CN108523257A - A kind of multifunction emulsion cotton health-care bra and preparation method thereof - Google Patents

A kind of multifunction emulsion cotton health-care bra and preparation method thereof Download PDF

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Publication number
CN108523257A
CN108523257A CN201810262559.XA CN201810262559A CN108523257A CN 108523257 A CN108523257 A CN 108523257A CN 201810262559 A CN201810262559 A CN 201810262559A CN 108523257 A CN108523257 A CN 108523257A
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China
Prior art keywords
cup
preparation
parts
silica gel
hull ash
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CN201810262559.XA
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Chinese (zh)
Inventor
喻正兵
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Foshan Yangmu Clothing Co Ltd
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Foshan Yangmu Clothing Co Ltd
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Priority to CN201810262559.XA priority Critical patent/CN108523257A/en
Publication of CN108523257A publication Critical patent/CN108523257A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41C—CORSETS; BRASSIERES
    • A41C3/00—Brassieres
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41C—CORSETS; BRASSIERES
    • A41C5/00—Machines, appliances, or methods for manufacturing corsets or brassieres
    • A41C5/005—Machines, appliances, or methods for manufacturing corsets or brassieres by moulding
    • C—CHEMISTRY; METALLURGY
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
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    • C04B35/71—Ceramic products containing macroscopic reinforcing agents
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    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
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    • C08K7/26—Silicon- containing compounds
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    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Corsets Or Brassieres (AREA)

Abstract

The invention discloses a kind of preparation methods of multifunction emulsion cotton health-care bra and preparation method thereof, the health-care bra cup includes cup frame (2), the frame (2) is provided with left cup (3) and right cup (4), it is connected by connect band (5) between the left cup (3) and right cup (4), left cup (3) upper end is provided with left shoulder belt (6), right cup (4) upper end is provided with right shoulder belt (7), the left end of the left cup (3) is provided with left bust band (10), the right end of the right cup (4) is provided with right bust band (11), on a left side, one end of right bust band is each provided with junction button, the junction button can be combined with each other, so that left, right bust band can be linked together by junction button；The upper part of the cup frame (2) uses toughening bioceramic material, the lower part of the cup frame (2) to use memory titanium.

Description

A kind of multifunction emulsion cotton health-care bra and preparation method thereof
Technical field
The invention belongs to field of photoelectric technology, a kind of multifunction emulsion cotton health-care bra and preparation method thereof is related generally to.
Background technology
Brassiere is the necessity for life that adult female often wears, all the time, the businessman in industry be devoted to how Its structure, fabric etc. are improved.But current brassiere still has a single function, and only plays support, stores chest, prevents under chest Vertical function rarely has other miscellaneous functions, it is difficult to meet people's increasingly higher demands.
Cup is important female living article, and cup currently on the market is typically made of sponge, but sponge The main raw material(s) TDI (toluene di-isocyanate(TDI)) of the inside is toxic chemical, and Long Term Contact can endanger health.And due to sea Continuous molecular structure it is unstable, it easily turns yellow, and since sponge is not easy to breathe freely, is easy to shelter evil people and countenance evil practices.
In order to solve the drawbacks described above of sponge cup, many manufacturers attempt to replace sea using foamed silica gel cup in industry Continuous cup, however at present factory during manufacturing foamed silica gel cup, it usually needs first with container to silica gel raw material into Luggage holds, and after processing, then silica gel raw material is transferred in container in foaming mould, and transfer process can be inevitably The container for causing the waste of silica gel former material section, and clearing up dressing silica gel former material section also to consume a large amount of time and manpower at This.
Traditional brassiere production process, which will pass through 20 multiple working procedures, to be completed, wherein to pass through multiple tracks sewing process, And the brassiere that current brassiere production technology is produced, the suture between cloth, which all exposes outside, to be come, and text is seriously affected Outside the aesthetics of chest, the comfort of wearing is had an effect on.Exposing outside the suture come can scratch skin, especially for cup, cover Caused the edge of cup to be close to than pulling by rear while cup wraps breast and push down human skin, traditional cup The exposed suture scratch skin of surrounding is quite serious, takes off and will appear apparent impression on cup skin, is short of comfort.
In addition, because the cup shape in brassiere is hemisphere jut shape, when production, needs to cover one layer in the outer surface of cup The trimming cloth of elasticity, but traditional sewing technology is difficult to that elastic decorative cloth is made to be stitched together with cup perfection, problem master The surrounding of cup is appeared in, such as the top edge of cup will appear gauffer, it is in the very big heart of Curvature varying that spy is standby Place, upper part edge gauffer is very serious, seriously affects the aesthetics and comfort level of brassiere.
As one of most common women furnishings, shape, material, design concept sustain its quality through age brassiere.Steel ring and other height Rigidity, high resiliency material support for cup, are moulding, and steel ring position soothes the skin discomfort in conjunction with soft material；Coordinate Fig. 1 institutes Show, existing brassiere cup, the filling sponge 3 ' or other with cellular typically between the internal layer 1 ' of cup and outer layer 2 ' Supporter for cup sizing support, although sponge have light, ventilative, absorbing sweat characteristic, be based on carcinogenicity, silicon The materials such as glue, latex are foamed to be processed into cellular, replacement sponge；Foam-rubber cushion, silicone oil silicagel pad, water cushion, gas cell or pad, justice Breast filling squeezes or is promoted breast；Increase massage, drug, fever tablet etc. and has physiotherapy function.But existing brassiere still without Method reaches best special efficacy light, ventilative, safe to use and good support effect, thus this case just generates.
The cup brassiere that women uses includes mainly cup and frame two parts, wherein cup is as cladding and protection breast The carrier in room plays the role of support to women, is promoted or gathered, and is the most direct part for moulding female chest curve modeling, For cup brassiere on the market based on sponge cup body, sponge is with TDI (toluene di-isocyanate(TDI)), PPG (polyethers), MC etc. now Made by industrial chemicals foaming, very big harm is caused to environment due to the use of a large amount of organic solvents in production process, is being polluted Its waste is also difficult to handle while environment；On the other hand, it in summer weather sweltering heat, due to sponge sulks, breathes freely and saturating It is moist poor, human body can be caused largely to perspire, the comfort of wearing is bad, and cup brassiere easily turns to be yellow made of this external application sponge, Harmful effect can be generated to health, thus be increasingly becoming women using sponge cup brassiere and chased after with human contact for a long time The beautiful obstruction lived is sought, therefore, exploitation and production good permeability, and the cup brassiere of health, environmental protection is very necessary.
Has relevant report for the exploitation of the Health-care bra with fine air permeability：
Patent CN200510132599.5 discloses a kind of air-permeable structure brassiere, be with the sandwiched middle layer of two coating and In the brassiere component of formation, with laser light setting penetrate a coating and through middle layer penetrate another coating run through through-hole, Reach ventilative purpose by the setting through through-hole, and assist the exclusion of sweat, it is bad to solve known brassieres breathing degree Problem.Patent CN200510045176.X discloses a kind of health breathable bra, and air hole, brassiere outer surface are equipped on brassiere It is laid with small convex body, simple structure has gas permeability.Above-mentioned two patent is manufactured brassiere using multilayer material superposition, Increase gas permeability by punching in the material, but the processing tool for forming perforative air hole wherein acquires a certain degree of difficulty.
Patent CN201210233539.2 discloses a kind of composite sandwich ventilation bra cup, is by inner cup and in overlaying on The watch glasses cup of cup surface is constituted, and is evenly distributed with air hole at inner cup, is used double-layer composite ventilating structure, inner cup Fitting chest completely, has and sets off and air permeability effect very well, watch glasses cup is for shapping function, shapeable perfection chest type.However, should The cup that item patent is related to needs to produce two layers of cup body, although inner layer cup is ventilative, the also presence of surface layer cup, together When process it is also more complicated.
Patent of invention CN201310359204.X discloses a kind of environment-friendlybreathable breathable vertical cotton bra cup, and cup ontology includes adding U.S. Core is coated on the fabric for adding U.S. core outer layer and internal layer, and it is the upright cotton with honeycomb stereochemical structure to add U.S. core, and the fabric is Sandwich fabric with three-dimensional mesh institutional framework, since without using traditional sponge cup, there is better gas permeability.It should Although patent has the gas permeability in structure, the fabric for being coated on the mesh institutional framework of vertical cotton outer layer and internal layer is to pass through spray It is bonded together with vertical cotton after spilling hot melt adhesive, glue can block the air hole in structure to a certain extent, add material therefor Be polyester fiber, since polyester fiber regain itself is only 0.2%, do not absorb water, wet guilding it is poor, wear and also have The feeling of sulks.
In order to overcome traditional sponge cup it is airtight, be easy turn yellow and it is personal wear it is issuable to health Poor air permeability existing for harmful effect and existing Health-care bra cup, the deficiencies of wet guilding is poor, processing technology is complicated, the present invention It provides and a kind of having both ventilative, moisture-inhibiting, pro-skin, ecological bacteriostatic, anti-mite and biodegradable cover by prepared by acid fiber by polylactic Cup and preparation method thereof.
The molecular structure of latex is special, has good comfort, gas permeability, inhibits the growth of bacterium and parasite；It opens The latex porous balloon structure for putting formula, make air in mattress still can free flow, skin and mattress in dispersible sleep Contact the hot gas generated, sweat gas；However, relying solely on the characteristic of latex itself, client is not met by ventilative requirement
Existing latex bra cup is usually the direct foaming in emulsion foaming molding die.Due to brassiere Cup cup side is relatively thin.On the one hand, the phenomenon that cup side is susceptible to tearing in demoulding causes the defect rate of product high；Another party Face is also easy to the phenomenon that edge is broken occur in the process of the processes such as the sewing in later stage, and can not normally produce and add Work.
To solve the above-mentioned problems, currently used solution is to improve latex bra cup and its thickness on cup side. However, the increase of latex bra cup and its cup side thickness necessarily causes brassiere comfort and inclusiveness to be deteriorated.Therefore, lead to The method for crossing increase thickness is not an effective solution.
Invention content
It is an object of the present invention to provide a kind of multifunction emulsion cotton health-care bras and preparation method thereof, can increase cup master While body elasticity, have that light weight, safe to use, support effect is good, perspiration discharging performance is good enables brassiere use more comfortable.
For deficiency in the prior art, the purpose of the present invention is to provide a kind of multifunction emulsion cotton health-care bra and its Preparation method.
In order to achieve the goal above, the application uses following technical solution：
A kind of multifunction emulsion cotton health-care bra, the brassiere include cup, shoulder belt, bust band, junction button, heart structure Part, wherein the interior material of the cup is latex cotton.
A kind of multifunction emulsion cotton health-care bra, the health-care bra cup include cup frame (2), the frame (2) It is provided with left cup (3) and right cup (4), is connected by connect band (5) between the left cup (3) and right cup (4), it is described Left cup (3) upper end is provided with left shoulder belt (6), and right cup (4) upper end is provided with right shoulder belt (7), the left cup (3) Left end is provided with left bust band (10), and the right end of the right cup (4) is provided with right bust band (11), in left and right bust band One end is each provided with junction button, and the junction button can be combined with each other, so that left and right bust band can be connected to by junction button Together；The upper part of the cup frame (2) uses Metal toughened bioceramic material, the lower part of the cup frame (2) Use memory titanium.
The left and right cup cup body (1) of the health-care bra cup uses modified latex cotton material.
It is provided with micro air pump (1a) in left and right cup cup body (1) the modified latex cotton material, in cup cup body (1) It is provided with pressure sensor (1b), the pressure sensor (1b), institute on the inside of inside, right and left shoulders band and on the inside of the bust band of left and right Pressure sensor (1b) is stated with micro air pump (1a) to be connected.
The health-care bra cup surface, is coated with waterproof photovoltaic coating, and the photovoltaic coating can convert light energy into Electric energy, and deliver the power to be arranged in energy-storage module (1c) in cup body (1) and be stored, the energy-storage module with it is miniature Air pump (1a) and pressure sensor (1b) are attached.
The material component and weight of the waterproof photovoltaic coating be：PbTiO350-60 parts, 5-10 parts of Ag, ZnO 1-5 parts, 1-5 parts of carbon fiber, 1-5 parts of boron fibre, 1-5 parts of silicon carbide whisker, 15-20 parts of aluminium oxide, 3-8 parts of manganese oxide.
The material component and weight of the cermet toughening bioceramic material be：It is 1-10 parts of zirconium oxide, swollen Moisten 5-15 parts of soil, 1-3 parts of glass microballoon, 5-8 parts of tourmaline, 1-3 parts of rice hull ash, 3-8 parts of alumine, 1-3 parts of titanium carbide, Ni1-2 parts, Co1-2 parts, Cr1-2 parts, Mo1-2 parts, W1-2 parts, 4-9 parts of carbon fiber, 8-12 parts of Alpha-alumina, titanium dioxide 3- 10 parts.
The thickness of the cermet frame is 0.25mm~1mm, hardness 0A~30A；The modified milk collodion is divided into Lining and bed course are additionally provided with polyester cotton layer between the lining and bed course, the porosity of the polyester cotton layer is 95-98%； Described includes rubber, zinc oxide, sulphur, thiazole accelerators, sulphur formiate accelerating agent, anion surfactant, antioxygen Component is arranged by following mass fraction in agent, potassium oleate, inorganic foam stabilizer, succinamide sulfonate, calcium carbonate and diatomite： 80-120 parts of rubber；2-5 parts of zinc oxide；1-5 parts of sulphur；0.5-2.0 parts of thiazole accelerators；Sulphur formiate accelerating agent 0.5- 1.5 part；1-4 parts of anion surfactant；1-2 parts of antioxidant；0.1-0.5 parts of potassium oleate；Inorganic foam stabilizer 0.2-2.0 parts； 1.5-3.0 parts of succinamide sulfonate；30-200 parts of calcium carbonate；1-40 parts of diatomite；
The preparation method of the multifunction emulsion cotton health-care bra, the preparation method comprises the following steps：
Step 1: the preparation of cup frame；
Step 2: the preparation of cup cup body；
Step 3: the preparation of accessory；
Step 4: sewing finished product.
The step 1 includes
The preparation of step 1 frame raw material：The preparation of rice hull ash；
Step (1) first, by the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying, removes it In impurity, in case rice hull ash making use；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room Temperature to 300 DEG C heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-room temperature, Temperature fall；
1. 20 DEG C or so to 300 DEG C heating 30min；
2. 300-400 DEG C of heating 30min；
3. 400-600 DEG C of heating 30min；
4. 600 DEG C of constant temperature 30min；
5. 600-300 DEG C of cooling about 4h；
6. 300 DEG C to room temperature cool down about 1.5h.
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, wait for that temperature is cold until descent of temperature is to after 300 DEG C or less by step (4) But manufactured rice hull ash is taken out from crucible afterwards, it is SiO to measure and fire the main component of successful rice hull ash2；
Step (5), the grinding of rice hull ash；(YJ-300 type high speed Universal pulverizers are good for the limited public affairs of Medical Devices by Jinan hundred million Department's manufacture, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, powder fineness are 50-300 mesh) it will be after burning Rice hull ash is put into progress grinding processing in pulverizer, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
Step 2, respectively every group weigh corresponding raw material；
Raw material by needed for each group is poured on mix plate progress mix 1min by step 3 respectively, forms mixture
Step 4 will determine that the mixing water of amount pours into mixture and stirs 2min
Step 5, casting；
Step 6, demoulding, are dried, 30-40 DEG C in an oven, dry 10-15h；
Step 7, sintering are sintered 5-7h at 900-1000 DEG C；
Step 8 obtains final products.
The step 2 specifically includes following steps：
S1：Raw material configures
Using latex as primary raw material, corresponding auxiliary material is added, is made into raw material mixture.
S2：Foaming
First inject foaming molding mold in carry out foamable molding, after molding out of foaming molding mold take out and to it Dewatered drying is carried out, latex bra cup semi-finished product are made；The edge of latex bra cup semi-finished product is thicker, and thickness usually exists 3.5~40mm, thus be easy to demould from foaming molding mold and take out.
S3：Thermocompression forming
By latex bra cup semi-finished product through thermo-pressing moulder carry out thermocompression forming, keep its thickness thinning, be made thickness compared with Thin latex bra cup finished product, edge thickness is up to 0.5-7.0mm.
Step 1, supporter cermet frame carry out 3D modeling, make mold；
Step 2, hard gel feed intake and are put under the corresponding cup of paliform skeleton die cavity plate outside, soft silica gel feeds intake To other positions；
Step 3, the ultra-soft matter silica gel room temperature of hardness 0A-10A pour method and enter internal layer kachoji shape silica gel mould, 10A-30A Die pressing enters internal layer kachoji shape silica gel mould；
Step 4, hardness 30A-70A medium hardness silica gel feed intake outer layer kachoji shape silica gel mould；
Step 5, by the silica gel paliform skeleton obtained respectively, internal layer, the outer layer combination of kachoji shape silica gel, obtain complete Cup main body；The assembling that flexible liner body and accessory are carried out after the step 5, obtains complete brassiere；It will treated through step 4 Molding die hot briquetting, cooling form removal, deburring, obtain cup finished product.
The preparation method of waterproof photovoltaic coating, it is characterised in that steps are as follows：
(1) at room temperature, butyl titanate is instilled in ethylene glycol monomethyl ether, after stirring evenly, a small amount of nitre is added thereto Acid is used as stabilizer, is made into stable colloidal sol containing Ti；
(2) plumbi nitras is dissolved into using lactic acid, citric acid as complexing agent, ethylene glycol monomethyl ether be solvent mixed solution in, Form colloidal sol containing Pb, wherein the molar ratio of lactic acid/butyl titanate is 2-3, and the molar ratio of citric acid/butyl titanate is 7- 8；
(3) it is 1 according to Pb: Ti molar ratio with colloidal sol containing Ti by above-mentioned colloidal sol containing Pb: (2-3) is mixed, and it is molten to obtain Pb-Ti Glue, it is than the amount for 25-30%, silver nitrate is molten according to Ag target volumes in film as the precursor colloidal sol of PbTiO3 films The precursor colloidal sol for solving PbTiO3 obtains precursor colloidal sol of the colloidal sol as Ag-PbTiO3 laminated films of Ag-Pb-Ti；
(4) surplus stock is mixed in proportion, is ground into nano powder, it is molten to be immersed in precursor under vacuum In, 15-25min is impregnated, 10~60min of drying under the conditions of 150-210 DEG C is then taken out；It repeats above step 2-4 times, completes Coating；
(5) by the thin-film material after coating, it is warming up to 750-800 DEG C with the speed of 2-5 DEG C/min, keeps the temperature 2-3h, is prepared Go out photovoltaic coating.
The preparation method of cup is also an option that following steps：
(1) one layer of water-proof silica-gel coating is coated on cloth, then cuts the cloth of the good water-proof silica-gel coating of coating It is cut into the size of needs；
(2) material cut out in step (1) is divided into interior bed of cloth and outer bed of cloth, then shaper is utilized to use Heating and negative pressure, which are combined, carries out pre-setting processing, for use；
(3) the outer bed of cloth that pre-setting in step (2) is handled is put into edge sealing mould, then fixes the outer bed of cloth Periphery, silica gel liquid is injected by product aequum on the outer bed of cloth in the edge sealing mould, then will be in step (2) The interior bed of cloth of pre-setting processing is laid on the silica gel on the outer bed of cloth, further according to cup body design form by the outer cloth The bed of material and interior bed of cloth edge sealing form bag body, wherein placement of the outer bed of cloth in the edge sealing mould is required to meet described The side with silica-gel coating of outer bed of cloth is directly contacted with the silica gel, laying of the interior bed of cloth on the silica gel The integrated quantum chip board band, is used in combination quantum chip mounting ring (9) to be fixed on the cup of left and right, strip is then laid on institute The side with silica-gel coating for stating interior bed of cloth is directly contacted with the silica gel；
(4) the bag body that step (3) obtains is put into the lower die of molding die, at the edge sealing for aligning the bag body, then The fixed bag body, squeezes the inner wall that the bag body is close to the lower die of the molding die, then by the upper of the molding die Mould is closed and is locked；
(5) cup finished product will be obtained through step (4) treated molding die hot briquetting, cooling form removal, deburring；
Wherein, in step (5), the cup semi-finished product after cooling form removal are punched out processing, then deburring again.
Rice, graminaceous plant originate in from Tropical Asian, there is 24 chromosomes.Rice is found and is planted in China first It plants, spread later all over the world.The rice that we eat is exactly thing of the grain of rice born of rice after removing shell.It is existing The present, in the world most of population make a living by rice.And rice husk is exactly the byproduct of rice, wrap up in outside rice that layer of shell is exactly Rice husk.The material composition of rice husk is：Crude fibre 35.5%-45%, lignin 21%-26%, polycondensation pentose 16%-22%, ash Divide 11.4%-22%, silica 1 0%-21%[9](being shown in Table 1-1).
The material composition of table 1-1 rice husks
Essential element group is also pressed from both sides as C, H, O, Si by a small amount of impurity in rice husk, this is just that rice husk manufactures high-performance fertilizer And composite soil obtains extremely beneficial condition.And rice is as world-class crops, the annual output of paddy has been in recent years Reach more than 600,000,000 tons, and as the China of large agricultural country, the annual output of rice also reaches the half in modern times circle；And rice husk is as water The byproduct of rice, its yield is huge, is the 20% of paddy weight.But while there are many potential agricultural use, rice for rice husk The major part of shell has not found the method reasonably recycled.
The preparation of rice hull ash；
Step (1) first, by the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying, removes it In impurity, in case rice hull ash making use；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room Temperature to 300 DEG C heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-room temperature, Temperature fall；Specifically, 20 DEG C or so to 300 DEG C heating 30min；300-400 DEG C of heating 30min；400-600℃ Heat up 30min；600 DEG C of constant temperature 30min；600-300 DEG C of cooling about 4h；300 DEG C to room temperature cool down about 1.5h；
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, wait for that temperature is cold until descent of temperature is to after 300 DEG C or less by step (4) But manufactured rice hull ash is taken out from crucible afterwards, it is SiO to measure and fire the main component of successful rice hull ash2；
The grinding of step (5) rice hull ash；Using YJ-300 type high speed Universal pulverizers, it is limited that Medical Devices are good for by Jinan hundred million Company manufactures, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, and powder fineness is 50-300 mesh, after burning Rice hull ash be put into pulverizer progress grinding processing, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
The chemical composition (%) of table 2-1 rice hull ash
Description of the drawings
Fig. 1：The application brassiere side view；
Fig. 2：The application bra structure schematic diagram；
Fig. 3：The SEM of the application waterproof photovoltaic coating schemes.
Advantageous effect
Brassiere prepared by the application method can dredge mammary gland, promote the absorption of mammary gland vacuole, turgid cell, strong chest big Flesh, improvement udder size differ, and can excite incretory, can preventing mammary gland hyperplasia, breast cancer, fibrocyst, fibroma generation；Also The development again of estrogen and chest can be excited；Can strengthen carry ligament function, effective lifting sagging, atrophy chest Type.Additionally it is possible to which activating cell, skin of moistening promote blood circulation and metabolic.
Specific implementation mode
Embodiment 1
The cup of a kind of multifunction emulsion cotton health-care bra, the health-care bra includes cup frame (2), the frame (2) it is provided with left cup (3) and right cup (4), is connected by connect band (5) between the left cup (3) and right cup (4), Left cup (3) upper end is provided with left shoulder belt (6), and right cup (4) upper end is provided with right shoulder belt (7), the left cup (3) left end is provided with left bust band (10), and the right end of the right cup (4) is provided with right bust band (11), in left and right bust One end of band is each provided with junction button, and the junction button can be combined with each other, so that left and right bust band can be connected by junction button It is connected together；The upper part of the cup frame (2) uses Metal toughened bioceramic material, under the cup frame (2) Part uses memory titanium.
The left and right cup cup body (1) of the health-care bra cup uses modified latex cotton material.
It is provided with micro air pump (1a) in left and right cup cup body (1) the modified latex cotton material, in cup cup body (1) It is provided with pressure sensor (1b), the pressure sensor (1b), institute on the inside of inside, right and left shoulders band and on the inside of the bust band of left and right Pressure sensor (1b) is stated with micro air pump (1a) to be connected.
The health-care bra cup surface, is coated with waterproof photovoltaic coating, and the photovoltaic coating can convert light energy into Electric energy, and deliver the power to be arranged in energy-storage module (1c) in cup body (1) and be stored, the energy-storage module with it is miniature Air pump (1a) and pressure sensor (1b) are attached.
The material component and weight of the waterproof photovoltaic coating be：PbTiO350 parts, 5 parts of Ag, 1 part of ZnO, 1 part of carbon fiber, 1 part of boron fibre, 1 part of silicon carbide whisker, 15 parts of aluminium oxide, 3 parts of manganese oxide.
The material component and weight of the cermet toughening bioceramic material be：1 part of zirconium oxide, bentonite 5 parts, 1 part of glass microballoon, 5 parts of tourmaline, 1 part of rice hull ash, 3 parts of alumine, 1 part of titanium carbide, Ni1 parts, Co1 parts, Cr1 parts, Mo1 parts, W1 parts, 4 parts of carbon fiber, 8 parts of Alpha-alumina, 3 parts of titanium dioxide.
The thickness of the cermet frame is 0.25mm, hardness 5A；The modified milk collodion is divided into lining and bed course, Polyester cotton layer is additionally provided between the lining and bed course, the porosity of the polyester cotton layer is 95%；Described includes rubber, oxygen Change zinc, sulphur, thiazole accelerators, sulphur formiate accelerating agent, anion surfactant, antioxidant, potassium oleate, inorganic steady Component is arranged by following mass fraction in infusion, succinamide sulfonate, calcium carbonate and diatomite：80 parts of rubber；Zinc oxide 2 Part；1 part of sulphur；0.5 part of thiazole accelerators；0.5 part of sulphur formiate accelerating agent；1 part of anion surfactant；Antioxidant 1 part；0.1 part of potassium oleate；0.2 part of inorganic foam stabilizer；1.5 parts of succinamide sulfonate；30 parts of calcium carbonate；1 part of diatomite；
The preparation method of the multifunction emulsion cotton health-care bra, the preparation method comprises the following steps：
Step 1: the preparation of cup frame；
Step 2: the preparation of cup cup body；
Step 3: the preparation of accessory；
Step 4: sewing finished product.
The step 1 includes
The preparation of step 1 frame raw material：The preparation of rice hull ash；
Step (1) first, by the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying, removes it In impurity, in case rice hull ash making use；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room Temperature to 300 DEG C heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-room temperature, Temperature fall；
1. 20 DEG C or so to 300 DEG C heating 30min；
2. 300-400 DEG C of heating 30min；
3. 400-600 DEG C of heating 30min；
4. 600 DEG C of constant temperature 30min；
5. 600-300 DEG C of cooling about 4h；
6. 300 DEG C to room temperature cool down about 1.5h.
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, wait for that temperature is cold until descent of temperature is to after 300 DEG C or less by step (4) But manufactured rice hull ash is taken out from crucible afterwards, it is SiO to measure and fire the main component of successful rice hull ash2；
Step (5), the grinding of rice hull ash；(YJ-300 type high speed Universal pulverizers are good for the limited public affairs of Medical Devices by Jinan hundred million Department's manufacture, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, powder fineness are 50-300 mesh) it will be after burning Rice hull ash is put into progress grinding processing in pulverizer, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
Step 2, respectively every group weigh corresponding raw material；
Raw material by needed for each group is poured on mix plate progress mix 1min by step 3 respectively, forms mixture
Step 4 will determine that the mixing water of amount pours into mixture and stirs 2min
Step 5, casting；
Step 6, demoulding, are dried, 30 DEG C in an oven, dry 10h；
Step 7, sintering are sintered 5h at 900 DEG C；
Step 8 obtains final products.
The step 2 specifically includes following steps：
S1：Raw material configures
Using latex as primary raw material, corresponding auxiliary material is added, is made into raw material mixture.
S2：Foaming
First inject foaming molding mold in carry out foamable molding, after molding out of foaming molding mold take out and to it Dewatered drying is carried out, latex bra cup semi-finished product are made；The edge of latex bra cup semi-finished product is thicker, and thickness usually exists 3.5mm, thus be easy to demould from foaming molding mold and take out.
S3：Thermocompression forming
By latex bra cup semi-finished product through thermo-pressing moulder carry out thermocompression forming, keep its thickness thinning, be made thickness compared with Thin latex bra cup finished product, edge thickness is up to 0.5mm.
Step 1, supporter cermet frame carry out 3D modeling, make mold；
Step 2, hard gel feed intake and are put under the corresponding cup of paliform skeleton die cavity plate outside, soft silica gel feeds intake To other positions；
Step 3, method enters internal layer kachoji shape silica gel mould to the pouring of the ultra-soft matter silica gel room temperature of hardness 2A, 10A die pressings enter Internal layer kachoji shape silica gel mould；
Step 4, hardness 30A medium hardness silica gel feed intake outer layer kachoji shape silica gel mould；
Step 5, by the silica gel paliform skeleton obtained respectively, internal layer, the outer layer combination of kachoji shape silica gel, obtain complete Cup main body；The assembling that flexible liner body and accessory are carried out after the step 5, obtains complete brassiere；It will treated through step 4 Molding die hot briquetting, cooling form removal, deburring, obtain cup finished product.
The preparation method of waterproof photovoltaic coating, it is characterised in that steps are as follows：
(1) at room temperature, butyl titanate is instilled in ethylene glycol monomethyl ether, after stirring evenly, a small amount of nitre is added thereto Acid is used as stabilizer, is made into stable colloidal sol containing Ti；
(2) plumbi nitras is dissolved into using lactic acid, citric acid as complexing agent, ethylene glycol monomethyl ether be solvent mixed solution in, Form colloidal sol containing Pb, wherein the molar ratio of lactic acid/butyl titanate is 2, and the molar ratio of citric acid/butyl titanate is 7；
(3) above-mentioned colloidal sol containing Pb is mixed according to Pb: Ti molar ratio for 1: 2 with colloidal sol containing Ti, obtains Pb-Ti colloidal sols, As PbTiO3Silver nitrate is dissolved into according to Ag target volumes in film than the amount for 25% by the precursor colloidal sol of film PbTiO3Precursor colloidal sol, obtain the colloidal sol of Ag-Pb-Ti as Ag-PbTiO3The precursor colloidal sol of laminated film；
(4) surplus stock is mixed in proportion, is ground into nano powder, it is molten to be immersed in precursor under vacuum In, 15min is impregnated, then takes out and dries 10min under the conditions of 150 DEG C；It repeats above step 2 times, completes coating；
(5) by the thin-film material after coating, 750 DEG C is warming up to the speed of 2 DEG C/min, keeps the temperature 2h, prepare photovoltaic painting Layer.
Embodiment 2
A kind of multifunction emulsion cotton health-care bra, the health-care bra include cup frame (2), frame (2) setting There are left cup (3) and right cup (4), is connected by connect band (5) between the left cup (3) and right cup (4), the left cover Cup (3) upper end is provided with left shoulder belt (6), and right cup (4) upper end is provided with right shoulder belt (7), the left end of the left cup (3) It is provided with left bust band (10), the right end of the right cup (4) is provided with right bust band (11), in one end of left and right bust band It is each provided with junction button, the junction button can be combined with each other, so that left and right bust band can be connected to one by junction button It rises；The upper part of the cup frame (2) uses Metal toughened bioceramic material, the lower part of the cup frame (2) to make With memory titanium.
The left and right cup cup body (1) of the health-care bra cup uses modified latex cotton material.
It is provided with micro air pump (1a) in left and right cup cup body (1) the modified latex cotton material, in cup cup body (1) It is provided with pressure sensor (1b), the pressure sensor (1b), institute on the inside of inside, right and left shoulders band and on the inside of the bust band of left and right Pressure sensor (1b) is stated with micro air pump (1a) to be connected.
The health-care bra cup surface, is coated with waterproof photovoltaic coating, and the photovoltaic coating can convert light energy into Electric energy, and deliver the power to be arranged in energy-storage module (1c) in cup body (1) and be stored, the energy-storage module with it is miniature Air pump (1a) and pressure sensor (1b) are attached.
The material component and weight of the waterproof photovoltaic coating be：PbTiO360 parts, Ag10 parts, 5 parts of ZnO, 5 parts of carbon fiber, 5 parts of boron fibre, 5 parts of silicon carbide whisker, 20 parts of aluminium oxide, 8 parts of manganese oxide.
The material component and weight of the cermet toughening bioceramic material be：10 parts of zirconium oxide, swelling 15 parts of soil, 3 parts of glass microballoon, 8 parts of tourmaline, 3 parts of rice hull ash, 8 parts of alumine, 3 parts of titanium carbide, Ni2 parts, Co2 parts, Cr2 Part, Mo2 parts, W2 parts, 9 parts of carbon fiber, 12 parts of Alpha-alumina, 10 parts of titanium dioxide.
The thickness of the cermet frame is 1mm, hardness 30A；The modified milk collodion is divided into lining and bed course, institute It states and is additionally provided with polyester cotton layer between lining and bed course, the porosity of the polyester cotton layer is 98%；Described includes rubber, oxidation Zinc, sulphur, thiazole accelerators, sulphur formiate accelerating agent, anion surfactant, antioxidant, potassium oleate, inorganic foam stabilizing Component is arranged by following mass fraction in agent, succinamide sulfonate, calcium carbonate and diatomite：120 parts of rubber；Zinc oxide 5 Part；5 parts of sulphur；2.0 parts of thiazole accelerators；1.5 parts of sulphur formiate accelerating agent；4 parts of anion surfactant；Antioxidant 2 parts；0.5 part of potassium oleate；2.0 parts of inorganic foam stabilizer；3.0 parts of succinamide sulfonate；200 parts of calcium carbonate；40 parts of diatomite；
The preparation method of the multifunction emulsion cotton health-care bra, the preparation method comprises the following steps：
Step 1: the preparation of cup frame；
Step 2: the preparation of cup cup body；
Step 3: the preparation of accessory；
Step 4: sewing finished product.
The step 1 includes
The preparation of step 1 frame raw material：The preparation of rice hull ash；
Step (1) first, by the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying, removes it In impurity, in case rice hull ash making use；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room Temperature to 300 DEG C heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-room temperature, Temperature fall；
1. 20 DEG C or so to 300 DEG C heating 30min；
2. 300-400 DEG C of heating 30min；
3. 400-600 DEG C of heating 30min；
4. 600 DEG C of constant temperature 30min；
5. 600-300 DEG C of cooling about 4h；
6. 300 DEG C to room temperature cool down about 1.5h.
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, wait for that temperature is cold until descent of temperature is to after 300 DEG C or less by step (4) But manufactured rice hull ash is taken out from crucible afterwards, it is SiO to measure and fire the main component of successful rice hull ash2；
Step (5), the grinding of rice hull ash；(YJ-300 type high speed Universal pulverizers are good for the limited public affairs of Medical Devices by Jinan hundred million Department's manufacture, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, powder fineness are 300 mesh) by the rice after burning Shell ash is put into progress grinding processing in pulverizer, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
Step 2, respectively every group weigh corresponding raw material；
Raw material by needed for each group is poured on mix plate progress mix 1min by step 3 respectively, forms mixture
Step 4 will determine that the mixing water of amount pours into mixture and stirs 2min
Step 5, casting；
Step 6, demoulding, are dried, 40 DEG C in an oven, dry 15h；
Step 7, sintering are sintered 7h at 1000 DEG C；
Step 8 obtains final products.
The step 2 specifically includes following steps：
S1：Raw material configures
Using latex as primary raw material, corresponding auxiliary material is added, is made into raw material mixture.
S2：Foaming
First inject foaming molding mold in carry out foamable molding, after molding out of foaming molding mold take out and to it Dewatered drying is carried out, latex bra cup semi-finished product are made；The edge of latex bra cup semi-finished product is thicker, and thickness usually exists 40mm, thus be easy to demould from foaming molding mold and take out.
S3：Thermocompression forming
By latex bra cup semi-finished product through thermo-pressing moulder carry out thermocompression forming, keep its thickness thinning, be made thickness compared with Thin latex bra cup finished product, edge thickness is up to 7.0mm.
Step 1, supporter cermet frame carry out 3D modeling, make mold；
Step 2, hard gel feed intake and are put under the corresponding cup of paliform skeleton die cavity plate outside, soft silica gel feeds intake To other positions；
Step 3, method enters internal layer kachoji shape silica gel mould to the pouring of the ultra-soft matter silica gel room temperature of hardness 10A, 30A die pressings enter Internal layer kachoji shape silica gel mould；
Step 4, hardness 70A medium hardness silica gel feed intake outer layer kachoji shape silica gel mould；
Step 5, by the silica gel paliform skeleton obtained respectively, internal layer, the outer layer combination of kachoji shape silica gel, obtain complete Cup main body；The assembling that flexible liner body and accessory are carried out after the step 5, obtains complete brassiere；It will treated through step 4 Molding die hot briquetting, cooling form removal, deburring, obtain cup finished product.
The preparation method of waterproof photovoltaic coating, it is characterised in that steps are as follows：
(1) at room temperature, butyl titanate is instilled in ethylene glycol monomethyl ether, after stirring evenly, a small amount of nitre is added thereto Acid is used as stabilizer, is made into stable colloidal sol containing Ti；
(2) plumbi nitras is dissolved into using lactic acid, citric acid as complexing agent, ethylene glycol monomethyl ether be solvent mixed solution in, Form colloidal sol containing Pb, wherein the molar ratio of lactic acid/butyl titanate is 3, and the molar ratio of citric acid/butyl titanate is 8；
(3) above-mentioned colloidal sol containing Pb is mixed according to Pb: Ti molar ratio for 1: 3 with colloidal sol containing Ti, obtains Pb-Ti colloidal sols, As PbTiO3Silver nitrate is dissolved into according to Ag target volumes in film than the amount for 30% by the precursor colloidal sol of film PbTiO3Precursor colloidal sol, obtain the colloidal sol of Ag-Pb-Ti as Ag-PbTiO3The precursor colloidal sol of laminated film；
(4) surplus stock is mixed in proportion, is ground into nano powder, it is molten to be immersed in precursor under vacuum In, 25min is impregnated, then takes out and dries 60min under the conditions of 210 DEG C；It repeats above step 4 times, completes coating；
(5) by the thin-film material after coating, 800 DEG C is warming up to the speed of 5 DEG C/min, keeps the temperature 3h, prepare photovoltaic painting Layer.
Embodiment 3
A kind of multifunction emulsion cotton health-care bra, the health-care bra cup include cup frame (2), the frame (2) It is provided with left cup (3) and right cup (4), is connected by connect band (5) between the left cup (3) and right cup (4), it is described Left cup (3) upper end is provided with left shoulder belt (6), and right cup (4) upper end is provided with right shoulder belt (7), the left cup (3) Left end is provided with left bust band (10), and the right end of the right cup (4) is provided with right bust band (11), in left and right bust band One end is each provided with junction button, and the junction button can be combined with each other, so that left and right bust band can be connected to by junction button Together；The upper part of the cup frame (2) uses Metal toughened bioceramic material, the lower part of the cup frame (2) Use memory titanium.
The left and right cup cup body (1) of the health-care bra cup uses modified latex cotton material.
It is provided with micro air pump (1a) in left and right cup cup body (1) the modified latex cotton material, in cup cup body (1) It is provided with pressure sensor (1b), the pressure sensor (1b), institute on the inside of inside, right and left shoulders band and on the inside of the bust band of left and right Pressure sensor (1b) is stated with micro air pump (1a) to be connected.
The health-care bra cup surface, is coated with waterproof photovoltaic coating, and the photovoltaic coating can convert light energy into Electric energy, and deliver the power to be arranged in energy-storage module (1c) in cup body (1) and be stored, the energy-storage module with it is miniature Air pump (1a) and pressure sensor (1b) are attached.
The material component and weight of the waterproof photovoltaic coating be：PbTiO358 parts, 9 parts of Ag, 4 parts of ZnO, 3 parts of carbon fiber, 4 parts of boron fibre, 4 parts of silicon carbide whisker, 19 parts of aluminium oxide, 7 parts of manganese oxide.
The material component and weight of the cermet toughening bioceramic material be：9 parts of zirconium oxide, bentonite 14 parts, 2 parts of glass microballoon, 7 parts of tourmaline, 2 parts of rice hull ash, 7 parts of alumine, 2 parts of titanium carbide, Ni2 parts, Co1 parts, Cr2 parts, Mo1 parts, W2 parts, 8 parts of carbon fiber, 11 parts of Alpha-alumina, 9 parts of titanium dioxide.
The thickness of the cermet frame is 1mm, hardness 30A；The modified milk collodion is divided into lining and bed course, institute It states and is additionally provided with polyester cotton layer between lining and bed course, the porosity of the polyester cotton layer is 98%；Described includes rubber, oxidation Zinc, sulphur, thiazole accelerators, sulphur formiate accelerating agent, anion surfactant, antioxidant, potassium oleate, inorganic foam stabilizing Component is arranged by following mass fraction in agent, succinamide sulfonate, calcium carbonate and diatomite：119 parts of rubber；Zinc oxide 4 Part；4 parts of sulphur；2.0 parts of thiazole accelerators；1.5 parts of sulphur formiate accelerating agent；3 parts of anion surfactant；Antioxidant 1 part；0.5 part of potassium oleate；2.0 parts of inorganic foam stabilizer；3.0 parts of succinamide sulfonate；190 parts of calcium carbonate；39 parts of diatomite；
The preparation method of the multifunction emulsion cotton health-care bra, the preparation method comprises the following steps：
Step 1: the preparation of cup frame；
Step 2: the preparation of cup cup body；
Step 3: the preparation of accessory；
Step 4: sewing finished product.
The step 1 includes
The preparation of step 1 frame raw material：The preparation of rice hull ash；
Step (1) first, by the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying, removes it In impurity, in case rice hull ash making use；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room Temperature to 300 DEG C heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-room temperature, Temperature fall；
1. 20 DEG C or so to 300 DEG C heating 30min；
2. 300-400 DEG C of heating 30min；
3. 400-600 DEG C of heating 30min；
4. 600 DEG C of constant temperature 30min；
5. 600-300 DEG C of cooling about 4h；
6. 300 DEG C to room temperature cool down about 1.5h.
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, wait for that temperature is cold until descent of temperature is to after 300 DEG C or less by step (4) But manufactured rice hull ash is taken out from crucible afterwards, it is SiO to measure and fire the main component of successful rice hull ash2；
Step (5), the grinding of rice hull ash；(YJ-300 type high speed Universal pulverizers are good for the limited public affairs of Medical Devices by Jinan hundred million Department's manufacture, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, powder fineness are 300 mesh) by the rice after burning Shell ash is put into progress grinding processing in pulverizer, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
Step 2, respectively every group weigh corresponding raw material；
Raw material by needed for each group is poured on mix plate progress mix 1min by step 3 respectively, forms mixture
Step 4 will determine that the mixing water of amount pours into mixture and stirs 2min
Step 5, casting；
Step 6, demoulding, are dried, 30-40 DEG C in an oven, dry 10-15h；
Step 7, sintering are sintered 7h at 1000 DEG C；
Step 8 obtains final products.
The step 2 specifically includes following steps：
S1：Raw material configures
Using latex as primary raw material, corresponding auxiliary material is added, is made into raw material mixture.
S2：Foaming
First inject foaming molding mold in carry out foamable molding, after molding out of foaming molding mold take out and to it Dewatered drying is carried out, latex bra cup semi-finished product are made；The edge of latex bra cup semi-finished product is thicker, and thickness usually exists 3.5~40mm, thus be easy to demould from foaming molding mold and take out.
S3：Thermocompression forming
By latex bra cup semi-finished product through thermo-pressing moulder carry out thermocompression forming, keep its thickness thinning, be made thickness compared with Thin latex bra cup finished product, edge thickness is up to 5mm.
Step 1, supporter cermet frame carry out 3D modeling, make mold；
Step 2, hard gel feed intake and are put under the corresponding cup of paliform skeleton die cavity plate outside, soft silica gel feeds intake To other positions；
Step 3, method enters internal layer kachoji shape silica gel mould to the pouring of the ultra-soft matter silica gel room temperature of hardness 8A, 15A die pressings enter Internal layer kachoji shape silica gel mould；
Step 4, hardness 38A medium hardness silica gel feed intake outer layer kachoji shape silica gel mould；
Step 5, by the silica gel paliform skeleton obtained respectively, internal layer, the outer layer combination of kachoji shape silica gel, obtain complete Cup main body；The assembling that flexible liner body and accessory are carried out after the step 5, obtains complete brassiere；It will treated through step 4 Molding die hot briquetting, cooling form removal, deburring, obtain cup finished product.
The preparation method of waterproof photovoltaic coating, it is characterised in that steps are as follows：
(1) at room temperature, butyl titanate is instilled in ethylene glycol monomethyl ether, after stirring evenly, a small amount of nitre is added thereto Acid is used as stabilizer, is made into stable colloidal sol containing Ti；
(2) plumbi nitras is dissolved into using lactic acid, citric acid as complexing agent, ethylene glycol monomethyl ether be solvent mixed solution in, Form colloidal sol containing Pb, wherein the molar ratio of lactic acid/butyl titanate is 2, and the molar ratio of citric acid/butyl titanate is 8；
(3) above-mentioned colloidal sol containing Pb is mixed according to Pb: Ti molar ratio for 1: 2 with colloidal sol containing Ti, obtains Pb-Ti colloidal sols, As PbTiO3Silver nitrate is dissolved into according to Ag target volumes in film than the amount for 28% by the precursor colloidal sol of film PbTiO3Precursor colloidal sol, obtain the colloidal sol of Ag-Pb-Ti as Ag-PbTiO3The precursor colloidal sol of laminated film；
(4) surplus stock is mixed in proportion, is ground into nano powder, it is molten to be immersed in precursor under vacuum In, 18min is impregnated, then takes out and dries 18min under the conditions of 180 DEG C；It repeats above step 3 times, completes coating；
(5) by the thin-film material after coating, 760 DEG C is warming up to the speed of 4 DEG C/min, keeps the temperature 2h, prepare photovoltaic painting Layer.
As can be seen from the above table, the cup that prepared by embodiment 1-3 is excellent with sponge cup in terms of thickness, cup depth and feel In common cup, but there is extraordinary breathable moisture permeability, color will not change with the permanent of time is worn, and biology Degradation rate reaches 100%, health and it is environmentally friendly, meanwhile, in the follow-up investigation to 100 proliferation of mammary gland patient, be divided into 5 groups, every group 20, the curative effect that the brassiere of the application has had the proliferation of mammary gland.
Finally it should be noted that：Obviously, above-described embodiment is only intended to clearly illustrate the application example, and simultaneously The non-restriction to embodiment.For those of ordinary skill in the art, it can also do on the basis of the above description Go out other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.And thus drawn Among the obvious changes or variations that Shen goes out are still in the protection domain of the application type.

Claims (4)

1. a kind of multifunction emulsion cotton health-care bra, it is characterised in that：The brassiere includes cup, shoulder belt, bust band, connection Button, heart component, wherein the interior material of the cup is latex cotton.
2. the preparation method of multifunction emulsion cotton health-care bra described in a kind of claim 1, which is characterized in that the preparation method Include the following steps：
Step 1: the preparation of cup frame；
Step 2: the preparation of cup cup body；
Step 3: the preparation of accessory；
Step 4: sewing finished product.
3. preparation method according to claim 2, which is characterized in that the step 1 includes：
The preparation of step 1 frame raw material：The preparation of rice hull ash；
First, the rice husk wash clean bought from Zhangjiakou City Wanquan County rice husk processing factory, drying remove therein for step (1) Impurity, in case the making of rice hull ash uses；
Temperature increasing schedule is arranged in step (2), and the firing maximum temperature of rice hull ash is set to 600 DEG C；Calcining system is designed as：Room temperature is extremely 300 DEG C of heating 30min；300-400 DEG C of heating 20min；400-600 DEG C of heating 30min；600 DEG C of constant temperature 30min；600 DEG C-often Temperature, Temperature fall；
1. 20 DEG C or so to 300 DEG C heating 30min；
2. 300-400 DEG C of heating 30min；
3. 400-600 DEG C of heating 30min；
4. 600 DEG C of constant temperature 30min；
5. 600-300 DEG C of cooling about 4h；
6. 300 DEG C to room temperature cool down about 1.5h.
The rice husk of drying is put into fire-clay crucible by step (3), and crucible is put into heating furnace and carries out burning processing；
Crucible taking-up is put into and is quickly cooled down outside window, after temperature cooling until descent of temperature is to after 300 DEG C or less by step (4) Manufactured rice hull ash is taken out from crucible, it is SiO to measure and fire the main component of successful rice hull ash2；
Step (5), the grinding of rice hull ash；(YJ-300 type high speed Universal pulverizers are good for Medical Devices Co., Ltd system by Jinan hundred million It makes, rated voltage 220V, power 1400W, 28000 revs/min of motor speed, powder fineness is 50-300 mesh) by the rice husk after burning Ash is put into progress grinding processing in pulverizer, wherein rice hull ash makees the grinding processing of 2min, 3min, 4min；
Grinding rice hull ash is carried out XRD diffraction analysis by step (6) with Antai Science and Technology Co., Ltd's X-ray diffractometer；
Step 2, respectively every group weigh corresponding raw material；
Raw material by needed for each group is poured on mix plate progress mix 1min by step 3 respectively, forms mixture
Step 4 will determine that the mixing water of amount pours into mixture and stirs 2min
Step 5, casting；
Step 6, demoulding, are dried, 30-40 DEG C in an oven, dry 10-15h；
Step 7, sintering are sintered 5-7h at 900-1000 DEG C；
Step 8 obtains final products.
4. preparation method according to claim 2, which is characterized in that the step 2 specifically includes following steps：
S1：Raw material configures
Using latex as primary raw material, corresponding auxiliary material is added, is made into raw material mixture.
S2：Foaming
It first injects and carries out foamable molding in foaming molding mold, taken out out of foaming molding mold after molding and it is carried out Latex bra cup semi-finished product are made in dewatered drying；The edge of latex bra cup semi-finished product is thicker, thickness usually 3.5~ 40mm, thus be easy to demould from foaming molding mold and take out.
S3：Thermocompression forming
Latex bra cup semi-finished product are subjected to thermocompression forming through thermo-pressing moulder, keep its thickness thinning, thinner thickness breast is made Glue bra cup finished product, edge thickness is up to 0.5-7.0mm.
Step 1, supporter cermet frame carry out 3D modeling, make mold；
Step 2, hard gel feed intake and are put under the corresponding cup of paliform skeleton die cavity plate outside, soft silica gel is dosed into it His position；
Step 3, the ultra-soft matter silica gel room temperature of hardness 0A-10A pour method and enter internal layer kachoji shape silica gel mould, 10A-30A moldings Method enters internal layer kachoji shape silica gel mould；
Step 4, hardness 30A-70A medium hardness silica gel feed intake outer layer kachoji shape silica gel mould；
Step 5, by the silica gel paliform skeleton obtained respectively, internal layer, the outer layer combination of kachoji shape silica gel, obtain complete cup Main body；The assembling that flexible liner body and accessory are carried out after the step 5, obtains complete brassiere；Will through step 4 treated molding Mold hot briquetting, cooling form removal, deburring, obtain cup finished product.
CN201810262559.XA 2018-03-28 2018-03-28 A kind of multifunction emulsion cotton health-care bra and preparation method thereof Pending CN108523257A (en)

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Application publication date: 20180914