CN108529988A - Shield duct piece water-tight concrete and preparation method thereof - Google Patents
Shield duct piece water-tight concrete and preparation method thereof Download PDFInfo
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- CN108529988A CN108529988A CN201810582782.2A CN201810582782A CN108529988A CN 108529988 A CN108529988 A CN 108529988A CN 201810582782 A CN201810582782 A CN 201810582782A CN 108529988 A CN108529988 A CN 108529988A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/56—Compositions suited for fabrication of pipes, e.g. by centrifugal casting, or for coating concrete pipes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Lining And Supports For Tunnels (AREA)
Abstract
The present invention relates to a kind of shield duct piece water-tight concretes and preparation method thereof, belong to high performance concrete field, it is intended to research and develop a kind of concrete with good anti-permeability performance.This kind of shield duct piece water-tight concrete, is counted in parts by weight, and raw material includes:400 420 parts of Portland cement, 100 120 parts of mineral admixture, 540 580 parts of sand, 770 790 parts of 5 25mm rubbles, 3 4.8 parts of additive, 110 120 parts of carbon fiber, 8 9.2 parts of water-reducing agent, 140 150 parts of water.High using the intensity of shield duct piece made of this kind of concrete, impermeability is strong, ensure that the water resistance and load-carrying properties in tunnel.
Description
Technical field
The present invention relates to high performance concrete fields, more specifically, it is related to a kind of shield duct piece water-tight concrete
And preparation method thereof.
Background technology
Shield duct piece is the main mounting structure of shield-tunneling construction, is the innermost layer barrier in tunnel, carries and resists soil layer pressure
The effect of power, groundwater pressure and some special loads.The high-strength water-tight concrete of production generally use of shield duct piece, with true
Reliable load and water resistance are protected, production is mainly i.e. plastic after sealing placing concrete using finished product segment die.
Shield duct piece is the permanent lining, secondary lining structure of shield tunnel, during using shield duct piece, shield duct piece matter
Amount is directly related to the total quality and safety in tunnel, influences the water resistance and load-carrying properties in tunnel.Therefore, a kind of tool is researched and developed
The concrete of good anti-permeability performance is very necessary.
Invention content
The purpose of the present invention is to provide a kind of shield duct piece water-tight concretes, utilize shield made of this kind of concrete
The intensity of section of jurisdiction is high, and impermeability is strong, ensure that the water resistance in tunnel.
The present invention above-mentioned purpose technical scheme is that:A kind of impervious coagulation of shield duct piece
Soil, characterized in that count in parts by weight, raw material includes:400-420 parts of Portland cement, mineral admixture 100-120
Part, 540-580 parts of sand, 770-790 parts of 5-25mm rubbles, 3-4.8 parts of additive, 110-120 parts of carbon fiber, water-reducing agent 8-9.2
Part, 140-150 parts of water.
Preferably, the additive includes the chloro- 2- trifluoromethylated benzaldehydes of 4- and 4- fluoro- 2- (trifluoromethyl) phenylacetic acid.
Preferably, the mass ratio of the chloro- 2- trifluoromethylated benzaldehydes of the 4- and 4- fluoro- 2- (trifluoromethyl) phenylacetic acid is 5:
1。
Preferably, the fiber number of the carbon fiber is 12-14g/9000m, and the length of the carbon fiber is 13-17mm.
Preferably, the water-reducing agent is polycarboxylate water-reducer.
Preferably, the fineness modulus of the sand is 2.5, apparent density 2690kg/m3, loose bulk density is
1640kg/m3, voidage 39%, clay content 0.6%, clod content is 0.1%, and 14 days alkali expansion rates are
0.08%.
Preferably, mineral admixture be silicon ash, flyash mixture, the mass ratio of the silicon ash and flyash is 1:1.
Preferably, the apparent density of the 5-25mm rubbles is 2800kg/m3, loose bulk density 1540kg/m3, pine
It is 45% to dissipate accumulation voidage, crush values 7%, clay content 0.5%, and flat-elongated particles content is 4%, sulfide and sulfuric acid
Salt content is 0.18%, and 14 days alkali expansion rates are 0.08%.
Another object of the present invention is to provide the preparation methods of shield duct piece water-tight concrete described above.
The present invention above-mentioned purpose technical scheme is that, a kind of shield duct piece water-tight concrete
Preparation method, include the following steps:
S1:Sand, 5-25mm rubbles is taken to be added in blender and be stirred, mixing time 10-14s obtains mixture;
S2:Portland cement, mineral admixture, carbon fiber is taken to be added in the mixture obtained in S1, mixing time 14-
18s obtains mixture;
S3:It takes additive, water-reducing agent, water to be fully stirred mixing, is then added in the mixture that S2 is obtained and is stirred 40-
60s discharges after stirring, obtains finished product concrete.
In conclusion the invention has the advantages that:
1, the shield duct piece that the present invention is prepared has good anti-permeability performance and compressive property with water-tight concrete, ensures
The water resistance and load-carrying properties in tunnel.
2, carbon fiber can effectively prevent the generation in concrete plasticity phase crack, since fiber is presented three in concrete
Dimension space network structure plays the role of support and gathers materials, and prevents thick, fine aggregate sedimentation to a certain extent;It also drops simultaneously
The low bleed phenomenon of concrete surface effectively prevents to cause plasticity phase larger volume to receive due to the rapid dehydration of concrete surface
Contracting, to inhibit plasticity phase concrete surface crack occur.Meanwhile the concrete strength of mecystasis is extremely low, fiber is in plasticity
The tensile stress generated due to drying shrinkage can be born in the concrete of state, reduce and prevent inside concrete crack under mecystasis
Generation, to effectively increase the mechanical property and anti-permeability performance of concrete.
3, the present invention utilizes the synergistic effect of the chloro- 2- trifluoromethylated benzaldehydes of 4- and 4- fluoro- 2- (trifluoromethyl) phenylacetic acid,
The generation and expansion for reducing inside concrete crack effectively increase the mechanical property and anti-permeability performance of concrete.
4, the present invention is mixed using mineral admixture with cement, and this not only reduces the dosages of cement, while also dropping
The low heat of hydration of cement, has delayed temperature peak of hydration, to avoid concrete surface crack from generating, to improve concrete
Cracking resistance, anti-erosion, anti-carbonation properties.
Specific implementation mode
Involved all substances are commercially available in the embodiment of the present invention.
One, embodiment is made.
Embodiment 1
S1:It takes sand 560kg, 5-25mm rubble 780kg to be added in blender to be stirred, mixing time 12s is mixed
Object;
S2:Take what is obtained in Portland cement 410kg, silicon ash 55kg, flyash 55kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 13g/9000m, the length of the carbon fiber
For 15mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 3kg, 4- (trifluoromethyl) the phenylacetic acids 0.6kg of 4-, polycarboxylate water-reducer
8.6kg, water 145kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 50s, after stirring
Discharging, obtains finished product concrete.
Embodiment 2
S1:It takes sand 540kg, 5-25mm rubble 770kg to be added in blender to be stirred, mixing time 10s is mixed
Object;
S2:Take what is obtained in Portland cement 420kg, silicon ash 60kg, flyash 50kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 18s obtains mixture;Wherein, the fiber number of carbon fiber is 12g/9000m, the length of the carbon fiber
For 13mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 2.5kg, 4- (trifluoromethyl) the phenylacetic acids 0.5kg of 4-, polycarboxylate water-reducer
9.2kg, water 150kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 40s, after stirring
Discharging, obtains finished product concrete.
Embodiment 3
S1:It takes sand 580kg, 5-25mm rubble 770kg to be added in blender to be stirred, mixing time 10s is mixed
Object;
S2:Take what is obtained in Portland cement 420kg, silicon ash 50kg, flyash 60kg, carbon fiber 120kg additions S1 to mix
It closes in object, mixing time 18s obtains mixture;Wherein, the fiber number of carbon fiber is 12g/9000m, the length of the carbon fiber
For 17mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 2.5kg, 4- (trifluoromethyl) the phenylacetic acids 0.5kg of 4-, polycarboxylate water-reducer
9.2kg, water 140kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 60s, after stirring
Discharging, obtains finished product concrete.
Embodiment 4
S1:It takes sand 540kg, 5-25mm rubble 770kg to be added in blender to be stirred, mixing time 14s is mixed
Object;
S2:Take what is obtained in Portland cement 400kg, silicon ash 60kg, flyash 55kg, carbon fiber 110kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 14g/9000m, the length of the carbon fiber
For 13mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 2.5kg, 4- (trifluoromethyl) the phenylacetic acids 0.7kg of 4-, polycarboxylate water-reducer
8kg, water 150kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 50s, go out after stirring
Material, obtains finished product concrete.
Embodiment 5
S1:It takes sand 580kg, 5-25mm rubble 790kg to be added in blender to be stirred, mixing time 14s is mixed
Object;
S2:Take what is obtained in Portland cement 400kg, silicon ash 50kg, flyash 50kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 14g/9000m, the length of the carbon fiber
For 17mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 3.5kg, 4- (trifluoromethyl) the phenylacetic acids 0.7kg of 4-, polycarboxylate water-reducer
8kg, water 140kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 40s, go out after stirring
Material, obtains finished product concrete.
Embodiment 6
S1:It takes sand 540kg, 5-25mm rubble 790kg to be added in blender to be stirred, mixing time 10s is mixed
Object;
S2:Take what is obtained in Portland cement 400kg, silicon ash 60kg, flyash 60kg, carbon fiber 120kg additions S1 to mix
It closes in object, mixing time 14s obtains mixture;Wherein, the fiber number of carbon fiber is 14g/9000m, the length of the carbon fiber
For 13mm;
S3:Take the chloro- fluoro- 2- of 2- trifluoromethylated benzaldehydes 3.5kg, 4- (trifluoromethyl) the phenylacetic acids 0.5kg of 4-, polycarboxylate water-reducer
8kg, water 150kg, are fully stirred mixing, are then added in the mixture that S2 is obtained and are stirred 60s, go out after stirring
Material, obtains finished product concrete.
Two, comparative example is made.
Comparative example 1
S1:It takes sand 560kg, 5-25mm rubble 780kg to be added in blender to be stirred, mixing time 12s is mixed
Object;
S2:Take what is obtained in Portland cement 410kg, silicon ash 55kg, flyash 55kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 13g/9000m, the length of the carbon fiber
For 15mm;
S3:Polycarboxylate water-reducer 8.6kg, water 145kg are taken, mixing is fully stirred, is then added in the mixture that S2 is obtained
It is stirred 50s, is discharged after stirring, finished product concrete is obtained.
Comparative example 2
S1:It takes sand 560kg, 5-25mm rubble 780kg to be added in blender to be stirred, mixing time 12s is mixed
Object;
S2:Take what is obtained in Portland cement 410kg, silicon ash 55kg, flyash 55kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 13g/9000m, the length of the carbon fiber
For 15mm;
S3:The chloro- 2- trifluoromethylated benzaldehydes 3.6kg of 4-, polycarboxylate water-reducer 8.6kg, water 145kg are taken, is fully stirred mixed
It closes, is then added in the mixture that S2 is obtained and is stirred 50s, discharge after stirring, obtain finished product concrete.
Comparative example 3
S1:It takes sand 560kg, 5-25mm rubble 780kg to be added in blender to be stirred, mixing time 12s is mixed
Object;
S2:Take what is obtained in Portland cement 410kg, silicon ash 55kg, flyash 55kg, carbon fiber 115kg additions S1 to mix
It closes in object, mixing time 16s obtains mixture;Wherein, the fiber number of carbon fiber is 13g/9000m, the length of the carbon fiber
For 15mm;
S3:4- fluoro- 2- (trifluoromethyl) phenylacetic acids 3.6kg, polycarboxylate water-reducer 8.6kg, water 145kg are taken, is fully stirred
Then mixing is added in the mixture that S2 is obtained and is stirred 50s, discharges after stirring, obtain finished product concrete.
Wherein, the above various embodiments is with comparative example, and the fineness modulus of sand is 2.5, apparent density 2690kg/m3, pine
It is 1640kg/m to dissipate bulk density3, voidage 39%, clay content 0.6%, clod content is 0.1%, and 14 days alkali gathers materials
It is 0.08% to react expansion rate.
The apparent density of 5-25mm rubbles is 2800kg/m3, loose bulk density 1540kg/m3, loosely-packed voidage
It is 45%, crush values 7%, clay content 0.5%, flat-elongated particles content is 4%, and sulfide and sulphates content are
0.18%, 14 days alkali expansion rates are 0.08%.
Three, the performance for the shield duct piece water-tight concrete being prepared in above example and comparative example is surveyed
Examination.
Evaluation index and inspection used by shield duct piece water-tight concrete prepared by the above various embodiments and comparative example
Survey method is as follows:
Anti-Chloride Ion Penetration:According to GB/T 50082《Standard for test methods of longterm performance and durability of ordinary concrete standard》
In quick chloride ion transport Y-factor method Y test concrete standard test block chloride permeability depth.
Water resistant permeance property:According to GB/T 50082《Standard for test methods of longterm performance and durability of ordinary concrete standard》
In pressurization step by step test concrete standard test block infiltration depth.
Anti-carbonation properties:According to GB/T 50082《Standard for test methods of longterm performance and durability of ordinary concrete standard》In
Carbonation depth of the carbonization experiment test concrete standard test block at the 28th day.
Compression strength:According to GB/T 50010《Code for design of concrete structures》In specification detect concrete standard test block
The compression strength with 100% fraction measured at the 7th day, the 28th day.
The performance indicator of the above various embodiments and comparative example is as shown in table 1.
The performance test results for the shield duct piece water-tight concrete that 1 each embodiment of table is prepared with comparative example
As can be seen from the above table, the shield duct piece that the present invention is prepared with water-tight concrete have good anti-permeability performance with
And compressive property, it ensure that the water resistance in tunnel.
Wherein, it is added without the chloro- 2- trifluoromethylated benzaldehydes of 4- and 4- fluoro- 2- (trifluoromethyl) phenylacetic acid in comparative example 1, makes
The crack of standby obtained inside concrete is more, and the anti-permeability performance and compression strength for the concrete being prepared are relatively low, much low
The shield duct piece water-tight concrete being prepared in embodiment 1.
The chloro- 2- trifluoromethylated benzaldehydes of 4- and the fluoro- 2- of 4- (trifluoromethyl) is only added in comparative example 2 and comparative example 3 respectively
Phenylacetic acid, it is simple to be less than the two using the chloro- 2- trifluoromethylated benzaldehydes of 4- and the effect of 4- fluoro- 2- (trifluoromethyl) phenylacetic acid
Synergistic effect causes the anti-permeability performance for the shield duct piece water-tight concrete being prepared to decline with compression strength, less than implementation
The shield duct piece water-tight concrete being prepared in example 1.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, people in the art
Member can as needed make the present embodiment the modification of not creative contribution after reading this specification, but as long as at this
It is all protected by Patent Law in the right of invention.
Claims (9)
1. a kind of shield duct piece water-tight concrete, characterized in that count in parts by weight, raw material includes:Normal silicate water
400-420 parts of mud, 100-120 parts of mineral admixture, 540-580 parts of sand, 770-790 parts of 5-25mm rubbles, additive 3-4.8
Part, 110-120 parts of carbon fiber, 8-9.2 parts of water-reducing agent, 140-150 parts of water.
2. shield duct piece water-tight concrete according to claim 1, characterized in that the additive includes the chloro- 2- of 4-
Trifluoromethylated benzaldehyde and 4- fluoro- 2- (trifluoromethyl) phenylacetic acid.
3. shield duct piece water-tight concrete according to claim 1, characterized in that the fluoro- 2- of 4- (trifluoromethyl)
The mass ratio of phenylacetic acid and the chloro- 2- trifluoromethylated benzaldehydes of 4- is 1:5.
4. shield duct piece water-tight concrete according to claim 1, characterized in that the fiber number of the carbon fiber is 12-
The length of 14g/9000m, the carbon fiber are 13-17mm.
5. shield duct piece water-tight concrete according to claim 1, characterized in that the water-reducing agent is polycarboxylic acids diminishing
Agent.
6. shield duct piece water-tight concrete according to claim 1, characterized in that the fineness modulus of the sand is 2.5,
Apparent density is 2690kg/m3, loose bulk density 1640kg/m3, voidage 39%, clay content 0.6%, clod contains
Amount is 0.1%, and 14 days alkali expansion rates are 0.08%.
7. shield duct piece water-tight concrete according to claim 1, characterized in that mineral admixture is silicon ash, fine coal
The mass ratio of the mixture of ash, the silicon ash and flyash is 1:1.
8. shield duct piece water-tight concrete according to claim 1, characterized in that the 5-25mm rubbles it is apparent close
Degree is 2800kg/m3, loose bulk density 1540kg/m3, loosely-packed voidage is 45%, crush values 7%, clay content
It is 0.5%, flat-elongated particles content is 4%, and sulfide and sulphates content are 0.18%, 14 days alkali expansion rates
It is 0.08%.
9. the preparation method of shield duct piece water-tight concrete as described in claim 1, characterized in that include the following steps:
S1:Sand, 5-25mm rubbles is taken to be added in blender and be stirred, mixing time 10-14s obtains mixture;
S2:Portland cement, mineral admixture, carbon fiber is taken to be added in the mixture obtained in S1, mixing time 14-
18s obtains mixture;
S3:It takes additive, water-reducing agent, water to be fully stirred mixing, is then added in the mixture that S2 is obtained and is stirred 40-
60s discharges after stirring, obtains finished product concrete.
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CN111333388A (en) * | 2020-03-27 | 2020-06-26 | 江苏昆腾新材料科技有限公司 | Environment-friendly concrete for shield segment pouring and preparation process thereof |
CN111720140A (en) * | 2020-07-31 | 2020-09-29 | 中铁科学研究院有限公司 | Synthetic fiber reinforced concrete shield segment and preparation method thereof |
CN112830727A (en) * | 2021-01-12 | 2021-05-25 | 南通铁建建设构件有限公司 | Anti-erosion and anti-corrosion concrete shield segment |
CN114988813A (en) * | 2022-06-27 | 2022-09-02 | 南京航空航天大学 | Anti-crack concrete for shield segment and preparation method thereof |
CN117776633A (en) * | 2024-02-27 | 2024-03-29 | 中铁二十二局集团轨道工程有限公司 | Preparation method of shield segment concrete |
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CN111720140A (en) * | 2020-07-31 | 2020-09-29 | 中铁科学研究院有限公司 | Synthetic fiber reinforced concrete shield segment and preparation method thereof |
CN112830727A (en) * | 2021-01-12 | 2021-05-25 | 南通铁建建设构件有限公司 | Anti-erosion and anti-corrosion concrete shield segment |
CN114988813A (en) * | 2022-06-27 | 2022-09-02 | 南京航空航天大学 | Anti-crack concrete for shield segment and preparation method thereof |
CN117776633A (en) * | 2024-02-27 | 2024-03-29 | 中铁二十二局集团轨道工程有限公司 | Preparation method of shield segment concrete |
CN117776633B (en) * | 2024-02-27 | 2024-06-07 | 中铁二十二局集团轨道工程有限公司 | Preparation method of shield segment concrete |
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