, Ji Wusi 1-3 parts of alcohol, 3-5 parts of melamine, 2-5 parts of phosphoric acid dihydro amine, 1-2 parts of dispersant, 0.2-0.5 parts of surfactant, film forming help 1-3 parts of agent, 1-3 parts of thickener, 0.1-0.3 parts of antilubricant, 0.5-0.8 parts of antifoaming agent, 0.2-0.5 parts of levelling agent, antifreezing agent 0.2-0.5 parts, 30-50 parts of deionized water.
2. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor according to claim 1, which is characterized in that described Titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
3. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor according to claim 1, which is characterized in that described Dispersant is hydrophobically modified dispersant.
4. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor according to claim 1, which is characterized in that described Coalescents be propylene glycol.
5. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor according to claim 1, which is characterized in that described Antifoaming agent be modified polyether ester.
6. a kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor according to claim 1, which is characterized in that described Antifreezing agent be ethylene glycol.
CN201810345422.0A 2018-04-17 2018-04-17 A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor Pending CN108531058A (en)

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Application Number Priority Date Filing Date Title
CN201810345422.0A CN108531058A (en) 2018-04-17 2018-04-17 A kind of anti-skidding fireproof coating in aqueous polyurethane one pack system floor

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108997895A (en) * 2018-09-17 2018-12-14 深圳市心版图科技有限公司 A kind of non-skid coating for athletic sports appliance
CN109354860A (en) * 2018-10-22 2019-02-19 安徽理工大学 A kind of composite non-slip material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108997895A (en) * 2018-09-17 2018-12-14 深圳市心版图科技有限公司 A kind of non-skid coating for athletic sports appliance
CN108997895B (en) * 2018-09-17 2020-10-23 深圳市欧耐新材股份有限公司 Anti-skid coating for sports equipment
CN109354860A (en) * 2018-10-22 2019-02-19 安徽理工大学 A kind of composite non-slip material and preparation method thereof
CN109354860B (en) * 2018-10-22 2021-12-21 安徽理工大学 Composite anti-skid material and preparation method thereof

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